KR900016392A - 염료, 형광 증백제 및 이들의 중간체를 제조하기 위한 공업공정을 조절하고 최적화하는 방법 - Google Patents
염료, 형광 증백제 및 이들의 중간체를 제조하기 위한 공업공정을 조절하고 최적화하는 방법 Download PDFInfo
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- KR900016392A KR900016392A KR1019900005963A KR900005963A KR900016392A KR 900016392 A KR900016392 A KR 900016392A KR 1019900005963 A KR1019900005963 A KR 1019900005963A KR 900005963 A KR900005963 A KR 900005963A KR 900016392 A KR900016392 A KR 900016392A
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- 239000000543 intermediate Substances 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title 2
- 238000001228 spectrum Methods 0.000 claims description 4
- 239000011541 reaction mixture Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 31
- 239000007858 starting material Substances 0.000 claims 10
- 239000007795 chemical reaction product Substances 0.000 claims 8
- 238000000862 absorption spectrum Methods 0.000 claims 5
- 238000004458 analytical method Methods 0.000 claims 5
- 238000006243 chemical reaction Methods 0.000 claims 3
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- 230000035484 reaction time Effects 0.000 claims 3
- 239000000538 analytical sample Substances 0.000 claims 2
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- 238000007254 oxidation reaction Methods 0.000 claims 2
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- 238000006722 reduction reaction Methods 0.000 claims 2
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- 238000000870 ultraviolet spectroscopy Methods 0.000 claims 2
- 238000002371 ultraviolet--visible spectrum Methods 0.000 claims 2
- VEPOHXYIFQMVHW-XOZOLZJESA-N 2,3-dihydroxybutanedioic acid (2S,3S)-3,4-dimethyl-2-phenylmorpholine Chemical compound OC(C(O)C(O)=O)C(O)=O.C[C@H]1[C@@H](OCCN1C)c1ccccc1 VEPOHXYIFQMVHW-XOZOLZJESA-N 0.000 claims 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 claims 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims 1
- 150000004056 anthraquinones Chemical class 0.000 claims 1
- 239000000987 azo dye Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 230000000536 complexating effect Effects 0.000 claims 1
- 238000010668 complexation reaction Methods 0.000 claims 1
- 150000004696 coordination complex Chemical class 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 claims 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 claims 1
- VMGAPWLDMVPYIA-HIDZBRGKSA-N n'-amino-n-iminomethanimidamide Chemical compound N\N=C\N=N VMGAPWLDMVPYIA-HIDZBRGKSA-N 0.000 claims 1
- 125000004999 nitroaryl group Chemical group 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- -1 polyazo Polymers 0.000 claims 1
- 238000007781 pre-processing Methods 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 230000009467 reduction Effects 0.000 claims 1
- BOLDJAUMGUJJKM-LSDHHAIUSA-N renifolin D Natural products CC(=C)[C@@H]1Cc2c(O)c(O)ccc2[C@H]1CC(=O)c3ccc(O)cc3O BOLDJAUMGUJJKM-LSDHHAIUSA-N 0.000 claims 1
- 238000004611 spectroscopical analysis Methods 0.000 claims 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 claims 1
- 235000021286 stilbenes Nutrition 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
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- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/14—Styryl dyes
- C09B23/141—Bis styryl dyes containing two radicals C6H5-CH=CH-
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/14—Monoazo compounds
- C09B45/16—Monoazo compounds containing chromium
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- C—CHEMISTRY; METALLURGY
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- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/24—Disazo or polyazo compounds
- C09B45/28—Disazo or polyazo compounds containing copper
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09B56/04—Stilbene-azo dyes
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- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/33—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using ultraviolet light
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/314—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths
- G01N2021/3155—Measuring in two spectral ranges, e.g. UV and visible
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/11—Automated chemical analysis
- Y10T436/115831—Condition or time responsive
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도 내지 제3도는 화합물의 참조 스펙트럼, 반응혼합물의 편향 순간 스펙트럼, 및 편차를 고정하기 위해 혼합물 균형을 바로잡는 소스(source)의 개략도이다.
Claims (22)
- 하나 이상의 출발화합물 및 하나 이상의 반응 생성물의 UV/VIS 흡수 스펙트라를 미분 분석(differential anal-ysis)하여 화학공업공정을 조절하고 최적화함을 특징으로 하여, 염료, 형광증백제 및 이들의 중간체를 제조하기 위한 화학공업공정을 조절하고 최적화하는 방법.
- 제1항에 있어서, 하나 이상의 출발화합물 및 하나 이상의 반응생성물의 UV/VIS흡수 스펙트라를 기록하고, 예비공정 과정에서 반응매스의 순간적인 UV/VIS흡수 스펙트럼 및 하나 이상의 반응 생성물의 UV/VIS흡수 스펙트럼을 미분 분석하여 공정을 조절하고 최적화함을 특징으로 하는 방법.
- 제1항에 있어서, 모노아조 또는 폴리아조 염료, 금속 착화합물 아조염료, 안트라퀴논, 프탈로시아닌, 포르마잔, 아조메틴, 니트로아릴, 디옥사진, 페나진 또는 스틸벤 염료를 제조하기 위한 공정을 조절하고 최적화함을 특징으로 하는 방법.
- 제1항 내지 제3항중 어느 한 항에 있어서, 디아조화, 커플링, 착화, 축합, 환원 및 산화반응을 조절하하고 최적화함을 특징으로 하는 방법.
- 제1항 내지 제4항중 어느 한항에 있어서, 연속 및 특히 불연속 예비공정을 조절하고 최적화하기 위한 UV/VIS 분광법을 사용함을 특징으로 하는 방법.
- 제1항 내지 제5항중 어느 한 항에 있어서, 일련의 조절 및 최적화를 위한 UV/VIS분광법을 사용함을 특징으로 하는 방법.
- 제2항에 있어서, 하나 이상의 출발화합물과 하나 이상의 반응생성물의 농도비를 미분 분석하여 예비공정을 조절하고 최적화함을 특징으로 하는 방법.
- 제7항에 있어서, 미분 분석이 특정 주파수로 반복되도록 예비공정을 조절하고 최적화함을 특징으로 하는 방법.
- 제8항에 있어서, 스펙트럼의 차이가 적어지도록 예비 공정을 조절하고 최적화함을 특징으로 하는 방법.
- 제1항 내지 제9항중 어느 한 항에 있어서, 온도, 압력, 출발물질의 양, 반응시간 및/또는 조절 및 최적화를 위한 PH값의 파라메터를 사용함을 특징으로 하는 방법.
- 제2항에 있어서, 하나 이상의 출발화합물과 하나 이상의 반응생성물의 UV/VIS스펙트라를 컴퓨터 기억장치에 저장하고, 예비공정의 과정에서 특정 주파수를 사용하여 반응혼합물의 실제 상태와 목적 반응생성물의 농도비를 미분 분석하여 반응의 순간적인 상태를 분광학적으로 측정한 다음, 이 차이로부터, 경우에 따라 온도, 압력, 출발물질의 양, 반응시간 및/또는 pH값의 파라메터중 하나 이상을 변화시키고, 스펙트라의 차이를 제로로 조절함을 특징으로 하는 방법.
- 제11항에 있어서, 하나 이상의 출발화합물 및 디아조화, 커플링, 착화, 축합, 산화 및 환원반응중 하나 이상의 반응생성물의 UV/VIS흡수 스펙트럼을 컴퓨터에 저장하고, 예비공정의 과정에서 특정 주파수를 사용하여 반응혼합물의 실제상태와 목적 반응생성물의 농도비를 미분 분석하여 반응의 순간적인 상태를 분광학적으로 측정한 다음, 이 차이로부터, 경우에 따라 온도, 압력, 출발물질의 양, 반응시간 및/또는 pH값의 파라메터중 하나 이상을 변화시키고, 스펙트라의 차이를 제로로, 조절함을 특징으로 하는 방법.
- 제1항 내지 제12항중 어느 한 항에 있어서, 불특정 UV/VIS스펙트럼 또는 분석용으로 불충분한 차이를 갖는 화합물의 유도체를 제조한 다음, 유도체를 사용하여 조절 및 최적화를 수행함을 특징으로 하는 방법.
- 제1항 내지 제13항중 어느 한 항에 있어서, 반응매질로부터 분광분석용 샘플을 취한 다음, 임의의 후속 단계에서 샘플을 처리하거나, 광학 센서를 밀어 반응매질중에서 측정함을 특징으로 하는 방법.
- 제1항 내지 제14항중 어느 한 항에 있어서, 분석용 샘플 및 UV/VIS측정 시스템을 광학 도파관으로 서로 연결시키는 방법.
- 제1항 내지 제15항중 어느 한 항에 있어서, UV/VIS측정 시스템으로서 다이오드-배열 분광광도계를 사용함을 특징으로 하는 방법.
- 제14항에 있어서, 분석용 샘플을 바이패스(by-pass) 또는 밸브에 의해 반응매질로부터 수득하는 방법.
- 실질적으로 본 발명의 실시예중 어느 하나에 기술한 바와 같은 방법.
- 출발물질 및/또는 생성물/부산물의 농도비를 제1항에 따른 예비 공정에서 측정하기 위한 제1항에서 청구한 바와 같은 방법의 용도.
- 출발물질/생성물 비를 분석하고 제1항에 따른 예비공정으로 부산물의 농도를 측정하기 위한 제1항에서 청구한 바와 같은 방법의 용도.
- 컴퓨터 집적, 자동화 예비공정을 일련의 공정으로 조절하기 위한 제1항에서 청구한 바와 같은 방법의 용도.
- 염료의 합성에서 사전선택된 색상을 세이딩(Shading)하기 위한 제1항에서 청구한 바와 같은 방법의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3914185.3 | 1989-04-28 | ||
| CH39141853 | 1989-04-28 | ||
| DE3914185A DE3914185A1 (de) | 1989-04-28 | 1989-04-28 | Verfahren zur steuerung und optimierung industrieller prozesse |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR900016392A true KR900016392A (ko) | 1990-11-13 |
| KR0166584B1 KR0166584B1 (ko) | 1999-01-15 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019900005963A KR0166584B1 (ko) | 1989-04-28 | 1990-04-27 | 염료, 형광증백제 및 이들의 중간체를 제조하기위한 공업공정을 조절하고 최적화하는 방법 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5153140A (ko) |
| EP (1) | EP0395587B1 (ko) |
| JP (1) | JP2986840B2 (ko) |
| KR (1) | KR0166584B1 (ko) |
| AR (1) | AR248455A1 (ko) |
| BR (1) | BR9001975A (ko) |
| DE (2) | DE3914185A1 (ko) |
| ES (1) | ES2099091T3 (ko) |
| MX (1) | MX171230B (ko) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4339207A1 (de) * | 1993-11-17 | 1995-05-18 | Hoechst Ag | Verfahren zur online Steuerung und Analytik industrieller Synthese- und Färbeverfahren mit der UV/VIS-Spektroskopie und Multikomponentenanalyse |
| EP0706041A1 (en) * | 1994-10-07 | 1996-04-10 | Bp Chemicals S.N.C. | Chemicals property determination |
| EP0801298B1 (en) * | 1996-04-09 | 2006-06-21 | Innovene Europe Limited | Control of process |
| EP0706050A1 (en) * | 1994-10-07 | 1996-04-10 | Bp Chemicals S.N.C. | Lubricant property determination |
| EP0706049A1 (en) * | 1994-10-07 | 1996-04-10 | Bp Chemicals S.N.C. | Cracking property determination |
| EP0706040A1 (en) * | 1994-10-07 | 1996-04-10 | Bp Chemicals S.N.C. | Property determination |
| GB9423063D0 (en) * | 1994-11-16 | 1995-01-04 | Rosand Precision Ltd | Improvements in and relating to reaction apparatus and to control systems for them |
| DE69631872D1 (de) * | 1996-04-09 | 2004-04-22 | Eutech Engineering Solutions L | Prozess-Steuerung |
| US6300633B1 (en) * | 1998-07-06 | 2001-10-09 | Bayer Corporation | In-line method for determining the residue content of an isocyanate and apparatus useful therefor |
| WO2006016889A1 (en) * | 2004-07-08 | 2006-02-16 | Tres-Ark, Inc. | Chemical mixing apparatus, system and method |
| US7281840B2 (en) * | 2004-07-09 | 2007-10-16 | Tres-Ark, Inc. | Chemical mixing apparatus |
| US20060080041A1 (en) * | 2004-07-08 | 2006-04-13 | Anderson Gary R | Chemical mixing apparatus, system and method |
| CN101403893B (zh) * | 2008-11-17 | 2010-06-02 | 杭州电子科技大学 | 染色配方的自动生成方法 |
| KR101538133B1 (ko) * | 2009-03-10 | 2015-07-22 | 주식회사 동진쎄미켐 | 염료감응 태양전지 흡착 염료용액의 모니터링 장치 및 염료용액의 조절 장치 |
| CN103558169A (zh) * | 2013-10-31 | 2014-02-05 | 天津德凯化工股份有限公司 | 一种检测蒽醌型蓝色基含量的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4042328A (en) * | 1976-04-06 | 1977-08-16 | Seymour George W | On-line analyzer |
| ZA796569B (en) * | 1978-12-15 | 1981-09-30 | Johnson Matthey Co Ltd | Monitoring process and apparatus |
| US4529203A (en) * | 1982-09-01 | 1985-07-16 | Ribaudo Nicholas A | Golf club |
| US4852967A (en) * | 1986-03-25 | 1989-08-01 | Ciba Corning Diagnostics Corp. | Evanescent wave sensors |
| EP0243310A3 (de) * | 1986-04-18 | 1989-10-18 | Ciba-Geigy Ag | Verfahren zur Steuerung und Optimierung industrieller Prozesse |
| DE3714346A1 (de) * | 1986-04-30 | 1987-11-05 | Anritsu Corp | Ultraviolett-ammoniakanalysegeraet |
| DE3625490A1 (de) * | 1986-07-28 | 1988-02-04 | Kernforschungsz Karlsruhe | Multikomponenten-prozessanalysensystem |
| EP0273641A3 (en) * | 1986-12-29 | 1990-01-24 | E.I. Du Pont De Nemours And Company | Photometric analyzer and controller for beverages |
-
1989
- 1989-04-28 DE DE3914185A patent/DE3914185A1/de active Granted
-
1990
- 1990-04-19 ES ES90810313T patent/ES2099091T3/es not_active Expired - Lifetime
- 1990-04-19 EP EP90810313A patent/EP0395587B1/de not_active Revoked
- 1990-04-19 DE DE59010667T patent/DE59010667D1/de not_active Revoked
- 1990-04-24 US US07/515,025 patent/US5153140A/en not_active Expired - Fee Related
- 1990-04-25 MX MX020455A patent/MX171230B/es unknown
- 1990-04-26 AR AR90316724A patent/AR248455A1/es active
- 1990-04-27 BR BR909001975A patent/BR9001975A/pt not_active IP Right Cessation
- 1990-04-27 KR KR1019900005963A patent/KR0166584B1/ko not_active IP Right Cessation
- 1990-04-27 JP JP2115020A patent/JP2986840B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AR248455A1 (es) | 1995-08-18 |
| JPH02298341A (ja) | 1990-12-10 |
| EP0395587A3 (de) | 1992-11-25 |
| DE59010667D1 (de) | 1997-04-17 |
| EP0395587B1 (de) | 1997-03-12 |
| EP0395587A2 (de) | 1990-10-31 |
| MX171230B (es) | 1993-10-12 |
| KR0166584B1 (ko) | 1999-01-15 |
| BR9001975A (pt) | 1991-07-30 |
| DE3914185A1 (de) | 1990-10-31 |
| DE3914185C2 (ko) | 1993-02-11 |
| ES2099091T3 (es) | 1997-05-16 |
| US5153140A (en) | 1992-10-06 |
| JP2986840B2 (ja) | 1999-12-06 |
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