KR930021749A - 물 기재의 코팅 조성물 및 가요성 코팅의 제조를 위한 그의 용도 - Google Patents

물 기재의 코팅 조성물 및 가요성 코팅의 제조를 위한 그의 용도 Download PDF

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KR930021749A
KR930021749A KR1019930006851A KR930006851A KR930021749A KR 930021749 A KR930021749 A KR 930021749A KR 1019930006851 A KR1019930006851 A KR 1019930006851A KR 930006851 A KR930006851 A KR 930006851A KR 930021749 A KR930021749 A KR 930021749A
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water
polyisocyanate
isocyanate
groups
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페다인 요제프
뮐러 하이노
마게르 디터
쇤펠더 만프레트
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크누트 샤우에르테, 클라우스 데너
바이엘 악티엔게젤샤프트
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/703Isocyanates or isothiocyanates transformed in a latent form by physical means
    • C08G18/705Dispersions of isocyanates or isothiocyanates in a liquid medium
    • C08G18/706Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/80Masked polyisocyanates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/80Masked polyisocyanates
    • C08G18/8003Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8048Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/34
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/80Masked polyisocyanates
    • C08G18/8061Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C08G18/8077Oximes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31605Next to free metal

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 결합제로서 a)의 수용성 또는 수분산성 폴리올 성분, 및 B) 평균 NCO관능도가 2.0내지 2.6이고, b1)평균 NCO관능도가 2.5내지 3.5이고 (ⅰ)적어도 15중량%의 유기 디이소시아네이트를 함유한 폴리이소시아네이트 혼합물, b2) 성분 b1)의 이소시아네이트를 기준으로 50내지 80당량%의 이소시아네이트기를 위한 블록킹제 및 b3) 성분 b1)의 이소시아네이트 및 성분 b3)의 히드록실기를 기준으로 20내지 50당량%의 지방족 모노히드록시모노카르복실산의 반응 생성물로 이루어지며, 상기 반응 생성물은 블록킹제 b2)의 이소시아네이트 반응성기 및 성분 b3)의 히드록실시를 기준으로 성분b1)의 이소시아네이트기에 대한 당량비가 적어도 0.9:1인 수용성 또는 수분산성의 블록킹된 폴리이소시아네이트를 함유하는 열 가교성 물 기재의 코팅 조성물에 관한 것이다.

Description

물 기재의 코팅 조성물 및 가요성 코팅의 제조를 위한 그의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. a) 수용성 또는 수분산성 폴리올 성분, 및 b) 블록킹된 이소시아네이트기를 함유하며, 평균 NCO관능고가 가역적으로 블록킹된 이소시아네이트기를 기준으로 2.0내지 2.6이며, b1) 평균 NCO관능도가 2.5내지 3.5이고 (ⅰ) 1종이상의 유기 디이소시아네이트를 함유한 적어도 15중량%의 디이소시아네이트 성분 및(ⅱ) 평균 NCO관능도가 2.5내지 3.5인 폴리이소시아네이트 혼합물 b1)을 제조하기에 충분한 량의 1종 이상의 3관능성 또는 고관능성의 폴리이소시아네이트를 함유한 폴리이소시아네이트 성분을 함유하는 폴리이소시아네이트 혼합물, b2) 성분 b1)의 이소시아네이트를 기준으로 50내지 80당량%의 1종 이상의 가역성 1관능성의, 이소시아네이트기를 위한 블록킹제 및 b3) 성분 b1)의 이소시아네이트 및 성분 b3)의 히드록실기를 기준으로 20내지 50당량%의 지방족 모노히드록시모노카르복실산의 반응 생성물로 이루어지며, 상기 반응 생성물은 혼입된 카르복실기의 중화에 의해서 적어도 부분적으로 염 형태로 전환되며 성분 b1)의 이소시아네이트기에 대한 당량비가 블록킹제 b2)의 이소시아네이트 반응성기 및 성분 b3)의 히드록실기를 기준으로 0.9:1인 수용성 또는 수분산성 폴리이소시아네이트 성분으로 이루어지는 결합제를 함유한 열가교성 물 기재의 코팅 조성물.
  2. 제1항에 있어서, 성분 a)및 b)가 히드록실기에 대한 블록킹된 이소시아네이트기의 당량비가 0.6:내지 1.5:1에 해당하는 량으로 존재하는 코팅 조성물.
  3. 제1항의 코팅 조성물로 코팅된 금속 기판.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930006851A 1992-04-24 1993-04-23 물기재의코팅조성물및가요성코팅의제조를위한그의용도 KR100252798B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4213527A DE4213527A1 (de) 1992-04-24 1992-04-24 Wäßrige Überzugsmittel für elastische Einbrennlackierungen
DEP4213527.3 1992-04-24

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KR930021749A true KR930021749A (ko) 1993-11-22
KR100252798B1 KR100252798B1 (ko) 2000-04-15

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US (1) US5455297A (ko)
EP (1) EP0566953B1 (ko)
JP (1) JP3375174B2 (ko)
KR (1) KR100252798B1 (ko)
AT (1) ATE155503T1 (ko)
CA (1) CA2094618C (ko)
DE (2) DE4213527A1 (ko)
ES (1) ES2103998T3 (ko)
MX (1) MX9302164A (ko)

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CA2094618C (en) 2003-07-29
MX9302164A (es) 1993-10-01
JP3375174B2 (ja) 2003-02-10
JPH0617002A (ja) 1994-01-25
DE4213527A1 (de) 1993-10-28
KR100252798B1 (ko) 2000-04-15
ES2103998T3 (es) 1997-10-01
ATE155503T1 (de) 1997-08-15
DE59306909D1 (de) 1997-08-21
EP0566953A1 (de) 1993-10-27
EP0566953B1 (de) 1997-07-16
US5455297A (en) 1995-10-03
CA2094618A1 (en) 1993-10-25

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