KR900016088A - 양쪽성 단량체 및 중합체 및 이의 하나 이상의 일분자층을 함유하는 필름 - Google Patents

양쪽성 단량체 및 중합체 및 이의 하나 이상의 일분자층을 함유하는 필름 Download PDF

Info

Publication number
KR900016088A
KR900016088A KR1019900004958A KR900004958A KR900016088A KR 900016088 A KR900016088 A KR 900016088A KR 1019900004958 A KR1019900004958 A KR 1019900004958A KR 900004958 A KR900004958 A KR 900004958A KR 900016088 A KR900016088 A KR 900016088A
Authority
KR
South Korea
Prior art keywords
formula
monomer
reacted
polymer
layer
Prior art date
Application number
KR1019900004958A
Other languages
English (en)
Inventor
루포 도날드
프라스 베르너
쇼이네만 우데
Original Assignee
엔겔하르트, 벡커
훽스트 아크티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 엔겔하르트, 벡커, 훽스트 아크티엔게젤샤프트 filed Critical 엔겔하르트, 벡커
Publication of KR900016088A publication Critical patent/KR900016088A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/20—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a carbon atom of an acyclic unsaturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/02—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C233/04—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C233/05—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/17—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom
    • C07C233/18—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by an acyclic carbon atom having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/02—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/04—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C235/06—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to acyclic carbon atoms and singly-bound oxygen atoms bound to the same carbon skeleton the carbon skeleton being acyclic and saturated having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F20/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters

Abstract

내용 없음.

Description

양쪽성 단량체 및 중합체 및 이의 하나 이상의 일분자층을 함유하는 필름
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 하기 일반식(Ⅰ) 또는(Ⅱ)의 양쪽성 단량체
    상기식에서, X는 (CH2)n 또는 (CH2-O-CH2)n이며, Y는 O 또는 NH이고, ℓ는 0내지 10의 정수이며, m은 10내지 26, 바람직하게는 13내지 21의 정수이고, n은 1내지 10의 정수이며, R1은 H, CH3Cl, CN, F 또는 Br이고, R2는 탄소수가 8개 이상인 알킬 쇄. 바람직하게는 탄소수가 12내지 22개인 n-알킬 쇄를 갖는 O-알킬 라디칼 또는 NH-알킬 라디칼이다.
  2. 하기 일반식(Ⅳ)의 디카복실산 또는 이의 활성화된 유도체를 하기 일반식(Ⅳ)의 불포화 알콜과 반응시키고, 생성된 모노에스테르를 장쇄 알콜 R2H 또는 1급 아민 R2H와 다시 반응시킴을 특징으로 하여, 하기 일반식(Ⅰ)의 단량체를 제조하는 방법.
    상기식에서, X, n, R1및 R2는 제1항에서 정의된 바와 같다.
  3. 먼저 하기 일반식(Ⅲ)의 디카복실산 또는 이의 활성화된 유도체를 장쇄 알콜 R2H 또는 1급 아민 R2H와 반응시키고, 생성된 생성물을 하기 일반식(Ⅳ)의 불포화 알콜과 다시 반응시킴을 특징으로 하여, 일반식(Ⅰ)의 단량체를 제조하는 방법.
    상기식에서, X. R1, R2및 n은 각각 제1항에서 정의된 바와 같다.
  4. 하기 일반식(Ⅴ)의 카복실산 또는 이의 반응성 유도체를 바람직하게는 3급 아민의 존재하에 하기 일반식(Ⅵ)의 알콜 또는 아민과 반응시킴을 특징으로 하여, 하기 일반식(Ⅱ)의 단량체를 제조하는 방법.
    상기식에서, ℓ, m, R1및 Y는 각각 제1항에서 정의한 바와 같다.
  5. 제1항에서 청구된 바와 같은 단량체의 중합화에 의해 수득한 단독중합체.
  6. 하나 이상의 일반식(Ⅰ) 및/또는 (Ⅱ)의 단량체를 추가의 친수성 공단량체와 함께 또는 부재하에 중합화시켜 수득한 공중합체.
  7. 유리 라디칼 형성제의 존재하에 단량체를 중합화시켜 제5 또는 6항에서 청구된 바와 같은 중합체를 제조하는 방법.
  8. 고체 기재상에 양폭성 화합물의 하나 이상의 일분자층(이때, 충은 제5및/또는 6항에서 청구된 바와 같은 중합체를 함유한다)의 필름을 함유하는 층 부재.
  9. 제5및/또는 6항에 청구된 바와 같은 하나 이상의 중합체를 수-불혼화성의 휘발성 유기 용매에 용해시키고, 이 용액을 물/공기 경계면상에 전개시켜, 용매를 증발시키고, 생성된 층을 압착시켜, 이 층을 랑무어-블로드겟(Langmuir-Blodgett) 기술에 의해 고체 기재에 이동시킴을 특징으로 하여, 제8항에서 청구된 바와 같은 층 부재를 제조하는 방법.
  10. 제5및/또는 6항 중 어느 한 항에서 청구된 바와 같은 중합체로부터 생성된, 필름의 표면 봉합용 및 표면간의 마찰을 감소시키기 위한 용도.
  11. 제8항에 청구된 바와 같은 층 부재의 광학적 목적을 위한 용도.
  12. 제5 및 6항중 어느 한 항에서 청구된 바와 같은 중합체 필름의 전기 절연 목적을 위한 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900004958A 1989-04-12 1990-04-11 양쪽성 단량체 및 중합체 및 이의 하나 이상의 일분자층을 함유하는 필름 KR900016088A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE39119297 1989-04-12
DE3911929A DE3911929A1 (de) 1989-04-12 1989-04-12 Amphiphile monomere und polymere und film aus mindestens einer monomolekularen schicht daraus

Publications (1)

Publication Number Publication Date
KR900016088A true KR900016088A (ko) 1990-11-12

Family

ID=6378466

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900004958A KR900016088A (ko) 1989-04-12 1990-04-11 양쪽성 단량체 및 중합체 및 이의 하나 이상의 일분자층을 함유하는 필름

Country Status (7)

Country Link
US (1) US5116925A (ko)
EP (1) EP0392464B1 (ko)
JP (1) JPH02296809A (ko)
KR (1) KR900016088A (ko)
CA (1) CA2014359A1 (ko)
DE (2) DE3911929A1 (ko)
FI (1) FI901815A0 (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6353061B1 (en) 1993-05-26 2002-03-05 Dentsply Gmbh α, ω-methacrylate terminated macromonomer compounds
US6369164B1 (en) 1993-05-26 2002-04-09 Dentsply G.M.B.H. Polymerizable compounds and compositions
US5998499A (en) 1994-03-25 1999-12-07 Dentsply G.M.B.H. Liquid crystalline (meth)acrylate compounds, composition and method
SE9303503D0 (sv) * 1993-10-22 1993-10-22 Perstorp Ab Acrylic Monomer
CA2146816A1 (en) 1994-04-22 1995-10-23 Joachim E. Klee Process and composition for preparing a dental polymer product
US6054606A (en) * 1996-05-22 2000-04-25 Nippon Paint Co., Ltd. Method for preparing malonate group-containing acrylate monomers
JP2952346B2 (ja) * 1997-03-11 1999-09-27 東京商船大学長 ラングミュア・ブロジェット膜およびその製造方法
CN113097384B (zh) * 2021-03-31 2023-11-21 南京大学 一种制备二维分子单层的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2117669A (en) * 1982-03-05 1983-10-19 Nat Res Dev Polymeric films
US4728696A (en) * 1985-12-02 1988-03-01 The Dow Chemical Company Amphiphilic monomer and hydrophobe associative composition containing a polymer of a water-soluble monomer and said amphiphilic monomer
DE3843194A1 (de) * 1988-12-22 1990-07-12 Hoechst Ag Amphiphile monomere mit gemischtkettiger struktur und polymere und film aus mindestens einer monomolekularen schicht daraus

Also Published As

Publication number Publication date
DE3911929A1 (de) 1990-10-18
CA2014359A1 (en) 1990-10-12
FI901815A0 (fi) 1990-04-10
EP0392464B1 (de) 1995-07-05
EP0392464A2 (de) 1990-10-17
JPH02296809A (ja) 1990-12-07
EP0392464A3 (de) 1991-12-11
US5116925A (en) 1992-05-26
DE59009362D1 (de) 1995-08-10

Similar Documents

Publication Publication Date Title
CA1287722C (en) Synthetic resin molded article having excellent antistatic propertyand process for preparing same
US4978473A (en) Polymeric solid electrolyte
BR9403174A (pt) Processo para a preparação de artigos moldados, processo para a preparação de uma lente de contato, artigo moldado, lente de contato, pré-polímero, processo para sua preparação
ES8707264A1 (es) Un procedimiento semicontinuo para preparar un producto de reaccion polimero no gelificado
DE3681569D1 (de) Dispersionspolymere, verfahren zu ihrer herstellung und ihre verwendung.
KR900016088A (ko) 양쪽성 단량체 및 중합체 및 이의 하나 이상의 일분자층을 함유하는 필름
ATE129257T1 (de) Verfahren zur herstellung von homopolymerisaten des propylens mit breitem molmassenverhältnis.
EP0382198A3 (en) Polyimidesiloxanes and methods for their preparation and use
CA2030958A1 (en) Polydimethylsiloxane terminated at one end with a branched aminoalkyl group and preparation thereof
KR890006407A (ko) 열 전사 인쇄용 염료시트 및 이것의 후면피복
ES8207561A1 (es) Procedimiento para preparar un gel polimerico hidrofilo de alto peso molecular
US5061768A (en) Vinylidene cyanide copolymer
KR900009703A (ko) α-올레핀을 중합시키는 동안 중합장치의 오염을 방지하는 방법
DE3884050D1 (de) Verfahren zur Herstellung eines Emulsionspolymers.
GB2206819B (en) Polymerisation reactors
CA1338082C (en) Production of thin films
JPH0160162B2 (ko)
JPS57177053A (en) Synthetic resin composition
KR850700227A (ko) 내마모성이 우수한 내열성 수지성형품 및 그의 제조방법
ATE262546T1 (de) Extrudierbare, migrationsarme silikonorganocopolymere mit hoher transparenz, deren herstellung und verwendung
KR850007444A (ko) 개질 폴리비닐렌 카르보네이트의 제조방법
US5035763A (en) Preparation of thin films
KR910009768A (ko) 이방성 쌍극성 단량체로 부터 제조된 신규의 중합체성 비선형 광학 물질
EP0473824B1 (en) Synthetic resin molded article having good antistatic property and process for preparation thereof
JP2598672B2 (ja) 帯電防止性合成樹脂成型品およびその製造方法

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid