KR930021736A - 대칭 아조 염료 - Google Patents

대칭 아조 염료 Download PDF

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Publication number
KR930021736A
KR930021736A KR1019930006109A KR930006109A KR930021736A KR 930021736 A KR930021736 A KR 930021736A KR 1019930006109 A KR1019930006109 A KR 1019930006109A KR 930006109 A KR930006109 A KR 930006109A KR 930021736 A KR930021736 A KR 930021736A
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South Korea
Prior art keywords
alkyl
substituted
oso
benzyl
compound
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KR1019930006109A
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English (en)
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KR100251825B1 (ko
Inventor
헤르트 카를-요셉
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만프레트 초벨, 요아힘 그렘
바이엘 아크티엔게젤샤프트
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Priority claimed from DE19924212465 external-priority patent/DE4212465A1/de
Priority claimed from DE19924218310 external-priority patent/DE4218310A1/de
Application filed by 만프레트 초벨, 요아힘 그렘, 바이엘 아크티엔게젤샤프트 filed Critical 만프레트 초벨, 요아힘 그렘
Publication of KR930021736A publication Critical patent/KR930021736A/ko
Application granted granted Critical
Publication of KR100251825B1 publication Critical patent/KR100251825B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/4401—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system
    • C09B62/4403—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring with two or more reactive groups at least one of them being directly attached to a heterocyclic system and at least one of them being directly attached to a non-heterocyclic system the heterocyclic system being a triazine ring
    • C09B62/4411—Azo dyes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C317/00—Sulfones; Sulfoxides
    • C07C317/26—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
    • C07C317/32—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C317/34—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring
    • C07C317/36—Sulfones; Sulfoxides having sulfone or sulfoxide groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton with sulfone or sulfoxide groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having sulfone or sulfoxide groups and amino groups bound to carbon atoms of six-membered aromatic rings being part of the same non-condensed ring or of a condensed ring system containing that ring with the nitrogen atoms of the amino groups bound to hydrogen atoms or to carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/02—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring
    • C09B62/04—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group directly attached to a heterocyclic ring to a triazine ring
    • C09B62/08—Azo dyes
    • C09B62/09—Disazo or polyazo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
    • C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
    • C09B62/503—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being an esterified or non-esterified hydroxyalkyl sulfonyl or mercaptoalkyl sulfonyl group, a quaternised or non-quaternised aminoalkyl sulfonyl group, a heterylmercapto alkyl sulfonyl group, a vinyl sulfonyl or a substituted vinyl sulfonyl group, or a thiophene-dioxide group
    • C09B62/507—Azo dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

모 및 셀룰로오즈 물질위에 개선된 염색물 또는 날염물을 생성시키는 하기 일반식(1)의 대칭 아조 염료가 기술되어 있다:
상기식에서, 치환체는 본 원의 발명의 상세한 설명에서 정의한 바와 같다.

Description

대칭 아조 염료
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 유리산 형태의 하기 일반식(1)의 다작용성 섬유-반응성 아조 염료.
    상기식에서, n은 0 또는 1이고, X는 CH=CH2또는 CH2CH2OSO3H이며, Y는 H, C1-6알킬, Cl, OH, CN, CO2H, OSO3H, SO3H, SO2X 또는 C1-4알콕시에 의해 치환된 C1-6알킬, 알릴, 사이클로알킬, CO2H, OSO3H 또는 SO3H에 의해 치환된 사이클로알킬, 벤질 또는 OH, CO2H 또는 SO3H에 의해 치환된 벤질이고, R은 H, C1-4알킬, Cl, OH, CN, CO2H, OSO3H, SO3H, SO2X 또는 C1-4알콕시에 의해 치환된 C1-4알킬, 알릴, 벤질 또는 OH, CO2H 또는 SO3H에 의해 치환된 벤질이며, NR-Y는 포화헤테로사이클릭 환을 나타내고, D는 이가 방향족 또는 헤테로방향족 라디칼이다.
  2. 제1항에 있어서, n이 1이고, D는 디아조 염료에 대해 통상적인 카보사이클릭 또는 헤테로사이클릭 중심 성분인 염료.
  3. 제1항 또는 제2항에 있어서, D가 하기 일반식 중 하나에 상응함을 특징으로 하는 염료.
    상기식에서, E, V 및 W는 서로 독립적으로 수소이거나 카보사이클릭 환에 대해 통상적인 치환체이고, B는 직접 결합 또는 브릿지 원이다.
  4. 제1항 내지 제3항 중 어느 한 항에 있어서, B가 CH2, CH2-CH, CH=CH, O, S, SO, SO2, CO, CO2, OCH2CH2O, CH2-O-CH2, CH2CH2OCH2CH2, NHCO, NHCONH, NR1, N=N, N=N→O, O←N=N→O, NHCOCONH,
    R1이 각각 서로 독립적으로 H 또는 C1-4알킬이고, T가 F, Cl, Br, OR2, SR2또는 NR3R4이며, R2가 H, C1-6알킬, OH, 할로겐, C1-4알콕시, CO2H, SO3H 또는 OSO3H에 의해 치환된 C1-6알킬, 사이클로헥실, 푸르푸릴, 페닐, OH, CO2H, SO3H, C1-4알킬 또는 C1-4알콕시에 의해 치환된 페닐 또는 비치환되거나 OH, CO2H 또는 SO3H에 의해 치환된 나프틸이고, R3및 R4가 서로 독립적으로 수소, C1-6알킬, C1-4알케닐, 할로겐, OH, CO2H, SO3H, OSO3H, 메톡시, 에톡시, SO2Z 또는 OCH2CH2SO2Z에 의해 치환된 C1-6알킬, 사이클로헥실, 사이클로펜틸, 벤질, 페닐 또는 나프틸, 또는 C1-4알킬, C1-4알콕시, 할로겐, CO2H, SO3H, SO2Z 또는 CH2SO2Z에 의해 치환된 페닐, 벤질 또는 나프틸이며, 여기서, R3및 R4는 N원자와 함께 5원- 또는 6-원의 헤테로사이클릭환의 라디칼을 형성할 수 있고, Z는 CH=CH2,CH2CH2OSO3H 또는 CH2CH2Cl임을 특징으로 하는 염료.
  5. 제1항 내지 제4항 중 어느 한 항에 있어서, 하기 일반식(2) 내지 (6)에 상응함을 특징으로 하는 반응성 염료.
    B1는 직접 결합 또는 CH2CH2,CH=CH, CO, SO2, NHCONH 또는 일반식의 트리아지닐 라디칼이며, T1은 Cl, F, OH 또는 NR3R4이고, X는 CH=CH2또는 C2H4OSO3H이며, R, Y, R3및 R는 제4항에서 정의한 바와같다.
  6. 하기 일반식(35)의 화합물.
    상기식에서,m은 서로 독립적으로 0 또는 2이고, n은 0 또는 1이며, R, Y 및 D는 제1항에서 정의한 바와 같다.
  7. 하기 일반식(36)의 화합물.
    상기식에서, m은 0 또는 2이고, Q는 NH2, NO2또는 NH-아실이며, 아실은 카보사이클산의 아실 라디칼을 나타내고, R, Y 및 D는 제1항에서 정의한 바와 같다.
  8. 하기 일반식(37)의 화합물.
    상기식에서, m은 0 또는 1이고, n은 0 또는 2이며, R, Y 및 D는 제1항에서 정의한 바와 같다.
  9. 하기 일반식(38)의 화합물.
    상기식에서, m은 0 또는 2이고, n은 0 또는 1이며, R, Y 및 D는 제1항에서 정의한 바와 같다.
  10. 하기 일반식(34)의 화합물.
    상기식에서, R, Y 및 D는 제1항에서 정의한 바와 같다.
  11. 하이드록실 그룹 또는 아미드 그룹을 함유하는 물질을 반응성 염료를 사용하여 염색하거나 날염하는 방법에 있어서, 제1항에 따른 반응성 염료를 사용함을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930006109A 1992-04-14 1993-04-13 대칭 아조 염료 KR100251825B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DEP4212465.4 1992-04-14
DE19924212465 DE4212465A1 (de) 1992-04-14 1992-04-14 Symmetrische Azofarbstoffe
DEP4218310.3 1992-06-03
DE19924218310 DE4218310A1 (de) 1992-06-03 1992-06-03 Symmetrische Azofarbstoffe

Publications (2)

Publication Number Publication Date
KR930021736A true KR930021736A (ko) 1993-11-22
KR100251825B1 KR100251825B1 (ko) 2000-04-15

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KR1019930006109A KR100251825B1 (ko) 1992-04-14 1993-04-13 대칭 아조 염료

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US (1) US5434251A (ko)
EP (1) EP0568816B1 (ko)
JP (1) JPH0649385A (ko)
KR (1) KR100251825B1 (ko)
DE (1) DE59303055D1 (ko)
TW (1) TW225549B (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW241289B (ko) * 1993-05-17 1995-02-21 Ciba Geigy
DE4423650A1 (de) * 1994-07-06 1996-01-11 Bayer Ag Azofarbstoffe mit einer faserreaktiven Gruppe
AU5156499A (en) * 1998-07-13 2000-02-07 Ciba Specialty Chemicals Holding Inc. Reactive colorants, production and use thereof
MX2008012702A (es) * 2006-04-07 2008-10-15 Clariant Finance Bvi Ltd Colorantes acidos.
AU2007251589A1 (en) * 2006-05-16 2007-11-22 Clariant Finance (Bvi) Limited Disazo acid dyes
CN101724291B (zh) * 2008-11-04 2015-06-10 明德国际仓储贸易(上海)有限公司 具有二烷醚基桥基的新型反应性染料
EP2910608B1 (en) * 2014-02-25 2017-05-31 Archroma IP GmbH Dimeric anionic monoazo dyes

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE51808C (de) * th. VOGEL in Saalfeld i. Thür Zeugziehapparat für Bierbrauereien
DE197418C (ko) *
DE3370349D1 (en) * 1982-11-19 1987-04-23 Ciba Geigy Ag Reactive dyes, their preparation and their use
US4629788A (en) * 1983-10-11 1986-12-16 Bayer Aktiengesellschaft Triphendioxazine reactive dyestuffs
DE3512340A1 (de) * 1985-04-04 1986-10-16 Bayer Ag, 5090 Leverkusen Azoreaktivfarbstoffe
US5003053A (en) * 1987-02-14 1991-03-26 Hoechst Aktiengesellschaft Water-soluble monoazo compounds containing a p-aminophenylamino- and chloro- or fluoro-substituted triazinylamino group and a fiber-reactive group selected from the vinylsulfone series, suitable as dyestuffs
DE3704660A1 (de) * 1987-02-14 1988-08-25 Hoechst Ag Wasserloesliche azoverbindungen, verfahren zu deren herstellung und ihre verwendung als farbstoffe
US5210187A (en) * 1988-07-28 1993-05-11 Basf Aktiengesellschaft Double attachment reactive dyes having alkyl- or alkenylsulfonyl and alkyl- or alkenylsulfonylalkyl groups
US5278291A (en) * 1989-12-02 1994-01-11 Bayer Aktiengesellschaft Hydroxyethylthio hydroxyethylamino-phenyl-azo and -azoxy dyestuffs
DE3939966A1 (de) * 1989-12-02 1991-06-06 Bayer Ag Azofarbstoffe und verfahren zur herstellung von (5-amino-2-(2-hydroxyethylamino)phenyl)(2-hydroxyethyl)-sulfon

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Publication number Publication date
TW225549B (ko) 1994-06-21
KR100251825B1 (ko) 2000-04-15
EP0568816B1 (de) 1996-06-26
JPH0649385A (ja) 1994-02-22
US5434251A (en) 1995-07-18
DE59303055D1 (de) 1996-08-01
EP0568816A1 (de) 1993-11-10

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