JPH02238098A - Stain-removing composition consisting mainly of oxygen-based bleaching agent - Google Patents
Stain-removing composition consisting mainly of oxygen-based bleaching agentInfo
- Publication number
- JPH02238098A JPH02238098A JP1060229A JP6022989A JPH02238098A JP H02238098 A JPH02238098 A JP H02238098A JP 1060229 A JP1060229 A JP 1060229A JP 6022989 A JP6022989 A JP 6022989A JP H02238098 A JPH02238098 A JP H02238098A
- Authority
- JP
- Japan
- Prior art keywords
- pref
- bleaching agent
- oxygen
- alkyl
- hydrogen peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 239000007844 bleaching agent Substances 0.000 title claims abstract description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000001301 oxygen Substances 0.000 title claims abstract description 14
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 14
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 18
- -1 alkyl glycoside Chemical class 0.000 claims abstract description 12
- 229930182470 glycoside Natural products 0.000 claims abstract description 11
- 239000007864 aqueous solution Substances 0.000 claims abstract description 7
- 150000002978 peroxides Chemical class 0.000 claims abstract description 4
- 125000000217 alkyl group Chemical group 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 125000002947 alkylene group Chemical group 0.000 abstract description 3
- 239000002736 nonionic surfactant Substances 0.000 abstract description 3
- 125000003342 alkenyl group Chemical group 0.000 abstract description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 abstract description 2
- 238000004061 bleaching Methods 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 238000009423 ventilation Methods 0.000 description 4
- 239000005708 Sodium hypochlorite Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 125000001891 dimethoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002772 monosaccharides Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229940045872 sodium percarbonate Drugs 0.000 description 2
- 229940014800 succinic anhydride Drugs 0.000 description 2
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 1
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、酸素系漂白剤を汚れ除去主成分として含む汚
れ除去用組成物に関する．
〔従来の技術及びその課題〕
色素に由来する汚れ、換気扇などの頑固な油汚れ、風呂
釜、排水管などの洗浄しにくい場所の汚れは、洗浄を主
目的とする普通の洗剤あるいは漂白洗浄剤ではなかなか
落とすことができない。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a stain removal composition containing an oxygen bleach as a main stain removal component. [Conventional technology and its problems] For stains derived from pigments, stubborn oil stains on ventilation fans, etc., and stains in hard-to-clean areas such as bathtubs and drain pipes, ordinary detergents or bleach cleaners whose main purpose is cleaning can be used. It is difficult to remove it.
これらの汚れの除去には塩素系または酸素系漂白剤を汚
れ除去主成分とする組成物の漂白作用あるいは発泡作用
が利用されている。To remove these stains, the bleaching action or foaming action of a composition containing a chlorine or oxygen bleach as the main stain removal component is utilized.
一例をあげると、浴室の天井、タイル目地、プラスチッ
クの壁や台所の三角コーナーなどの黒ずみ汚れはＣｌａ
ｄｏｓｐｏｒｉｕｍ属のカビの生産する色素が原因であ
り、クレンザーや活性剤だけでは除去しがたいので、次
亜塩素酸ナトリウム水溶液の漂白作用により除去されて
いる。For example, dark stains on bathroom ceilings, tile joints, plastic walls, and triangular corners in the kitchen can be treated with Cla.
This is caused by pigments produced by molds of the genus Dosporium, and is difficult to remove with cleansers or active agents alone, so it is removed using the bleaching action of an aqueous solution of sodium hypochlorite.
しかしながら、次亜塩素酸ナトリウムを使用したカビ取
り剤は、性能は優れているが、目や皮膚に対する危険性
が大きく、また特脊の塩素系の臭いが強《、狭い浴室な
どで使用するには抵抗がある上、誤って酸性の洗剤と併
用したりすると有毒ガスを発生するという問題がある．
このため、酸素系漂白剤を使用したカビ取り剤も提案さ
れているが、次亜塩素酸ナトリウムを使用したカビ取り
剤に対して漂白力が劣るという欠点がある。However, although mold removers using sodium hypochlorite have excellent performance, they are very dangerous to the eyes and skin, and have a particularly strong chlorine-based odor (which makes them unsuitable for use in small bathrooms, etc.). In addition to being resistant to cleaning, there is also the problem that toxic gases can be generated if used in conjunction with acidic detergents.
For this reason, mold removers using oxygen bleach have been proposed, but they have the drawback of being inferior in bleaching power to mold removers using sodium hypochlorite.
酸素系漂白剤を汚れ除去主成分とする組成物には、汚れ
への浸透、あるいは除去した汚れを分散するために少量
の界面活性剤が配合されている。Compositions containing oxygen bleach as the main stain removal ingredient contain a small amount of surfactant to penetrate into stains or disperse removed stains.
本発明者らは、かかる界面活性剤について鋭意研究した
結果、アルキルグリコシッドを界面活性剤として添加す
ることによって、酸素系漂白剤を汚れ除去主成分とする
組成物の汚れ除去効果を更に高め得ることを見出し、本
発明を完成するに至った。As a result of intensive research on such surfactants, the present inventors found that by adding an alkyl glycoside as a surfactant, the stain removal effect of a composition containing oxygen bleach as the main stain removal component can be further enhanced. This discovery led to the completion of the present invention.
すなわち本発明は、酸素系漂白剤を汚れ除去主成分とす
る組成物に、アルキルグリコシッドを０．１〜５％配合
したことを特徴とする汚れ除去用組成物を提供するもの
である。That is, the present invention provides a stain removal composition characterized in that 0.1 to 5% of alkyl glycoside is blended into a composition containing an oxygen bleach as a main stain removal component.
本発明においては、酸素系漂白剤として有機過酸、過硫
酸塩、過酸化水素、及び過炭酸ソーダ、過硼酸ソーダな
どの水溶液中で過酸化水素を生成する過酸化物が使われ
る。In the present invention, organic peracids, persulfates, hydrogen peroxide, and peroxides that produce hydrogen peroxide in an aqueous solution, such as sodium percarbonate and sodium perborate, are used as the oxygen bleaching agent.
本発明の汚れ除去用組成物には各種の基剤、剤型、用途
のものが含まれるが、例えばカビ取り剤、衣料用漂白剤
、排水管、風呂釜、換気扇清浄剤などが挙げられる。The stain removal composition of the present invention includes various bases, formulations, and uses, such as mold removers, clothing bleaches, drain pipes, bathtubs, ventilation fan cleaners, and the like.
酸素系漂白剤の配合量は基剤、剤型、用途により異なる
。例えば排水管、風呂釜、換気扇清浄剤などの顆粒品は
、水溶液中で過酸化水素を生成する過酸化物を一般に約
６５〜８５％、衣料用前処理剤などの液体品では過酸化
水素を一般に約２〜７％配合した商品が市販されている
が、これらに限定されるものではない。The amount of oxygen bleach varies depending on the base, dosage form, and purpose. For example, granular products such as drain pipe, bath kettle, and ventilation fan cleaners generally contain about 65 to 85% peroxide, which produces hydrogen peroxide in an aqueous solution, while liquid products such as pre-treatment agents for clothing contain hydrogen peroxide. Generally, products containing about 2 to 7% are commercially available, but the invention is not limited to these.
本発明の組成物に用いられるアルキルグリコシッドは下
記一般式で表される非イオン性界面活性剤である。The alkyl glycoside used in the composition of the present invention is a nonionic surfactant represented by the following general formula.
Ｒ＋（ＯＲｚ）ＸＧｙ
（上記式中、Ｒ１は直鎖または分岐鎖を有する炭素数８
〜１８のアルキル基、アルケニル基またはアルキルフェ
ニル基を表し、Ｒ２は炭素数２〜４のアルキレン基を表
し、Ｇは炭素数５〜６を有する還元糖に由来する残基で
あり、Ｘはその平均値がＯ〜５である。ｙはその平均値
が１〜１０である．）
上記の一般式において、Ｒ１は炭素数９〜１４のアルキ
ル基、Ｒ２は炭素数２〜３のアルキレン基、ＸがＯ〜２
、ｙが１．１〜３．０、特に１．２ 〜１．４５である
のが好ましい。R+(ORz)XGy (In the above formula, R1 is a linear or branched carbon number 8
~18 alkyl group, alkenyl group or alkylphenyl group, R2 represents an alkylene group having 2 to 4 carbon atoms, G is a residue derived from a reducing sugar having 5 to 6 carbon atoms, and X is a residue derived from a reducing sugar having 5 to 6 carbon atoms; The average value is O-5. The average value of y is 1 to 10. ) In the above general formula, R1 is an alkyl group having 9 to 14 carbon atoms, R2 is an alkylene group having 2 to 3 carbon atoms, and X is O-2
, y is preferably from 1.1 to 3.0, particularly from 1.2 to 1.45.
Ｇは単糖もしくは２Ｉ！以上の原料によってその構造が
決定されるが、このＧ原料としては、入手性及びコスト
の面から単糖ではグルコース、フルクトースが、２Ｉ！
以上ではマルトース、スクロースが望ましい。G is a monosaccharide or 2I! Its structure is determined by the above-mentioned raw materials, and from the viewpoint of availability and cost, monosaccharides such as glucose and fructose are used as G raw materials.
In the above cases, maltose and sucrose are preferable.
本発明においてアルキルグリコシッドは組成物中に０．
１〜５％、好ましくは０．３〜３％配合される．配合量
が０．１％未満では汚れ除去効果が充分でなく、また５
％を越えると貯蔵安定性が悪くなる他、顆粒品では粉末
物性が悪くなるという問題も生ずる。In the present invention, 0.0% of the alkyl glycoside is contained in the composition.
It is blended in an amount of 1 to 5%, preferably 0.3 to 3%. If the blending amount is less than 0.1%, the stain removal effect will not be sufficient;
If it exceeds 10%, storage stability deteriorates, and in the case of granules, the powder physical properties also deteriorate.
本発明の組成物には、剤型、用途に応じてテトラアセチ
ルエチレンジアミン、グルコースペンタアセテート、ノ
ナノイルオキシベンゼンスルホン酸ソーダ、無水コハク
酸などの漂白活性剤、炭酸塩、ケイ酸塩、水酸化アルカ
リ、アンモニア、アルカノールアミンなどのｐＨ緩［＋
１、増粘剤、研磨剤、酵素、色素、香料などが配合され
る。また、ポリオキシエチレンアルキルエーテルなどの
他の界面活性剤も併用できるが、界面活性剤の総量は５
％以下とするのが望ましい。The composition of the present invention may contain bleaching activators such as tetraacetylethylenediamine, glucose pentaacetate, sodium nonanoyloxybenzenesulfonate, succinic anhydride, carbonates, silicates, and alkali hydroxides, depending on the dosage form and use. , ammonia, alkanolamines, etc.
1. Contains thickeners, abrasives, enzymes, pigments, fragrances, etc. Other surfactants such as polyoxyethylene alkyl ether can also be used in combination, but the total amount of surfactants is 5.
% or less.
以下、本発明の実施例を挙げて説明するが、本発明はこ
れらの実施例に限定されるものではない。The present invention will be described below with reference to Examples, but the present invention is not limited to these Examples.
過炭酸ナトリウム１０％、表−１に示す漂白活性化剤（
無水コハク酸またはエチレングリコールジメトキシアセ
テート）９％、及び表−１に示す各種界面活性剤０．５
％を含有する各種カビ取り剤組成物水溶液を調製し、そ
れぞれの漂白力を以下の基準によって評価した。Sodium percarbonate 10%, bleach activator shown in Table 1 (
9% of succinic anhydride or ethylene glycol dimethoxy acetate, and 0.5% of various surfactants shown in Table 1.
%, and the bleaching power of each solution was evaluated according to the following criteria.
これらの結果を表＝１に示す。These results are shown in Table 1.
〈漂白力測定方法〉
モデルカビプレートを水平に置き、カビ取りモデルカビ
プレートを水平に置き、カビ取り剤組成物水溶液を４０
ｐ１滴下し、３０分放置後、水洗、風乾した後、日本電
気工業株式会社製測色計１００１ＤＰを用いて明度（Ｌ
値）を測定した。<Method for measuring bleaching power> Place the model mold plate horizontally, place the mold removal model mold plate horizontally, and apply 40% of the mold remover composition aqueous solution.
After adding a drop of p1 and leaving it for 30 minutes, washing with water and air drying, the brightness (L
value) was measured.
Ｌ値が高いほどカビ漂白力は高い。The higher the L value, the higher the mold bleaching power.
モデルカビプレート
タラドスボリウム・ヘルバルム（Ｃｌａｄｏｓｐｏｒｉ
ｕｍｈｅｒｂａｒｕｍ）を接種し、３０゜Ｃ．２０日間
培養した素焼き板をモデルカビプレートとした。（素焼
き板のＬ値９２．４、モデルカビプレートのＬ値７４〜
７８。）
実施例２
過酸化水素３％及びアルキルグリコシッド（Ｒ＋ ＝Ｃ
１ｏ． ｘ＝Ｏ，Ｇ＝グルコース残基．ｙ−１．４）を
２％または８％配合した水溶液を調製し、４０゜Ｃで１
週間保存した。保存後サンプルにエチレングリコールジ
メトキシアセテート９％を配合し、実施例１と同じ方法
でそれぞれの漂白力を測定した。その結果、アルキルグ
リコシッド２％配合品（本発明品）はＬ値が９２であり
、８％配合品（比較品）はＬ値が８９であった。Model mold plate Taladosborium herbalum (Cladospori)
umherbarum) and incubated at 30°C. A clay plate cultured for 20 days was used as a model mold plate. (L value of unglazed plate is 92.4, L value of model mold plate is 74 ~
78. ) Example 2 3% hydrogen peroxide and alkyl glycoside (R+ = C
1o. x=O, G=glucose residue. Prepare an aqueous solution containing 2% or 8% of y-1.4) and incubate at 40°C for 1
Saved for a week. After storage, 9% ethylene glycol dimethoxy acetate was added to the samples, and the bleaching power of each sample was measured in the same manner as in Example 1. As a result, the product containing 2% alkyl glycoside (product of the present invention) had an L value of 92, and the product containing 8% alkyl glycoside (comparative product) had an L value of 89.
本発明によれば、アルキルグリコシッドの優れた作用に
より、酸素系漂白剤を汚れ除去主成分とするカビ取り剤
、衣料用漂白剤、排水管、風呂釜、換気扇清浄剤などの
組成物の漂白作用あるいは発泡作用による汚れ除去力を
向上させることができる。According to the present invention, the excellent action of alkyl glycosides enables bleaching of compositions containing oxygen bleach as the main stain removal ingredient, such as mold removers, clothing bleaches, drain pipes, bathtubs, ventilation fan cleaners, etc. It is possible to improve the dirt removal power by the action or foaming action.
出願人代理人 古 谷 馨一９５８−Applicant's agent: Koichi Furutani 958-
Claims (1)
ルキルグリコシッドを０．１〜５％配合したことを特徴
とする汚れ除去用組成物。 ２ 酸素系漂白剤が、過酸化水素または水溶液中で過酸
化水素を生成する過酸化物である請求項１記載の組成物
。[Scope of Claims] 1. A stain removal composition comprising 0.1 to 5% of an alkyl glycoside added to a composition containing an oxygen bleach as a main stain removal component. 2. The composition according to claim 1, wherein the oxygen bleach is hydrogen peroxide or a peroxide that produces hydrogen peroxide in an aqueous solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1060229A JP2594351B2 (en) | 1989-03-13 | 1989-03-13 | Mold remover composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1060229A JP2594351B2 (en) | 1989-03-13 | 1989-03-13 | Mold remover composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02238098A true JPH02238098A (en) | 1990-09-20 |
| JP2594351B2 JP2594351B2 (en) | 1997-03-26 |
Family
ID=13136135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1060229A Expired - Fee Related JP2594351B2 (en) | 1989-03-13 | 1989-03-13 | Mold remover composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2594351B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0634480A1 (en) * | 1993-07-14 | 1995-01-18 | The Procter & Gamble Company | Detergent compositions |
| US7135450B2 (en) * | 2002-07-29 | 2006-11-14 | Kao Corporation | Foamy composition for bleaching clothing |
| JP2009149776A (en) * | 2007-12-20 | 2009-07-09 | Lion Corp | Detergent composition for pipe |
| US7638474B1 (en) * | 2008-08-05 | 2009-12-29 | The Clorox Company | Natural laundry detergent compositions |
| JP2015232057A (en) * | 2014-06-09 | 2015-12-24 | 花王株式会社 | Mold remover composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6028499A (en) * | 1983-07-27 | 1985-02-13 | タイホ−工業株式会社 | Detergent |
| JPS6337313A (en) * | 1986-07-31 | 1988-02-18 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン | Contact lens sterilizing/cleaning system |
-
1989
- 1989-03-13 JP JP1060229A patent/JP2594351B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6028499A (en) * | 1983-07-27 | 1985-02-13 | タイホ−工業株式会社 | Detergent |
| JPS6337313A (en) * | 1986-07-31 | 1988-02-18 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン | Contact lens sterilizing/cleaning system |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0634480A1 (en) * | 1993-07-14 | 1995-01-18 | The Procter & Gamble Company | Detergent compositions |
| US7135450B2 (en) * | 2002-07-29 | 2006-11-14 | Kao Corporation | Foamy composition for bleaching clothing |
| JP2009149776A (en) * | 2007-12-20 | 2009-07-09 | Lion Corp | Detergent composition for pipe |
| US7638474B1 (en) * | 2008-08-05 | 2009-12-29 | The Clorox Company | Natural laundry detergent compositions |
| JP2015232057A (en) * | 2014-06-09 | 2015-12-24 | 花王株式会社 | Mold remover composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2594351B2 (en) | 1997-03-26 |
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