KR940011509A - 라디칼 그래프팅에 의해 제조한 사이클릭 카보닐 함유 화합물 - Google Patents

라디칼 그래프팅에 의해 제조한 사이클릭 카보닐 함유 화합물 Download PDF

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KR940011509A
KR940011509A KR1019930023315A KR930023315A KR940011509A KR 940011509 A KR940011509 A KR 940011509A KR 1019930023315 A KR1019930023315 A KR 1019930023315A KR 930023315 A KR930023315 A KR 930023315A KR 940011509 A KR940011509 A KR 940011509A
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제임스 브로이스 스탠리
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앤 허쉬코위츠 제이콥슨
엑손 리써치 앤드 엔지니어링 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
    • C07C49/747—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
    • C07D239/60—Three or more oxygen or sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Pyrane Compounds (AREA)
  • Pyrrole Compounds (AREA)
  • Quinoline Compounds (AREA)
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Abstract

라디칼 그래프팅에 의해 제조한 사이클릭 카보닐 함유 화합물 따라서, 신규한 카보닐 함유 조성물들은 자유 라디칼 개시제의 존재하에 포화 탄화수소, 치환된 포화 탄화수소, 중합체 및 이들의 혼합물로 이루어진 군 중에서 선택된 화합물을 하기 일반식을 갖는 카보닐 함유 화합물 또는 이들의 혼합물과 접촉 반응시킴으로써 제조된다 :
상기식에서, Q는 HOH, MeOH, EtOH 또는 n-BuOH이고, n은 0, 1 또는 그 이상이며, X 및 Y는 독립적으로 CH2및 C=0로 이루어진 군 중에서 선택되고, W는 독립적으로 CH2, C=0, 0, NH, CMe2, C=N-알킬 및 N-알킬(이때, 알킬은 C1내지 C18이다)로 이루어진 군 중에서 선택되며, U와 V는 독립적으로 W와 동일한 그룹중에서 선택되고, 종속적으로는 함께 결합된 U와 V가 1,2-페닐렌, 1,8-나프탈렌-디일 및 1,2-나프탈렌-디일 중 하나를 형성하도록 선택된다.

Description

라디칼 그래프팅에 의해 제조한 사이클릭 카보닐 함유 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 자유 라디칼 개시제의 존재하에, 포화 탄화수소, 치환된 포화 탄화수소, 중합체 및 이들의 혼합물로 이루어진 군 중에서 선택된 화합물을 하기 일반식을 갖는 카보닐 함유 화합물 또는 이들의 혼합물과 접촉 반응시킴으로써 형성된 카보닐 함유 조성물 :
    상기식에서, Q는 HOH, MeOH, EtOH 또는 n-BuOH이고, n은 0, 1 또는 그 이상이며, X 및 Y는 독립적으로 CH2및 C=0로 이루어진 군 중에서 선택되고, W는 독립적으로 CH2, C=0, 0, NH, CMe2, C=N-알킬 및 N-알킬(이때, 알킬은 C1내지 C18이다)로 이루어진 군 중에서 선택되며, U와 V는 독립적으로 W와 동일한 그룹중에서 선택되고, 종속적으로는 함께 결합된 U와 V가 1,2-페닐렌, 1,8-나프탈렌-디일 및 1,2-나프탈렌-디일 중 하나를 형성하도록 선택되나, 단, X, Y, U, V 및 W중 적어도 하나는 C=O이다.
  2. 제1항에 있어서, 상기 접촉 반응 온도가 약 90℃ 내지 약 220℃ 인 조성물.
  3. 제2항에 있어서, 상기 탄화수소가 약 Cl0내지 약 C50인 조성물.
  4. 제2항에 있어서, 상기 탄화수소가 약 500 내지 약 천만 범위의 Mn을 갖는 중합체인 조성물.
  5. 제3항 또는 제4항에 있어서, 상기 카보닐 화합물이 하기 일반식을 갖는 조성물 :
    상기식에서, Q, n, X, Y, W, U 및 V는 제1항에서 정의한 바와 같다.
  6. 제3항 또는 제4항에 있어서, 상기 카보닐 화합물이 하기 일반식을 갖는 조성물 :
    상기식에서, Q, n, X, Y, W, U 및 V는 제1항에서 정의한 바와 같다.
  7. (a)탄화수소 라디칼 및 (b)하기 일반식으로 이루어진 군 중에서 선택된 사이클릭 라디칼을 포함하는 조성물 :
    상기식에서, X 및 Y는 독립적으로 CH2및 C=0로 이루어진 군 중에서 선택되고, W는 독립적으로 CH2, C=0, 0, NH, CMe2, C=N-알킬 및 N-알킬(이때, 알킬은 C1내지 C18이다)로 이루어진 군 중에서 선택되며, U와 V는 독립적으로 W와 동일한 그룹중에서 선택되고, 종속적으로는 함께 결합된 U와 V가 1,2-페닐렌, 1,8-나프탈렌-디일 및 1,2-나프탈렌-디일 중 하나를 형성하도록 선택되나, 단, X, Y, U, V 및 W중 적어도 하나는 C=O이다.
  8. 제7항에 있어서, 탄화수소 라디칼이 포화 탄화수소, 치환된 포화 탄화수소 및 중합체로 이루어진 군 중에서 선택되는 조성물.
  9. 제8항에 있어서, 치환된 탄화수소가 OH, 0[CH2CH20]xH(이때, x는 1 내지 10이다), Cl, CN, COOH, COO알킬(이때, 알킬은 Cl내지 Cl8이다), 아릴 및 에틸렌으로 이루어진 군 중에서 선택된 적어도 하나의 작용기를 갖는 조성물.
  10. 제8항에 있어서, 중합체가 약 500 내지 천만 범위의 수평균 분자량을 가지며, 폴리올레핀, 폴리알킬 에스테르, 폴리스티렌, 폴리아크릴레이트, 폴리비닐 할라이드 및 에스테르로 이루어진 군 중에서 선택되는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930023315A 1992-11-05 1993-11-04 라디칼그래프팅에의해제조한사이클릭카보닐함유화합물 KR100249986B1 (ko)

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US972,270 1992-11-05
US07/972,270 US5288811A (en) 1992-11-05 1992-11-05 Cyclic carbonyl containing compounds via radical grafting

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US (1) US5288811A (ko)
EP (1) EP0596671B1 (ko)
JP (1) JPH06219988A (ko)
KR (1) KR100249986B1 (ko)
BR (1) BR9304405A (ko)
CA (1) CA2102476A1 (ko)
DE (1) DE69320912T2 (ko)

Cited By (1)

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KR102244399B1 (ko) * 2020-07-20 2021-04-26 경해정공 주식회사 케이블 덕트 제조장치

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US5646098A (en) * 1990-07-23 1997-07-08 Exxon Chemical Patents Inc Carbonyl containing compounds and their derivatives as multi-functional fuel and lube additives
CA2176706C (en) * 1993-12-03 2006-01-24 Stanley J. Brois Carbonyl containing compounds
DE19854573A1 (de) * 1998-11-26 2000-05-31 Basf Ag Verfahren zur Nachvernetzung von Hydrogelen mit 2-Oxo-tetrahydro-1,3-oxazinen
EP1257812B1 (en) * 1999-11-30 2009-04-01 Electric Power Research Institute Method for the photometric detection of ions using capillary electrophoresis probes, method for the manufacturing and usage of said probes
US7550065B2 (en) * 2005-04-21 2009-06-23 Lyondell Chemical Technology, L.P. Method for recovering solvents

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US3554973A (en) * 1963-09-12 1971-01-12 Monsanto Co Modifying halogenated cycloalkenyl ketone containing alpha olefin polymers
JPS58444B2 (ja) * 1979-01-19 1983-01-06 三枝 武夫 大環状ビス↓−１，３↓−ジケトンを有するスチレン系重合体およびその製造方法
JPS5834180B2 (ja) * 1979-04-28 1983-07-25 岩夫 田伏 重金属捕促剤およびその製造方法
NL8301035A (nl) * 1983-03-23 1984-10-16 Organon Teknika Bv Macromoleculair materiaal met carbonylgroepen geschikt als sorbent voor stikstofverbindingen.
DE4008218A1 (de) * 1990-03-15 1991-09-19 Huels Chemische Werke Ag Formmassen auf basis von thermoplastisch verarbeitbaren, funktionalisierten, olefinischen polymeren und polyamiden
US5057564A (en) * 1990-07-23 1991-10-15 Exxon Research And Engineering Company Cyclic carbonyl containing polymers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102244399B1 (ko) * 2020-07-20 2021-04-26 경해정공 주식회사 케이블 덕트 제조장치

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BR9304405A (pt) 1994-07-05
DE69320912T2 (de) 1999-02-11
DE69320912D1 (de) 1998-10-15
US5288811A (en) 1994-02-22
JPH06219988A (ja) 1994-08-09
CA2102476A1 (en) 1994-05-06
EP0596671B1 (en) 1998-09-09
EP0596671A2 (en) 1994-05-11
KR100249986B1 (ko) 2000-03-15
EP0596671A3 (en) 1994-11-23

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