KR102348234B1 - Tissue and foam cleaner for cleaning personal protective equipment to remove heavy metals and polycyclic aromatic hydrocarbons - Google Patents

Tissue and foam cleaner for cleaning personal protective equipment to remove heavy metals and polycyclic aromatic hydrocarbons Download PDF

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KR102348234B1
KR102348234B1 KR1020200182699A KR20200182699A KR102348234B1 KR 102348234 B1 KR102348234 B1 KR 102348234B1 KR 1020200182699 A KR1020200182699 A KR 1020200182699A KR 20200182699 A KR20200182699 A KR 20200182699A KR 102348234 B1 KR102348234 B1 KR 102348234B1
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parts
weight
cleaning
heavy metals
tissue
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박제섭
한동훈
최아영
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대한민국
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D19/00Recovery of glycerol from a saponification liquor
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • C11D11/0058
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/2034Monohydric alcohols aromatic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2079Monocarboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

A tissue for cleaning personal protective equipment to remove heavy metals and polycyclic aromatic hydrocarbons of the present invention comprises a metal removal composition comprising a chelating agent, a sequestering agent, an anionic surfactant, a cleaning aid, a moisturizing agent, a preservative, and water; and a cleaning sheet impregnated with the metal removal composition; and removes heavy metals and polycyclic aromatic hydrocarbons adsorbed on equipment. The effect of the present invention provides a tissue and a foam cleaner for cleaning personal protective equipment to remove heavy metals and polycyclic aromatic hydrocarbons, capable of quickly removing heavy metals and polycyclic aromatic hydrocarbons attached to the surface of personal protective equipment and preventing secondary pollution to other firefighters by manufacturing the cleaning sheet impregnated with the metal removal composition.

Description

중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈 및 폼세정제{Tissue and foam cleaner for cleaning personal protective equipment to remove heavy metals and polycyclic aromatic hydrocarbons}Tissue and foam cleaner for cleaning personal protective equipment to remove heavy metals and polycyclic aromatic hydrocarbons

본 발명은 수많은 종류의 유해물질이 발생하는 재난현장에서 활동하는 과정에서 노출된 개인보호장비 표면에 흡착된 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈 및 폼세정제에 관한 것이다.The present invention relates to a tissue and foam cleaner for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons adsorbed on the surface of personal protective equipment exposed in the course of activities at disaster sites where numerous kinds of harmful substances are generated.

소방대원은 화재현장, 인명구조현장 등 다양한 현장에서 업무를 수행한다. 이러한 현장에서 작업을 하는 동안, 현장에서 발생된 다량의 중금속, 유기화합물, 다환방향족탄화수소류, 산류 등 인체에 유해한 화학물질에 노출된다. Firefighters perform their duties at various sites such as fire sites and lifesaving sites. While working at these sites, you are exposed to chemicals harmful to the human body, such as heavy metals, organic compounds, polycyclic aromatic hydrocarbons, and acids generated in the field.

이때, 인체에 유해한 화학물질은 현장에서 사용된 공기통, 등지게, 헬멧, 안전화, 방화복 등의 개인보호장비에 흡착된다.At this time, chemical substances harmful to the human body are adsorbed to personal protective equipment such as air tanks, back covers, helmets, safety boots, and fire suits used in the field.

그리고, 소방대원은 현장으로부터 복귀한 후, 장비에 흡착된 화학물질을 제거하는 작업을 한다. 이 작업은 또 다른 소방대원에게 2차 오염을 유발하지 않기 위해서 꼭 필요하다. And, after returning from the scene, the firefighters work to remove the chemical substances adsorbed to the equipment. This operation is essential in order not to cause secondary pollution to other firefighters.

이에 따라, 소방대원은 소방서로 복귀하기 전, 현장에서 업무가 끝난 다음, 신속하게 화학물질을 장비로부터 제거할 필요가 있었다. As a result, firefighters needed to quickly remove chemicals from the equipment before returning to the fire station, after work on site, and then.

현장에서 화학물질을 제거하기 위하여, 종래의 물티슈를 이용하였다. 종래의 물티슈는 불특정 다수인을 위한 상업적인 영업장(예컨대, 음식점 등)이라든지 공중시설(예컨대, 대중교통수단, 의료기관 등)을 이용하는 경우 또는 유아들의 배설물 후처리 등을 위해 신체의 일부를 위생적으로 세정하기 위한 목적으로 주로 사용한다. 일반적으로 사용하는 물티슈 외에, 항균성 물티슈를 사용하기도 하며, 항균성 물티슈는 피부용 뿐만 아니라, 물체에 묻은 이물질을 제거하는 용도로도 사용할 수 있다.In order to remove chemicals on site, conventional wet wipes were used. Conventional wet wipes are used for hygienic cleaning of parts of the body when using a commercial business place (e.g., restaurant) or public facility (e.g., public transportation, medical institution, etc.) for an unspecified number of people, or for post-treatment of infant excrement. It is mainly used for In addition to commonly used wipes, antibacterial wipes are also used, and the antibacterial wipes can be used not only for skin but also for removing foreign substances from objects.

그러나, 종래의 물티슈를 사용하더라도, 현장에서 유해물질에 노출된 공기통, 등지게, 헬멧, 안전화, 방화복 등의 개인보호장비 표면에 부착되어 있는 중금속 특히 납, 카드뮴, 구리, 니켈, 바륨, 비소, 크롬, 망간, 스트론튬, 셀레늄 등을 용이하게 제거하는데 어려움이 있었다.However, even with conventional wet wipes, heavy metals, especially lead, cadmium, copper, nickel, barium, arsenic, It was difficult to easily remove chromium, manganese, strontium, selenium, and the like.

대한민국 공개특허 10-2009-0025423Republic of Korea Patent Publication 10-2009-0025423 대한민국 공개특허 10-2009-0116543Republic of Korea Patent Publication 10-2009-0116543 대한민국 공개특허 10-2016-0070532Republic of Korea Patent Publication 10-2016-0070532

상술한 바와 같은 문제점을 해결하기 위해 안출된 본 발명의 목적은, 금속제거용 조성물이 함침된 세척용 시트를 제조함으로써, 개인보호장비 표면에 부착된 중금속 및 다환방향족 탄화수소류를 현장에서 신속하게 제거하고 또 다른 소방대원에게 2차 오염을 예방할 수 있도록 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈 및 폼세정제를 제공하기 위함이다.An object of the present invention, devised to solve the above problems, is to quickly remove heavy metals and polyaromatic hydrocarbons attached to the surface of personal protective equipment in the field by manufacturing a cleaning sheet impregnated with a metal removal composition. This is to provide other firefighters with tissues and foam cleaners for cleaning personal protective equipment to remove heavy metals and polycyclic aromatic hydrocarbons to prevent secondary contamination.

상기한 바와 같은 목적을 달성하기 위한 본 발명의 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈에 따르면, 킬레이트제, 금속이온봉쇄제, 음이온성 계면활성제, 세정보조제, 보습제, 보존제 및 물을 포함하는 금속제거용 조성물; 및 상기 금속제거용 조성물이 함침된 세척용 시트;를 포함하고, 장비에 흡착된 중금속 및 다환방향족 탄화수소류를 제거하는 것을 특징으로 한다.According to the tissue for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons of the present invention for achieving the above object, chelating agent, sequestering agent, anionic surfactant, cleaning aid, moisturizing agent, preservative and a composition for metal removal comprising water; and a cleaning sheet impregnated with the metal removal composition, characterized in that it includes, and removes heavy metals and polyaromatic hydrocarbons adsorbed to the equipment.

또한, 상기 금속제거용 조성물은, 상기 물 100중량부에 대하여, 상기 킬레이트제 1.0~1.2중량부, 상기 금속이온봉쇄제 0.2~0.3중량부, 상기 음이온성 계면활성제 1.0~6.5중량부, 상기 세정보조제 2.0~ 12중량부, 상기 보습제 1.0~6.0중량부 및 상기 보존제 1.0~1.2중량부인 것을 특징으로 한다.In addition, the composition for metal removal, with respect to 100 parts by weight of the water, 1.0 to 1.2 parts by weight of the chelating agent, 0.2 to 0.3 parts by weight of the sequestering agent, 1.0 to 6.5 parts by weight of the anionic surfactant, the washing 2.0 to 12 parts by weight of the auxiliary agent, 1.0 to 6.0 parts by weight of the moisturizing agent, and 1.0 to 1.2 parts by weight of the preservative.

또한, 상기 킬레이트제는, EDTA·4NA(Ethylenediaminetetraacetic acid)인 것을 특징으로 한다.In addition, the chelating agent is characterized in that EDTA·4NA (Ethylenediaminetetraacetic acid).

또한, 상기 금속이온봉쇄제는, 글루콘산 나트륨(Sodium gluconate)으로 이루어진 것을 특징으로 한다.In addition, the sequestering agent is characterized in that it consists of sodium gluconate (Sodium gluconate).

또한, 상기 음이온성 계면활성제는, 천연식물 유래 추출물로서, 코코아미도프로필 베타인(cocoamido propyl betaine), 코코넛 디에탄올 아미드(coconut diethanol amide), 소듐코코일글루타메이트(Sodium cocoyl glutamate)와 트리에탄올아민라우릴설페이트(Triethanolamine lauryl sulfate) 중 어느 하나 이상으로 이루어진 것을 특징으로 한다.In addition, the anionic surfactant is a natural plant-derived extract, cocoamido propyl betaine, coconut diethanol amide, sodium cocoyl glutamate (Sodium cocoyl glutamate) and triethanolamine lauryl It is characterized in that it consists of any one or more of sulfate (Triethanolamine lauryl sulfate).

또한, 상기 세정보조제는, 다이프로필렌 글리콜 메틸 에테르(Dipropylene glycol monomethyl ether), 디에틸렌글리콜 모노부틸 에테르(Diethylene glycol monobutyl ether) 중 어느 하나 이상으로 이루어지고, 상기 보습제는, 프로필렌글리콜(Propylene Glycol)으로 이루어지고, 상기 보존제는, 벤질알코올(Benzyl Alcohol), 벤조산나트륨(Sodium Benzoate) 및 PH50 중 어느 하나 이상으로 이루어지고, 상기 금속제거용 조성물은, 상기 보습제를 통해 6.5 내지 7.5pH인 것을 특징으로 한다.In addition, the cleaning aid is made of at least one of dipropylene glycol monomethyl ether and diethylene glycol monobutyl ether, and the moisturizing agent is propylene glycol. and the preservative is made of at least one of benzyl alcohol, sodium benzoate, and PH50, and the metal removal composition is characterized in that it is 6.5 to 7.5 pH through the moisturizer. .

또한, 향료 및 탈취제를 더 포함하고, 상기 물 100중량부에 대하여, 향료 및 탈취제가 각각 1.0~1.2중량부인 것을 특징으로 한다.In addition, it further includes a fragrance and a deodorant, and is characterized in that the amount of the fragrance and the deodorant is 1.0 to 1.2 parts by weight, respectively, with respect to 100 parts by weight of the water.

한편, 본 발명에 따른 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 폼세정제는, 물을 포함하는 에어로졸 원액 100중량부에 대하여, 에어로졸 분사제를 1.0∼20중량부, 킬레이트제 2.0~3.0중량부, 금속이온봉쇄제 0.5~1.0중량부, 음이온성 계면활성제 3.0~3.5중량부, 세정보조제 10.0~ 12중량부, 보습제 1.0~6.0중량부 및 보존제 2.0~2.5중량부를 포함하는 세척용 폼 조성물; 및 상기 세척용 폼 조성물이 내장되고, 세척용 폼으로 분사시키는 용기;를 포함하고, 상기 용기로부터 분사되는 세척용 폼으로 장비에 흡착된 중금속 및 다환방향족 탄화수소류를 제거하는 것을 특징으로 한다.On the other hand, the foam cleaner for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons according to the present invention, with respect to 100 parts by weight of an aerosol stock solution containing water, 1.0 to 20 parts by weight of an aerosol propellant, 2.0 to a chelating agent 3.0 parts by weight, 0.5 to 1.0 parts by weight of sequestering agent, 3.0 to 3.5 parts by weight of anionic surfactant, 10.0 to 12 parts by weight of cleaning aid, 1.0 to 6.0 parts by weight of moisturizing agent, and 2.0 to 2.5 parts by weight of preservative. composition; and a container in which the cleaning foam composition is embedded and sprayed with the cleaning foam; it characterized in that it includes, and removes heavy metals and polyaromatic hydrocarbons adsorbed to the equipment with the cleaning foam sprayed from the container.

이상 살펴본 바와 같은 본 발명의 효과는, 금속제거용 조성물이 함침된 세척용 시트를 제조함으로써, 개인보호장비 표면에 부착된 중금속 및 다환방향족 탄화수소류를 현장에서 신속하게 제거하고 또 다른 소방대원에게 2차 오염을 예방할 수 있도록 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈 및 폼세정제을 제공할 수 있다.As described above, the effect of the present invention is that by manufacturing a cleaning sheet impregnated with a metal removal composition, heavy metals and polyaromatic hydrocarbons adhering to the surface of personal protective equipment are quickly removed from the field, and 2 Tissues and foam cleaners for cleaning personal protective equipment to remove heavy metals and polycyclic aromatic hydrocarbons can be provided to prevent car contamination.

도 1은 본 발명의 바람직한 실시예에 따른 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈를 나타낸 사진이다.
도 2는 본 발명의 바람직한 실시예에 따른 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈를 사용하는 사진이다.
1 is a photograph showing a tissue for cleaning personal protective equipment for removing heavy metals and polyaromatic hydrocarbons according to a preferred embodiment of the present invention.
2 is a photograph using a tissue for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons according to a preferred embodiment of the present invention.

본 발명의 이점 및 특징, 그리고 그것들을 달성하는 방법은 첨부되는 도면과 함께 상세하게 후술되어 있는 실시예들을 참조하면 명확해질 것이다. 그러나 본 발명은 이하에서 개시되는 실시예들에 한정되는 것이 아니라 서로 다른 다양한 형태로 구현될 수 있으며, 단지 본 실시예들은 본 발명의 개시가 완전하도록 하고, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자에게 발명의 범주를 완전하게 알려주기 위해 제공되는 것이며, 본 발명은 청구항의 범주에 의해 정의될 뿐이다. 명세서 전체에 걸쳐 동일 참조 부호는 동일 구성 요소를 지칭한다.Advantages and features of the present invention and methods of achieving them will become apparent with reference to the embodiments described below in detail in conjunction with the accompanying drawings. However, the present invention is not limited to the embodiments disclosed below, but may be implemented in various different forms, and only these embodiments allow the disclosure of the present invention to be complete, and common knowledge in the art to which the present invention pertains It is provided to fully inform those who have the scope of the invention, and the present invention is only defined by the scope of the claims. Like reference numerals refer to like elements throughout.

이하, 본 발명의 실시예들에 의하여 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈를 설명하기 위한 도면들을 참고하여 본 발명에 대해 설명하도록 한다.Hereinafter, the present invention will be described with reference to the drawings for explaining a tissue for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons according to embodiments of the present invention.

도 1은 본 발명의 바람직한 실시예에 따른 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈를 나타낸 사진이다. 도 2는 본 발명의 바람직한 실시예에 따른 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈를 사용하는 사진이다.1 is a photograph showing a tissue for cleaning personal protective equipment for removing heavy metals and polyaromatic hydrocarbons according to a preferred embodiment of the present invention. 2 is a photograph using a tissue for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons according to a preferred embodiment of the present invention.

도 1 및 도 2를 참조하면, 본 발명에 따른 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈는, 금속제거용 조성물 및 시트를 포함한다.1 and 2, the tissue for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons according to the present invention includes a metal removal composition and sheet.

먼저, 금속제거용 조성물은, 킬레이트제, 금속이온봉쇄제, 음이온성 계면활성제, 세정보조제, 보습제, 보존제 및 물을 포함한다.First, the composition for metal removal includes a chelating agent, a sequestering agent, an anionic surfactant, a cleaning aid, a moisturizing agent, a preservative, and water.

세척용 시트는 금속제거용 조성물이 함침된다. The cleaning sheet is impregnated with a metal removal composition.

이때, 세척용 시트는 장비 표면에 흡착된 오염물질을 쉽게 제거할 수 있도록 마이크로파이버 소재의 부직포 (Non-woven fabric)로 이루어진다. In this case, the cleaning sheet is made of a microfiber non-woven fabric so that the contaminants adsorbed on the surface of the equipment can be easily removed.

즉, 사용자는, 금속제거용 조성물이 함침된 세척용 시트를 갖고, 장비에 흡착된 중금속 및 다환방향족 탄화수소류를 제거할 수 있다.That is, the user has a cleaning sheet impregnated with the metal removal composition, and can remove heavy metals and polyaromatic hydrocarbons adsorbed to the equipment.

금속제거용 조성물에 대해 살펴보면, 물 100중량부에 대하여, 킬레이트제 1.0~1.2중량부, 금속이온봉쇄제 0.2~0.3중량부, 음이온성 계면활성제 1.0~6.5중량부, 세정보조제 2.0~ 12중량부, 보습제 1.0~6.0중량부 및 보존제 1.0~1.2중량부를 포함한다.Looking at the composition for metal removal, with respect to 100 parts by weight of water, 1.0 to 1.2 parts by weight of a chelating agent, 0.2 to 0.3 parts by weight of a sequestering agent, 1.0 to 6.5 parts by weight of an anionic surfactant, 2.0 to 12 parts by weight of a cleaning aid. , containing 1.0 to 6.0 parts by weight of a moisturizer and 1.0 to 1.2 parts by weight of a preservative.

킬레이트제는, EDTA(Ethylenediaminetetraacetic acid)인 것이 바람직하다. The chelating agent is preferably EDTA (Ethylenediaminetetraacetic acid).

EDTA(Ethylenediaminetetraacetic acid)는 금속 이온을 중심으로 하는 팔면체의 여섯 꼭짓점에 동시에 배위할 수 있으며, 그 결과 중심 금속은 리간드에 의해 둘러싸이게 된다. 따라서 EDTA는 특정 금속 이온에 대하여 강한 친화력을 가지며 다양한 범위의 제품에 응용되는데 욕조세제의 첨가제, 금속이온 봉쇄제, 혈액응고방지제 등으로 쓰인다. 염의 형태로는 물에 비교적 잘 녹아 수용성 성질이 매우 우수하다.Ethylenediaminetetraacetic acid (EDTA) can coordinate simultaneously to six vertices of an octahedron centered on a metal ion, and as a result, the central metal is surrounded by a ligand. Therefore, EDTA has a strong affinity for specific metal ions and is applied to a wide range of products. In the form of salt, it dissolves relatively well in water and has very good water-soluble properties.

특히, EDTA는 EDTA·2NA, EDTA·4NA 중 보다 안정적인 EDTA·4NA으로 이루어진다.In particular, EDTA consists of EDTA·4NA, which is more stable among EDTA·2NA and EDTA·4NA.

이러한, EDTA·4NA는 금속이온의 분리, 제거, 미량 금속이온의 분석 등에 널리 쓰이는 성분으로 거의 모든 금속이온과 안정한 수용성 킬레이트를 형성하며, 안정적이다. EDTA·4NA is a component widely used in the separation and removal of metal ions and analysis of trace metal ions, and forms stable water-soluble chelates with almost all metal ions and is stable.

금속이온봉쇄제는 글루콘산 나트륨(sodium gluconate)으로 이루어진다. The sequestering agent consists of sodium gluconate.

글루콘산 나트륨은 흰색 또는 노란색을 띄는 파우더 성분으로 금속이온을 물에 용해 또는 분산시키는 성질이 있어 금속이온 봉쇄제, 금속 제거제로 사용된다. 또 유화를 안정시키는 기능을 가지며, 세정기능 제품의 세정 기능 저하를 막아준다.Sodium gluconate is a white or yellowish powder component that dissolves or disperses metal ions in water, so it is used as a metal ion sequestrant and metal remover. In addition, it has the function of stabilizing emulsification and prevents the deterioration of the cleaning function of cleaning products.

글루콘산나트륨은 표면의 세정 작용 및 금속성 입자의 제거를 위하여 첨가될 수 있다. 글루콘산나트륨은 또한 분산제로 기능을 가질 수 있고 분말 형태로 첨가될 수 있다.Sodium gluconate may be added for cleaning the surface and for removing metallic particles. Sodium gluconate may also function as a dispersant and may be added in powder form.

음이온성 계면활성제는, 천연식물 유래 추출물로서, 코코아미도프로필 베타인(cocoamido propyl betaine), 코코넛 디에탄올 아미드(coconut diethanol amide), 소듐코코일글루타메이트(Sodium cocoyl glutamate)와 트리에탄올아민라우릴설페이트(Triethanolamine lauryl sulfate) 중 어느 하나 이상으로 이루어진다. Anionic surfactants are natural plant-derived extracts, cocoamido propyl betaine, coconut diethanol amide, sodium cocoyl glutamate, and triethanolamine lauryl sulfate. lauryl sulfate).

바람직하게는, 음이온성 계면활성제는 소듐코코일글루타메이트(Sodium cocoyl glutamate)와 트리에탄올아민라우릴설페이트(Triethanolamine lauryl sulfate)이다. Preferably, the anionic surfactant is sodium cocoyl glutamate and triethanolamine lauryl sulfate.

이때, 물 100중량부에 대하여, 소듐코코일글루타메이트 0.3~0.5중량부, 트리에탄올아민라우릴설페이트 0.7~6.0중량부를 포함한다. At this time, based on 100 parts by weight of water, 0.3 to 0.5 parts by weight of sodium cocoyl glutamate and 0.7 to 6.0 parts by weight of triethanolamine lauryl sulfate.

한편, 계면활성제는 표면활성제라고도 하며, 표면장력이 물에 비하여 훨씬 작다. 대개 친수성 부분과 친유성 부분을 모두 갖는다. 계면활성제는 일반적으로 세척력, 에멀젼화력, 분산력, 삼투력, 기포력(起泡力) 등을 지니고 있어, 각기 그 특성에 따라 세척제, 섬유처리제, 에멀젼화제, 부유선광제(浮遊選鑛劑), 시멘트용 기포제, 윤활유 첨가제, 살균제, 도료분산제(塗料分散劑) 등으로 널리 이용되며, 유기물 제거용 조성물 중에서는 세정 대상인 물체, 즉 금속 표면으로부터 이물질의 분리를 돕고, 일단 분리된 이물질이 재부착되는 것을 방지하여 세정력을 높이는 기능을 한다.On the other hand, a surfactant is also called a surface active agent, and the surface tension is much lower than that of water. It usually has both a hydrophilic and a lipophilic moiety. Surfactants generally have cleaning power, emulsifying power, dispersing power, osmotic power, and foaming power. It is widely used as a foaming agent for cement, lubricating oil additive, disinfectant, paint dispersant, etc., and among the organic matter removal compositions, it helps the separation of foreign substances from the object to be cleaned, that is, the metal surface, It prevents and improves the cleaning power.

여기서, 음이온성 계면활성제는 코코넛 등의 식물성 오일에서 추출되는 천연식물 유래 추출물인 것이 바람직하다.Here, the anionic surfactant is preferably a natural plant-derived extract extracted from vegetable oil such as coconut.

세정보조제는, 다이프로필렌 글리콜 메틸 에테르(Dipropylene glycol monomethyl ether), 디에틸렌글리콜 모노부틸 에테르(Diethylene glycol monobutyl ether) 중 어느 하나 이상으로 이루어진다.The cleaning aid is made of at least one of dipropylene glycol monomethyl ether and diethylene glycol monobutyl ether.

세정보조제는, 물 100중량부에 대하여, 다이프로필렌 글리콜 메틸 에테르와 디에틸렌글리콜 모노부틸 에테르 각각 1.0~6.0중량부로 이루어진다.The cleaning aid consists of 1.0 to 6.0 parts by weight of dipropylene glycol methyl ether and diethylene glycol monobutyl ether, respectively, based on 100 parts by weight of water.

다이프로필렌 글리콜 메틸 에테르는 주용매로서 휘발도가 낮은 휘발성 용매이다. 다이프로필렌 글리콜 메틸 에테르의 색상은 무채색으로서, 물리적으로는 액체상태이며, 달콤한 냄새가 난다.Dipropylene glycol methyl ether is a volatile solvent with low volatility as the main solvent. Dipropylene glycol methyl ether is colorless, physically liquid, and has a sweet odour.

특히, 인화점이 약 86℃로서, 종래의 래커 시너에 포함된 다른 유기용제보다 화재 위험성이 낮으며, 상온 및 상압에서 안정하여 반응성이 매우 낮은 특징이 있다.In particular, it has a flash point of about 86° C., which has a lower fire risk than other organic solvents included in conventional lacquer thinners, and is stable at room temperature and pressure and has very low reactivity.

그리고, 다이프로필렌 글리콜 메틸 에테르는 래커 스프레이나 유성매직 등의 유성도료를 녹여 제거하는 역할을 한다.And, dipropylene glycol methyl ether serves to dissolve and remove oil-based paints such as lacquer spray or oil-based magic.

이에 따라, 소방장비에 필요에 따라 유성매직으로 기재한 내용이나 체크 표시 등을 손쉽게 제거할 수 있고, 화재로 인해 발생하는 그을음, 불에 타고 남은 재로부터 뭍는 이물질을 세척용 시트로 이용하여 제거할 수 있는 효과가 있다.Accordingly, it is possible to easily remove the contents written with oily magic or check marks as needed in the firefighting equipment, and the soot caused by fire and foreign substances from the ash remaining after burning can be removed using a cleaning sheet. can have an effect.

보습제는, 프로필렌글리콜(Propylene Glycol)으로 이루어진다. 이때, 금속제거용 조성물은 보습제를 통해 6.5 내지 7.5pH인 것이 바람직하다. The moisturizer is made of propylene glycol (Propylene Glycol). At this time, the composition for metal removal is preferably 6.5 to 7.5 pH through the moisturizing agent.

프로필렌 글리콜은 글리세린(glycerin)의 수산기 하나가 수소로 치환되는 화합물이지만, 생물에서 독성이 낮고 무미, 무취여서 보습제, 윤활제, 유화제, 부동액, 용매 등으로 사용된다. Propylene glycol is a compound in which one hydroxyl group of glycerin is substituted with hydrogen, but is used as a moisturizer, lubricant, emulsifier, antifreeze, solvent, etc. because of its low toxicity and tasteless and odorless properties in living things.

보존제는, 벤질알코올(Benzyl Alcohol), 벤조산나트륨(Sodium Benzoate) 및 PH50 중 어느 하나 이상으로 이루어진다. The preservative is made of at least one of benzyl alcohol, sodium benzoate, and PH50.

보존제는 물 100중량부에 대하여, 벤질알코올 1.0~1.2중량부, 벤조산나트륨 1.0~1.2중량부 및 PH50 1.0~1.2중량부으로 이루어진다. The preservative consists of 1.0-1.2 parts by weight of benzyl alcohol, 1.0-1.2 parts by weight of sodium benzoate, and 1.0-1.2 parts by weight of PH50 based on 100 parts by weight of water.

벤질알코올은 방향족 알코올류 중의 하나로 무색 투명한 액체이며, 특유의 향기와 타는 듯한 맛이 있어 용해제 및 추출제, 휘발보류제, 식품 착향료 등으로 사용된다.Benzyl alcohol is one of the aromatic alcohols, and it is a colorless and transparent liquid. It has a characteristic scent and burning taste, so it is used as a solvent, extractant, volatile retention agent, and food flavoring agent.

벤조산나트륨은 미생물의 생육을 억제하여 보존료로 사용된다. 특히, 세균과 곰팡이의 생육을 억제 한다. 곰팡이, 효모 등 여러 종류의 미생물에 효과가 있으며 항균 범위가 넓은 편이나 주로 pH가 낮은 범위에서 효과가 있다.Sodium benzoate is used as a preservative by inhibiting the growth of microorganisms. In particular, it inhibits the growth of bacteria and fungi. It is effective against various types of microorganisms such as mold and yeast, and although the antibacterial range is wide, it is mainly effective in the low pH range.

한편, 금속제거용 조성물은 향료 및 탈취제를 더 포함한다.On the other hand, the composition for metal removal further includes a fragrance and a deodorant.

이때, 물 100중량부에 대하여, 향료 및 탈취제가 각각 1.0~1.2중량부인 것이 바람직하다.At this time, with respect to 100 parts by weight of water, it is preferable that the perfume and the deodorant are 1.0 to 1.2 parts by weight, respectively.

향료는 과일향을 낼 수 있으면 충분하며, 사과향료인 것일 수 있으나, 이에 한정하지 않는다. The flavoring is sufficient as long as it can give off a fruity flavor, and may be an apple flavoring, but is not limited thereto.

한편, 금속제거용 조성물은, 금속부식방지제가 더 포함될 수 있다. 금속부식방지제는 바람직하게는 치환 또는 비치환된 벤조트리아졸로부터 선택될 수 있으며, 적절한 부류의 치환된 벤조트리아졸로는 알킬기, 아릴기, 할로겐기, 아미노기, 니트로기, 알콕시기 및 하이드록시기로 치환된 벤조트리아졸을 포함할 수 있으나, 이에 한정하지 않는다.On the other hand, the composition for removing metal may further include a metal corrosion inhibitor. The metal corrosion inhibitor may preferably be selected from substituted or unsubstituted benzotriazoles, and suitable classes of substituted benzotriazoles include those substituted with alkyl groups, aryl groups, halogen groups, amino groups, nitro groups, alkoxy groups and hydroxyl groups. and benzotriazole, but is not limited thereto.

또한, 금속제거용 조성물은 물 100중량부에 대하여, 항균제 0.5∼1.7중량부를 더 포함한다.In addition, the metal removal composition further comprises 0.5 to 1.7 parts by weight of an antibacterial agent with respect to 100 parts by weight of water.

이때, 항균제는 100중량부에 대하여 박하 추출액 19∼25중량부, 구연산 7∼12중량부, 어성초 추출액 27∼32중량부, 편백나무 추출액 30∼34중량부, 나노은 분말 3∼6중량부을 포함할 수 있다. At this time, the antibacterial agent may contain 19-25 parts by weight of mint extract, 7-12 parts by weight of citric acid, 27-32 parts by weight of eoseongcho extract, 30-34 parts by weight of cypress extract, 3-6 parts by weight of nano-silver powder based on 100 parts by weight of the antibacterial agent. can

박하 추출액은 향료, 약용, 식용, 음료로 이용되는 허브식물을 총칭하는 것으로 특히 개박하로 불리는 캣닢은 모기가 아주 싫어하는 식물이다. 페퍼민트의 사촌격인 이 허브는 네페탈락톤이라는 천연 화학물질이 들어 있어 모기를 쫓는 효능이 있다. Mint extract is a generic term for herbal plants used for flavoring, medicinal, edible, and beverage. Peppermint's cousin, this herb contains a natural chemical called nepetalactone that has mosquito repellent properties.

구연산은 피부트러블을 완화시키고, 항산화 효과가 있으며, 석회나 얼룩, 녹 등을 세정하는 효과가 있고, 바이러스 및 박테리아의 소독 효과가 있다.Citric acid relieves skin troubles, has an antioxidant effect, has an effect of cleaning lime, stains, rust, etc., and has an effect of disinfecting viruses and bacteria.

어성초 추출물은 어성초의 잎과 뿌리를 건조시킨 후 용매를 통해 추출한 것으로, 플라보노이드, 쿠에르시트린, 마이르센, 라우리알데히드 등의 성분이 풍부하게 들어있어 뛰어난 항균작용을 할 수 있는데 특히 대장균, 장티푸스균, 황색포도상구균, 폐렴구균 등을 확실히 억제한다. 또한 피부 진균에도 효과가 뛰어나 염증작용을 억제하고 조직을 재생시켜 줄 수 있는 천연 항생제이다. 또한, 어성초는 피부미백효과, 항산화 효과과 있고, 독소제거 효과가 우수한 효능이 있다.Eoseongcho extract is extracted through a solvent after drying the leaves and roots of eoseongcho, and contains abundant components such as flavonoids, quercitrin, myrcene, and laurialdehyde, and has excellent antibacterial action. , Staphylococcus aureus, pneumococcus, etc. are definitely inhibited. In addition, it is a natural antibiotic that can suppress inflammation and regenerate tissues because it is effective against skin fungi. In addition, eoseongcho has a skin whitening effect, antioxidant effect, and has an excellent effect of removing toxins.

편백나무 추출물은 편백나무를 가공하여 제조된 추출액으로 편백나무 특유의 향으로 인해 탈취제, 항균제 등으로 널리 사용되고 있다. 편백나무에서 생산되는 피톤치드는 식물의 자기방어물질로써 병원균 및 해충, 곰팡이 등에 저항하기 위해 식물이 내뿜거나 분비하는 물질로 그 자체에 살균, 살충성분이 포함되어 있다. 그리고, 피톤치드의 구성물질은 테르펜을 비롯한 페놀 화합물, 알칼로이드 성분, 글리코시드 등으로 이루어진 유기화합물이며, 항균작용, 진정작용, 탈취작용, 스트레스 해소작용 등을 하는 것으로 알려져 있다. 이러한 피톤치드는 화학합성 물질이 아닌 천연물질이고, 인간의 신체에 무리 없이 흡수되며, 인간에게 해로운 균들을 선택적으로 살균한다. 또한, 피톤치드는 항균작용, 소취작용, 진정작용 및 스트레스 해소 작용 등 수많은 기능을 하는 것으로 알려져 있다. 또한, 피톤치드는 뛰어난 살균, 항균, 세정작용으로 피부를 깨끗하게 하고 보습작용도 하며, 체내의 면역기능을 강화한다.Cypress tree extract is an extract prepared by processing cypress tree and is widely used as a deodorant and antibacterial agent due to the unique scent of cypress tree. Phytoncide produced from cypress is a plant's self-defense substance, and it is a substance that plants emit or secrete to resist pathogens, pests, and fungi. And, the constituent material of phytoncide is an organic compound consisting of phenolic compounds including terpenes, alkaloids, glycosides, etc., and is known to have antibacterial action, sedative action, deodorizing action, and stress relieving action. These phytoncides are natural substances, not chemically synthesized substances, and are easily absorbed by the human body, and selectively sterilize bacteria harmful to humans. In addition, phytoncide is known to have numerous functions such as antibacterial action, deodorizing action, sedative action and stress relieving action. In addition, phytoncide has excellent sterilization, antibacterial, and cleansing action to clean the skin and moisturize the skin, and to strengthen the immune function of the body.

한편, 세척용 시트는, 일정크기로 이루어지고, 길이방향으로 갈수록 두꺼워지게 형성되되, 일측은 1mm로 형성되고, 중간은 2mm, 타측은 3mm로 형성됨이 바람직하다. On the other hand, the cleaning sheet is made of a predetermined size, is formed to be thicker in the longitudinal direction, one side is formed of 1mm, the middle is formed of 2mm, the other side is preferably formed of 3mm.

이는, 소방장비의 경우, 날카로운 부분이 다수 존재하기에, 날카로운 부분을 닦을 때, 찢어져 다칠 위험이 있다. 즉, 날카로운 부분을 안정적으로 닦을 수 있고, 강한 힘을 가할 때 찢어지지 않기 위함이다. 또한, 소방장비의 틈새에 존재하는 중금속을 제거하기 위해서 얇은 일측부분을 이용하면 쉽게 세척용 시트의 타측이 일측보다 두껍게 형성되는 것이 바람직하다.This is, in the case of firefighting equipment, since there are many sharp parts, when wiping the sharp parts, there is a risk of being torn and injured. That is, the sharp part can be stably wiped and it is not torn when a strong force is applied. In addition, it is preferable that the other side of the cleaning sheet be formed thicker than the one side if a thin one side is used to remove the heavy metal present in the gap of the firefighting equipment.

또한, 본 발명에 따른 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈는, 세척용 시트의 일측 끝단에는 세척바가 구비된다. In addition, the tissue for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons according to the present invention is provided with a cleaning bar at one end of the cleaning sheet.

바람직하게는, 세척바는 세척용 시트의 일측 끝단에 1~2바퀴 말려서 고정된다. 이는, 장비의 틈새나 깊은 구멍에 꽂아서 중금속 및 다환방향족탄화수소류를 제거하기 위함이다. Preferably, the washing bar is fixed to one end of the washing sheet by rolling 1 to 2 turns. This is to remove heavy metals and polycyclic aromatic hydrocarbons by inserting them into gaps or deep holes of equipment.

예를 들어, 장비의 구멍을 세척하고자 할 때, 세척용 시트를 구멍에 놓고 세척바로 찔러 넣고, 빼내며 세척할 수도 있고, 세척용 시트를 세척바에 감아서 구멍에 넣고 빼내며 세척할 수도 있다.For example, when cleaning a hole in the equipment, a cleaning sheet can be placed in the hole and inserted with a cleaning bar, and then washed with a cleaning bar.

한편, 본 발명에 따른 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 폼세정제는, 세척용 폼 조성물 및 용기를 포함한다.On the other hand, the foam cleaner for washing personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons according to the present invention includes a foam composition for washing and a container.

세척용 폼 조성물은, 물을 포함하는 에어로졸 원액 100중량부에 대하여, 에어로졸 분사제를 1.0∼20중량부, 킬레이트제 2.0~3.0중량부, 금속이온봉쇄제 0.5~1.0중량부, 음이온성 계면활성제 3.0~3.5중량부, 세정보조제 10.0~ 12중량부, 보습제 1.0~6.0중량부 및 보존제 2.0~2.5중량부를 포함한다. 여기서, 세척용 폼 조성물은 금속제거용 조성물에 포함된 성분이 더 포함될 수 있으며, 금속제거용 조성물보다 1.5~2.5배 더 많음 함량으로 포함될 수 있다. The foam composition for washing contains 1.0 to 20 parts by weight of an aerosol propellant, 2.0 to 3.0 parts by weight of a chelating agent, 0.5 to 1.0 parts by weight of a sequestering agent, 0.5 to 1.0 parts by weight of an anionic surfactant, based on 100 parts by weight of an aerosol stock solution containing water. 3.0 to 3.5 parts by weight, 10.0 to 12 parts by weight of a cleaning aid, 1.0 to 6.0 parts by weight of a moisturizing agent, and 2.0 to 2.5 parts by weight of a preservative. Here, the cleaning foam composition may further include a component included in the metal removal composition, and may contain 1.5 to 2.5 times more content than the metal removal composition.

즉, 세척용 폼 조성물은, 금속제거용 조성물에 포함된 킬레이트제, 금속이온봉쇄제, 음이온 계면활성제, 세정보조제, 보습제 및 보존제를 더 많이 함유하고, 용기에 내장된다.That is, the cleaning foam composition contains more of the chelating agent, sequestering agent, anionic surfactant, cleaning aid, moisturizing agent and preservative contained in the metal removal composition, and is embedded in the container.

용기는, 세척용 폼 조성물이 내장되고, 세척용 폼으로 분사시킬 수 있다.The container, the foam composition for cleaning is built-in, it can be sprayed with the foam for cleaning.

이에 따라, 장비의 오염도가 심한 경우에는, 금속제거용 조성물이 함침된 세척용 시트와 용기로부터 분사된 세척용 폼을 겸용하여 중금속 및 다환방향족탄화수소류를 보다 용이하게 세척할 수 있다.Accordingly, when the degree of contamination of the equipment is severe, heavy metals and polycyclic aromatic hydrocarbons can be more easily washed by using both the cleaning sheet impregnated with the metal removal composition and the cleaning foam sprayed from the container.

이하, 본 발명에 따른 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈 및 폼세정제에 대한 실시예 및 비교예를 들어 더욱 구체적으로 설명하기로 한다.Hereinafter, examples and comparative examples of the tissue and foam cleaner for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons according to the present invention will be described in more detail.

[실시예 1][Example 1]

물 100중량부에 대하여, EDTA·4NA 1.0~1.2중량부, 글루콘산 나트륨 0.2~0.3중량부, 소듐코코일글루타메이트 0.3~0.5중량부, 트리에탄올아민라우릴설페이트 0.7~6.0중량부, 다이프로필렌 글리콜 메틸 에테르 1.0~6.0중량부, 디에틸렌글리콜 모노부틸 에테르 1.0~6.0중량부, 자일렌 1~1.5중량부, 프로필렌글리콜 1.0~6.0중량부, 벤질알코올 1.0~1.2중량부, 벤조산나트륨 1.0~1.2중량부, PH50 1.0~1.2중량부, 향료 1.0~1.2중량부, 탈취제 1.0~1.2중량부 및 항균제 0.5∼1.7중량부의 중량 비율로 금속제거용 조성물을 함침시킨 세척용 티슈를 제조하였다. Based on 100 parts by weight of water, EDTA·4NA 1.0 to 1.2 parts by weight, sodium gluconate 0.2 to 0.3 parts by weight, sodium cocoyl glutamate 0.3 to 0.5 parts by weight, triethanolamine lauryl sulfate 0.7 to 6.0 parts by weight, dipropylene glycol methyl 1.0-6.0 parts by weight of ether, 1.0-6.0 parts by weight of diethylene glycol monobutyl ether, 1-1.5 parts by weight of xylene, 1.0-6.0 parts by weight of propylene glycol, 1.0-1.2 parts by weight of benzyl alcohol, 1.0-1.2 parts by weight of sodium benzoate , PH50 1.0 to 1.2 parts by weight, perfume 1.0 to 1.2 parts by weight, deodorant 1.0 to 1.2 parts by weight, and antibacterial agent 0.5 to 1.7 parts by weight of a cleaning tissue impregnated with the composition for metal removal was prepared.

[실시예 2][Example 2]

물을 포함하는 에어로졸 원액 100중량부에 대하여, EDTA·4NA 2.0~2.4중량부, 글루콘산 나트륨 0.4~0.6중량부, 소듐코코일글루타메이트 0.6~1.0중량부, 트리에탄올아민라우릴설페이트 1.4~12.0중량부, 다이프로필렌 글리콜 메틸 에테르 1.4~12.0중량부, 디에틸렌글리콜 모노부틸 에테르 1.4~12.0중량부, 자일렌 2~3.중량부, 프로필렌글리콜 1.4~12.0중량부, 벤질알코올 2.0~2.4중량부, 벤조산나트륨 2.0~2.4중량부, PH50 2.0~2.4중량부, 향료 1.5~1.8중량부, 탈취제 1.5~1.8중량부 및 항균제 1.0∼3.4중량부의 중량 비율로 세척용 폼 조성물을 분무가능한 용기에 내장하여 폼세정제를 제조하였다. Based on 100 parts by weight of the aerosol stock solution containing water, 2.0 to 2.4 parts by weight of EDTA·4NA, 0.4 to 0.6 parts by weight of sodium gluconate, 0.6 to 1.0 parts by weight of sodium cocoyl glutamate, 1.4 to 12.0 parts by weight of triethanolamine lauryl sulfate , dipropylene glycol methyl ether 1.4 to 12.0 parts by weight, diethylene glycol monobutyl ether 1.4 to 12.0 parts by weight, xylene 2-3 parts by weight, propylene glycol 1.4 to 12.0 parts by weight, benzyl alcohol 2.0 to 2.4 parts by weight, benzoic acid Sodium 2.0 to 2.4 parts by weight, PH50 2.0 to 2.4 parts by weight, fragrance 1.5 to 1.8 parts by weight, deodorant 1.5 to 1.8 parts by weight, and antibacterial agent 1.0 to 3.4 parts by weight. was prepared.

[비교예 1][Comparative Example 1]

시중에 판매되고 있는 물티슈를 구입하여 비교예 1에 따른 세척용 티슈로 사용하였다.A commercially available wet tissue was purchased and used as a cleaning tissue according to Comparative Example 1.

1. 기호도 평가1. Preference evaluation

실시예들과, 비교예에 따라 제조된 세척용 티슈의 향, 끈적임, 청량감 등 기호도에 대하여 관능평가를 실시하였으며, 그 결과를 아래 [표 2]에 나타내었다. 관능시험은 소방대원 20명을 대상으로 실시하고, 점수 및 평가기준은 9점 채점법을 이용하였으며, 아래 [표 1]에 나타내었다.The sensory evaluation was performed on the taste, stickiness, refreshing feeling, etc. of the cleaning tissues prepared according to the Examples and Comparative Examples, and the results are shown in [Table 2] below. The sensory test was conducted for 20 firefighters, and a 9-point scoring method was used for the score and evaluation criteria, and is shown in [Table 1] below.

점수score 평가 기준Evaluation standard 99 매우 좋음very good 77 좋음good 55 보통usually 33 나쁨bad 1One 매우 나쁨very bad

구분division incense 끈적임stickiness 종합적 기호도Comprehensive symbology 실시예1Example 1 8.38.3 8.88.8 8.58.5 실시예2Example 2 8.78.7 9.49.4 9.09.0 비교예1Comparative Example 1 5.85.8 5.45.4 5.65.6

[표 2]에서 살펴본 바와 같이, 실시예들에 비교예1에비해 향, 끈적임 등에 대한 기호도가 우수한 것을 확인할 수 있었다.As seen in [Table 2], it was confirmed that the Examples were superior to those of Comparative Example 1 in terms of taste, stickiness, and the like.

2. 중금속 잔류실험2. Heavy metal residue test

소방장비가 화재현장과 유사한 상황에 노출된 상태에서, 세척전과 실시예들 및 비교예1을 통해 소방장비(공기통 및 헬멧)의 표면을 세척 후 표면 중금속 잔류량을 측정하였고, 그 결과는 [표 3]과 같다. In a state where the firefighting equipment was exposed to a situation similar to the fire scene, the residual amount of heavy metals on the surface was measured before washing and after washing the surface of the firefighting equipment (reservoir and helmet) through Examples and Comparative Example 1, and the results are [Table 3] ] is the same as

구분division 중금속 잔류량Heavy Metal Residue 제거율removal rate 평균average 표준편차Standard Deviation ppmppm ppmppm %% 세척전before washing 17.14417.144 8.4128.412 실시예 1Example 1 2.6802.680 0.6960.696 84.3784.37 실시예 2Example 2 1.5721.572 0.5530.553 90.8390.83 비교예 1Comparative Example 1 3.3563.356 0.4290.429 80.4380.43

[표 3]을 통해, 실시예들은 비교예 1보다 높은 중금속 제거율을 확인할 수 있었다. 실시예 1은 세척 전(17.144 ppm, 표준편차 ±8.412) 대비 2.680 ppm(표준편차 ±0.696)이 잔류하였다. Through [Table 3], Examples were able to confirm a higher heavy metal removal rate than Comparative Example 1. In Example 1, before washing (17.144 ppm, standard deviation ±8.412), 2.680 ppm (standard deviation ±0.696) remained.

또한, [표 4]와 같이, 실시예들이 비교예1보다 각각의 중금속 제거율이 높음을 살펴볼 수 있다. In addition, as shown in [Table 4], it can be seen that the respective heavy metal removal rates are higher than those of Comparative Example 1.

구분division 중금속 잔류량 (ppm)Heavy Metal Residue (ppm) CdCD CoCo CrCr CuCu MoMo NiNi PbPb SbSb SeSe SnSn TiTi TotalTotal 세척전before washing 0.0530.053 0.1880.188 0.7060.706 1.1031.103 1.9851.985 0.8640.864 0.3710.371 6.3636.363 1.9381.938 2.7632.763 0.8070.807 17.14417.144 실시예 1Example 1 0.0190.019 0.003 0.003 0.0810.081 0.1050.105 0.027 0.027 0.0740.074 0.2690.269 1.6861.686 0.349 0.349 NDND 0.0620.062 2.6802.680 실시예 2Example 2 0.0020.002 0.001 0.001 0.0630.063 0.222 0.222 0.128 0.128 0.202 0.202 ND ND 0.495 0.495 0.3690.369 NDND 0.085 0.085 1.5721.572 비교예 1Comparative Example 1 0.002 0.002 0.017 0.017 0.1130.113 0.1290.129 0.0600.060 0.127 0.127 0.302 0.302 1.0831.083 1.1601.160 0.295 0.295 0.0630.063 3.3563.356

[표 4]를 참조하면, 실시예 1에서는 인체 독성이 높은 Sn이 불검출되었으며, 실시예2에서는 인체에 독성이 높은 Pb, Sn이 불검출되었고, Cd, Co는 거의 검출되지 않았다. Referring to Table 4, Sn, which is highly toxic to the human body, was not detected in Example 1, Pb and Sn, which were highly toxic to the human body, were not detected in Example 2, and Cd and Co were hardly detected.

상술한 바와 같이, 소방대원의 개인장비에 흡착된 중금속 및 다환방향족탄화수소류는 본 발명의 세척용 티슈와 폼세정제가 시중에서 판매되는 세척용 티슈보다 제거율이 높았음을 살펴봄으로써, 향후 소방대원의 개인장비 관리에 유용하며, 세척용 티슈와 폼세정제를 혼용할 경우, 유해물질의 제거효율을 향상시킬 수 있다.As described above, by examining that the removal rate of heavy metals and polycyclic aromatic hydrocarbons adsorbed on firefighters' personal equipment was higher than that of commercially available cleaning tissues in the cleaning tissue and foam cleaner of the present invention, It is useful for managing personal equipment, and when a cleaning tissue and a foam cleaner are mixed, the removal efficiency of harmful substances can be improved.

본 발명이 속하는 기술분야의 통상의 지식을 가진 자는 본 발명이 그 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다. 그러므로 이상에서 기술한 실시예들은 모든 면에서 예시적인 것이며 한정적이 아닌 것으로 이해해야만 한다. 본 발명의 범위는 상세한 설명보다는 후술하는 특허청구의 범위에 의하여 나타내어지며, 특허청구의 범위의 의미 및 범위 그리고 그 균등 개념으로부터 도출되는 모든 변경 또는 변형된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다. 더불어, 상술하는 과정에서 기술된 구성의 작동순서는 반드시 시계열적인 순서대로 수행될 필요는 없으며, 각 구성 및 단계의 수행 순서가 바뀌어도 본 발명의 요지를 충족한다면 이러한 과정은 본 발명의 권리범위에 속할 수 있음은 물론이다.Those of ordinary skill in the art to which the present invention pertains will understand that the present invention may be embodied in other specific forms without changing the technical spirit or essential features thereof. Therefore, it should be understood that the embodiments described above are illustrative in all respects and not restrictive. The scope of the present invention is indicated by the following claims rather than the detailed description, and all changes or modifications derived from the meaning and scope of the claims and their equivalent concepts are interpreted as being included in the scope of the present invention. should be In addition, the operation sequence of the components described in the above process does not necessarily have to be performed in a time-series order, and if the gist of the present invention is satisfied even if the execution order of each configuration and step is changed, such a process may fall within the scope of the present invention. Of course you can.

Claims (8)

킬레이트제, 금속이온봉쇄제, 음이온성 계면활성제, 세정보조제, 보습제, 보존제 및 물을 포함하는 금속제거용 조성물; 및
상기 금속제거용 조성물이 함침된 세척용 시트;를 포함하고,
상기 금속제거용 조성물은 물 100중량부에 대하여, 항균제 0.5∼1.7중량부를 포함하고, 항균제는 100중량부에 대하여 박하 추출액 19∼25중량부, 구연산 7∼12중량부, 어성초 추출액 27∼32중량부, 편백나무 추출액 30∼34중량부, 나노은 분말 3∼6중량부를 포함하고,
상기 세척용 시트는, 길이방향으로 갈수록 두께가 두꺼워지고,
장비에 흡착된 중금속 및 다환방향족 탄화수소류를 제거하는 것을 특징으로 하는 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈.
a metal removal composition comprising a chelating agent, a sequestering agent, an anionic surfactant, a cleaning aid, a moisturizing agent, a preservative, and water; and
Including; a cleaning sheet impregnated with the metal removal composition;
The metal removal composition contains 0.5 to 1.7 parts by weight of an antibacterial agent based on 100 parts by weight of water, and the antibacterial agent is 19 to 25 parts by weight of mint extract, 7 to 12 parts by weight of citric acid, 27 to 32 parts by weight of eosincho extract based on 100 parts by weight of the antibacterial agent. parts, including 30 to 34 parts by weight of cypress extract, 3 to 6 parts by weight of nano silver powder,
The cleaning sheet, the thickness increases in the longitudinal direction,
A tissue for cleaning personal protective equipment for removing heavy metals and polyaromatic hydrocarbons, characterized in that it removes heavy metals and polyaromatic hydrocarbons adsorbed to the equipment.
제1항에 있어서,
상기 금속제거용 조성물은, 상기 물 100중량부에 대하여, 상기 킬레이트제 1.0~1.2중량부, 상기 금속이온봉쇄제 0.2~0.3중량부, 상기 음이온성 계면활성제 1.0~6.5중량부, 상기 세정보조제 2.0~ 12중량부, 상기 보습제 1.0~6.0중량부 및 상기 보존제 1.0~1.2중량부인 것을 특징으로 하는 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈.
According to claim 1,
The metal removal composition is, with respect to 100 parts by weight of the water, 1.0 to 1.2 parts by weight of the chelating agent, 0.2 to 0.3 parts by weight of the sequestering agent, 1.0 to 6.5 parts by weight of the anionic surfactant, and 2.0 parts by weight of the cleaning aid. ~ 12 parts by weight, 1.0 to 6.0 parts by weight of the moisturizing agent, and 1.0 to 1.2 parts by weight of the preservative. Tissue for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons.
제1항에 있어서,
상기 킬레이트제는, EDTA·4NA인 것을 특징으로 하는 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈.
According to claim 1,
The chelating agent is EDTA·4NA. A tissue for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons.
제1항에 있어서,
상기 금속이온봉쇄제는, 글루콘산 나트륨(Sodium gluconate)으로 이루어진 것을 특징으로 하는 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈.
According to claim 1,
The sequestering agent, a tissue for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons, characterized in that consisting of sodium gluconate.
제1항에 있어서,
상기 음이온성 계면활성제는, 소듐코코일글루타메이트(Sodium cocoyl glutamate)와 트리에탄올아민라우릴설페이트(Triethanolamine lauryl sulfate) 중 어느 하나 이상으로 이루어진 것을 특징으로 하는 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈.
According to claim 1,
The anionic surfactant, sodium cocoyl glutamate (Sodium cocoyl glutamate) and triethanolamine lauryl sulfate (Triethanolamine lauryl sulfate) Personal protective equipment washing for removal of heavy metals and polycyclic aromatic hydrocarbons, characterized in that consisting of any one or more dragon tissue.
제1항에 있어서,
상기 세정보조제는, 다이프로필렌 글리콜 메틸 에테르(Dipropylene glycol monomethyl ether), 디에틸렌글리콜 모노부틸 에테르(Diethylene glycol monobutyl ether) 중 어느 하나 이상으로 이루어지고,
상기 보습제는, 프로필렌글리콜(Propylene Glycol)으로 이루어지고,
상기 보존제는, 벤질알코올(Benzyl Alcohol), 및 벤조산나트륨(Sodium Benzoate) 중 어느 하나 이상으로 이루어지는
것을 특징으로 하는 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈.
According to claim 1,
The cleaning aid is made of at least one of dipropylene glycol monomethyl ether and diethylene glycol monobutyl ether,
The moisturizer is made of propylene glycol (Propylene Glycol),
The preservative, benzyl alcohol (Benzyl Alcohol), and sodium benzoate (Sodium Benzoate) consisting of any one or more
Tissue for cleaning personal protective equipment for removing heavy metals and polycyclic aromatic hydrocarbons, characterized in that.
제1항에 있어서,
향료 및 탈취제를 더 포함하고,
상기 물 100중량부에 대하여, 향료 및 탈취제가 각각 1.0~1.2중량부인 것을 특징으로 하는 중금속 및 다환방향족탄화수소류 제거를 위한 개인보호장비 세척용 티슈.
According to claim 1,
Further comprising a fragrance and deodorant,
With respect to 100 parts by weight of the water, a personal protective equipment cleaning tissue for removing heavy metals and polycyclic aromatic hydrocarbons, characterized in that each 1.0 to 1.2 parts by weight of the fragrance and the deodorant.
삭제delete
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JPH07166126A (en) * 1993-12-14 1995-06-27 Daiei Kikai:Kk Production of polyfunctional water glass coating material
KR20090025423A (en) 2007-09-06 2009-03-11 주식회사 하이닉스반도체 Method of forming a shallow junction in a semiconductor device and method of manufacturing a semiconductor device using it
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