KR920016612A - 수성 수지분산체 및 코팅용 수지조성물 - Google Patents

수성 수지분산체 및 코팅용 수지조성물 Download PDF

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KR920016612A
KR920016612A KR1019920002936A KR920002936A KR920016612A KR 920016612 A KR920016612 A KR 920016612A KR 1019920002936 A KR1019920002936 A KR 1019920002936A KR 920002936 A KR920002936 A KR 920002936A KR 920016612 A KR920016612 A KR 920016612A
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South Korea
Prior art keywords
beta
weight
ethylene unsaturated
alpha
weight part
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KR1019920002936A
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KR100205630B1 (ko
Inventor
가즈히꼬 우스끼
가즈히꼬 니시모또
아끼오 도꾸야마
고이찌 사이또
마나부 요시오까
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후지이 히로시
닛뽄 페인트 가부시기가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F246/00—Copolymers in which the nature of only the monomers in minority is defined
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/283—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

내용 없음

Description

수성 수지분산체 및 코팅용 수지조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. α,β-에틸렌불포화 모노머 100중량부중에, (i)β-케토에스테르기가 있는 α,β-에틸렌불포화 모너머 1~20중량부, (ⅱ)2개이상의 라디칼 중합성기가 있는 가교성의 α,β-에틸렌 불포화 모노머 0.05~5중량부, 및 (ⅲ)상기 모노머(i)과 (ⅱ)이외의 α,β-에틸렌불포화 모노머 나머지 중량부의 비율로 함유하는 모노머혼합물을 상기 α,β-에틸렌불포화 모노머의 합계 100중량부에 대해 0.2~10중량부의 비율로 라디칼중합성 유화제를 사용하여 에멀전중합체시키는 것에 의해 수득되며, 산가가 0~15인 것을 특징으로 하는 수성 수지분산체.
  2. 제1항에 있어서, α,β-에틸렌불포화 모노머 100중량부중에, (i)β-케토에스테르기가 있는 α,β-에틸렌불포화 모노머 3~15중량부, (ⅱ)2개이상의 라디칼 중합성기가 있는 가교성의 α,β-에틸렌 불포화 모노머 0.1~3중량부, 및 (ⅲ)상기 모노머(i)과 (ii)이외의 α,β-에틸렌불포화 모노머 나머지 중량부의 비율로 함유하는 모노머혼합물을 상기 α,β-에틸렌불포화 모노머의 합계 100중량부에 대해 0.5~5중량부의 비율로 라디칼 중합성 유화제를 사용하여 에멀젼 중합시키는 것에 의해 수득되며, 산가가 0~15인 것을 특징으로 하는 수성 수지분산체.
  3. α,β-케토에스테르기가 모노머 100중량부중에, (i)β-케토에스테르기가 있는 α,β-에틸렌불포화 모노머 13205중량부, (ⅱ)2개이상의 라디칼 중합성기가 있는 가교성의 α,β-에틸렌 불포화 모노머 0.05~5중량부, 및 (ⅲ)상기 모노머(i)과 (ii)이외의 α,β-에틸렌불포화 모노머 나머지 중량부의 비율로 함유하는 모노머혼합물을, 상기 α,β-에틸렌불포화 모노머의 합계 100중량부에 대해 0.2~10중량부의 비율로 라디칼 중합성 유화제를 사용하여 에멀젼 중합시키는 것에 의해 수득되는 산가 0~15의 수성 수지분산체를 함유하는 것을 특징으로 하는 코팅용 수지조성물.
  4. 제3항에 있어서, α,β-에틸렌불포화 모노머 100중량부중에, (i)β-케토에스테르기가 있는 α,β-에틸렌불포화 모노머 3~15중량부, (ii)2개이상의 라디칼 중합성기가 있는 가교성의 α,β-에틸렌 불포화 모노머 0.1~3중량부, 및 (ⅲ)상기 모노머(i)과 (ii)이외의 α,β-에틸렌불포화 모노머 나머지 중량부의 비율로 함유하는 모노머혼합물을 상기 α,β-에틸렌불포화 모노머의 합계 100중량부에 대해 0.5~5중량부의 비율로 라디칼 중합성 유화제를 사용하여 에멀젼 중합시키는 것에 의해 수득되며, 산가가 0~15의 수성 수지분산체를 함유하는 것을 특징으로 하는 코팅용 수지조성물.
  5. 제3항 또는 제4항에 있어서, 수지고형분에 대하여 1/100~1/10의 중량비로 크롬(V I)이온을 함유하는 것을 특징으로 하는 코팅용 수지조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920002936A 1991-02-27 1992-02-25 수성 수지분산체 및 코팅용 수지조성물 KR100205630B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP91-033133 1991-02-27
JP3033133A JP2554401B2 (ja) 1991-02-27 1991-02-27 水性樹脂分散体および被覆用樹脂組成物

Publications (2)

Publication Number Publication Date
KR920016612A true KR920016612A (ko) 1992-09-25
KR100205630B1 KR100205630B1 (ko) 1999-07-01

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Country Status (6)

Country Link
US (1) US5380784A (ko)
EP (1) EP0501666B1 (ko)
JP (1) JP2554401B2 (ko)
KR (1) KR100205630B1 (ko)
CA (1) CA2061418A1 (ko)
DE (1) DE69214687T2 (ko)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5912293A (en) * 1994-08-18 1999-06-15 Allied Colloids Limited Aqueous polymer dispersions for coating wood
DE69523019T2 (de) * 1994-12-09 2002-02-07 Fuji Photo Film Co., Ltd. Feine Polymerpartikel mit heterogener Phasenstruktur, photographisches lichtempfindliches Silberhalogenidmaterial feine Polymerpartikel enthaltend und Bilderzeugungsverfahren
JP3836904B2 (ja) * 1996-05-16 2006-10-25 日新製鋼株式会社 耐アルカリ性に優れた有機被膜処理電気亜鉛めっき鋼帯の製造方法
US5866042A (en) * 1997-07-18 1999-02-02 Betzdearborn Inc. Methods and compositions for inhibiting corrosion
US6037390A (en) * 1997-12-31 2000-03-14 E. I. Du Pont De Nemours And Company Smear resistant pigmented ink jet inks containing β-diketone or ureido dispersants
CA2348895C (en) 1998-11-20 2005-04-12 The Sherwin-Williams Company Curable compositions comprising acetoacetoxy and imine functionality
DE10011387A1 (de) * 2000-03-09 2001-09-13 Basf Ag Beschichtungsmassen auf Basis emissionsarmer Bindemittel
GB0015245D0 (en) * 2000-06-22 2000-08-16 Avecia Ltd Composition and process
US6756459B2 (en) * 2000-09-28 2004-06-29 Rohm And Haas Company Binder compositions for direct-to-metal coatings
US20030134973A1 (en) * 2002-01-15 2003-07-17 Chen Robert Gow-Sheng Waterborne latexes for anti-corrosive and solvent-resistant coating compositions
DE10239932B4 (de) * 2002-08-21 2006-12-07 Clariant Produkte (Deutschland) Gmbh Copolymere aus Alkylenoxiden und Glycidylethern und deren Verwendung als polymerisierbare Emulgatoren
US7388068B2 (en) * 2002-08-21 2008-06-17 Clariant Produkte (Deutschland) Gmbh Copolymers made of alkylene oxides and glycidyl ethers and use thereof as polymerizable emulsifiers
US8906703B2 (en) 2006-12-21 2014-12-09 3M Innovative Properties Company Surface-bound fluorinated esters for amine capture
US8357540B2 (en) 2006-12-21 2013-01-22 3M Innovative Properties Company Polymeric substrates with fluoroalkoxycarbonyl groups for amine capture
JP2009242481A (ja) * 2008-03-28 2009-10-22 Jsr Corp 水系バインダー用ポリマー組成物
JP5121017B2 (ja) * 2008-06-26 2013-01-16 日本ペイント株式会社 水性塗料組成物
AU2011231745A1 (en) 2010-03-23 2012-11-08 Basf Se Paper coating or binding formulations and methods of making and using same
US9102848B2 (en) 2011-02-28 2015-08-11 Basf Se Environmentally friendly, polymer dispersion-based coating formulations and methods of preparing and using same
EP2765142A4 (en) * 2011-10-07 2015-05-27 Dai Ichi Kogyo Seiyaku Co Ltd EMULSION POLYMERIZATION PROCEDURE USING A REACTIVE EMULSIFICATION AGENT, AQUEOUS POLYMER DISPERSION MADE IN THIS PROCESS, AND POLYMERIC FILM
CA2992498C (en) * 2015-07-20 2022-11-22 Dow Global Technologies Llc A coating additive
CN109517104B (zh) * 2018-11-20 2021-03-26 东方雨虹民用建材有限责任公司 一种外墙涂料用乳液及其制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1241226A (en) * 1967-11-25 1971-08-04 Basf Ag Air-drying coating materials and impregnants and production of coatings and impregnations therefrom
ES450388A1 (es) * 1975-08-08 1977-12-01 Hoechst Ag Procedimiento para obtener dispersiones de plastico.
US4250070A (en) * 1978-01-26 1981-02-10 Basf Aktiengesellschaft Aqueous dispersions, containing hydrazine derivatives, of carbonyl-containing copolymers
DE2927932A1 (de) * 1979-07-11 1981-02-05 Hoechst Ag Vinylpolymer mit acetylacetoxygruppen, verfahren zu seiner herstellung und daraus erhaltenes mittel
US4503099A (en) * 1983-06-15 1985-03-05 Borg-Warner Corporation Heat transfer surfaces having scale resistant polymer coatings thereon
DE3329622A1 (de) * 1983-08-17 1985-02-28 Bayer Ag, 5090 Leverkusen Thermoplastische formmassen aus polymerisaten mit eingebauten acetylacetatgruppen
DE3700534A1 (de) * 1987-01-10 1988-07-21 Basf Ag Waessrige polymerdispersionen fuer die holzbeschichtung
US4906684A (en) * 1988-12-09 1990-03-06 Rtz Chemicals, Ltd. Ambient temperature curing polymer compositions containing acetoacetoxyethyl methacrylate, glycidyl methacrylate and a polymerizable acid
DE3935137A1 (de) * 1989-10-21 1991-04-25 Hoechst Ag Urethangruppen enthaltende copolymerisate auf der basis von ethylenisch ungesaettigten monomeren, verfahren zu ihrer herstellung und ihre verwendung

Also Published As

Publication number Publication date
KR100205630B1 (ko) 1999-07-01
DE69214687D1 (de) 1996-11-28
EP0501666A1 (en) 1992-09-02
JPH04272903A (ja) 1992-09-29
DE69214687T2 (de) 1997-05-28
CA2061418A1 (en) 1992-08-28
JP2554401B2 (ja) 1996-11-13
US5380784A (en) 1995-01-10
EP0501666B1 (en) 1996-10-23

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