KR920701138A - 살진균용 옥심 카바메이트 - Google Patents

살진균용 옥심 카바메이트

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Publication number
KR920701138A
KR920701138A KR1019910701440A KR910701440A KR920701138A KR 920701138 A KR920701138 A KR 920701138A KR 1019910701440 A KR1019910701440 A KR 1019910701440A KR 910701440 A KR910701440 A KR 910701440A KR 920701138 A KR920701138 A KR 920701138A
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KR
South Korea
Prior art keywords
substituted
phenyl
alkyl
ring
dimethylamino
Prior art date
Application number
KR1019910701440A
Other languages
English (en)
Inventor
리 하트젤 스티븐
Original Assignee
원본미기재
이.아이.듀퐁 드 네모아 앤드 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 원본미기재, 이.아이.듀퐁 드 네모아 앤드 캄파니 filed Critical 원본미기재
Publication of KR920701138A publication Critical patent/KR920701138A/ko

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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/79—Acids; Esters
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    • C07C271/60—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups having oxygen atoms of carbamate groups bound to nitrogen atoms
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    • C07C309/45—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton
    • C07C309/46—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton having the sulfo groups bound to carbon atoms of non-condensed six-membered aromatic rings
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    • C07C309/72—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
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    • C07C311/15—Sulfonamides having sulfur atoms of sulfonamide groups bound to carbon atoms of six-membered aromatic rings
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Abstract

내용 없음

Description

살진균용 옥심 카바메이트
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 보호하고자 하는 지역에 하기 일반식(I)화합물을 유효량으로 적용함을 특징으로 하여, 식물질병, 특히 진균을 방제하는 방법.
    상기식에서, A는 C(=O)R, C(=O)OR1, C(=O)SR1, P(=O)QR2Q1R3, C(=O)NHR, SO2R5또는 SO2NR6R7이고, Q 및 Q1은 독립적으로 산소, NR8또는 직접결합이고, X는 Cl 또는 Br이고(단, X가 Br인 경우, A는 C(=O)R이다), G는 C(=L)R9, C(=L)NR10R11, C(=O)OR12, CN, SO2NR10R11또는 SOmR13이고, L은 O 또는 S이고, m은 0,1 또는 2이고, R은 C1-C20알킬, C2-C20알켄일 또는 C2-C20알킨일이거나, R은 C1-C8알킬, C2-C8알켄일, C2-C8알킨일 또는 C3-C7사이클로알킬(이때, 이들은 각각 할로겐,C1-C6알콕시, C2-C6알콕시알킬, C1-C6알킬티오, C3-C6사이클로알킬 또는 CN에 의해 임의로 치환되거나, 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐 그룹에 의해 치환된다)(단, A가 C(=O)NHR인 경우, R은 C2알켄일 또는 C2알킨일이 아니다)이고, R은 페닐환 또는 C10-C14융합된 카보사이클릭 방향족 환 시스템(이때, 환은 0 내지 4개의 할로겐, 및 -CH2(CH2)pCH2-, -O(CH2)pCH2-, -S(CH2)pCH2-, -O(CH2)pO, -O(CH2)pS-, -R4N(CH2)pCH2- 및 -O(CH2)pNR4- 중에서 선택된 0 내지 1개의 치환체, 및 NH(C=O)OR16, SCN, C1-C4알킬, C1-C4할로알킬, C2-C4알콕시알킬, C2-C4알켄일, C2-C4할로알켄일, C2-C4알킨일, C3-C6사이클로알콕시, C3-C6사이클로알킬, NO2, C(=O)R14, CN, OR14, C(=O)OR14, C(=O)NR14R15, NR14R15, SR14, SOR14,SO2F, SO2Cl 또는 SO2NR14R15및 2-, 3- 또는 4-피리딜 중에서 선택된 0 내지 2개의 치환제에 의해 치환된다)이거나, R은 0내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노 및 아미노중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐이며, R은 또한, A가 C(=O)R인 경우 환-탄소원자가 카보닐 그룹에 결합되거나, A가 C(=O)NHR인 경우 환-탄소원자가 N에 결합되며, 질소원자 1 또는 2개, 또는 질소원자 1개 및 산소원자 1개, 또는 질소원자 1개 및 황원자 1개를 함유하는 3 내지 8원의 헤테로사이클릭 환시스템일 수 있거나, R은 또한, 환 구성원이 3개 보다 많은 경우 2개의 산소원자를 함유하는 3 내지 8원의 헤테로사이클릭 환시스템일 수 있거나(단, 이때 산소원자들을 서로 결합되지 않는다), R은 또한, 1 또는 2개의 황원자를 함유하는 3 내지 8원의 헤테로사이클릭 환 시스템일 수 있고, R은 또한, A가 C(=O)R인 경우 환-탄소원자가 카보닐 그룹에 결합되거나, A가 C(=O)NHR인 경우 환-탄소원자가 N에 결합하는 5 내지 10원의 헤테로방향족 또는 융합된 헤테로사방향족 환 시스템일 수 있으며(이때, 헤테로 원자는 1 내지 3개의 질소원자, 또는 1 내지 2개의 질소원자 및 1개의 산소원자 또는 황원자, 또는 1 내지 2개의 산소원자 또는 황원자를 포함한다)일 수 있으며 (이때, 이들 환은 0 내지 1개의 (-CH2(CH2)pCH2-)에 의해 치환되거나 CH3, OCH3, OCF3, OCH2CF3, F, Cl, Br, OCH2CH3, NO2, C(=O)CH3, N(CH3)2, CO2CH3, CON(CH3)3, SO2N(CH3)2, SCH3, CN 및 CF3중에서 선택된 0 내지 2개의 치환체에 의해 치환된다), R1은 C1-C20알킬, C3-C20알켄일 또는 C3-C20알킨일이거나, R1은 C1-C8알킬, C3-C8알켄일 또는 C3-C8알킨일(이때, 이들은 각각 할로겐, C1-C6알콕시, C2-C6알콕시알킬, C1-C6알킬티오, C3-C6사이클로알킬 또는 CN에 의해 임의로 치환되거나, 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐에 의해 치환된다)(단, R1이 알켄일 또는 알킨일인 경우, 불포화된 탄소원자가의 산소원자에 직접 결합되지 않는다)이며, R2및 R3는 독립적으로 C1-C4알킬, C1-C4할로알킬, 벤질 및 페닐중에서 선택되고, R4는 수소 또는 C1-C4알킬이고, R5는 0 내지 3개의 할로겐에 의해 치환된 C1-C4알킬이거나 R6는 0 내지 3개의 할로겐 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 니트로, 페닐 및 페녹시중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐 그룹이고, R6는 수소이거나, 0 내지 3개의 할로겐에 의해 치환된 C1-C4알킬이거나, SP>6과 R7은 이들이 결합한 질소원자와 함께, 각각 0 내지 2개이 메틸 그룹에 의해 치환된 피페리딘, 피롤리딘 또는 모르폴린을 형성할 수 있고, R8은 수소 또는 C1-C4알킬이고, R9는 0 내지 3개의 할로겐에 의해 치환된 C1-C8알킬이거나, R9는 할로겐, CH3, CF3, CH3O 및 CN 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐이고, R10과 R11은 독립적으로, 수소, C1-C4알킬, C1-C4할로알킬 또는 C2-C4알콜시알킬이거나, 벤질환 또는 페닐환(이때, 이들 환은 할로겐, CH3, CF3, CH3O 및 CN 중에서 선택된 0 내지 2개의 치환체에 의해 치환된다)이거나, R10과 R11은 이들이 결합한 질소원자와 함께, 각각 0 내지 2개의 메틸 그룹에 의해 치환된 아제티딘, 피페리딘, 호모피페리딘, 피롤리딘 또는 모르폴린을 형성할 수 있고, R12는 C1-C12알킬 또는 할로알킬이거나, 할로겐, CH3, CF3, CH3O 및 CN 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 벤질이고, R13은 C1-C4알킬, 할로알킬 또는 C2-C4알콕시알킬이거나, C3-C4알켄, 할로알켄일, 알킨일 또는 할로알킨일이거나, 벤질환 또는 페닐환(이때, 이들 환은 할로겐, CH3, CF3, CH3O 및 CN 중에서 선택된 0 내지 2개의 치환체에 의해 치환된다)이고, R14는 수소, C1-C4알킬, C1-C4할로알킬 또는 C2-C4알콕시알킬이거나, C3-C4알켄일, 할로 알켄일, 알킨일 또는 할로알킨일이거나, 벤질환 또는 페닐환(이때, 이들환은 할로겐, CH3, CF3, CH3O, CH3S 및 CN 중에서 선택된 0 내지 2개의 치환체에 의해 치환된다)이며, R15는 수소 또는 C1-C4알킬이고, R15는 C1-C6알킬 또는 C3-C4알켄일이거나, 할로겐, 메틸, 트리플루오로메틸, 니트로 및 메톡시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 벤질이고, p는 1또는 2이다.
  2. 제1항에 있어서, A가 C(=0)R, C(=O)OR1, C(=O)NHR 또는 P(=O)QR2Q1R3이고, G는 C(=O)NR10R11또는 C(=O)OR12인 방법.
  3. 제1항에 있어서, A가 C(=O)R, 또는 C(=O)NHR 이고, G는 C(=O)NR10R11또는 C(=O)OR12이고, X는 Cl인 방법.
  4. 제1항에 있어서, A가 C(=O)R, 또는 C(=O)NHR 이고, G는 C(=O)NR10R11C(=O)OR12이고, R은 페닐 그룹에 의해 치환된 C1-C2알킬(이때, 페닐그룹은 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된다)이거나, R은 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐환 또는 나프틸 환이고, R10및 R11은 독립적으로 수소, C1-C4알킬 또는 할로알킬이거나, 할로겐, CH3, CF3, CH3O 및 CN 중에서 선택된 0 내지 2개의 치환체에 의해치환된 벤질이거나, R10과 R11은 이들이 결합된 질소원소와 함께, 각각 0 내지 2개의 메틸 그룹에 의해 치환된 피페리딘, 피롤리딘 또는 모르폴린을 형성할 수 있고, X는 Cl인 방법.
  5. 제4항에 있어서, A가 C(=O)R이고, G는 C(=O)NR10R11이고, R은 페닐 그룹에 의해 치환된 C1-C2알킬(이때, 페닐 그룹은 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환제에 의해 치환된다)이거나, R은 치환된 페닐환 또는 나프탈환(이때, 차환체는 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체 중에서 선택된다)이며, X는 Cl인 방법.
  6. 제4항에 있어서, A가 C(=0)NHR이고, G는 C(=O)NR10R11이고, R은 페닐 그룹에 의해 치환된 C1-C2알킬(이때, 페닐 그룹은 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된다.)이거나, R은 치환된 페닐환 또는 나프탈환(이때, 치환체는 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체 중에서 선택된다)이며, X는 Cl인 방법.
  7. 하기 일반식(I)의 화합물.
    상기식에서, A는 C(=O)R, C(=O)OR1, C(=O)SR1, P(=O)QR2Q1R3, C(=O)NHR, SO2R5또는 SO2NR6R7이고, Q 및 Q1은 독립적으로 산소, NR8또는 직접결합이고, X는 Cl 또는 Br이고(단, X가 Br인 경우, A는 C(=O)R이다), G는 C(=L)R9, C(=L)NR10R11, C(=O)OR12, CN, SO2NR10R11또는 SOmR13이고, L은 O 또는 S이고, m은 0,1 또는 2이고, R은 C1-C20알킬, C2-C20알케닐 또는 C2-C20알키닐이거나, C1-C8알킬, C2-C8알케닐, C2-C8알키닐 또는 C3-C7사이클로알킬(이때, 이들은 각각 할로겐, 및 C1-C6알콕시, C2-C6알콕시알킬, C1-C6알킬티오, C3-C6사이클로알킬 또는 CN에 의해 임의로 치환되거나, 0 내지 3개의 할로겐, CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐 그룹에 의해 치환된다)이고 (단, A가 C(=0)NHR인 경우, R은 C2알케닐 또는 C2알키닐이 아니다)이고, R은 페닐환 또는 C10-C14카보사이클릭 방향족 환 시스템(이때, 이들 환은 0 내지 4개의 할로겐, 및 -CH2(CH2)pCH2-, -O(CH2)pCH2-, -S(CH2)pCH2-, -O(CH2)pO, -O(CH2)pS-, -R4N(CH2)pCH2- 및 -O(CH2)pNR4- 중에서 선택된 0 내지 1개의 치환체, 및 NH(C=O)OR16, SCN, C1-C4알킬, C1-C4할로알킬, C2-C4알콕시알킬, C2-C4알케닐, C2-C4할로알케닐, C2-C4알키닐, C3-C6사이클로알콕시, C3-C6사이클로알킬, NO2, C(=O)R14, CN, OR14, C(=O)OR14, C(=O)NR14R15, NR14R15, SR14, SOR14,SO2F, SO2Cl 또는 SO2NR14R15및 2-, 3- 또는 4-피리딜 중에서 선택된 0 내지 2개의 치환제에 의해 치환된다)이거나, R은 0내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노 및 아미노중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐이며, R은 또한, A가 C(=O)R인 경우 환-탄소원자가 카보닐 그룹에 결합되거나, A가 C(=0)NHR인 경우 환-탄소원자가 N에 결합되는 3 내지 8원의 헤테로사이클릭 환 시스템일 수 있거나(이때, 헤테로원자는 1 또는 2개의 질소원자, 또는 1개의 질소원자 및 1개의 산소원자 또는 1개의 질소원자 및 1개의 황원자를 함유한다), R은 또한, 환 구성원이 3개 보다 많은 경우 2개의 산소원자를 함유하는 3 내지 8원의 헤테로사이클릭 환 시스템일 수 있거나(단, 이때 산소원자들을 서로 결합하지 않는다), R은 또한, 1 또는 2개의 황원자를 함유하는 3 내지 8원의 헤테로사이클릭 환 시스템일 수 있고, R은 또한, (-CH2(CH2)pCH2-) 0 또는 1개에 의해 치환되거나, CH3, OCH3, OCF3, OCH2, CF3, F, Cl, Br, OCH2CH3, NO2, C(=O)CH3, N(CH3)2, CO2CH3, CON(CN3)2, SO2N(CH3)2, SCH3, CN 및 CF3중에서 선택된 0 내지 2개의 치환체에 의해 치환된 5 내지 10원 헤테로방향족 또는 융합된 헤테로방향족 환시스템(여기에서, 헤테로 원자는 1 내지 3개의 질소원자, 또는 1 내지 2개의 질소원자 및 1개의 산소 또는 황원자, 또는 1 내지 2개의 산소 또는 황원자를 포함한다)일 수 있고(이때, A가 C(=O)R인 경우 환-탄소원자는 카보닐그룹에 결합되거나, A가 C(=O)NHR인 경우 환-탄소원자는 N에 결합된다), R1은 C1-C20알킬, C3-C20알케닐 또는 C3-C20알키닐이거나, R1은 C1-C8알킬, C3-C8알케닐 또는 C3-C8알키닐(이때, 이들은 각각 할로겐, C1-C6알콕시, C2-C6알콕시알킬, C1-C6알킬키오, C3-C6사이클로알킬 또는 CN에 의해 임의로 치환되거나, 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환제에 의해 치환된 페닐 그룹에 의해 임의로 치환된다)이고 (단, R1이 알케닐 또는 알키닐인 경우, 불포화된 탄소는의 산소원자에 직접 결합되지 않는다)이며, R2및 R3는 독립적으로 C1-C4알킬, C1-C4할로알킬, 벤질 및 페닐중에서 선택되고, R4는 H 또는 C1-C4알킬이며, R5는 0 내지 3개의 할로겐에 의해 치환된 C1-C4알킬이거나 R6는 0 내지 3개의 할로겐 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 니트로, 페닐 및 페녹시중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐 그룹이고, R6는 H이거나, 0 내지 3개의 할로겐에 의해 치환된 C1-C4알킬이거나, 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐 그룹이며, R7은 H이거나, 0 내지 3개의 할로겐에 의해 치환된 C1-C4알킬이거나, R6과 R7은 이에 결합된 질소원자와 함께, 각각 0 내지 2개이 메틸 그룹에 의해 치환된 피페리딘, 피롤리딘 또는 모르폴린을 형성할 수 있고, R8은 H 또는 C1-C4알킬이며, R9는 0 내지 3개의 할로겐에 의해 치환된 C1-C8알킬이거나, R9는 할로겐, CH3, CF3, CH3O 및 CN 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐이고, R10및 R11은 독립적으로, H, C1-C4알킬, C1-C4할로알킬 또는 C2-C4알콜시알킬이거나, 벤질환 또는 페닐환(이때, 이들 환은 할로겐, CH3, CF3, CH3O 및 CN 중에서 선택된 0 내지 2개의 치환체에 의해 치환된다)이거나, R10과 R11은 이에 결합한 질소원자와 함께, 각각 0 내지 2개의 메틸 그룹에 의해 치환된 아제티딘, 피페리딘, 호모피페리딘, 피롤리딘 또는 모르폴린일 수 있으며, R12는 C1-C12알킬또는 할로알킬이거나, 할로겐, CH3, CF3, CH3O 및 CN 중에서 선택된 0 내지 2개의 치환제에 의해 치환된 벤질이고, R13은 C1-C4알킬, 할로알킬, C2-C4알콕시알킬, C3-C4알케닐, 할로알케닐, 알키닐 또는 할로알키닐이거나, 벤질환 또는 페닐환(이때, 이들 환은 할로겐, CH3, CF3, CH3O 및 CN 중에서 선택된 0 내지 2개의 치환체에 의해 치환된다)이고, R14는 수소, C1-C4알킬, C1-C4할로알킬 또는 C2-C4알콕시알킬이거나, R14는 C3-C4알케닐, 할로 알케닐, 알키닐 또는 할로알키닐이거나, R14는 벤질환 또는 페닐환(이때, 이들 환은 할로겐, CH3, CF3, CH3O, CH3S 및 CN 중에서 선택된 0 내지 2개의 치환체에 의해 치환된다)이며, R15는 H 또는 C1-C4알킬이고, R16는 C1-C6알킬 또는 C3-C4알케닐이거나, 할로겐, 메틸, 트리플루오로메틸, 니트로 및 메톡시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 벤질이고, p는 1또는 2이며, 단, 1. A가 C(=O)SR1또는 C(=O)OR1인 경우, G는 C(=L)NR10R11또는 C(=O)RO12가 아니고, 2. A가 C(=O)NHR G가 C(=L)NR10R11또는 C(=O)RO12인 경우, R은 비치환된 페닐 또는 C1-C3알킬은 아니다.
  8. 제7항에 있어서, A가 C(=O)R, C(=O)OR1, C(=O)NHR 또는 P(=O)QR2Q1R3이고, G는 C(=O)NR10R11또는 C(=O)OR12인 방법.
  9. 제7항에 있어서, A가 C(=O)R, 또는 C(=O)NHR이고, G는 C(=O)NR10R11또는 C(=O)OR12이며, X는 Cl인 방법.
  10. 제7항에 있어서, A가 C(=O)R 또는 C(=O)NHR이고, G는 C(=O)NR10R11또는 C(=O)OR12이며, R은 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐 그룹에 의해 치환된 C1-C2알킬이거나, R은 페닐환 또는 나프탈환(이때, 이들 환은 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된다)이며, R10및 R11은 독립적으로 H, C1-C4알킬 또는 할로알킬이거나, 할로겐, CH3, CF3, CH3O 및 CN 중에서 선택된 0 내지 2개에 의해 치환된 벤질이거나, R10및 R11은 이에 결합된 질소원소와 함께, 각각 0 내지 2개의 메틸 그룹에 의해 치환된 피페리딘, 피롤리딘 또는 모르폴린일 수 있고, X는 Cl인 방법.
  11. 제10항에 있어서, A가 C(=O)R이고, G는 C(=O)NR10R11이며, C(=O)NHR이고, R은 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐 그룹에 의해 치환된 C1-C2알킬이거나, R은 치환된 페닐환 또는 나프틸환(이때,치환체는 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체 중에서 선택된다)이며, X는 Cl인 화합물.
  12. 제10항에 있어서, A가 C(=0)R이고, G는 C(=O)NR10R11이며, R은 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸셀포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체에 의해 치환된 페닐 그룹에 의해 치환된 C1-C2알킬이건, R은 치환된 페닐환 또는 나프틸환(이때, 치환체는 0 내지 3개의 할로겐, 및 CH3, CF3, CH3O, CN, CH3S, 메틸설포닐, 디메틸아미노, 아미노, 페닐 및 페녹시 중에서 선택된 0 내지 2개의 치환체 중에서 선택된다)이며, X는 Cl인 방법.
  13. N-[[2-니프틸카보닐]옥시]-2-(디메틸아미노)-2-옥소에탄이미도일 클로라이드, N-[[[(3.5-디클로로페닐)아미노]카보닐]옥시]-2-(디메틸아미노)-2-옥소에탄이미도일]클로라이드,N-[[[(2.6-디클로로페닐)아미노]카보닐]옥시]-2-(디메틸아미노)-2-옥소에탄이미도일 클로라이드,N-[[[(3.5-비스(트리플루오로메틸페닐]아미노]카보닐]옥시]-2-(디메틸아미노)-2-옥소에탄이미도일 클로라이드,N-[3.4-디클로로페닐)아미노]카보닐]옥시]-2-(디메틸아미노)-2-옥소에탄이미도일 클로라이드,N-[[[(3.4-디클로로페닐)아미노]카보닐]옥시]-2-옥소-3-2-피페리디노 에탄이미도일 클로라이드,N-[[[(3.5-디클로로페닐)아미노]카보닐]옥시-∝옥소-1-피페리딘에탄이미도일 클로라이드, N-[[비스(2,2,2-트리클로로에톡시)포스피닐]옥시]-2-(디메틸아미노)-2-옥소에탄이미도일 클로라이드,N-[[[(2-클로로페닐)메틸]아미노]카보닐]옥시]-2-(디에틸아미노)-2-옥소에탄이미도일 클로라이드, N-[[[(1.1-비페닐]-4-일)카보닐]옥시]-2-(디메틸아미노)-2-옥소에탄이미도일 클로라이드, N-[[[(3.5-디플루오로페닐)아미노]카보닐]옥시]-∝-옥소-1-피페리딘에탄이미도일 클로라이드,N-[[(2-나프탈레닐)카보닐]옥시]-∝-옥소-1-피페리딘에탄이미도일 클로라이드,2-(디메틸아미노_-2-옥소-N-[[[(2,4,5-트리클로로-페닐)아미노]카보닐]옥시]에탄이미도일 클로라이드, 2-(디메틸아미노)-2-옥소-N-[(1-옥소옥타데실)옥시]-에탄이미도일 클로라이드, 및 2-(디메틸아미노)-2-옥소-N-[[(페닐메톡시)-카보닐]옥시]에탄이미도일 클로라이드 중에서 선택된 화합물.
  14. N-[(클로로카보닐)옥시]-2-디메틸아미노-2-옥소-에탄이미도일 클로라이드, 및N-[(클로로카보닐)옥시]-∝-옥소-1-피페리딘-에탄이미도일 클로라이드 중에서 선택된, 제7 내지 13항중 어느 한 항에 따른 살진균제를 제조하기 위해 유용한 화합물.
  15. 제7 내지 13항중 어느 한 항에 따른 화합물 살진균적 활성량, 및 계면 활성제, 고체 희석제 또는 액체 희석제중 적어도 1개를 포함하는, 제7내지 13항중 어느 한 항에 따른 화합물의 농업적으로 적합한 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910701440A 1989-04-25 1990-04-24 살진균용 옥심 카바메이트 KR920701138A (ko)

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US34287689A 1989-04-25 1989-04-25
US07/342876 1989-04-25
US39826689A 1989-08-24 1989-08-24
US07/398266 1989-08-24
PCT/US1990/002124 WO1990012784A1 (en) 1989-04-25 1990-04-24 Fungicidal oxime carbamates

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WO1992003050A1 (en) * 1990-08-16 1992-03-05 E.I. Du Pont De Nemours And Company Fungicidal sulfoneoxime esters
MY110439A (en) * 1991-02-07 1998-05-30 Ishihara Sangyo Kaisha N-phenylcarbamate compound, process for preparing the same and biocidal composition for control of harmful organisms
US5649979A (en) * 1993-08-09 1997-07-22 Firmenich S.A. Process for perfuming textiles
JP2779905B2 (ja) * 1993-10-28 1998-07-23 純正化學株式会社 工業用抗菌剤及びこれを含有した工業用抗菌剤組成物

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CH490004A (de) * 1967-10-31 1970-05-15 Agripat Sa Schädlingsbekämpfungsmittel und seine Verwendung
FR2097552A5 (ko) * 1970-07-10 1972-03-03 Roussel Uclaf
FR2327984A1 (fr) * 1973-03-15 1977-05-13 Roussel Uclaf Nouveaux derives substitues de l'o chlore o isonitrose acetophenone, procede de preparation et application comme pesticides
DE2621102A1 (de) * 1976-05-10 1977-11-24 Schering Ag Propan-1,2-diondioxime, schaedlingsbekaempfungsmittel enthaltend diese verbindungen sowie verfahren zu ihrer herstellung
US4278613A (en) * 1978-08-28 1981-07-14 Ciba-Geigy Corporation Sulfur-containing oxime compounds, processes for producing them, and their use for protecting cultivated plants
AT365410B (de) * 1978-08-31 1982-01-11 Ciba Geigy Ag Mittel zum schutz von kulturpflanzen vor aggressi-ven herbiziden
US4272453A (en) * 1980-07-24 1981-06-09 Morton-Norwich Products, Inc. 1-Chloro-1-p-methoxybenzoylformaldoxime-N-methylcarbamate

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