KR940014476A - 리튬-기본 염 함유 연질 포움, 이것의 제조방법, 및 이것을 위한 폴리올 조성물 - Google Patents

리튬-기본 염 함유 연질 포움, 이것의 제조방법, 및 이것을 위한 폴리올 조성물 Download PDF

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Publication number
KR940014476A
KR940014476A KR1019930027755A KR930027755A KR940014476A KR 940014476 A KR940014476 A KR 940014476A KR 1019930027755 A KR1019930027755 A KR 1019930027755A KR 930027755 A KR930027755 A KR 930027755A KR 940014476 A KR940014476 A KR 940014476A
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KR
South Korea
Prior art keywords
parts
foam
carboxylic acid
weight
lithium salt
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KR1019930027755A
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English (en)
Inventor
엘. 발로피 발레리
엘. 크리스만 도날드
Original Assignee
로버트 엠. 쇼우
바스프 코포레이션
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Application filed by 로버트 엠. 쇼우, 바스프 코포레이션 filed Critical 로버트 엠. 쇼우
Publication of KR940014476A publication Critical patent/KR940014476A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/225—Catalysts containing metal compounds of alkali or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/125—Water, e.g. hydrated salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0033—Foam properties having integral skins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0066—≥ 150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Cell Electrode Carriers And Collectors (AREA)

Abstract

본 발명은 C2내지 C7을 갖는 지방족 또는 지환족의 포화 또는 불포화 카르복실산의 리튬염을 함유하는 폴리올 조성물, 및 이에 의해 생성된 개방 셀 구조를 갖는 연질 폴리우레탄 포움에 관한 것이다.

Description

리튬-기본 염 함유 연질 포움, 이것의 제조방법, 및 이것을 위한 폴리올 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (a) 1.5 내지 3의 평균 작용기성, 750 내지 3,500의 당량, 및 15 내지 100의 히드록실기를 갖는, 2개 이상의 이소시아네이트 반응성 수소를 갖는 폴리올 화합물 ; (b) 하나 이상의 발포제 ; (c) 우레탄 조촉매 ; (d) 사슬 연장제 ; 및 (e) 폴리올 조성물 100중량부에 대해 0.1 내지 2.0중량부의 C2내지 C7을 갖는 지방족 또는 지환족의 포화 또는 불포화 카르복실산의 리튬염으로 구성된 폴리올 조성물.
  2. (a) 2개 이상의 반응성 수소를 갖는 폴리올 화합물 ; (b) 하나이상의 발포제 ; (c) 폴리우레탄 조촉매 ; (d) 사슬 연장제 ; 및 (e) C2내지 C7을 갖는 지방족 또는 지환족의 포화 또는 불포화 카르복실산으로 구성된 폴리올 화합물과 방향족 유기 폴리이소시아네이트의 반응 생성물로 이루어지는 연질 폴리우레탄 포움.
  3. 제2항에 있어서, 리튬염의 양이 폴리올 조성물 100중량부에 대해 0.1중량부 내지 2.0중량부임을 특징으로 하는 연질 포움.
  4. 제2항에 있어서, 카르복실산이 아세트산, 프로피온산 및 부티르산으로 구성된 군으로부터 선택됨을 특징으로 하는 연질 포움.
  5. 제2항에 있어서, 발포제가 물로 구성됨을 특징으로 하는 연질 포움.
  6. 제2항에 있어서, 포움이 슬랩 스톡 포움임을 특징으로 하는 연질 포움.
  7. 제2항에 있어서, 포움이 인티그럴 스킨 포움임을 특징으로 하는 연질 포움.
  8. 개방 또는 밀폐 예열 모울드에서, 방향족 유기 폴리이소시아네이트를, (a) 2개 이상의 이소시아네이트 반응성 수소, 750 내지 4000의 당량, 및 1.5 내지 3의 작용기성을 갖는 폴리올 화합물 ; (b) 하나이상의 발포제 ; (c) 폴리우레탄-조 촉매 ; (d) 사슬 연장제 ; 및 (e) C2내지 C7을 갖는 지방족 또는 지환족의 포화 또는 불포화 카르복실산의 리튬염으로 구성된 폴리올 조성물과 반응시키는 것으로 이루어지는, 연질 폴리우레탄 포움의 제조방법.
  9. 제8항에 있어서, 리튬염의 양이 폴리올 조성물 100중량부에 대해 0.1 내지 2.0중량부이고, 카르복실산이 아세트산 및 부티르산으로 구성된 군으로부터 선택됨을 특징으로 하는 방법.
  10. 제8항에 있어서, 발포제가 물로 구성됨을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930027755A 1992-12-14 1993-12-14 리튬-기본 염 함유 연질 포움, 이것의 제조방법, 및 이것을 위한 폴리올 조성물 KR940014476A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/990,405 US5324754A (en) 1992-12-14 1992-12-14 Lithium-based salts in flexible foams
US7/990,405 1992-12-14

Publications (1)

Publication Number Publication Date
KR940014476A true KR940014476A (ko) 1994-07-18

Family

ID=25536118

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930027755A KR940014476A (ko) 1992-12-14 1993-12-14 리튬-기본 염 함유 연질 포움, 이것의 제조방법, 및 이것을 위한 폴리올 조성물

Country Status (9)

Country Link
US (1) US5324754A (ko)
EP (1) EP0603597B1 (ko)
JP (1) JPH06322062A (ko)
KR (1) KR940014476A (ko)
AT (1) ATE166080T1 (ko)
CA (1) CA2111044A1 (ko)
DE (1) DE69318525T2 (ko)
DK (1) DK0603597T3 (ko)
ES (1) ES2115710T3 (ko)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19529406A1 (de) * 1995-08-10 1997-02-13 Henkel Kgaa Polyurethan-Prepolymer mit NCO-Gruppen
UA61089C2 (uk) * 1996-11-08 2003-11-17 Хантсмен Ай Сі Ай Кемікалз, Ллс Спосіб одержання жорстких та еластичних пінополіуретанових матеріалів
US5958990A (en) * 1998-11-23 1999-09-28 Air Products And Chemicals, Inc. Trimerization catalysts for making polyisocyanurate foams
DE10142296C1 (de) * 2001-08-29 2003-02-13 Bayer Ag Polyurethanelastomere, Verfahren zu ihrer Herstellung und ihre Verwendung
US6825238B2 (en) * 2003-01-29 2004-11-30 Air Products And Chemicals, Inc. Low acid organometallic catalyst for the production of flexible, semi-flexible and rigid polyurethane foams
CN101842404B (zh) * 2007-08-27 2014-06-18 陶氏环球技术有限责任公司 具有铋化合物的基于天然油的柔性聚氨酯泡沫的催化剂
PT2209827T (pt) * 2007-11-14 2016-08-31 Basf Se Poliuretanos espumados, possuindo propriedades melhoradas de resistência a flexões repetidas
WO2009065826A1 (de) * 2007-11-19 2009-05-28 Basf Se Verwendung von chlorierten kohlenwasserstoffen und chorierten alkylphosphaten bei der herstellung von polyurethanintegralschaumstoffen
US10266635B2 (en) 2012-07-27 2019-04-23 Basf Se Polyurethane foams comprising phosphorus compounds
EP2690118A1 (de) * 2012-07-27 2014-01-29 Basf Se Polyurethane enthaltend Phosphorverbindungen
JP2018509490A (ja) * 2015-01-22 2018-04-05 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ Ｌｉ／Ｂｉ触媒に基づくコーティング材料系

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2894919A (en) * 1954-08-02 1959-07-14 Lockheed Aircraft Corp Flexible resilient cellular polyurethane resin products
BE589099A (ko) * 1959-03-31
BE757421A (fr) * 1969-10-14 1971-04-13 Scott Paper Co Mousse de polyurethane incombustible
US4107069A (en) * 1975-07-02 1978-08-15 M&T Chemicals Inc. Storage-stable precursors for rigid polyurethane foams
US4250005A (en) * 1976-08-20 1981-02-10 Scott Paper Company Radiation cross-linked polyurethane foams
US4256847A (en) * 1979-10-17 1981-03-17 Mooney Chemicals, Inc. Rigid polyurethane foam process using lithium/zinc catalyst

Also Published As

Publication number Publication date
US5324754A (en) 1994-06-28
ES2115710T3 (es) 1998-07-01
ATE166080T1 (de) 1998-05-15
JPH06322062A (ja) 1994-11-22
DK0603597T3 (da) 1998-10-07
DE69318525T2 (de) 1998-09-10
CA2111044A1 (en) 1994-06-15
DE69318525D1 (de) 1998-06-18
EP0603597B1 (en) 1998-05-13
EP0603597A1 (en) 1994-06-29

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