KR920016419A - 신규한 테트라알킬피페리딘 화합물 - Google Patents
신규한 테트라알킬피페리딘 화합물 Download PDFInfo
- Publication number
- KR920016419A KR920016419A KR1019920002409A KR920002409A KR920016419A KR 920016419 A KR920016419 A KR 920016419A KR 1019920002409 A KR1019920002409 A KR 1019920002409A KR 920002409 A KR920002409 A KR 920002409A KR 920016419 A KR920016419 A KR 920016419A
- Authority
- KR
- South Korea
- Prior art keywords
- alkyl
- compound
- formula
- hydrogen
- mole
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title claims 21
- 125000000217 alkyl group Chemical group 0.000 claims 26
- 229910052739 hydrogen Inorganic materials 0.000 claims 15
- 239000001257 hydrogen Substances 0.000 claims 15
- 150000002431 hydrogen Chemical group 0.000 claims 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 6
- 125000003545 alkoxy group Chemical group 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 125000003342 alkenyl group Chemical group 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 3
- 229920005989 resin Polymers 0.000 claims 3
- 239000011347 resin Substances 0.000 claims 3
- 229920000178 Acrylic resin Polymers 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- 229920000180 alkyd Polymers 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims 2
- 229910052736 halogen Inorganic materials 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 239000004922 lacquer Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 229920000647 polyepoxide Polymers 0.000 claims 2
- 229920001225 polyester resin Polymers 0.000 claims 2
- 239000004645 polyester resin Substances 0.000 claims 2
- 229920001228 polyisocyanate Polymers 0.000 claims 2
- 239000005056 polyisocyanate Substances 0.000 claims 2
- 125000006704 (C5-C6) cycloalkyl group Chemical group 0.000 claims 1
- 125000002252 acyl group Chemical group 0.000 claims 1
- 125000005037 alkyl phenyl group Chemical group 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000001301 oxygen Chemical group 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/08—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms
- C07D211/10—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms
- C07D211/14—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hydrocarbon or substituted hydrocarbon radicals directly attached to ring carbon atoms with radicals containing only carbon and hydrogen atoms attached to ring carbon atoms with hydrocarbon or substituted hydrocarbon radicals attached to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
- C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D211/56—Nitrogen atoms
- C07D211/58—Nitrogen atoms attached in position 4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/48—Stabilisers against degradation by oxygen, light or heat
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Hydrogenated Pyridines (AREA)
- Plural Heterocyclic Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- 하기 일반식(I)의 화합물;상기식에서, R은 수소,산소, -OH, C1-8알킬, -O-C1-8알킬,-O-CO-C1-8알킬, -O-CO-C1-8알킬, -O-CO-페닐 또는 -COR5이고 R5는 -C(R3)=CH2,C1-6알킬, 페닐, -CO-페닐,-NR7R8, -COC6H5,-CH2-C6H5, -CO-OC1-12알킬 또는 -COOH이고, R7은 수소, C1-12알킬, C5-6사이클로알킬, 페닐, 페닐-C1-4알킬, 또는1-2알킬페닐이고, R8은 C1-12알킬 또는 수소이고, R1은 각각 독립적으로 -CH3또는 -CH2(C1-4알킬)이거나, 또는 2개의 R1그룹이 함께 -(CH2)5-그룹을 형성하고, R2는 각각 독립적으로 수소 또는 -CH3또는 -CH2(C1-4알킬)이거나, 또는 2개의 R2그룹이 함께 (CH2)5-그룹을 형성하고, R3는 각각 독립적으로 수소 또는 C1-4알킬이고, X는 하기 일반식,,γ 또는의 그룹이고,R10은C1-22알킬, C2-22알케닐,-N-(C1-4알킬)2, -NH(C1-4알킬)또는 할로겐이고, R6은 수소, 할로겐, C1-8알킬 또는 C2-8알케닐이거나 또는 R10은 C1-22알콕시이고, R6은 수소, C1-8알킬 도는 C1-8알킬 또는 C1-8알콕시이나, 단 R10이 알콕시이고 R이 아실일때 R6은 수소가 아니면, X1은이고, n는 1또는 2이고, A는 -S-또는 -O-이다.
- 제1항에 있어서, R이 수소, C1-4알킬, 0-C1-4알킬 또는 -CO-R5´(여기서, R5´는 -CH=CH2, C1-4알킬 또는 -CO-O-C1-4알킬이다)인 화합물.
- 제1항에 잇어서, X가 일반식(α´)또는 (β´)의 그룹인 화합물 :상기식에서, R10´는 C1-4알킬, C2-4알케닐, -N〔C1-4알킬〕2, -NH(C1-4알킬)및 페닐중에서 선택되고, R6´는 수소 또는 메틸이거나 또는 R10´는 C1-4알콕시이고, R6´는 수소, C1-4알킬 또는 C1-4알콕시이거나, 단 R10´가 알콕시이고 R´가 아실일때, R6´는 수소가 아니며, n은 1또는 2이다.
- 제1항에 잇어서, 각각의 R1및 각각의 R2가 메틸인 화합물.
- 제1항에 잇어서, R3가 -CH3또는 수소인 화합물
- 제1항에 있어서, 실시예 1내지 7중 어느 하나와 관련하여 정의한 바와 본질적으로 같은 일반식(Ⅰ)의 화합물.
- 승온에서, ⅰ)하기 일반식(Ⅱ)의 화합물 2몰을 하기 일반식(Ⅲ)의 화합물 1몰과 반응시키거나 또는 ⅱ)일반식 (Ⅱ)의 화합물 1몰을 하기 일반식(Ⅲa)의 화합물 1몰과 반응시킴을 포함하는 제1항에 정의된 일반식(Ⅰ)화합물위 제조방법 :상기식에서, R,R1,R2,R3,X및 X1은 제1항에서 저의한 바와 같고, R4는 수소, 메틸 또는 에틸이다.
- 승온에서, (ⅲ)하기 일반식(Ⅳ)의 화합물 2몰을 하기 일반식(Ⅴ)의 화합물 1몰과 반응시키거나 또는 (ⅳ)일반식(Ⅳ)의 화합물 1몰을 하기 일반식(Ⅴa)의 화합물 1몰과 반응시킴을 포함하는 제1항에 정의된 일반식(Ⅰ)화합물의 제조방법 :상기식에서, R,R1,R2,R3,X및 X1은 제1항에서 정의한 바와같고, R14는 수소, 메틸 또는 에틸이다.
- 제7항에 잇어서, 실시얘 1내지 12중 어느 하나와 관련하여 개시한 바와 본질적으로 같은 방법.
- 중합체성 물질과 제1항에 정의된 일반식(Ⅰ)의 화합물을 포함하는 조성물.
- 제1항에 정의된 일반식(Ⅰ)의 화합물 하나 이상을 아크릴, 알키드 또는 폴리에스테르 수지(경우에 따라 멜라민/포름알데하이드 수지, 에폭사이드 수지 또는 폴리이소시아네이트와 가교결합될 수 있음)에 혼입함을 포함하는, 상기 수지를 기재로 하는 래커 조성물을 안정화시키는 방법.
- 제1항에 정의된 일반식(Ⅰ)의 화합물 하나 이상을 함유하는, 아크릴, 알키드 및/또는 폴리에스테르 수지(경우에 따라 멜라민/포름알데하이드 수지, 에폭사이드 수지 또는 폴리이소시아네이트와 가교결합될 수 있음)를 기재로 하는 래커 조성물.
- 적용에 A내지 D중 어느 하나와 관련하여 개시한 바와 본질적으로 같은 조성물.
- 제1항에 정의된 일반식(Ⅰ)의 화합물 하나 이상이 적용된 플라스틱 물질.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB919103415A GB9103415D0 (en) | 1991-02-19 | 1991-02-19 | Improvements in or relating to organic compounds |
| GB9103415.7 | 1991-02-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR920016419A true KR920016419A (ko) | 1992-09-24 |
Family
ID=10690207
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019920002409A KR920016419A (ko) | 1991-02-19 | 1992-02-18 | 신규한 테트라알킬피페리딘 화합물 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5306823A (ko) |
| JP (1) | JPH0578318A (ko) |
| KR (1) | KR920016419A (ko) |
| CA (1) | CA2061404A1 (ko) |
| CH (1) | CH683688A5 (ko) |
| DE (1) | DE4203771A1 (ko) |
| FR (1) | FR2672889B1 (ko) |
| GB (2) | GB9103415D0 (ko) |
| IT (1) | IT1262952B (ko) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1492494A (en) * | 1975-05-28 | 1977-11-23 | Sankyo Co | Derivatives of 4-aminopiperidine |
| FR2587340B1 (fr) * | 1985-09-13 | 1990-04-20 | Sandoz Sa | Nouvelles tetraalkylpiperidines, leur preparation et leur utilisation comme stabilisants des matieres polymeres |
| GB8626609D0 (en) * | 1986-11-07 | 1986-12-10 | Sandoz Ltd | Organic compounds |
| DE3823112A1 (de) * | 1988-07-08 | 1990-01-11 | Basf Ag | 2,6-polyalkyl-piperidin-4-amide, deren verwendung als stabilisatoren, insbesondere fuer kunststoffe, sowie diese amide enthaltendes organisches material |
| EP0389427B1 (en) * | 1989-03-21 | 1994-04-27 | Ciba-Geigy Ag | Compounds containing both uv-absorber and 1-hydrocarbyloxy hindered amine moieties and stabilized compositions |
| DE69012619T2 (de) * | 1989-03-21 | 1995-01-26 | Ciba Geigy Ag | Bis(1-Hydrocarbyloxy-2,2,6,6-tetramethylpiperidin-4-yl)-amin-derivate und stabilisierte Zusammensetzungen. |
-
1991
- 1991-02-19 GB GB919103415A patent/GB9103415D0/en active Pending
-
1992
- 1992-02-10 DE DE4203771A patent/DE4203771A1/de not_active Withdrawn
- 1992-02-12 FR FR9201660A patent/FR2672889B1/fr not_active Expired - Fee Related
- 1992-02-14 US US07/836,027 patent/US5306823A/en not_active Expired - Fee Related
- 1992-02-17 CH CH465/92A patent/CH683688A5/de not_active IP Right Cessation
- 1992-02-18 KR KR1019920002409A patent/KR920016419A/ko not_active Application Discontinuation
- 1992-02-18 JP JP4030948A patent/JPH0578318A/ja active Pending
- 1992-02-18 GB GB9203363A patent/GB2252974B/en not_active Expired - Fee Related
- 1992-02-18 IT ITRM920102A patent/IT1262952B/it active IP Right Grant
- 1992-02-18 CA CA002061404A patent/CA2061404A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0578318A (ja) | 1993-03-30 |
| FR2672889A1 (fr) | 1992-08-21 |
| CH683688A5 (de) | 1994-04-29 |
| ITRM920102A0 (it) | 1992-02-18 |
| GB2252974B (en) | 1995-05-24 |
| IT1262952B (it) | 1996-07-23 |
| GB2252974A (en) | 1992-08-26 |
| GB9103415D0 (en) | 1991-04-03 |
| ITRM920102A1 (it) | 1993-08-18 |
| DE4203771A1 (de) | 1992-08-20 |
| US5306823A (en) | 1994-04-26 |
| CA2061404A1 (en) | 1992-08-20 |
| FR2672889B1 (fr) | 1995-05-12 |
| GB9203363D0 (en) | 1992-04-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |