KR950014916B1 - Method for recycling waste plastic - Google Patents

Method for recycling waste plastic Download PDF

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Publication number
KR950014916B1
KR950014916B1 KR1019920011712A KR920011712A KR950014916B1 KR 950014916 B1 KR950014916 B1 KR 950014916B1 KR 1019920011712 A KR1019920011712 A KR 1019920011712A KR 920011712 A KR920011712 A KR 920011712A KR 950014916 B1 KR950014916 B1 KR 950014916B1
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South Korea
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separated
plastic
polyester
polyethylene
washed
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KR1019920011712A
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Korean (ko)
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KR940002022A (en
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김태완
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김태완
도갑수
성수엔지니어링주식회사
이영재
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)

Abstract

Polyethylene terephthalate is separated from the waste plastic bottle. The waste polyester plastic bottles are cut less than 15 cm in a first crusher, and alien matters such as a label are separated by an air separator. The polyester is impregnated in this process, and polyethylene is separated and washed by a chemicals and water. The separated polyethylene is dewatered and dried by a centrifugal separator, and crushed less than 1 cm in second crusher. Aluminium is removed from the polyethylene compound to give the polyethylene terephthalate particles.

Description

플라스틱 폐자재의 분리 재생처리방법Separation and Recycling Method of Plastic Waste Materials

제1도는 본 발명의 일실시예를 나타낸 폐자재 재생처리공정도.1 is a waste material recycling treatment process showing an embodiment of the present invention.

* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings

1 : 플라스틱 폐자재 2 : 1차 분쇄기1: Plastic waste material 2: Primary grinder

3 : 공기분리기 4 : 1차 재료분리기3: air separator 4: primary material separator

5 : 약품세척장치 7 : 원심분리기5: chemical washing device 7: centrifuge

10 : PET재생품10: PET recycled products

본 발명은 플라스틱 폐자재의 분리 재생처리방법에 관한 것으로, 특히, 콜라, 사이다 등의 음료수나 요구르트 등을 담는 플라스틱으로 된 폐품용기를 큰 입자로 가압 1차 분쇄하고 이를 분리시켜 약품으로 처리한 것을 원심분리로 이물질과 탈수를 하여준 것을 미립자로 2차 분쇄하고 알루미늄을 제거 분리한 재생자재를 재사용할 수 있게 할 목적으로 한 것이다.The present invention relates to a method for separating and regenerating plastic waste materials, and in particular, a waste container made of plastic containing a beverage or yogurt, such as cola, cider, etc., which is first pressurized with large particles and separated and processed into chemicals. The object of dehydration and dehydration by centrifugation is to make the secondary material crushed into fine particles and reuse the recycled materials from which aluminum is removed.

여기에서 플라스틱은 주로 콜라나 사이다 등을 포함한 음료수를 병으로 사용하는 PET병 및 비식용생활용품 용기인 PEㆍPPㆍHDPE용기 등으로서 불포화 포리에스테르(PET) 및 PEㆍPPㆍHDPE 등으로 제조된 용기에 고밀도 포리에틸렌(HDPE)제 베이스컵, 알루미늄캡 및 종이라벨 또는 레이온 라벨, 접착제 등이 가해져 플라스틱 용기를 형성한 것들이다.Here, plastic is mainly made of unsaturated polyesters (PET), PE, PP, HDPE, etc., such as PET bottles and PE, PP, HDPE containers, etc., which mainly use beverages including cola, cider, etc. as bottles. High density polyethylene (HDPE) base cups, aluminum caps and paper labels or rayon labels, adhesives, and the like are applied to the containers to form plastic containers.

종래 여러가지 플라스틱의 재생재료가 여러가지 형태의 방식에 의하여 재가공되어 사용되어지고 있는 것으로, PET, PE, PP, HDPE용기 등도 수작업에 의한 재가공이 이루어지고 있으나, 회수되는 플라스틱 용기의 종류나 형태 등에 따라 분리하여 재가공하여야 하는 관계로 폐품 재활용의 입장에서나 생산성 등에서 여러가지 문제점이 있어 상업적인 이용이 불가능하였다.Conventionally, recycled materials of various plastics have been reprocessed by various types of methods, and PET, PE, PP, and HDPE containers have been manually reprocessed, but are separated according to the type and shape of the plastic container to be recovered. Due to the need to be reprocessed, there were various problems in terms of product recycling and productivity.

즉 알루미늄캡과 HDPE베이스컵 및 기타 부착이물질을 수작업으로 일일이 분리하여야 하는 작업성의 저능률성과 라벨 등의 부착품이 그대로 붙어있는 상태에서 분쇄하여 처리하는 방법이거나 또는 라벨을 대강 떼어내고 톨루엔 등의 용액에 첨지하여 알루미늄이나 폴리에틸렌 등을 제거 분리하여 분쇄하는 방법 등이 일반적인 작업공정으로 활용되어지고 있으나, 이는 고가의 톨루엔 용액을 사용하고 라벨 등을 수작업으로 제거하여야 되므로 약품값과 인건비의 과다지출로 폐품재생 생산원가를 높혀 저렴한 가격으로서의 생산을 할 수 없는 결점이 있었다.In other words, the aluminum cap and HDPE base cup and other attached foreign matters must be separated by hand, and the work efficiency is low and the attachments such as labels are crushed and processed, or the labels are roughly peeled off and the solution of toluene, etc. It is used as a general work process by removing and grinding aluminum or polyethylene by adding it to the general work process.However, it is necessary to use an expensive toluene solution and manually remove the label. There was a drawback that it was impossible to produce at a low price by increasing the cost of regeneration production.

본 발명은 종래의 이와 같은 제반 문제점을 감안하여 수작업에 의존하는 분리 제거작업을 하지 않은 상태에서 플라스틱 폐품을 기계적으로 1차 가압 절단 분쇄처리하고 공기를 이용하는 분리기에서 종이, 레이온 및 기타 이물질 등을 수거하며, 컨베이어 스크류 등을 이용하는 재료 분리기로 PET는 침체시키고 HDPE, PE, PP 등은 걷어 분리시킨후 세척하여 원심 분리기에서 탈수 및 건조한후 2차 분쇄기에서 분쇄하여 알루미늄은 제거하고 최종적으로 PET재생품만을 재생 원료로 분리하는 폐자재분리 재생시스템을 제시한 것이다.The present invention is mechanically primary pressure cutting and grinding the plastic waste in the state without the separation and removal work dependent on the manual operation in order to solve the conventional problems such as the conventional paper and rayon and other foreign matters collected in the separator using air PET is stagnated with a material separator using a conveyor screw, HDPE, PE, PP, etc. are kicked off, washed, washed, dehydrated in a centrifuge and dried, and then crushed in a second grinder to remove aluminum and finally recycled only PET recycled products. It presents a waste material separation and recycling system for separating raw materials.

본 발명의 일실시예를 첨부도면에 의한 제조공정별로 나누어 구체적으로 설명하면 다음과 같다.One embodiment of the present invention will be described in detail by dividing according to the manufacturing process according to the accompanying drawings.

[제1공정][Step 1]

수집한 각종 플라스틱 용기 등으로 된 플라스틱 폐자재(1)를 컨베이어로 운반하면서 이송도중 선별하고 선별이 된 것은 1차 분쇄기(2)에서 15㎝ 이하 정도의 적당한 입자크기로 압축절단 분쇄하여 준다. 1차 분쇄기에서 압축 분쇄된 플라스틱에 섞여있는 종이라벨 및 레이온 라벨(11)을 공기분리기(3)에서 가압공기 및 블로워를 이용한 공기분리방식에 의하여 분쇄플라스틱과 별도 분리처리한다. 이때 압축절단 분쇄된 플라스틱에 붙어있는 일부의 작은 이물질은 블로워의 가압공기에 의하여 제거된다.The plastic waste materials (1) made of various plastic containers, etc. collected are transported to a conveyor and sorted during the transfer, and the sorted materials are compressed and crushed to a suitable particle size of about 15 cm or less in the primary mill (2). The paper label and rayon label 11 mixed in the compression-crushed plastic in the first mill are separately separated from the milled plastic by an air separation method using pressurized air and a blower in the air separator 3. At this time, some small foreign matter adhering to the crushed plastic is removed by the pressurized air of the blower.

[제2공정][Step 2]

제1공정에 의하여 종이, 레이온 라벨(11) 등이 분리된 플라스틱 분쇄물을 스크류 컨베이어를 이용하여 1차 재료분리기(4)로 보내어 포리에스테르(PET)는 침전시키고, 침전되지 않고 부상하는 PE, PP 및 HDPE등은 걷어내어 분리하여 준다.Send the plastic pulverized product separated from paper, rayon label 11, etc. by the first process to the primary material separator 4 using a screw conveyor to precipitate the polyester (PET), and not to precipitate PE, PP and HDPE are rolled out and separated.

이때 분리된 PE, PP 및 HDPE는 별도 수거하여 재생원료화 하고 침전되어 남은 포리에스테르(PET)를 스크류 컨베이어로 이동시키면서 톨루엔 등의 유기용매세제 등을 사용 약품으로 하는 약품세척장치(5)에서 전 공정에서의 잔존 이물질을 완전 세척하며 세척액의 손실을 최소화 하는 방법으로 휠터 등을 이용한 순환 시설을 부착사용하여 세척약품의 손실도 최소화시킨다.At this time, the separated PE, PP, and HDPE are separately collected and recycled, and the remaining polyesters (PET) are transferred to the screw conveyor and transferred to the chemical washing apparatus (5) using organic solvent detergents such as toluene. It also minimizes the loss of cleaning chemicals by completely attaching a circulation facility using filter, etc., to completely clean the remaining foreign substances in the process and to minimize the loss of cleaning liquid.

[제3공정][Step 3]

제2공정에 의하여 약품세척 처리된 플라스틱 분쇄물질을 흐르는 물에 의한 물세척장치(6)로 잔류약품이 없도록 깨끗히 세척한 것을 원심분리기(7)에 넣고 탈수 및 건조하여 준다.The cleansed plastic crushed material by the second step is washed with clean water so that there is no residual chemical in the water washing device 6 by flowing water, and put into a centrifuge 7 and dehydrated and dried.

이때 사용하는 원심분리기는 수직형 원심분리드럼이나 횡형드럼을 사용하여 원심분리로 탈수와 건조를 동시에 할 수 있는 것으로 하며, 이때 사용되는 물은 공해방지시설 및 정수시설을 통하여 재사용 가능케함으로써 폐수유출이 전혀 없도록 한다.At this time, the centrifuge used is capable of simultaneously dehydrating and drying by centrifugation using a vertical centrifugal drum or a horizontal drum. The water used can be reused through pollution prevention facilities and water purification facilities to prevent wastewater leakage. Don't have it at all.

[제4공정][Step 4]

제3공정에 의하여 약품세척 및 탈수건조시킨 플라스틱의 1차 분쇄물을 2차 분쇄기(8)에서 약 1㎝ 정도 이하 적당한 크기의 입자로 분쇄하여 2차 재료분리기(9)에 넣고 알루미늄과 PET재생품(10)을 분리시킨다.The primary pulverized product of the chemical washed and dehydrated plastic by the third process is crushed into particles of a suitable size of about 1 cm or less in the secondary pulverizer 8 and placed in the secondary material separator 9 to recycle aluminum and PET. Separate (10).

상기한 재료 분리기(9)에서 분리된 알루미늄은 별도의 수거장치에서 수거처리하고 잔여 PET재생품은 재생원료로 포장하여 준다.The aluminum separated in the material separator 9 is collected and treated in a separate collection device, and the remaining PET regenerated material is packaged with recycled raw materials.

상기와 같은 분리 재생방법에 의하여 처리된 재생원료는 화학섬유 등 기타 원자재의 원료로 활용할 수 있는 것으로, 본 발명의 바람직한 일실시예는 수집한 플라스틱병과 같은 폐품으로 된 폐자재를 컨베이어로 운반하면서 중간에서 선별하고 15㎝ 이하의 입자크기로 압축하며, 절단 분쇄시켜 분쇄된 플라스틱에 섞인 종이라벨이나 레이온 라벨을 가압공기나 블로워를 이용하여 각각 분기수거 처리한다.The recycled raw material treated by the separate regeneration method as described above may be utilized as a raw material for other raw materials such as chemical fibers, and a preferred embodiment of the present invention may be used to transport waste materials such as collected plastic bottles to a conveyor. After sorting and compressing to a particle size of 15 cm or less, the paper labels or rayon labels mixed with the pulverized plastics are cut and pulverized by pressurized air or blower, respectively.

이와 같은 과정에 의하여 플라스틱에 있는 이물질들로 종이라벨이나 레이온 라벨과 함게 분리되어 제거된다.By this process, the foreign substances in the plastic are separated and removed together with the paper label or the rayon label.

이물질이나 라벨이 분리제거된 절단분쇄되어 있는 플라스틱류를 스크류 컨베이어를 이용하는 재료분리장치로 이송시켜 포리에스테르(PET)는 침전시키고 부상하는 포리에틸렌은 걷어내어 분리수거하여 재생원료로 사용한다.The cut and pulverized plastics from which foreign substances or labels are separated and removed are transferred to a material separation device using a screw conveyor, whereby the polyester is precipitated and the floating polyethylene is collected and separated and used as recycled material.

이와 같이 하여 침전되어 남는 포리에스테르(PET)를 스크류 컨베이어로 이동시키면서 톨루엔 등의 유기용매, 세제 등을 사용하는 약품에 의하여 세척하는 것으로, 약품의 손실을 최소화시키기 위하여 순환시설을 부착사용함을 원칙으로 한다.In this way, the remaining polyesters (PET) are washed by chemicals using organic solvents such as toluene, detergents, etc. while moving to the screw conveyor, and in principle, the circulation facility is attached to minimize the loss of chemicals. do.

약품세척을 한 상태에서 물로 수세시켜 원심분리기를 사용하여 탈수와 건조과정을 동시에 수행한다.Washing with water in the state of chemical washing is carried out simultaneously with dehydration and drying process using a centrifuge.

이때 사용하는 원심분리기로는 횡형드럼식 원심분리방법을 사용할 수도 있다.At this time, the centrifugal separator used may be a horizontal drum centrifugation method.

상기한 수세후 원심분리형 탈수 건조방식에서도 공해방지 시설과 정수시설을 한다.After washing with water, centrifugal dehydration drying method also has pollution prevention facilities and water purification facilities.

이와 같이 탈수와 건조가 된 플라스틱 분쇄물을 2차에서 다시 분쇄시켜 입자의 크기를 1㎝ 이하 적당한 크기의 입자로 분쇄시켜 재료분리장치에서 알루미늄은 별도 제거분리하고 최종적으로 PET재생품만 선별하여 재생원료로 사용토록 한 것이다.In this way, the dehydrated and dried plastic pulverized product is pulverized again in the second time, and the size of the particles is pulverized into particles having a suitable size of 1 cm or less, and aluminum is separately removed and separated from the material separation device. It is intended to be used.

이상에서 상세히 설명한 바와 같은 재생방법으로 처리된 플라스틱병이나 용기를 이용한 PEㆍPPㆍHDPE 및 PET재생자재는 화학섬유 등 기타 원자재의 원료로 활용할 수 있으며, 본 재생원료는 초기원료로서의 PEㆍPPㆍHDPE 및 PET버진 가격에 비하여 상대적으로 매우 저렴할 뿐만 아니라, 플라스틱병이나 용기를 그냥 버리게되면 이는 영구적으로 썩지않아 자연을 훼손하게 되므로 공해물질로 남게되나 본 발명의 분리재생처리방법을 이용하여 이를 여러가지 재생원료로 재활용하면 공해발생방지 등의 효과도 동시에 얻을 수 있는 일거양득이라 할 수 있는 것이다.PE, PP, HDPE and PET recycled materials using plastic bottles or containers treated by the regeneration method as described above can be used as raw materials for other raw materials such as chemical fibers. Not only is relatively inexpensive compared to the price of HDPE and PET, but if the plastic bottles or containers are simply thrown away, they will not perish permanently and damage nature, leaving them as pollutants. If recycled as raw materials, it can be said that the benefits such as pollution prevention can be obtained at the same time.

Claims (1)

포리에스테르 플라스틱병이나 용기 등의 폐품으로 되는 플라스틱 폐자재(1)를 분쇄할때 폐품끼리의 기계적 마찰로 라벨과 이물질을 분리할 수 있게 한 공지의 플라스틱 폐자재 재생원료 회수 방법에 있어서, 상기 분쇄기(2)의 1차 분쇄때는 15㎝ 미만으로 가압 절단하며 공기분리기(3)에서는 라벨 등의 이물질을 분리 제거한 상태에서 포리에스테르는 침체시키고, 포리에틸렌은 분리한후 약품 및 물수세하고 원심분리기로 탈수건조시킨 것을 2차 분쇄기(8)에서 1㎝ 미만의 입자로 분쇄하고 알루미늄은 제거하여 PET재생 입자만 원료로 사용할 수 있도록 하여서 됨을 특징으로 한 플라스틱 폐자재의 분리 재생처리방법.In the known plastic waste material recycling raw material recovery method which makes it possible to separate a label and a foreign substance by the mechanical friction of waste materials, when grinding the plastic waste materials (1) which become waste products, such as a polyester plastic bottle and a container, the said grinder In the first pulverization of (2), press-cutting is less than 15 cm. In the air separator (3), the polyester is stagnated while the foreign substances such as labels are separated and the polyester is stagnated. The polyethylene is separated, washed with chemicals, and washed with centrifuge. Separating and drying the dehydrated to a particle less than 1cm in the secondary mill (8), and the aluminum is removed so that only PET reclaimed particles can be used as raw materials.
KR1019920011712A 1992-07-02 1992-07-02 Method for recycling waste plastic KR950014916B1 (en)

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