KR950012792A - 리튬2차전지용 정극활물질의 제조방법 - Google Patents

리튬2차전지용 정극활물질의 제조방법 Download PDF

Info

Publication number
KR950012792A
KR950012792A KR1019940026795A KR19940026795A KR950012792A KR 950012792 A KR950012792 A KR 950012792A KR 1019940026795 A KR1019940026795 A KR 1019940026795A KR 19940026795 A KR19940026795 A KR 19940026795A KR 950012792 A KR950012792 A KR 950012792A
Authority
KR
South Korea
Prior art keywords
positive electrode
transition metal
lithium
active material
electrode active
Prior art date
Application number
KR1019940026795A
Other languages
English (en)
Inventor
요시가즈 야마모도
Original Assignee
오가 노리오
소니 가부시기가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 오가 노리오, 소니 가부시기가이샤 filed Critical 오가 노리오
Publication of KR950012792A publication Critical patent/KR950012792A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

리튬염과 천이금속염의 혼합물을 산소분위기하에서 소성하여, LixNiyM1-yO2(단,M은 1종 또는 1종 이상의 천이금속이고 x,y는 각각 0.05≤x≤1.01, 0.5≤y≤1.0임)인 조성의 리튬천이금속 복합산화물을 합성함에 있어서, 소성분위기의 산소압력을 최소한 소성공정의 어떤 한 시기에 있어서 147.1kP이상한다.
조성, 특성이 균일하고, 정극활(正極活)물질로서 우수한 기능을 발휘하는 리튬천이금속 복합산화물을 얻을 수 있다. 따라서, 이와 같이 하여 합성된 리튬천이금속 복합산화물을 정극활물질로 하여 정극을 구성하면, 사이클 특성이 우수하고, 고에너지밀도인 동시에 재료코스트가 낮고, 또한 전지용량에 불균일이 없는 품질이 균일한 리튬2차전지를 얻는 것이 가능하게 된다.

Description

리튬2차전지용 정극활물질의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 제조방법으로 제조된 정극활물질을 적용한 리튬2차전지의 구성을 나타낸 개략종단면도,
제2도는 소성에 있어서의 분위기의 산소압력과 전지용량의 불균일의 관계를 나타낸 특성도.

Claims (2)

  1. 리튬염과 천이금속염의 혼합물을 산소분위기하에서 소성하여, LixNiyM1-yO2(단,M은 1종 또는 1종 이상의 천이금속이고 x,y는 각각 0.05≤x≤1.01, 0.5≤y≤1.0임)인 조성의 리튬천이금속 복합산화물을 합성함에 있어서, 소성분위기의 산소압력을 최소한 소성공정의 어떤 한 시기에 있어서 147.1kP이상으로 하는 것을 특징으로 하는 리튬2차전지용 정극활(正極活)물질의 제조방법.
  2. 제1항에 있어서, 합성되는 리튬천이금속 복합산화물이 LixNiyM1-yO2(단, x,y는 각각 0.05≤x≤1.01, 0.5≤y≤1.0임)인 조성인 것을 특징으로 하는 리튬2차전지용 정극활물질의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940026795A 1993-10-29 1994-10-20 리튬2차전지용 정극활물질의 제조방법 KR950012792A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP93-272,847 1993-10-29
JP5272847A JPH07130367A (ja) 1993-10-29 1993-10-29 リチウム二次電池用正極活物質の製造方法

Publications (1)

Publication Number Publication Date
KR950012792A true KR950012792A (ko) 1995-05-17

Family

ID=17519608

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019940026795A KR950012792A (ko) 1993-10-29 1994-10-20 리튬2차전지용 정극활물질의 제조방법

Country Status (5)

Country Link
US (1) US5474752A (ko)
EP (1) EP0655791B1 (ko)
JP (1) JPH07130367A (ko)
KR (1) KR950012792A (ko)
DE (1) DE69408286T2 (ko)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9305058D0 (en) * 1993-03-12 1993-04-28 Penn Pharm Ltd Pharmaceutical compositions
DE69416640T2 (de) * 1993-05-31 1999-10-21 Hitachi Maxell, Ltd. Lithiumsekundärzelle mit organischem elektrolyten, aktives material für positive elektrode einer li-sekundärzelle und verfahren zur herstellung des aktiven materials
JP3067531B2 (ja) * 1994-07-13 2000-07-17 松下電器産業株式会社 非水電解液二次電池の正極活物質およびそれを用いた電池
EP0714144B1 (en) * 1994-11-22 1999-09-15 Sumitomo Chemical Company Limited Cathode for lithium secondary battery and production method for the same
JP3606290B2 (ja) * 1995-04-28 2005-01-05 日本電池株式会社 非水系電池の正極活物質用コバルト含有ニッケル酸リチウムの製造方法
US5630994A (en) * 1995-08-01 1997-05-20 Boyle; Timothy J. Non-aqueous solution preparation of doped and undoped lixmnyoz
DE69620154T2 (de) * 1995-11-24 2002-10-02 Fuji Chemical Industry Co., Ltd. Lithium-nickel-verbundoxid, verfahren zu seiner herstellung und positives aktives material für sekundäre batterie
US5792574A (en) * 1996-03-04 1998-08-11 Sharp Kabushiki Kaisha Nonaqueous secondary battery
US6077496A (en) * 1996-09-12 2000-06-20 Dowa Mining Co., Ltd. Positive electrode active material for nonaqueous secondary cells and a process for producing said active material
JPH10106566A (ja) * 1996-09-24 1998-04-24 Japan Storage Battery Co Ltd リチウム二次電池用正極活物質の製造法
KR100393194B1 (ko) * 1996-12-05 2003-11-01 삼성에스디아이 주식회사 졸-겔법을이용한리튬이차전지용양극활물질LixMn₂O₄분말의제조방법
US6071489A (en) * 1996-12-05 2000-06-06 Samsung Display Device Co., Ltd. Methods of preparing cathode active materials for lithium secondary battery
US6040090A (en) * 1997-04-15 2000-03-21 Sanyo Electric Co., Ltd. Positive electrode material for use in non-aqueous electrolyte battery, process for preparing the same, and non-aqueous electrolyte battery
US6045950A (en) * 1998-06-26 2000-04-04 Duracell Inc. Solvent for electrolytic solutions
US6350543B2 (en) 1999-12-29 2002-02-26 Kimberly-Clark Worldwide, Inc. Manganese-rich quaternary metal oxide materials as cathodes for lithium-ion and lithium-ion polymer batteries
US6844110B2 (en) * 2000-05-24 2005-01-18 Ngk Insulators, Ltd. Lithium secondary cell and assembly thereof
US20040053136A1 (en) * 2002-09-13 2004-03-18 Bauman William C. Lithium carbide composition, cathode, battery and process
TWI233231B (en) * 2003-12-25 2005-05-21 Ind Tech Res Inst Cathode material with nano-oxide layer on the surface and the produce method
US7608332B2 (en) * 2004-06-14 2009-10-27 Industrial Technology Research Institute Cathode material particle comprising of plurality of cores of coated grains
JP4213659B2 (ja) * 2004-12-20 2009-01-21 株式会社東芝 非水電解質電池および正極活物質

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2797390B2 (ja) * 1989-04-03 1998-09-17 ソニー株式会社 非水電解質二次電池
US5264201A (en) * 1990-07-23 1993-11-23 Her Majesty The Queen In Right Of The Province Of British Columbia Lithiated nickel dioxide and secondary cells prepared therefrom
US5180574A (en) * 1990-07-23 1993-01-19 Moli Energy (1990) Limited Hydrides of lithiated nickel dioxide and secondary cells prepared therefrom
JPH05299092A (ja) * 1992-01-17 1993-11-12 Matsushita Electric Ind Co Ltd 非水電解質リチウム二次電池及びその製造方法

Also Published As

Publication number Publication date
DE69408286D1 (de) 1998-03-05
EP0655791B1 (en) 1998-01-28
JPH07130367A (ja) 1995-05-19
EP0655791A1 (en) 1995-05-31
DE69408286T2 (de) 1998-08-27
US5474752A (en) 1995-12-12

Similar Documents

Publication Publication Date Title
KR950012792A (ko) 리튬2차전지용 정극활물질의 제조방법
KR870010642A (ko) 유기 전해질 전지
CA2102738A1 (en) Inverse Spinel Compounds as Cathodes for Lithium Batteries
CA2162456A1 (en) Cathode material, method of preparing it and nonaqueous solvent type secondary battery having a cathode comprising it
EP1447866A4 (en) POSITIVE ELECTRODE ACTIVE MATERIAL FOR A LITHIUM SECONDARY CELL AND LITHIUM CELL
TW342537B (en) Polymeric electrode, electrolyte, article of manufacture and composition
KR940006306A (ko) 비수용성 전해액의 2차 전지와 그 제조방법
EP0989622A4 (en) NON-AQUEOUS ELECTROLYTIC SECONDARY CELL
KR980006595A (ko) 비수전해액계(非水電解液系) 이차전지
JP2000138053A5 (ko)
WO1994029915A3 (en) Manganese oxide cathode active material
KR940001482A (ko) 리튬 2차 전지용 전극과 그 제조방법 및 그 정극을 사용한 비수전해질리튬 2차전지
SE9802103D0 (sv) A device for production of electrical energy
EA200201086A1 (ru) Электрохимический элемент с керамическими частицами в слое электролита
TW373346B (en) Positive electrode material and non-hydraulic electrolytic battery using the said material
KR910007028A (ko) 전자관음극 및 그 제조방법
JPS5782969A (en) Battery
KR970054746A (ko) 비수계 리튬 이차 전지용 양극 활물질의 제조방법
EP4345939A3 (en) Composite positive electrode active material, positive electrode and lithium battery including the same, and preparing method thereof
JPS6410576A (en) Oxygen electrode fuel battery with solid electrolyte
JPS5533743A (en) Sealed type lead storage battery
JPS5750768A (en) Battery
JPS56130075A (en) Alkaline battery
FR2159665A5 (en) High energy density cell - having metal chromate cathode depolariser light metal anode and organic electrolyte soln
EP0855754A3 (de) Kathodenwerkstoff für eine Hochtemperaturbrennstoffzelle

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid