JP2594351B2 - Mold remover composition - Google Patents
Mold remover compositionInfo
- Publication number
- JP2594351B2 JP2594351B2 JP1060229A JP6022989A JP2594351B2 JP 2594351 B2 JP2594351 B2 JP 2594351B2 JP 1060229 A JP1060229 A JP 1060229A JP 6022989 A JP6022989 A JP 6022989A JP 2594351 B2 JP2594351 B2 JP 2594351B2
- Authority
- JP
- Japan
- Prior art keywords
- oxygen
- mold
- composition
- bleaching
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Detergent Compositions (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、酸素系漂白剤を汚れ除去主成分として含む
カビ取り剤組成物に関する。Description: TECHNICAL FIELD The present invention relates to a mold remover composition containing an oxygen-based bleach as a main component for removing stains.
色素に由来する汚れ、換気扇などの頑固な油汚れ、風
呂釜、排水管などの洗浄しにくい場所の汚れは、洗浄を
主目的とする普通の洗剤あるいは漂白洗浄剤ではなかな
か落とすことができない。Stain derived from pigments, stubborn oil stains such as ventilation fans, and stains in hard-to-wash places such as bathtubs and drain pipes cannot be easily removed with ordinary detergents or bleaching detergents whose main purpose is washing.
これらの汚れの除去には塩素系または酸素系漂白剤を
汚れ除去主成分とする組成物の漂白作用あるいは発泡作
用が利用されている。To remove these stains, a bleaching action or a foaming action of a composition containing a chlorine-based or oxygen-based bleach as a main component for removing stains is used.
一例をあげると、浴室の天井、タイル目地、プラスチ
ックの壁や台所の三角コーナーなどの黒ずみ汚れはClad
osporium属のカビの生産する色素が原因であり、クレン
ザーや活性剤だけでは除去しがたいので、次亜塩素酸ナ
トリウム水溶液の漂白作用により除去されている。For example, dark stains such as bathroom ceilings, tile joints, plastic walls and kitchen triangle corners are Clad
It is caused by the pigment produced by mold of the genus osporium, and it is difficult to remove it only with a cleanser or an activator. Therefore, it is removed by the bleaching action of an aqueous solution of sodium hypochlorite.
しかしながら、次亜塩素酸ナトリウムを使用したカビ
取り剤は、性能は優れているが、目や皮膚に対する危険
性が大きく、また特有の塩素系の臭いが強く、狭い浴室
などで使用するには抵抗がある上、誤って酸性の洗剤と
併用したりすると有毒ガスを発生するという問題があ
る。However, although the mold remover using sodium hypochlorite is excellent in performance, it has a large danger to eyes and skin, and has a strong chlorine-based odor, and is resistant to use in a small bathroom. In addition, there is a problem that a toxic gas is generated when used in combination with an acidic detergent by mistake.
このため、酸素系漂白剤を使用したカビ取り剤も提案
されているが、次亜塩素酸ナトリウムを使用したカビ取
り剤に対して漂白力が劣るという欠点がある。For this reason, a mold remover using an oxygen bleach has been proposed, but there is a disadvantage that the bleaching power is inferior to a mold remover using sodium hypochlorite.
酸素系漂白剤を汚れ除去主成分とする組成物には、汚
れへの浸透、あるいは除去した汚れを分散するために少
量の界面活性剤が配合されている。A composition containing an oxygen-based bleach as a main component of soil removal contains a small amount of a surfactant to penetrate the soil or to disperse the removed soil.
本発明者らは、かかる界面活性剤について鋭意研究し
た結果、アルキルグリコシッドを界面活性剤として添加
することによって、酸素系漂白剤を汚れ除去主成分とす
る組成物のカビ汚れ除去効果を更に高め得ることを見出
し、本発明を完成するに至った。The present inventors have conducted intensive studies on such surfactants, and as a result, by adding an alkyl glycoside as a surfactant, the composition having an oxygen-based bleach as a main component for removing stains further enhances the mold stain removal effect. It was found that the present invention was obtained, and the present invention was completed.
すなわち本発明は、酸素系漂白剤を汚れ除去主成分と
する組成物に、アルキルグリコシッドを0.1〜５％配合
したことを特徴とするカビ取り剤組成物を提供するもの
である。That is, the present invention provides a mold remover composition characterized in that 0.1 to 5% of an alkyl glycoside is added to a composition containing an oxygen-based bleach as a main component for removing stains.
本発明においては、酸素系漂白剤として有機過酸、過
硫酸塩、過酸化水素、及び過炭酸ソーダ、過硼酸ソーダ
などの水溶液中で過酸化水素を生成する過酸化物が使わ
れる。In the present invention, as an oxygen-based bleaching agent, an organic peracid, a persulfate, hydrogen peroxide, and a peroxide that generates hydrogen peroxide in an aqueous solution such as sodium percarbonate and sodium perborate are used.
酸素系漂白剤の配合量は基剤、剤型、用途により異な
る。例えば顆粒品は、水溶液中で過酸化水素を生成する
過酸化物を一般に約65〜85％、液体品では過酸化水素を
一般に約２〜７％配合した商品が市販されているが、こ
れらに限定されるものではない。The amount of the oxygen-based bleach varies depending on the base, dosage form, and application. For example, granules are commercially available, which generally contain about 65 to 85% of a peroxide that produces hydrogen peroxide in an aqueous solution, and liquid products generally contain about 2 to 7% of hydrogen peroxide. It is not limited.
本発明の組成物に用いられるアルキルグリコシッドは
下記一般式で表される非イオン性界面活性剤である。The alkyl glycoside used in the composition of the present invention is a nonionic surfactant represented by the following general formula.
R1（OR2）xGy （上記式中、R1は直鎖または分岐鎖を有する炭素数８〜
18のアルキル基、アルケニル基またはアルキルフェニル
基を表し、R2は炭素数２〜４のアルキレン基を表し、Ｇ
は炭素数５〜６を有する還元糖に由来する残基であり、
ｘはその平均値が０〜５である。ｙはその平均値が１〜
10である。） 上記の一般式において、R1は炭素数９〜14のアルキル
基、R2は炭素数２〜３のアルキレン基、ｘが０〜２、ｙ
が1.1〜3.0、特に1.2〜1.45であるのが好ましい。R 1 (OR 2 ) x G y (in the above formula, R 1 has a straight or branched chain carbon number of 8 to
An alkyl group, an alkenyl group or an alkylphenyl group of 18; R 2 represents an alkylene group having 2 to 4 carbon atoms;
Is a residue derived from a reducing sugar having 5 to 6 carbon atoms,
x has an average value of 0 to 5. y has an average value of 1 to
It is 10. In the above general formula, R 1 is an alkyl group having 9 to 14 carbon atoms, R 2 is an alkylene group having 2 to 3 carbon atoms, x is 0 to 2, y
Is preferably 1.1 to 3.0, particularly 1.2 to 1.45.
Ｇは単糖もしくは２糖以上の原料によってその構造が
決定されるが、このＧ原料としては、入手性及びコスト
の面から単糖ではグルコース、フルクトースが、２糖以
上ではマルトース、スクロースが望ましい。The structure of G is determined by a raw material of monosaccharide or disaccharide or more. G raw material is preferably glucose and fructose for monosaccharide and maltose and sucrose for disaccharide or more from the viewpoint of availability and cost.
本発明においてアルキルグリコシッドは組成物中に0.
1〜５％、好ましくは0.3〜３％配合される。配合量が0.
1％未満では汚れ除去効果が充分でなく、また５％を越
えると貯蔵安定性が悪くなる他、顆粒品では粉末物性が
悪くなるという問題も生ずる。In the present invention, the alkyl glycoside is contained in the composition in an amount of 0.
1-5%, preferably 0.3-3% is blended. The blending amount is 0.
If it is less than 1%, the effect of removing dirt is not sufficient, and if it exceeds 5%, storage stability deteriorates, and in the case of granules, there is a problem that powder properties deteriorate.
本発明の組成物には、剤型、用途に応じてテトラアセ
チルエチレンジアミン、グルコースペンタアセテート、
ノナノイルオキシベンゼンスルホン酸ソーダ、無水コハ
ク酸などの漂白活性剤、炭酸塩、ケイ酸塩、水酸化アル
カリ、アンモニア、アルカノールアミンなどのpH緩衝
剤、増粘剤、研磨剤、酵素、色素、香料などが配合され
る。また、ポリオキシエチレンアルキルエーテルなどの
他の界面活性剤も併用できるが、界面活性剤の総量は５
％以下とするのが望ましい。The composition of the present invention, dosage form, depending on the use tetraacetylethylenediamine, glucose pentaacetate,
Bleaching activators such as sodium nonanoyloxybenzenesulfonate and succinic anhydride, pH buffers such as carbonates, silicates, alkali hydroxides, ammonia and alkanolamines, thickeners, abrasives, enzymes, dyes and fragrances Are blended. Further, other surfactants such as polyoxyethylene alkyl ether can be used together, but the total amount of the surfactants is 5%.
% Is desirable.
以下、本発明の実施例を挙げて説明するが、本発明は
これらの実施例に限定されるものではない。Hereinafter, the present invention will be described with reference to examples, but the present invention is not limited to these examples.
過炭酸ナトリウム10％、表−１に示す漂白活性化剤
（無水コハク酸またはエチレングリコールジメトキシア
セテート）９％、及び表−１に示す各種界面活性剤0.5
％を含有する各種カビ取り剤組成物水溶液を調製し、そ
れぞれの漂白力を以下の基準によって評価した。Sodium percarbonate 10%, bleach activator (succinic anhydride or ethylene glycol dimethoxyacetate) 9% shown in Table 1, and various surfactants 0.5 shown in Table 1
% Of various fungicide composition aqueous solutions were prepared, and the bleaching power of each was evaluated according to the following criteria.
これらの結果を表−１に示す。 Table 1 shows these results.
＜漂白力測定方法＞ モデルカビプレートを水平に置き、カビ取り モデルカビプレートを水平に置き、カビ取り剤組成物
水溶液を40μｍ滴下し、30分放置後、水洗、風乾した
後、日本電気工業株式会社製測色計1001DPを用いて明度
（Ｌ値）を測定した。<Measurement method of bleaching force> Place the model mold plate horizontally and remove the mold. Place the model mold plate horizontally and drop an aqueous solution of the fungicide composition 40 μm, leave it for 30 minutes, wash it with water, and air-dry it. The lightness (L value) was measured using a company colorimeter 1001DP.
Ｌ値が高いほどカビ漂白力は高い。 The higher the L value, the higher the mold bleaching power.
モデルカビプレート クラドスポリウム・ヘルバルム（Cladosporium herba
rum）を接種し、30℃,20日間培養した素焼き板をモデル
カビプレートとした。（素焼き板のＬ値92.4、モデルカ
ビプレートのＬ値74〜78。） 実施例２ 過酸化水素３％及びアルキルグリコシッド（R1＝C10,
x＝0,G＝グルコース残基,y＝1.4）を２％または８％配
合した水溶液を調製し、40℃で１週間保存した。保存後
サンプルにエチレングリコールジメトキシアセテート９
％を配合し、実施例１と同じ方法でそれぞれの漂白力を
測定した。その結果、アルキルグリコシッド２％配合品
（本発明品）はＬ値が92であり、８％配合品（比較品）
はＬ値が89であった。Model mold plate Cladosporium herbarum
rum) and inoculated at 30 ° C. for 20 days to obtain a model plate. (L value of unglazed plate 92.4, L value of model mold plate 74-78.) Example 2 3% hydrogen peroxide and alkyl glycoside (R 1 = C 10 ,
(x = 0, G = glucose residue, y = 1.4) was prepared in 2% or 8% aqueous solution and stored at 40 ° C. for 1 week. After storage, add ethylene glycol dimethoxy acetate 9
%, And the bleaching power was measured in the same manner as in Example 1. As a result, the product containing 2% alkyl glycoside (product of the present invention) has an L value of 92 and the product containing 8% (comparative product)
Had an L value of 89.
本発明によれば、アルキルグリコシッドの優れた作用
により、酸素系漂白剤を汚れ除去主成分とするカビ取り
剤組成物の漂白作用あるいは発泡作用による汚れ除去力
を向上させることができる。ADVANTAGE OF THE INVENTION According to this invention, by the excellent effect | action of an alkyl glycoside, the stain removal power by the bleaching action or the foaming action of the mold remover composition which has an oxygen bleaching agent as a stain removal main component can be improved.
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭60−28499（ＪＰ，Ａ) 特開 昭63−37313（ＪＰ，Ａ) ──────────────────────────────────────────────────続 き Continuation of the front page (56) References JP-A-60-28499 (JP, A) JP-A-63-37313 (JP, A)
Claims (2)
物に、アルキルグリコシッドを0.1〜５％配合したこと
を特徴とするカビ取り剤組成物。A fungicide composition characterized in that 0.1 to 5% of an alkyl glycoside is added to a composition containing an oxygen bleach as a main component for removing stains.
中で過酸化水素を生成する過酸化物である請求項１記載
の組成物。2. The composition according to claim 1, wherein the oxygen-based bleach is hydrogen peroxide or a peroxide that generates hydrogen peroxide in an aqueous solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1060229A JP2594351B2 (en) | 1989-03-13 | 1989-03-13 | Mold remover composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1060229A JP2594351B2 (en) | 1989-03-13 | 1989-03-13 | Mold remover composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02238098A JPH02238098A (en) | 1990-09-20 |
| JP2594351B2 true JP2594351B2 (en) | 1997-03-26 |
Family
ID=13136135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1060229A Expired - Fee Related JP2594351B2 (en) | 1989-03-13 | 1989-03-13 | Mold remover composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2594351B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0634480B1 (en) * | 1993-07-14 | 2000-09-20 | The Procter & Gamble Company | Detergent compositions |
| US7135450B2 (en) * | 2002-07-29 | 2006-11-14 | Kao Corporation | Foamy composition for bleaching clothing |
| JP5331335B2 (en) * | 2007-12-20 | 2013-10-30 | ライオン株式会社 | Pipe cleaning composition |
| US7638474B1 (en) * | 2008-08-05 | 2009-12-29 | The Clorox Company | Natural laundry detergent compositions |
| JP6345496B2 (en) * | 2014-06-09 | 2018-06-20 | 花王株式会社 | Mold remover composition |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6028499A (en) * | 1983-07-27 | 1985-02-13 | タイホ−工業株式会社 | Detergent |
| DE3626082A1 (en) * | 1986-07-31 | 1988-02-11 | Henkel Kgaa | DISINFECTANT AND CLEANER SYSTEM FOR CONTACT LENSES |
-
1989
- 1989-03-13 JP JP1060229A patent/JP2594351B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH02238098A (en) | 1990-09-20 |
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