KR930010126A - 열경화성 오르가노폴리실록산 조성물, 예비성형된 잠복성 백금 촉매 및 그의 제조 방법 - Google Patents
열경화성 오르가노폴리실록산 조성물, 예비성형된 잠복성 백금 촉매 및 그의 제조 방법 Download PDFInfo
- Publication number
- KR930010126A KR930010126A KR1019920022748A KR920022748A KR930010126A KR 930010126 A KR930010126 A KR 930010126A KR 1019920022748 A KR1019920022748 A KR 1019920022748A KR 920022748 A KR920022748 A KR 920022748A KR 930010126 A KR930010126 A KR 930010126A
- Authority
- KR
- South Korea
- Prior art keywords
- integer
- platinum catalyst
- preformed
- nitrogen compound
- organic nitrogen
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
- B01J31/183—Ligands comprising condensed ring systems, e.g. acridine, carbazole with more than one complexing nitrogen atom, e.g. phenanthroline
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/0244—Pincer-type complexes, i.e. consisting of a tridentate skeleton bound to a metal, e.g. by one to three metal-carbon sigma-bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/828—Platinum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
- C08G77/08—Preparatory processes characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
본 발명은 비닐 실리콘 오르가노폴리실록산 유체, 실리콘 하이드라이드 실록산 및 오르가노폴리실록산 유체의 실질적인 부재 하에, 0가 백금 촉매와 2.2'-비피리딘 또는 디에틸 아조디카르복실세이트와 같은 유기 질소 화합물의 반응으로 부터 생성된 유효량의 예비성형된 잠복성 백금 촉매를 사용하여 제조한 열경화성 오르가노폴리실록산 조성물에 관한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- (A)비닐 오르가노폴리실록산 유체 (B)실리콘 하이드라이드 실록산, 및 (C)(A)와 (B)의 부가 반응을 촉매화하기에 유효한 양의 예비성형된 잠복성 백금 촉매로 이루어지고, 예비성형된 잠복성 백금촉매는 (A)또는 (B), 또는 그의 혼합물의 실질적인 부재하에 0가 백금 착물과 백금 1몰당 유기 질소 화합물 1.0내지 60몰을 반응시켜 제조하며, 유기 질소 화합물은 하기 일반식(1)의 특정적인 다가구조 단위를 갖는 지방족 질소 화합물, 헤테로시클릭 방향족 질소 화합물 및 이들의 혼합물로 이루어진 군중에서 선택된 것인, 50℃에서 5일 이상의 촉진 노화기간후에 실질적인 점도 증가에 견딜 수 있는 열경화성 오르가노폴리실록산 조성물.여기서, Q 및 Q'는 각각 탄소 또는 질소기이고, n은 2또는 3의 정수이며, m은 1또는 2의 정수이다.
- (A)비닐 오르가노폴리실록산 유체 100중량부 (B)실리콘 하이드라이드 실록산 유체 1내지 20중량부, 및 (C) (A)와 (B)의 부가 반응을 촉매화하기에 유효한 양의 예비성형된 잠복성 백금 촉매로 이루어지고, 예비성형된 잠복성 백금 촉매는 (A) 또는 (B), 또는 그이 혼합물의 실질적인 부재 하에 0가 백금 착물과 1.0내지 60몰의 유기 질소 화합물을 반응시켜 제조하며, 유기 질소 화합물은 하기 일반식(1)의 특징적인 다가 구조 단위를 갖는 지방족 질소 화합물, 헤테로시클릭 방향족 질소 화합물 및 이들의 혼합물로 이루어진 군중에서 선택된 것인 50℃에서 5일 촉진 노화 기간후에 실질적인 점도 증가에 결딜수 있는 열경화성 오르가노폴리실록산 조성물.여기서, Q 및 Q'는 각각 탄소 또는 질소이고, n은 2 또는 3의 정수이며, m은 1 또는 2의 정수이다.
- 제1항에 있어서, 실리콘 오르가노폴리실록산 유체가 비닐 폴리디메틸실록산 유체인 열경화성 오르가르폴리실록산 조성물.
- 제1항에 있어서, 실리콘 하이드라이드 실록산이 실리콘 하이드라이드 메틸실록산인 열경화성 오르가노폴리실록산 조성물.
- 제1항에 있어서, 예비성형된 잠복성 백금 촉매의 제조시 사용되는 유기 질소 화합물이 2,2'-비피리딘, 디에틸 아조디카르복실레이트 디이소프로필 아조디카르복실레이트, 4-페닐-1,2,4-트리아졸린-3,5-디온 및 아조비스톨루오일로 이루어진 군 중에서 선택된 것인 열경화성 오르가노폴리실록산 조성물.
- (a)0가 백금 착물, (b)0가 백금 촉매 1몰 당 유기 질소 화합물 1.0내지 60몰, 및 (c) (a), (b) 및 (c)의 총합 100중량부 기준으로 불활성 유기 용매 0내지 99중량부로 필수적으로 이루어지는 혼합물을 0℃내지 100의 온도로 가열하는 것으로 이루어지고, 유기 질소 화합물은 하기 일반식(1)의 특징적인 다가구조 단위를 갖는 지방족 질소화합불, 헤테로시클릭 방향족 질소 화합물 및 이들의 혼합물로 이루어지는 군으로부터 선택된 것인, 예비성형된 잠복성 백금 촉매의 제조방법.여기서, Q 및 Q'는 각각 탄소 또는 질소이고, n은 2 또는 3의 정수이며, m은 1 또는 2의 정수이다.
- 0가 백금 착물과 오르가노폴리실록산 유체의 실질적인 부재 하에 하기 일반식(1)의 특징적인 다가 구조 단위를 갖는 지방족 질소 화합물, 헤테로시클릭 방향족 질소 화합물 및 이들의 혼합물로 이루어지는 군으로부터 선택되는 유기 질소 화합물의 반응으로부터 생성된 예비성형된 잠복성 백금 촉매.여기서, Q 및 Q'는 각각 탄소 또는 질소이고, n은 2 또는 3의 정수이며, m은 1 또는 2의 정수이다.
- 제8항에 있어서, 유기 질소 화합물이 디이소프로필 아조디카르복실레이트, 아조비스벤조일, 아조비스(N,N'-디메틸포름아미드), 4-메틸-1,2,4-트리아졸린-3,5-디온, 1, 10-페난트롤린, 디-t-부틸 아조디카르복실레이트, 네오쿠프로인, 디벤질 아조디카르복실레이트, 2,2'-비피리딘, 디에틸 아조디카르복실레이트 4-페닐-1,2,4-트라아졸린-3,5-디온, 프탈라진, 퀴나졸린, 퀴녹살린, 퀴놀린, 이소퀴놀린, 4,4'-디피리딜, 3,3'-디피리딜, 2,4-디피리딜, 벤즈이미다졸, 인다졸, 이피리딜 케톤, 피리딘, 2,2':6',2"-터어피리딘 및 4,4'-트리메틸렌 디피리딘으로 이루어진 군 중에서 선택된 것인 예비성형된 잠복성 백금 촉매.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US80031191A | 1991-11-29 | 1991-11-29 | |
US800,311 | 1991-11-29 | ||
US07/955,987 US5331075A (en) | 1991-11-29 | 1992-10-13 | Heat curable organopolysiloxane compositions, preformed latent platinum catalysts, and methods for making |
US955,987 | 1992-10-13 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR930010126A true KR930010126A (ko) | 1993-06-22 |
KR100237819B1 KR100237819B1 (ko) | 2000-01-15 |
Family
ID=25178059
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019920022748A KR100237819B1 (ko) | 1991-11-29 | 1992-11-28 | 열경화성 오르가노폴리실록산 조성물, 예비성형된 잠재성 백금 촉매 및 그의 제조 방법 |
Country Status (3)
Country | Link |
---|---|
US (1) | US5331075A (ko) |
KR (1) | KR100237819B1 (ko) |
CA (1) | CA2080153A1 (ko) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05295269A (ja) * | 1991-11-29 | 1993-11-09 | General Electric Co <Ge> | 熱硬化性オルガノポリシロキサン組成物、予備生成済み潜伏性白金触媒およびそれの調製方法 |
US5446113A (en) * | 1994-04-28 | 1995-08-29 | General Electric Company | Method for making heat curable zero valent platinum-vinylsilane silicone compositions |
TW289761B (ko) * | 1994-08-31 | 1996-11-01 | Gen Electric | |
US5496906A (en) * | 1994-08-31 | 1996-03-05 | General Electric Company | Production of nitrosamine-free silicone articles |
US5543457A (en) * | 1994-12-07 | 1996-08-06 | General Electric Company | Additive for the prevention of nitrosamine formation in silicone articles |
US5661222A (en) * | 1995-04-13 | 1997-08-26 | Dentsply Research & Development Corp. | Polyvinylsiloxane impression material |
US5830951A (en) * | 1995-04-13 | 1998-11-03 | Dentsply Detrey G.M.B.H. | Polyvinylsiloxane impression material |
US6561807B2 (en) | 1998-05-27 | 2003-05-13 | Dentsply Research & Development Corp. | Polyvinylsiloxane impression material |
US6107434A (en) * | 1998-08-14 | 2000-08-22 | General Electric Company | Heat curable organopolysiloxane compositions |
JP3912523B2 (ja) * | 2002-11-29 | 2007-05-09 | 信越化学工業株式会社 | 難燃性シリコーン組成物、及びシリコーンゴム硬化物又はシリコーンゲル硬化物の難燃性向上方法 |
US20050181324A1 (en) * | 2004-02-13 | 2005-08-18 | Hare Robert V. | Polyorganosiloxane dental impression materials with improved wetting and stability |
US20090247680A1 (en) * | 2006-06-06 | 2009-10-01 | Avery Dennison Corporation | Adhesion promoting additive |
CA2751722A1 (en) * | 2009-02-17 | 2010-08-26 | Dow Corning Corporation | Silicone gel seal and method for its preparation and use |
US8236915B2 (en) * | 2009-07-10 | 2012-08-07 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
US9782763B2 (en) | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
US9447125B2 (en) | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
WO2014182670A2 (en) | 2013-05-06 | 2014-11-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
US9440999B2 (en) | 2013-05-15 | 2016-09-13 | Momentive Performance Materials Inc. | Activation of metal salts with silylhydrides and their use in hydrosilylation reactions |
WO2015077304A1 (en) | 2013-11-19 | 2015-05-28 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
US9381506B2 (en) | 2013-11-19 | 2016-07-05 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
EP3071584B1 (en) | 2013-11-19 | 2017-11-08 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
RU2752784C1 (ru) * | 2020-12-15 | 2021-08-03 | федеральное государственное автономное образовательное учреждение высшего образования "Казанский (Приволжский) федеральный университет" (ФГАОУ ВО КФУ) | Способ получения катализатора гидросилилирования на основе комплекса платины с карбеновыми лигандами и катализатор гидросилилирования, полученный данным способом |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE61241C (de) * | W. RÖCKER in Löchgau bei Besigheim, Württemberg | Häckse'schneidmaschine mit Vorschubwalzen | ||
GB1054658A (ko) * | ||||
US3188299A (en) * | 1963-02-28 | 1965-06-08 | Gen Electric | Preparation of stable mixtures of organosilicon compositions in the presence of a nitrogen-containing ligand |
US3775452A (en) * | 1971-04-28 | 1973-11-27 | Gen Electric | Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes |
GB1432339A (en) * | 1972-12-11 | 1976-04-14 | Ici Ltd | Organopolysiloxane compositions |
DE2809875C2 (de) * | 1978-03-08 | 1983-05-05 | Consortium für elektrochemische Industrie GmbH, 8000 München | Verfahren zum Anlagern von Si-gebundenem Wasserstoff an aliphatische Mehrfachbindung |
US4256616A (en) * | 1978-11-22 | 1981-03-17 | Masayuki Hatanaka | Platinum complexes for silicone compositions |
EP0015346A1 (en) * | 1979-01-31 | 1980-09-17 | Imperial Chemical Industries Plc | Catalyst compositions and their use in the preparation of release coatings |
US4511715A (en) * | 1981-03-20 | 1985-04-16 | Minnesota Mining And Manufacturing Company | Platinum-nitrogen complex catalysts |
US4374967A (en) * | 1981-07-06 | 1983-02-22 | Dow Corning Corporation | Low temperature silicone gel |
US4584361A (en) * | 1985-06-03 | 1986-04-22 | Dow Corning Corporation | Storage stable, one part polyorganosiloxane compositions |
US4681963A (en) * | 1985-12-19 | 1987-07-21 | General Electric Company | Hydrosilylation catalyst, method for making and use |
US4801642A (en) * | 1987-12-28 | 1989-01-31 | Dow Corning Corporation | Thermally stable organosiloxane compositions and method for preparing same |
US4791186A (en) * | 1988-01-04 | 1988-12-13 | Dow Corning Corporation | Method for preparing storage stable, one part curable polyorganosiloxane compositions |
US4916169A (en) * | 1988-09-09 | 1990-04-10 | Minnesota Mining And Manufacturing Company | Visible radiation activated hydrosilation reaction |
US5036117A (en) * | 1989-11-03 | 1991-07-30 | Dow Corning Corporation | Heat-curable silicone compositions having improved bath life |
US5125998A (en) * | 1989-11-03 | 1992-06-30 | Dow Corning Corporation | Process for improving the bath life and cure time of heat-curable silicone compositions |
US5066699A (en) * | 1990-08-31 | 1991-11-19 | Dow Corning Corporation | Storage stable heat curable organosiloxane compositions containing a microencapsulated catalyst and method for preparing said catalyst |
US5122585A (en) * | 1990-12-10 | 1992-06-16 | General Electric Company | One part heat curable organopolysiloxane compositions |
-
1992
- 1992-10-08 CA CA002080153A patent/CA2080153A1/en not_active Abandoned
- 1992-10-13 US US07/955,987 patent/US5331075A/en not_active Expired - Fee Related
- 1992-11-28 KR KR1019920022748A patent/KR100237819B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CA2080153A1 (en) | 1993-05-30 |
KR100237819B1 (ko) | 2000-01-15 |
US5331075A (en) | 1994-07-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR930010126A (ko) | 열경화성 오르가노폴리실록산 조성물, 예비성형된 잠복성 백금 촉매 및 그의 제조 방법 | |
US3313773A (en) | Platinum addition catalyst system | |
US4029629A (en) | Solvent resistant room temperature vulcanizable silicone rubber composition | |
US3294737A (en) | Organopolysiloxanes | |
US4234713A (en) | Curable solventless organopolysiloxane compositions | |
US4239867A (en) | Inhibited curable solventless organopolysiloxane compositions | |
US4818805A (en) | Vulcanizable fluorinated silicone compositions | |
US5483017A (en) | High temperature thermosets and ceramics derived from linear carborane-(siloxane or silane)-acetylene copolymers | |
US2437204A (en) | Sulfuric acid polymerization of diorganosiloxanes | |
JPH05279481A (ja) | フルオロシリコ−ンブロック共重合体およびその製造方法 | |
US4563514A (en) | Curable polysilarylene-polysiloxane copolymers | |
KR900012941A (ko) | 선택적으로 모노히드로사일레이션 (monohydrosilation)된 노보넨 화합물과 그의 제조 방법 및 그로부터 제조된 중합체 | |
JPH03170530A (ja) | 片末端分岐状アミノアルキル基封鎖オルガノポリシロキサン及びその製造方法 | |
EP0307098B1 (en) | Polyalkoxysilylalkylenedisilazanes and silylamines | |
US5086124A (en) | High heat distortion temperature epoxy siloxane/organic epoxy compositions | |
JPH07165919A (ja) | ターポリマー性流体からなる組成物用添加剤 | |
CA1053252A (en) | Preparation of organosilicon products | |
US2793222A (en) | 1, 2-bis-heptamethylcyclotetrasiloxanylethane and polymeric derivatives thereof | |
US3296199A (en) | Method for making organosilicon polymers | |
US6265336B1 (en) | High temperature ceramics derived from linear carborane-(siloxane or silane)-acetylene copolymers | |
US5552505A (en) | High temperature copolymers from inorganic-organic hybrid polymers and multi-ethynylbenzenes | |
JPS584732B2 (ja) | 耐加水分解性、耐熱性に優れたボロシロキサンポリマ−の製造方法 | |
KR840007019A (ko) | 알콕시-말단 폴리실록산의 제조방법 | |
US3661962A (en) | Molecular weight control and polysiloxanes | |
KR100853550B1 (ko) | 용제형 실리콘 종이 이형제 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
LAPS | Lapse due to unpaid annual fee |