KR940006468A - 포스포릴옥시피라졸 유도체를 기본으로 하는 제초제 - Google Patents
포스포릴옥시피라졸 유도체를 기본으로 하는 제초제 Download PDFInfo
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- KR940006468A KR940006468A KR1019930017122A KR930017122A KR940006468A KR 940006468 A KR940006468 A KR 940006468A KR 1019930017122 A KR1019930017122 A KR 1019930017122A KR 930017122 A KR930017122 A KR 930017122A KR 940006468 A KR940006468 A KR 940006468A
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- Prior art keywords
- alkyl
- cyano
- chlorine
- fluorine
- phosphoryloxypyrazole
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- -1 phosphoryloxypyrazole Chemical class 0.000 title claims abstract 65
- 239000004009 herbicide Substances 0.000 title claims abstract 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 7
- 239000001257 hydrogen Substances 0.000 claims abstract 7
- 150000002431 hydrogen Chemical class 0.000 claims abstract 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract 6
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 6
- 239000001301 oxygen Substances 0.000 claims abstract 6
- 229910052717 sulfur Chemical group 0.000 claims abstract 6
- 239000011593 sulfur Chemical group 0.000 claims abstract 6
- 125000004414 alkyl thio group Chemical group 0.000 claims abstract 4
- 125000003118 aryl group Chemical group 0.000 claims abstract 4
- 125000000547 substituted alkyl group Chemical group 0.000 claims abstract 4
- 125000003545 alkoxy group Chemical group 0.000 claims abstract 3
- 125000000217 alkyl group Chemical group 0.000 claims abstract 3
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims abstract 2
- 125000004457 alkyl amino carbonyl group Chemical group 0.000 claims abstract 2
- 125000003282 alkyl amino group Chemical group 0.000 claims abstract 2
- 125000004644 alkyl sulfinyl group Chemical group 0.000 claims abstract 2
- 125000001691 aryl alkyl amino group Chemical group 0.000 claims abstract 2
- 125000004663 dialkyl amino group Chemical group 0.000 claims abstract 2
- 125000004473 dialkylaminocarbonyl group Chemical group 0.000 claims abstract 2
- 229910052736 halogen Inorganic materials 0.000 claims abstract 2
- 150000002367 halogens Chemical class 0.000 claims abstract 2
- 229910052731 fluorine Inorganic materials 0.000 claims 11
- 229910052801 chlorine Inorganic materials 0.000 claims 10
- 239000000460 chlorine Chemical group 0.000 claims 10
- 239000011737 fluorine Substances 0.000 claims 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 9
- 229910052794 bromium Inorganic materials 0.000 claims 7
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 6
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical group FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 6
- 125000004093 cyano group Chemical group *C#N 0.000 claims 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 6
- 125000001153 fluoro group Chemical group F* 0.000 claims 5
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 5
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 5
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 5
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 4
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 4
- 241000196324 Embryophyta Species 0.000 claims 3
- 241000238631 Hexapoda Species 0.000 claims 3
- 125000006125 ethylsulfonyl group Chemical group 0.000 claims 3
- 230000002363 herbicidal effect Effects 0.000 claims 3
- 229910052740 iodine Inorganic materials 0.000 claims 3
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 claims 3
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 claims 2
- 125000004890 (C1-C6) alkylamino group Chemical group 0.000 claims 2
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 claims 2
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 2
- 125000004799 bromophenyl group Chemical group 0.000 claims 2
- 125000004775 chlorodifluoromethyl group Chemical group FC(F)(Cl)* 0.000 claims 2
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 claims 2
- 125000000068 chlorophenyl group Chemical group 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 125000006003 dichloroethyl group Chemical group 0.000 claims 2
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 claims 2
- 125000006001 difluoroethyl group Chemical group 0.000 claims 2
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 claims 2
- 125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 claims 2
- 125000001207 fluorophenyl group Chemical group 0.000 claims 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 2
- 239000011630 iodine Substances 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 claims 2
- 125000006337 tetrafluoro ethyl group Chemical group 0.000 claims 2
- 125000003944 tolyl group Chemical group 0.000 claims 2
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 claims 2
- SYKNUAWMBRIEKB-UHFFFAOYSA-N [Cl].[Br] Chemical group [Cl].[Br] SYKNUAWMBRIEKB-UHFFFAOYSA-N 0.000 claims 1
- HXELGNKCCDGMMN-UHFFFAOYSA-N [F].[Cl] Chemical compound [F].[Cl] HXELGNKCCDGMMN-UHFFFAOYSA-N 0.000 claims 1
- 125000000440 benzylamino group Chemical group [H]N(*)C([H])([H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229920005556 chlorobutyl Polymers 0.000 claims 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 claims 1
- 125000004802 cyanophenyl group Chemical group 0.000 claims 1
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 claims 1
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 claims 1
- 125000005817 fluorobutyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000003784 fluoroethyl group Chemical group [H]C([H])(F)C([H])([H])* 0.000 claims 1
- 125000005816 fluoropropyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])* 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000004458 methylaminocarbonyl group Chemical group [H]N(C(*)=O)C([H])([H])[H] 0.000 claims 1
- 125000006216 methylsulfinyl group Chemical group [H]C([H])([H])S(*)=O 0.000 claims 1
- 125000005740 oxycarbonyl group Chemical group [*:1]OC([*:2])=O 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 125000006000 trichloroethyl group Chemical group 0.000 claims 1
- 125000004205 trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 claims 1
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 claims 1
- 125000001889 triflyl group Chemical group FC(F)(F)S(*)(=O)=O 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6503—Five-membered rings
- C07F9/65031—Five-membered rings having the nitrogen atoms in the positions 1 and 2
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
본 발명은 다음 일반식(Ⅰ)의 신규 및 공지 포스포릴옥시피라졸 유도체의 제초제로서의 용도와 다음 일반식 (ⅠA1)의 신규 물질 및 그의 농약으로서의 용도에 관한 것이다.
상기식에서, Q는 산소 또는 황을 나타내고, R1은 각 경우에 임의로 치환된 알킬 또는 아릴을 나타내며, R2및 R3는 동일하거나 상이하고 서로 독립적으로 수소, 시아노, 니트로, 카바모일, 카복실 또는 할로겐을 나타내거나, 각 경우에 임의로 치환된 알킬, 알콕시, 알킬티오, 알킬설피닐, 아킬설포닐, 알콕시카보닐, 알킬아미노카보닐, 디알킬 아미노카보닐 또는 아릴을 나타내며, R4는 알킬을 나타내고, R5는 알킬티오, 알킬아미노, 아르알킬아미노 또는 디알킬아미노를 나타내며, A1, A2, A3, A4, 및 A5는 명세서에 기재된 바와 같다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 일반식(Ⅰ)의 포스포릴옥시피라졸 유도체를 적어도 하나 함유함을 특징으로 하는 제초제.상기식에서, Q는 산소 또는 황을 나타내고, R1은 각 경우에 임의로 치환된 알킬 또는 아릴을 나타내며, R2및 R3는 동일하거나 상이하고 서로 독립적으로 수소, 시아노, 니트로, 카바모일, 카복실 또는 할로겐을 나타내거나, 각 경우에 임의로 치환된 알킬, 알콕시, 알킬티오, 알킬설피닐, 아킬설포닐, 알콕시카보닐, 알킬아미노카보닐, 디알킬 아미노카보닐 또는 아릴을 나타내며, R4는 알킬을 나타내고, R5는 알킬티오, 알킬아미노, 아르알킬아미노 또는 디알킬아미노를 나타낸다.
- 제1항에 있어서, Q는 산소 또는 황을 나타내고, R1은 불소, 염소 또는 시아노에 의해 임의로 치환되는 C1-C6-알킬을 나타내거나, 불소, 염소, 브롬, 시아노, C1-C4-알킬 또는 C1-C4-알콕시에 의해 임의로 치환되는 페닐을 나타내며, R2및R3는 동일하거나 상이하고 서로 독립적으로 수소, 시아노, 니트로, 카보모일, 카복실, 불소, 염소, 브롬 또는 요오드를 나타내거나, 각 경우에 불소ㅡ 염소, 시아노, C1-C4-알콕시 또는 C1-C4-알콕시카보닐에 의해 임의로 치환되는 C1-C6-알킬, C1-C6-알콕시 C1-C6-알킬티오, C1-C6-알킬설피닐 C1-C6-알킬설포닐, C1-C6-알콕시카보닐, C1-C6-알킬아미노카보닐, 디-(C1-C4-알킬)-아미노카보닐 또는 페닐을 나타내며, R4는 C1-C6-알킬을 나타내고, R5는 C1-C6-알킬티오, C1-C6-알킬아미노, 벤질아미노 또는 디-(C1-C4-알킬)-아미노를 나타냄을 특징으로 하는, 일반식(Ⅰ)의 포스포릴옥시피라족 유도체를 적어도 하나 함유함을 특징으로 하는 제초제.
- 제1항에 있어서, Q가 산소 또는 황을 나타내고, R1은 메틸, 에틸, n- 또는 i-프로필, n-,i-,s- 또는 t-부틸, 시아노에틸, 시아노프로필, 시아노부틸, 페닐, 플루오로페닐, 클로로페닐, 브로모페닐, 메틸페닐 또는 메톡시페닐을 나타내며, R2는 수소, 시아노, 니트로, 카바모일, 불소, 염소, 브롬, 요오드, 메일, 에틸, n-또는 i-프로필, n-,i-,s- 또는 t-부틸, 트리플루오로메틸, 메톡시, 에톡시, n- 또는 i-프로폭시, n-,i-,s- 또는 t-부톡시, 메틸티오, 에틸티오, n-또는 i-프로필티오, n-,i-,s- 또는 t-부틸티오, 메틸설피닐, 에틸설피닐, n-또는 i-프로필설피닐, n-,i-,s- 또는 t-부틸설피닐, 메틸설포닐, 에틸설포닐, n-또는 i-프로필설포닐, n-,i-,s- 또는 t-부틸설포닐, 메톡시카보닐, 에톡시카보닐, n-또는 i-프로폭시카보닐, n-,i- 또는 s-부톡시카보닐, 메틸아미노카보닐, 에틸아미노카보닐, n-또는 i-프로필아미노보닐, n-,i- 또는 s- 부틸아미노카보닐, 디메틸아미노카보닐, 디메틸아미노카보닐 또는 페닐을 나타내고, R3는 수소, 시아노,니트로, 카바모일, 카복실, 불소, 염소, 브롬, 요오드, 메틸, 에틸, 트리플루오로메틸, 메톡시, 에톡시, 메틸디오, 에틸티오, 메틸설피닐, 에틸설피닐, 메틸설피닐, 에틸설포닐, 메톡시카보닐, 에톡시카보닐, 디플루오로메톡시, 트리플루오로메톡시, 디플루오로메틸티오, 트리플루오로메틸티오, 디플루오로메틸설피닐, 트리플루오로메틸설피닐, 디플루오로메틸설포닐 또는 트리메틸설포닐을 나타내며, R4는 메틸, 에틸 n-또는 i-프로필, n-,i-,s- 또는 t-부틸을 나타내고, R5는 메틸티오, 에틸티오, n-또는 i-프로필티오, n-,i-,s- 또는 t-부틸티오, 메틸아미노, 에틸아미노, n-또는 i-프로필아미노, n-,i-,s- 또는 t-부틸아미노, 디메틸아미노 또는 디에틸아미노를 나타냄을 특징으로 하는, 일반식(Ⅰ)의 포스포릴옥시피라졸 유도체를 적어도 하나 함유함을 특징으로 하는 제초제.
- 일반식 (Ⅰ)의 포스포릴옥시피라졸 유도체를 잡초 및/또는 그들의 환경에 적용시킴을 특징으로 하는 잡초의 방제방법.
- 잡초를 방제하기 위한 일반식 (Ⅰ)의 포스포릴옥시피라졸 유도체의 용도.
- 제1항에 따르는 일반식 (Ⅰ)의 포스포릴옥시피라졸 유도체를 중량제 및/또는 계면활성 물질과 혼합함을 특징으로 하는 제초제의 제조방법.
- 일반식 (ⅠA1)의 포스포릴옥시피라졸 유도체.상기식에서, Q는 산소 또는 황을 나타내고, A1은 불소, 염소 또는 시아노에 의해 임의로 치환되는 C1-C6-알킬 또는 불소, 염소, 브롬, 시아노, C1-C4-알킬 또는 C1-C4-알콕시에 의해 임의로 치환되는 페닐을 나타내며, A2는 불소, 염소 브롬 또는 요오드에 의해 치환되는 C1-C6-알킬을 나타내고, A3는 수소, 시아노, 닌트로, 카바모일, 카복실, 불소, 염소,브롬 또는 요오드를 나타내거나. 각각 불소, 염소, 시아노, C1-C4-알콕시 또는 C1-C4-알콕시 카보닐에 의해 임의로 치환되는 C1-C6-알킬, C1-C6-알콕시 C1-C6-알킬티오, C1-C6-알킬설피닐 C1-C6-알킬설포닐, C1-C6-알콕시카보닐, C1-C6-알킬아미노카보닐, 디-(C1-C4-알킬)-아미노카보닐 또는 페닐을 나타내며, A4는 C1-C6-알킬을 나타내고, A5는 C1-C6-알킬티오, C1-C6-알킬아미노 또는 디-(C1-C4-알킬)-아미노를 나타낸다.
- 제7할에 있어서, Q가 산소 또는 황을 나타내고, A1은 메틸, 에틸, n- 또는 i-프로필, n-,i-,s- 또는 t-부틸, 시아노에틸, 시아노프로필, 시아노부틸, 페닐, 플루오로페닐, 클로로페닐, 브로모페닐, 메틸페닐 또는 메톡시페닐을 나타내며, A2는 플루오로메틸, 클로로메틸. 디플루오로메틸, 디콜로로메틸, 트리플루오로메틸,트리클로로메틸, 플루오로디클로로메틸, 클로로디플루오로메틸, 플루오로에틸, 클로로에틸, 디플루오로에틸, 디클로로에틸, 트리클로로메틸, 플루오로디클로로메틸, 클로로디플루오로메틸, 테트라플루오로에틸, 플루오로메틸, 클로로에틸, 디플루오로에틸, 디클로로에틸, 트리플루오로에틸, 트리클로로에틸, 플루오로디클로로에틸, 클로로디플루오로에틸, 테트라플루오로에틸, 펜타플루오로프로필, 핵사플루오로프로필, 플루오로부틸, 클로로부틸, 디플루오로부틸 또는 트리플루오로부틸(각 경우에 할로겐화 프로필 또는 부틸 래디칼은 직쇄 또는 측쇄이다)을 나타내고, A3는 수소, 시아노, 니트로, 카바모일, 카복실, 불소, 염소, 브롬, 요오드, 메틸, 에틸, 트리플루오로메틸, 메톡시, 에톡시, 메틸티오, 에틸티오, 메틸설피닐, 에틸설피닐, 메틸설포닐, 에틸설포닐, 메톡시카보닐, 에톡시카보닐, 디플루오로메톡시, 트리플루오로메톡시, 디플루오로메탈티오, 트리플루오로메탈티오, 디플루오로메틸설피닐, 트리플루오로메틸설피닐, 디플루오로메틸설포닐 또는 트리플루오로메틸설포닐을 나타내며, A4는 메일, 에틸, n-또는 i-프로필, n-,i-,s- 또는 t-부틸을 나타내고, A5는 메틸티오, 에틸티오, n-또는 i-프로필티오, n-,i-,s- 또는 t-부틸티오, 메틸아미노, 에틸아미노, n-또는 i-프로필아미노, n-,i-,s- 또는 t-부틸아미노, 디메틸아미노 또는 디에틸아미노를 나타냄을 특징으로 하는 일반식(ⅠA1)의 포스포릴옥시피라졸 유도체.
- 제7항 및 제8항에 따르는 일반식(ⅠA1)의 포스포릴옥시피라졸 유도체를 곤충 및/또는 그의 환경에 적용시킴을 특징으로 하는 곤충의 구제방법.
- 곤충을 구제하기 위한 제7항 및 8항에 따르는 일반식(ⅠA1)의 포스포릴옥시피라졸 유도체의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4229478 | 1992-09-03 | ||
| DEP4229478.9 | 1992-09-03 | ||
| DE4315384A DE4315384A1 (de) | 1992-09-03 | 1993-05-08 | Phosphoryloxypyrazolderivate |
| DEP4315384.4 | 1993-05-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR940006468A true KR940006468A (ko) | 1994-04-25 |
Family
ID=25918215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930017122A KR940006468A (ko) | 1992-09-03 | 1993-08-31 | 포스포릴옥시피라졸 유도체를 기본으로 하는 제초제 |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0588105A1 (ko) |
| JP (1) | JPH06192282A (ko) |
| KR (1) | KR940006468A (ko) |
| CN (1) | CN1084853A (ko) |
| DE (1) | DE4315384A1 (ko) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5922885A (en) * | 1995-12-19 | 1999-07-13 | Rhone-Poulenc Inc. | Pesticidal 1-arylpyrazole derivatives |
| US5817688A (en) * | 1995-12-19 | 1998-10-06 | Rhone-Poulenc Inc. | Pesticidal 1-arylpyrazole derivatives |
| KR100375594B1 (ko) * | 1995-12-28 | 2003-04-23 | 주식회사 엘지생명과학 | 티아(디아)졸아세트산의반응성티오포스페이트유도체의신규한제조방법 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1235928B (de) * | 1960-01-25 | 1967-03-09 | Dow Chemical Co | Verfahren zur Herstellung von biozid wirksamen Phosphor- bzw. Thiophosphorsaeureesteramiden |
| US3010969A (en) * | 1960-01-25 | 1961-11-28 | Dow Chemical Co | O-pyrazolyl o-lower alkyl phosphoramidates and phosphoramidothioates |
| CH513925A (de) * | 1968-08-07 | 1971-10-15 | Bayer Ag | Verfahren zur Herstellung von Thionophosphonsäureestern |
| IT1090364B (it) * | 1977-12-23 | 1985-06-26 | Montedison Spa | Esteri fosforici e tiofosforici di 5(3) idrossipirazoli sostituiti in posizione 3(5) insetticidi |
| NL7812293A (nl) * | 1977-12-23 | 1979-06-26 | Montedison Spa | Fosforzuur en thiofosforzuuresters van 5(3)-hydroxypyrazolen met insecticide werking. |
| US4643757A (en) * | 1985-05-20 | 1987-02-17 | Nissan Chemical Industries, Ltd. | Herbicidal 4-benzoyl-1-methyl-5-hydroxypyrazoles |
| JPS63122673A (ja) * | 1986-11-10 | 1988-05-26 | Nissan Chem Ind Ltd | ピラゾ−ル誘誉体および除草剤 |
| KR900003088B1 (ko) * | 1988-03-26 | 1990-05-07 | 재단법인 한국화학연구소 | 5-하이드록시피라졸 유도체 |
-
1993
- 1993-05-08 DE DE4315384A patent/DE4315384A1/de not_active Withdrawn
- 1993-08-23 EP EP93113398A patent/EP0588105A1/de not_active Withdrawn
- 1993-08-30 JP JP5235899A patent/JPH06192282A/ja active Pending
- 1993-08-31 KR KR1019930017122A patent/KR940006468A/ko not_active Application Discontinuation
- 1993-09-03 CN CN93117252A patent/CN1084853A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0588105A1 (de) | 1994-03-23 |
| JPH06192282A (ja) | 1994-07-12 |
| CN1084853A (zh) | 1994-04-06 |
| DE4315384A1 (de) | 1994-03-10 |
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