KR910008116A - Stable and Thickened Liquid Washing Composition Containing Bleach - Google Patents

Stable and Thickened Liquid Washing Composition Containing Bleach Download PDF

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KR910008116A
KR910008116A KR1019900015653A KR900015653A KR910008116A KR 910008116 A KR910008116 A KR 910008116A KR 1019900015653 A KR1019900015653 A KR 1019900015653A KR 900015653 A KR900015653 A KR 900015653A KR 910008116 A KR910008116 A KR 910008116A
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composition
alkali metal
sodium
potassium
mixtures
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KR1019900015653A
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Korean (ko)
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말론 와이스 로드니
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리챠드 챨스 위트
더 프록터 앤드 갬블 캄파니
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Publication of KR910008116A publication Critical patent/KR910008116A/en

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Stored Programmes (AREA)
  • Saccharide Compounds (AREA)

Abstract

Liquid cleaning compositions displaying enhanced physical stability in the presence of bleach are provided, comprising a chlorine bleach ingredient, cross-linked polycarboxylate polymer, a rheology stabilizing agent, and a buffering agent to maintain the pH of the composition above about 10. Preferred liquid automatic dishwashing detergent compositions containing builder and optional surfactant and metalate, and displaying shear thinning behavior, are disclosed.

Description

표백제를 함유하는 안정하고 농후화된 액체 세척 조성물Stable and Thickened Liquid Washing Composition Containing Bleach

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (33)

(a) 약0.2 내지 약 2.5중량%의 이용가능한 염소를 제조하는 염소 표백 성분; (b) 가교 결합된 폴리카복실레이트 중합체 농후화제 약 0.1 내지 약 10중량%; (c)일반식(a) about 0.2 to about 2.5 weight percent of a chlorine bleach component to make available chlorine; (b) about 0.1 to about 10 weight percent of a crosslinked polycarboxylate polymer thickener; (c) general formula (여기서, X,Y 및 Z는 각각-H,-COO-M-,-Cl,-Br,-SO3 -M2,-NO2,-DCH3또는 C1-C4알킬이고, M은 수소 또는 알칼리 금속이다)를 갖는 물성 안정화제 또는 이의 혼합물 약 0.05내지 약 5중량%; 및 (d) 조성물에 약 10 이상의 pH를 제공하기에 충분한 알칼리성 완충제로 이루어진 액체 세척 조성물.(Wherein, X, Y and Z are each - H, - COO - M - , - Cl, - Br, - SO 3 - M 2, - NO 2, - a DCH or 3 C 1 -C 4 alkyl, M is From about 0.05 to about 5 weight percent of a physical stabilizer or mixture thereof; And (d) an alkaline buffer sufficient to provide the composition with a pH of at least about 10. 제1항에 있어서, (a) 세제 계면활성제 0 내지 약 5%; 및 (b) 세척 증강제 물질 약 5 내지 약 50%를 추가로 함유하는 액체 자동 식기세척 세제 조성물.The process of claim 1, wherein (a) 0 to about 5% detergent surfactant; And (b) about 5 to about 50% of a wash enhancer material. 제2항에 있어서, 양성 금속 음이온의 알칼리 금속염 0 내지 약 1%를 추가로 함유하며, 약 40 내지 약 800dyne/㎠의 겉보기 항복가를 갖는 조성물.The composition of claim 2 further comprising 0 to about 1% of an alkali metal salt of the amphoteric metal anion and having an apparent yield value of about 40 to about 800 dyne / cm 2. 제1항에 있어서, 염소 표백 성분이 나트륨 차아염소산염, 칼륨 차아염소산염 및 이외 혼합물로 이루어진 그룹 중에서 선택된 조성물.The composition of claim 1 wherein the chlorine bleach component is selected from the group consisting of sodium hypochlorite, potassium hypochlorite and other mixtures. 제1항에 있어서, 조성물의 중량을 기준으로 하여 약 0.5 내지 약 1.5%의 이용가능한 염소를 제공하는 염소표백 성분을 함유하는 조성물.The composition of claim 1 comprising a chlorine bleach component that provides from about 0.5 to about 1.5% of available chlorine by weight of the composition. 제4항에 있어서, 조성물의 중량을 기준으로 하여 약0.5 내지 약 1.5%의 이용가능한 염소를 제공하는 염소표백 성분을 함유하는 조성물.The composition of claim 4 comprising a chlorine bleach component that provides from about 0.5 to about 1.5% of available chlorine by weight of the composition. 제1항에 있어서, 폴리카복실레이트 중합체 농후화제의 분자량이 약 750,000 내지 4,000,000인 조성물.The composition of claim 1 wherein the polycarboxylate polymer thickening agent has a molecular weight of about 750,000 to 4,000,000. 제1항에 있어서, 약 0,25 내지 약 5%의 폴리카복실레이트 중합체 농후화제를 함유하는 조성물.The composition of claim 1 containing from about 0,25 to about 5% polycarboxylate polymer thickening agent. 제7항에 있어서, 약 0,5 내지 약 2%의 폴리카복실레이트 중합체 농후화제를 함유하는 조성물.8. The composition of claim 7, which contains about 0,5 to about 2% polycarboxylate polymer thickening agent. 제8항에 있어서, 약 0.5 내지 약 약 2%의 폴리카복실레이트 중합체 농후화제를 함유하는 조성물.The composition of claim 8 containing from about 0.5 to about 2% polycarboxylate polymer thickening agent. 제1항에 있어서, 물성 안정화제 중의 Z가 수소인 조성물.The composition of claim 1 wherein Z in the property stabilizer is hydrogen. 제11항에 있어서, 물성 안정화제가 벤조산, 프탈산, 톨루산, 또는 이의 염 또는 혼합물인 조성물.The composition of claim 11 wherein the physical property stabilizer is benzoic acid, phthalic acid, toluic acid, or a salt or mixture thereof. 제1항에 있어서, 약 0.1 내지 약 2%의 몰성 안정화제를 함유하는 조성물.The composition of claim 1 containing from about 0.1 to about 2% of a molar stabilizer. 제12항에 있어서, 약 0.2 내지 약 1%의 몰성 안정화제를 함유하는 조성물.The composition of claim 12 containing from about 0.2 to about 1% of a molar stabilizer. 제13항에 있어서, 약 0.2 내지 약 1%의 몰성 안정화제를 함유하는 조성물.The composition of claim 13 containing from about 0.2 to about 1% of a molar stabilizer. 제1항에 있어서, 알칼리성 완중제가 알칼리 금속 실리케이트, 알칼리 금속 카보네이트, 알칼리 금속 하이드록사이드 및 이의 혼합물로 이루어진 그룹 중에서 선택된 조성물.The composition of claim 1 wherein the alkaline buffering agent is selected from the group consisting of alkali metal silicates, alkali metal carbonates, alkali metal hydroxides and mixtures thereof. 제1항에 있어서, 약 11.5 이상의 pH를 갖는 조성물을 제공하기에 충분한 알칼리성 완충제를 함유하는 조성물.The composition of claim 1 containing sufficient alkaline buffer to provide a composition having a pH of at least about 11.5. 제16항에 있어서, 약 11.5 이상의 pH를 갖는 조성물을 제공하기에 충분한 알칼리성 완충제를 함유하는 조성물.The composition of claim 16 containing sufficient alkaline buffer to provide a composition having a pH of at least about 11.5. 제2항에 있어서, 계면활성제가 캡핑된 프로필렌 옥사이드, 에틸렌 옥사이드 블록 공중합체: 캡핑딘 잔여 하이드록실을 갖는 모노－. 디－, 또는 폴리－하이드록실 화합물과 에틸렌 옥사이드 및 프로필렌 옥사이드의 축합 생성물: 모노－ 및/또는 디－(C8-14)알킬디페닐 옥사이드 모노－및/또는 디－설포네이트의 알칼리 금속염:C8-18알킬실페이트: C8-18알킬 실포네이트: 및 이의 혼합물로 이루어진 그룹중에서 선택된 조성물.3. The propylene oxide, ethylene oxide block copolymer of claim 2, wherein the surfactant is capped: mono with cappingdine residual hydroxyl. Condensation products of di- or poly-hydroxyl compounds with ethylene oxide and propylene oxide: Alkali metal salts of mono- and / or di- (C 8-14 ) alkyldiphenyl oxide mono- and / or di-sulfonates: C 8-18 alkylsulfate: A composition selected from the group consisting of C 8-18 alkyl silfonates: and mixtures thereof. 제2항에 있어서, 약 0.1 내지 2.5%의 계면활성제를 함유하는 조성물.The composition of claim 2 containing from about 0.1 to 2.5% of a surfactant. 제19항에 있어서, 약 0.1 내지 2.5%의 계면활성제를 함유하는 조성물.The composition of claim 19 containing from about 0.1 to 2.5% of a surfactant. 제2항에 있어서, 증강제가 알칼리 금속 트리폴리포스페이트, 알칼리 금속 피로포스페이트, 알칼리 금속실리케이트, 알칼리 금속 카보네이트, 폴리카복실레이트 및 이의 혼합물로 이루어진 그룹 중에서 선택된 조성물.The composition of claim 2 wherein the enhancer is selected from the group consisting of alkali metal tripolyphosphates, alkali metal pyrophosphates, alkali metal silicates, alkali metal carbonates, polycarboxylates, and mixtures thereof. 제2항에 있어서, 약 15 내지 약 40%의 증강제를 함유하는 조성물.The composition of claim 2 containing from about 15 to about 40% of an enhancer. 제22항에 있어서, 약 15 내지 약 40%의 증강제를 함유하는 조성물.The composition of claim 22 containing from about 15 to about 40% of an enhancer. 제3항에 있어서, 양성 금속 음이온의 알칼리 금속염이 나트륨 또는 칼륨 알루미네이트 나트륨 또는 칼륨징케이트, 나트륨 또는 칼륨 스타네이트(Ⅳ), 나트륨 또는 칼륨 티타네이트(Ⅳ) 또는 이의 혼합물인 조성물.4. The composition of claim 3, wherein the alkali metal salt of the amphoteric metal anion is sodium or potassium aluminate sodium or potassium zicate, sodium or potassium stannate (IV), sodium or potassium titanate (IV) or mixtures thereof. 제3항에 있어서, 약 0.01내지 약 0.1%의 양성 금속 음이온의 알칼리 금속염을 함유하는 조성물.The composition of claim 3 containing from about 0.01 to about 0.1% of an alkali metal salt of an amphoteric metal anion. 제25항에 있어서, 약 0.01내지 약 0.1%의 양성 금속 음이온의 알칼리 금속염을 함유하는 조성물.The composition of claim 25 containing from about 0.01 to about 0.1% of an alkali metal salt of an amphoteric metal anion. 제19항에 있어서, 증강제가 알칼리 금속 트리폴리포스페이트, 알칼리 금속 피로포스페이트, 알칼리 금속실리케이트, 알칼리 금속 카보네이트, 폴리카복실레이트 및 이의 혼합물로 이루어진 그룹 중에서 선택되고, 염소표백 성분이 나트륨 차아염소산염, 칼륨차아염소산염, 및 이의 혼합물로 이루어진 ㄱ룹 중에서 선택된 조성물.20. The composition of claim 19 wherein the enhancer is selected from the group consisting of alkali metal tripolyphosphates, alkali metal pyrophosphates, alkali metal silicates, alkali metal carbonates, polycarboxylates and mixtures thereof, wherein the chlorine bleach component is sodium hypochlorite, potassium hypochlorite And a group consisting of a mixture thereof. 제28항에 있어서 폴리카복실레이트 중합체 농후화제의 분자량이 약 750,000 내지 약 4,000,000이고 물성안정화제가 벤조산, 프탈산, 톨루산, 또는 이의 염 또는 혼합물인 조성물.The composition of claim 28 wherein the polycarboxylate polymer thickening agent has a molecular weight of about 750,000 to about 4,000,000 and the physical stabilizer is benzoic acid, phthalic acid, toluic acid, or a salt or mixture thereof. 제29항에 있어서, 알칼리성 완충제가 알칼리 금속 실리케이트, 알칼리 금속 카보네이트, 알칼리 금속 하이드록사이드 및 이의 혼합물로 이루어진 그룹 중에서 선택되고 pH가 약 11.5이상인 조성물.The composition of claim 29 wherein the alkaline buffer is selected from the group consisting of alkali metal silicates, alkali metal carbonates, alkali metal hydroxides and mixtures thereof and has a pH of at least about 11.5. 제30항에 있어서 (a)약0.5 내지 약 1.5중량%의 이용가능한 염소를 제공하는 염소 표백성분:(b)가교결합된 폴리카복실레이트 중합체 농후화제 약 0.5내지 약 2중량%: (c)물성 안정화제 약 0.2 내지 약 1중량%: (d)계면활성제 약 0.1 내지 약 2.5 중량%: 및 (e)약 15 내지 약 40중량%의 증강제로 이루어진 조성물.31. A chlorine bleach component according to claim 30 which provides about 0.5 to about 1.5 weight percent of available chlorine: (b) about 0.5 to about 2 weight percent of a crosslinked polycarboxylate polymer thickener: (c) About 0.2 to about 1 weight percent stabilizer: (d) about 0.1 to about 2.5 weight percent surfactant; and (e) about 15 to about 40 weight percent enhancer. 제30항에 있어서, 양성 금속 음이온의 알칼리 금속염이 나트륨 또는 칼륨 알루미네이트, 나트륨 또는 칼륨징케이트. 나트륨 또는 칼륨 스타네이트(Ⅳ). 나트륨 또는 칼륨 티타네이트(Ⅳ) 또는 이의 혼합물인 조성물.32. The sodium or potassium aluminate, sodium or potassium catenate of claim 30, wherein the alkali metal salt of the amphoteric metal anion is sodium or potassium aluminate. Sodium or potassium stannate (IV). Sodium or potassium titanate (IV) or mixtures thereof. 제32항에 있어서, 약 0.01내지 약 0.1%의 양성 금속 음이온의 알칼리 금속염을 함유하는 조성물.33. The composition of claim 32, comprising from about 0.01 to about 0.1% of an alkali metal salt of an amphoteric metal anion. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019900015653A 1989-10-04 1990-09-29 Stable and Thickened Liquid Washing Composition Containing Bleach KR910008116A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8330158D0 (en) * 1983-11-11 1983-12-21 Procter & Gamble Ltd Cleaning compositions
NZ226174A (en) * 1987-09-23 1991-03-26 Colgate Palmolive Co Aqueous cleaning composition; no- or low-phosphorus built mixture
CA1321115C (en) * 1987-12-30 1993-08-10 Robert Corring Gel detergent compositions
US4836948A (en) * 1987-12-30 1989-06-06 Lever Brothers Company Viscoelastic gel detergent compositions
US4859358A (en) * 1988-06-09 1989-08-22 The Procter & Gamble Company Liquid automatic dishwashing compositions containing metal salts of hydroxy fatty acids providing silver protection
US4988452A (en) * 1988-06-09 1991-01-29 The Procter & Gamble Company Liquid automatic dishwashing detergent compositions containing bleach-stable nonionic surfactant

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HK1006466A1 (en) 1999-02-26
JP2766064B2 (en) 1998-06-18
JPH03166299A (en) 1991-07-18
AU648993B2 (en) 1994-05-12
EP0421738A2 (en) 1991-04-10
PT95491A (en) 1991-07-05
FI904873A0 (en) 1990-10-03
ES2087132T3 (en) 1996-07-16
AU6378690A (en) 1991-04-11
EP0421738A3 (en) 1991-10-16
EP0421738B1 (en) 1996-05-22
TR24870A (en) 1992-07-01
ATE138410T1 (en) 1996-06-15
CA2026332C (en) 1995-02-21
CA2026332A1 (en) 1991-04-05
DE69027086D1 (en) 1996-06-27
IE903545A1 (en) 1991-04-10

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