KR940019772A - 강성 사이클로올레핀 공중합체 필름 - Google Patents
강성 사이클로올레핀 공중합체 필름 Download PDFInfo
- Publication number
- KR940019772A KR940019772A KR1019940002496A KR19940002496A KR940019772A KR 940019772 A KR940019772 A KR 940019772A KR 1019940002496 A KR1019940002496 A KR 1019940002496A KR 19940002496 A KR19940002496 A KR 19940002496A KR 940019772 A KR940019772 A KR 940019772A
- Authority
- KR
- South Korea
- Prior art keywords
- film
- cycloolefin copolymer
- film according
- repeating unit
- gpa
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/04—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
- B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L45/00—Compositions of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2345/00—Characterised by the use of homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic ring system; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/91—Product with molecular orientation
Abstract
본 발명은 하나 이상의 층이, 유리전이온도(Tg)에 대한 고유 E 모듈러스(Ei)의 의존성이 다음과 같은 사이클로올레핀 공중합체를 포함하는, 강성 단층 또는 다층의 비배향되거나 단축 또는 쌍축 배향된 필름에 관한 것이다.
Ei=(0.0025[GPa/℃]×Tg[℃])×B[GPa]
상기식에서, B는 2.93 내지 3.19이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1 도는 본 발명에 따른 미세구조를 갖는 사이클로올레핀 공중합체의 전형적인 스펙트럼을 도시한 것이다,
제 2 도는 본 발명에 따른 미세구조를 갖지 않는 사이클로올레핀 공중합체의 스펙트럼을 도시한 것이다(비교용),
제 3 도는 개별적인 중합체의 Tg에 대한 Ei 값의 의존도를 도시한 것이다.
Claims (17)
- 하나 이상의 층이, 유리전이온도에 대한 고유 E 모듈러스(Ei)의 의존성이 다음과 같은 사이클로올레핀 공중합체를 포함하는, 단층 또는 다층의 비배향되거나 단축 또는 쌍축 배향된 필름.Ei=(0.0025[GPa/℃]×Tg[℃])×B[GPa]상기식에서, B는 2.93 내지 3.19이다.
- 하나 이상의 층이,13C-NMR 스펙트럼이 40.8ppm에서 피크를 갖는 사이클로올레핀 공중합체를 포함하는, 단층 또는 다층의 비배향되거나 단축 또는 쌍축 배향된 필름.
- 제 1 항 또는 제 2 항에 있어서, 사이클로올레핀 공중합체의13C-NMR 스펙트럼이 29.3, 33.3, 40.8 및 49.8ppm에서 피크를 갖는 필름.
- 제 1 항 또는 제 2 항에 있어서, 단층인 필름.
- 제 1 항 또는 제 2 항에 있어서, 단축 배향된 필름.
- 제 1 항 또는 제 2 항에 있어서, 쌍축 배향된 필름.
- 제 1 항 또는 제 2 항에 있어서, 사이클로올레핀 공중합체가 일반식(Ⅰ) 및 (Ⅱ)의 반복단위와, 필요한 경우, (Ⅲ) 및/또는 (Ⅳ) 및/또는 (Ⅴ)의 반복단위를 포함하는 필름.상기식에서, 반복단위(Ⅲ)은 반복단위(Ⅰ)과 동일하지 않으며, R1내지 R5는 동일하거나 상이하고, H, 아릴, C1-C10알킬, C2-C10-알케닐, C3-C10-사이클로알케닐이며, R6내지 R14는 동일하거나, 상이하고, R1내지 R5에 대해 위에서 정의한 바와 같거나, 라디칼 쌍 R6/R7, R8/R9, R10/R11및/또는 R12/R13, 각각의 경우, 서로 결합하고, 이들이 결합된 탄소원자와 함께 C4-C10-사이클로 알킬 또는 C4-C10-사이클로알케닐 라디칼[이때, 이들 라디칼은 다시 -C(R1, R2)-라디칼(여기서, R1및 R2는 R1내지 R5에 대해 위에서 정의한 바와 같다)에 의해 가교될 수 있다]을 형성한다.
- 제 7 항에 있어서, R1, R2, R3, R4및 R5가 수소인 필름.
- 제 1 항 또는 제 2 항에 있어서, 사이클로올레핀 공중합체가 메탈로센 촉매시스템을 사용하여 제조되는 필름.
- 제 1 항 또는 제 2 항에 있어서, 사이클로올레핀 공중합체의 유리전이온도가 50 내지 250℃, 바람직하게는 80 내지 200℃인 필름.
- 제 1 항 또는 제 2 항에 있어서, 사이클로올레핀 공중합체의 점도수가 25 내지 500ml/g, 바람직하게는 35 내지 200ml/g인 필름.
- 제 1 항 또는 제 2 항에 있어서, 필름의 중량을 기준으로 하여, 불활성 입자를 0 내지 2중량% 포함하는 필름.
- 제 1 항 내지 12항 중의 어느 한 항에서 청구한 필름의 커패시터 유전체로서의 용도.
- 제 1 항 내지 제 12 항 중의 어느 한 항에서 청구한 필름의 전기 절연물로서의 용도.
- 제 1 항 내지 제 12 항 중의 어느 한 항에서 청구한 필름의 팩키징 필름으로서의 용도.
- 제 1 항 내지 제 12 항 중의 어느 한 항에서 청구한 필름의 재생 필름으로서의 용도.
- 제 1 항 내지 제 12 항 중의 어느 한 항에서 청구한 필름의 LCD 셀용 디스플레이 윈도우로서의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4304308.9 | 1993-02-12 | ||
DE4304308A DE4304308A1 (de) | 1993-02-12 | 1993-02-12 | Steife Cycloolefincopolymer-Folie |
Publications (2)
Publication Number | Publication Date |
---|---|
KR940019772A true KR940019772A (ko) | 1994-09-15 |
KR100287603B1 KR100287603B1 (ko) | 2001-04-16 |
Family
ID=6480347
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019940002496A KR100287603B1 (ko) | 1993-02-12 | 1994-02-12 | 강성사이클로올레핀공중합체필름 |
Country Status (10)
Country | Link |
---|---|
US (1) | US5534606A (ko) |
EP (1) | EP0610816B1 (ko) |
JP (1) | JP3539999B2 (ko) |
KR (1) | KR100287603B1 (ko) |
CN (1) | CN1053207C (ko) |
AU (1) | AU670653B2 (ko) |
CA (1) | CA2115190C (ko) |
DE (2) | DE4304308A1 (ko) |
MX (1) | MX9401120A (ko) |
TW (1) | TW304966B (ko) |
Cited By (1)
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KR100576117B1 (ko) * | 1998-12-04 | 2006-08-30 | 삼성전자주식회사 | 액정표시장치용 픽셀 구동 시스템 |
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DE4425408A1 (de) | 1994-07-13 | 1996-01-18 | Hoechst Ag | Cycloolefinpolymere |
JP3534127B2 (ja) * | 1995-01-20 | 2004-06-07 | 日本ゼオン株式会社 | ノルボルネン系付加型共重合体 |
DE19510086A1 (de) * | 1995-03-20 | 1996-09-26 | Hoechst Ag | Siegelfähige Polyolefin-Mehrschichtfolie mit partikelförmigen Hohlkörpern, Verfahren zu ihrer Herstellung und ihre Verwendung |
EP0745637A1 (de) * | 1995-05-31 | 1996-12-04 | Hoechst Aktiengesellschaft | Biaxial orientierte Polypropylenfolie mit hohem Flächenmodul |
DE19539093A1 (de) | 1995-10-20 | 1997-04-24 | Hoechst Ag | Metallisierte Polyolefinfolie |
DE19647954A1 (de) * | 1996-11-20 | 1998-06-04 | Hoechst Ag | Biaxial orientierte Folie aus cycloolefinischen Polymeren, Verfahren zu deren Herstellung und deren Verwendung |
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US6800340B1 (en) | 1999-09-10 | 2004-10-05 | Renolit-Werke Gmbh | Use of plastic films for printing with organic inks in an inkjet process |
DE19943330C2 (de) * | 1999-09-10 | 2002-03-07 | Renolit Werke Gmbh | Mit organischen Tinten per Inkjet bedruckbare Folie |
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DE10121150A1 (de) * | 2001-04-30 | 2002-11-07 | Trespaphan Gmbh | Opake Folie aus PLA |
US7767131B2 (en) * | 2001-08-30 | 2010-08-03 | Bayer Technology Services Gmbh | Method for production of moulded bodies, in particular optical structures and use thereof |
US20030125662A1 (en) | 2002-01-03 | 2003-07-03 | Tuan Bui | Method and apparatus for providing medical treatment therapy based on calculated demand |
US7238164B2 (en) | 2002-07-19 | 2007-07-03 | Baxter International Inc. | Systems, methods and apparatuses for pumping cassette-based therapies |
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US20040219338A1 (en) * | 2003-05-01 | 2004-11-04 | Hebrink Timothy J. | Materials, configurations, and methods for reducing warpage in optical films |
US20050186373A1 (en) * | 2004-02-20 | 2005-08-25 | Honeywell International Inc. | Multilayer sheets and films composed of polypropylene and cyclic olefin copolymer |
US20060159888A1 (en) * | 2004-10-29 | 2006-07-20 | Hebrink Timothy J | Optical films incorporating cyclic olefin copolymers |
JP2008518280A (ja) * | 2004-10-29 | 2008-05-29 | スリーエム イノベイティブ プロパティズ カンパニー | 環状オレフィンコポリマーを組み入れた光学フィルム |
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US8394474B2 (en) * | 2005-04-07 | 2013-03-12 | Cryovac, Inc. | Sterilizable coextruded film for aseptic packaging |
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US8558964B2 (en) | 2007-02-15 | 2013-10-15 | Baxter International Inc. | Dialysis system having display with electromagnetic compliance (“EMC”) seal |
US7998115B2 (en) | 2007-02-15 | 2011-08-16 | Baxter International Inc. | Dialysis system having optical flowrate detection |
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US7731689B2 (en) | 2007-02-15 | 2010-06-08 | Baxter International Inc. | Dialysis system having inductive heating |
US8870812B2 (en) | 2007-02-15 | 2014-10-28 | Baxter International Inc. | Dialysis system having video display with ambient light adjustment |
KR101495346B1 (ko) * | 2007-04-27 | 2015-02-24 | 후지필름 가부시키가이샤 | 환형 올레핀 중합체, 광학 재료, 편광판 및 액정디스플레이 |
US20090123611A1 (en) * | 2007-11-09 | 2009-05-14 | Cryovac, Inc. | Printed sterilizable laminate for aseptic packaging |
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KR102525861B1 (ko) | 2015-08-03 | 2023-04-26 | 도레이 카부시키가이샤 | 올레핀계 적층 필름 및 필름 콘덴서 |
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Publication number | Priority date | Publication date | Assignee | Title |
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DE224538C (ko) * | ||||
DE241971C (ko) * | ||||
CA2010320C (en) * | 1989-02-20 | 2001-04-17 | Yohzoh Yamamoto | Sheet or film of cyclo-olefin polymer |
DE3922546A1 (de) * | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
EP0818472B2 (en) * | 1990-10-05 | 2009-07-29 | Idemitsu Kosan Co., Ltd. | Cyclic olefin copolymers, compositions and molded articles comprising the copolymers |
TW227005B (ko) * | 1990-11-14 | 1994-07-21 | Hoechst Ag | |
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DE59209354D1 (de) * | 1991-03-09 | 1998-07-09 | Targor Gmbh | Verfahren zur Herstellung chemisch einheitlicher Cycloolefincopolymere |
TW212809B (ko) * | 1991-09-03 | 1993-09-11 | Hoechst Ag |
-
1993
- 1993-02-12 DE DE4304308A patent/DE4304308A1/de not_active Withdrawn
-
1994
- 1994-02-03 DE DE59409024T patent/DE59409024D1/de not_active Expired - Lifetime
- 1994-02-03 EP EP94101640A patent/EP0610816B1/de not_active Expired - Lifetime
- 1994-02-08 CN CN94101361A patent/CN1053207C/zh not_active Expired - Fee Related
- 1994-02-08 CA CA002115190A patent/CA2115190C/en not_active Expired - Fee Related
- 1994-02-10 AU AU55049/94A patent/AU670653B2/en not_active Ceased
- 1994-02-10 JP JP01648494A patent/JP3539999B2/ja not_active Expired - Fee Related
- 1994-02-11 MX MX9401120A patent/MX9401120A/es unknown
- 1994-02-12 KR KR1019940002496A patent/KR100287603B1/ko not_active IP Right Cessation
- 1994-02-14 US US08/195,084 patent/US5534606A/en not_active Expired - Lifetime
- 1994-02-18 TW TW083101321A patent/TW304966B/zh active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100576117B1 (ko) * | 1998-12-04 | 2006-08-30 | 삼성전자주식회사 | 액정표시장치용 픽셀 구동 시스템 |
Also Published As
Publication number | Publication date |
---|---|
EP0610816B1 (de) | 1999-12-29 |
AU5504994A (en) | 1994-08-18 |
EP0610816A2 (de) | 1994-08-17 |
AU670653B2 (en) | 1996-07-25 |
DE4304308A1 (de) | 1994-08-18 |
CN1099774A (zh) | 1995-03-08 |
CA2115190C (en) | 2004-09-21 |
US5534606A (en) | 1996-07-09 |
CA2115190A1 (en) | 1994-08-13 |
JPH06336526A (ja) | 1994-12-06 |
DE59409024D1 (de) | 2000-02-03 |
TW304966B (ko) | 1997-05-11 |
JP3539999B2 (ja) | 2004-07-07 |
MX9401120A (es) | 1994-08-31 |
CN1053207C (zh) | 2000-06-07 |
KR100287603B1 (ko) | 2001-04-16 |
EP0610816A3 (en) | 1995-10-11 |
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