KR910000878A - 비이드형 발포성 스티렌 중합체의 제조방법 - Google Patents

비이드형 발포성 스티렌 중합체의 제조방법 Download PDF

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Publication number
KR910000878A
KR910000878A KR1019900009594A KR900009594A KR910000878A KR 910000878 A KR910000878 A KR 910000878A KR 1019900009594 A KR1019900009594 A KR 1019900009594A KR 900009594 A KR900009594 A KR 900009594A KR 910000878 A KR910000878 A KR 910000878A
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South Korea
Prior art keywords
polymerization
styrene
conversion
batch
expandable styrene
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KR1019900009594A
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English (en)
Inventor
힌츠 한스
구르 우베
한 클라우스
게오르크 케플러 한스
Original Assignee
방에르트. 바르츠
바스프 악티엔게젤샤프트
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Application filed by 방에르트. 바르츠, 바스프 악티엔게젤샤프트 filed Critical 방에르트. 바르츠
Publication of KR910000878A publication Critical patent/KR910000878A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16—Making expandable particles
    • C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

내용 없음

Description

비이드형 발포성 스티렌 중합체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. a) 최대로 2시간내에 중합배치를 80 내지 90℃로 급속히 가열시켜 중합을 개시하고, b) 이어서 반응온도를 시간당 8내지 17℃씩 120℃내지 130℃로 증가시키는데, 여기에서 c)100℃에 이를 때 전환율은 30 내지 60%이고, d) 최대온도에 이를때 전환율은 80%이상이며, 그리고 e) 중합체 내의 잔류단량체 함량이 0.1%미만으로 떨어질때까지 배치를 100내지 130℃로 유지하는 것으로 이루어진, 통상적인 현탁안정제 및 통상적인 스티렌용성 중합촉매의 존재하에 물현탁액중에서 발포제로서 1 내지 10wt.%의 C3-내지 C6-탄화수소 및 만일 필요하다면 효과량의 통상적인 첨가제의 부가와 함께, 스티렌의 중합, 만일 필요하다면 스티렌과 공단량체 와의 중합에 의한 비이드형 발포성 스티렌 중합체의 제조방법.
  2. 제1항에 있어서, 중합이 스티렌의 양에 근거하여, 0.0001 내지 0.01wt. %의 양으로 통상적인 연쇄이동제, 특히 3차 도데실 메르캅탄의 존재하에서 수행되는 것을 특징으로 하는 방법.
  3. 0.005 내지 0.1g/㎤의 밀도를 갖는 포음성형물의 제조를 위해, 제1항에 기재된 바와같이 제조된 발포성 스티렌 중합체를 사용하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900009594A 1989-06-28 1990-06-28 비이드형 발포성 스티렌 중합체의 제조방법 KR910000878A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3921147A DE3921147A1 (de) 1989-06-28 1989-06-28 Verfahren zur herstellung von perlfoermigen expandierbaren styrolpolymerisaten
DEP39211479 1989-06-28

Publications (1)

Publication Number Publication Date
KR910000878A true KR910000878A (ko) 1991-01-30

Family

ID=6383756

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900009594A KR910000878A (ko) 1989-06-28 1990-06-28 비이드형 발포성 스티렌 중합체의 제조방법

Country Status (9)

Country Link
US (1) US4980381A (ko)
EP (1) EP0405324B1 (ko)
JP (1) JPH0339334A (ko)
KR (1) KR910000878A (ko)
AT (1) ATE111130T1 (ko)
AU (1) AU626433B2 (ko)
CA (1) CA2018278A1 (ko)
DE (2) DE3921147A1 (ko)
ES (1) ES2058688T3 (ko)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3914292A1 (de) * 1989-04-29 1990-10-31 Basf Ag Expandierbare styrolpolymerisate
AU622024B2 (en) * 1989-05-12 1992-03-26 Basf Aktiengesellschaft Expandable styrene polymers
DE3921148A1 (de) * 1989-06-28 1991-01-10 Basf Ag Perlfoermige expandierbare styrolpolymerisate mit hohem expandiervermoegen
DE4038044A1 (de) * 1990-11-29 1992-06-04 Basf Ag Expandierbare styrolpolymerisate mit hoher expandierbarkeit
US5455321A (en) * 1993-12-02 1995-10-03 The Dow Chemical Company Process for producing high molecular weight monovinylidene aromatic polymers
GB9420645D0 (en) * 1994-10-13 1994-11-30 Dow Chemical Co Non-linear stytrenic polymer compositions and articles prepared therefrom
DE4438376A1 (de) * 1994-10-27 1996-05-02 Basf Ag Recyclat enthaltende, expandierbare Styrolpolymerisate
DE19819058C5 (de) * 1998-04-29 2015-06-25 Basf Se Verfahren zur Herstellung von vorgeschäumten EPS-Partikeln mit grober Schaumstruktur aus teilchenförmigen, schwach angeschäumten, expandierten Styrolpolymerisaten
KR100280214B1 (ko) * 1998-06-25 2001-02-01 황규억 발포성 스티렌 중합체 수지비드의 제조방법
KR100280215B1 (ko) * 1998-06-25 2001-02-01 황규억 발포성 스티렌 중합체 수지비드의 제조방법
EP1057838B1 (en) * 1999-06-03 2005-03-02 Nova Chemicals (International) S.A. Process for the preparation of polymer particles
CA2309442C (en) 1999-06-03 2009-04-28 Nova Chemicals (International) S.A. Process for the preparation of polymer particles
JP2006328290A (ja) * 2005-05-30 2006-12-07 Mitsubishi Chemicals Corp 粒状重合体の製造方法、イオン交換樹脂の製造方法、及び合成吸着剤の製造方法、並びにアニオン交換樹脂、カチオン交換樹脂、及び合成吸着剤

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1370635A (fr) * 1963-05-20 1964-08-28 Pechiney Saint Gobain Procédé de fabrication de copolymères du styrène expansibles
US3192169A (en) * 1965-01-07 1965-06-29 Kenneth W Doak Method of making expandable polymeric styrene particles
SE346114B (ko) * 1965-05-13 1972-06-26 Hoechst Ag
US3462380A (en) * 1966-03-24 1969-08-19 Dow Chemical Co Suspension polymerization process for vinyl aryl monomers
GB1243197A (en) * 1968-01-18 1971-08-18 British Petroleum Co Polymerisation process
US3647723A (en) * 1968-09-20 1972-03-07 Kaucuk Narodni Podnik Process for preparing expandable vinyl aromatic polymers
US3558534A (en) * 1969-03-21 1971-01-26 Michal Niechwiadowicz Molding expandable alkenyl aromatic polymer beads
GB1411444A (en) * 1972-12-14 1975-10-22 Monsanto Ltd Suspension polymerisation process
DE2638839A1 (de) * 1976-08-28 1978-03-02 Basf Ag Verfahren zur herstellung von styrol-suspensionspolymerisaten
AU526349B2 (en) * 1979-04-29 1983-01-06 N.Z. Forest Products Limited Phenol-aldehyde bonding agents
DE3331569A1 (de) * 1983-09-01 1985-03-21 Chemische Werke Hüls AG, 4370 Marl Verfahren zum steuern der groesse der perlen bei der herstellung von expandierbaren styrolpolymerisaten durch suspensionspolymerisation
DK465887A (da) * 1986-09-17 1988-03-18 Charbonnages Ste Chimique Fremgangsmaade til polymerisering og en derved fremstillet polystyren
DE3914292A1 (de) * 1989-04-29 1990-10-31 Basf Ag Expandierbare styrolpolymerisate

Also Published As

Publication number Publication date
AU5784890A (en) 1991-01-03
EP0405324A2 (de) 1991-01-02
CA2018278A1 (en) 1990-12-28
US4980381A (en) 1990-12-25
JPH0339334A (ja) 1991-02-20
EP0405324A3 (en) 1991-06-05
AU626433B2 (en) 1992-07-30
EP0405324B1 (de) 1994-09-07
DE3921147A1 (de) 1991-01-10
DE59007037D1 (de) 1994-10-13
ATE111130T1 (de) 1994-09-15
ES2058688T3 (es) 1994-11-01

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