KR900014318A - 헤테로사이클릭 화합물 - Google Patents

헤테로사이클릭 화합물 Download PDF

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KR900014318A
KR900014318A KR1019900002482A KR900002482A KR900014318A KR 900014318 A KR900014318 A KR 900014318A KR 1019900002482 A KR1019900002482 A KR 1019900002482A KR 900002482 A KR900002482 A KR 900002482A KR 900014318 A KR900014318 A KR 900014318A
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dichloro
pyridine
methyl
methylenephenethyl
hydrogen
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피터 이젠링 한스
젠더 비트
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장-자크 오게이,로랜드 보러
에프.호프만-라 로슈 에이지
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    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
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    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/28Radicals substituted by singly-bound oxygen or sulphur atoms
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    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
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    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
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    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/89Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members with hetero atoms directly attached to the ring nitrogen atom
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    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F1/00Compounds containing elements of Groups 1 or 11 of the Periodic Table
    • C07F1/005Compounds containing elements of Groups 1 or 11 of the Periodic Table without C-Metal linkages

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Abstract

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Description

헤테로사이클릭 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 일반식(I)의 화합물, 일반식(I)화합물의 N-옥사이드, N-아미노염 및 구리 착화물, 및 이의 산부가염 및 이의 N-옥사이드의 산부가염.
    상기식에서, X는 구룹(a) 또는 (b)이고,
    R1및 R2는 메틸 또는 함께 에틸렌을 나타내고, R3는 수소, 염소, C1-4-알킬 또는 메톡시이고, R4는 수소 또는 메틸이고 R5는 메틸(R4가 수소인 경우), C1-4알킬, 알릴 또는 프로파르길이거나, R4및 R5가 함께 에틸렌을 나타낸다.
  2. 제 1항에 있어서, R1및 R2가 함께 에틸렌을 나타내는 화합물.
  3. 제 1항 또는 2항에 있어서, R3가 수소 또는 메톡시인 화합물.
  4. 제 1항 내지 3항중 어느 한항에 있어서, R4가 수소인 화합물.
  5. 제 1항 내지 4항중 어느 한항에 있어서, R5가 메틸인 화합물.
  6. 제 1항에 있어서, 3-(2, 4-디클로로-α, α-디메틸-β-메틸렌펜에틸)-피리딘, 3-[1-(2, 4-디클로로-α-메틸렌벤질)-사이클로 프로필]-피리딘.
    3-[1-(2, 4-디클로로-α-메틸렌벤질)-사이클로 프로필]-피리딘 및 구리(II) 아세테이트의 1:1 착화물, 3-[1-(2, 4-디클로로-α-메틸렌벤질)-사이클로 프로필]-피리딘 1-옥사이드.
    3-[1-(2, 4-디클로로-α-메톡시메틸렌벤질)-사이클로프로필]-피리딘, 3-[1-(2, 4-디클로로-α-에틸리덴벤질)-사이클로프로필]-피리딘, 3-(2, 4-디클로로-α-메톡시메틸렌-β-메틸펜에틸)-피리딘.
    3-(α-부틸리덴-2, 4-디클로로-β-메틸펜에틸)-피리딘, 3-(2, 4-디클로로-β,β-디메틸-α-메틸렌펜에틸)-피리딘, 3-[1-(2, 4-디클로로-α-메틸렌-β-(2-프로피닐)-펜에틸]-피리딘.
    3-[1-(2, 4-디클로로-α-메톡시메틸렌-β-(2-프로피닐)-펜에틸]-피리딘, 3-(2, 4-디클로로-α-메틸렌-β-프로피닐펜에틸)-피리딘, 3-(α-디클로로메틸렌-2,4-디클로로-β-메틸렌펜에틸)-피리딘.
    3-[α-클로로메틸렌-2, 4-디클로로-β-(2-프로피닐)-펜에틸)-피리딘, 3-(β-알릴-2, 4-디크로로-α-메틸렌펜에틸)-피리딘.
    3-[α-부틸리덴-2, 4-디클로로-β-메틸펜에틸)-피리딘 및 구리(II)아세테이트의 1:1 착화물, 3-[α-부틸리덴-2,4-디클로로-β-(2-프로피닐)-펜에틸]-피리딘, 3-(2, 4-디클로로-β-메틸-α-메틸렌펜에틸)-피리딘, 3-(2,4-디클로로-β-메틸-α-메틸렌펜에틸)-프리딘 및 구리(II) 아세테이트의 1:1 착화 및 3-(2, 4-디클로로-β-메틸-α-메톡시메틸렌펜에틸)-피리딘으로부터 선택된 화합물.
  7. 유효량의 하나 이상의 일반식(I)화합물, 이의 N-옥사이드, N-아미노염 또는 구리 착화물, 또는 일반식(I)화합물의 산부가염 또는 이의 N-옥사이드의 산부가염 및 제형 보조제를 함유하는 살진균성 조성물.
    상기식에서, X는 그룹(a) 또는(b)
    R1및 R2는 메틸 또는 함께 에틸렌을 나타내고, R3는 수소, 염소, C1-4-알킬 또는 메톡시이고, R4는 수소 또는 메틸이고, R5는 메틸(R4가 수소인 경우), C1-4알킬, 알릴 또는 프로파르길이거나, R4및 R5가 함께 에틸렌을 나타낸다.
  8. 제 7항에 있어서, 3-(2, 4-디클로로-α, α-디메틸-β-메틸렌펜에틸)-피리딘, 3-[1-(2, 4-디클로로-α-메틸렌벤질)-사이클로 프로필]-피리딘, 3-[1-(2, 4-디클로로-α-메틸렌벤질)-사이클로 프로필]-피리딘 및 구리(II)아세테이트의 1:1 착화물.
    3-[1-(2, 4-디클로로-α-메틸렌벤질)-사이클로프로필]-피리딘 1-옥사이드, 3-[1-(2, 4-디클로로-α-메톡시메틸렌벤질)-사이클로프로필]-피리딘, 3-(2, 4-디클로로-α-메톡시메틸렌-β-메틸펜에틸)-피리딘, 3-(α-부틸리덴-2, 4-디클로로-β-메틸펜에틸)-피리딘, 3-[2, 4-디클로로-β, β-디메틸-α-메틸렌펜에틸)-피리딘, 3-[2, 4-디클로로-α-메틸렌-β-(2-프로피닐)-펜에틸]-피리딘, 3-[2, 4-디클로로-α-메톡시메틸렌-β-(2-프로피닐-펜에틸]-피리딘, 3-(2,4-디클로로-α-메틸렌-β프로피닐펜에틸)-피리딘, (3-α-클로로메틸렌-2, 4-디클로로-β-메틸렌 펜에틸)-피리딘, 3-[α-클로로메틸렌-2, 4-디클로로-β-(2-프로피닐)-펜에틸]-피리딘, 3-(β-알릴-2, 4-디클로로-α-메틸렌펜에틸)-피리딘, 3-(α-부틸리덴-2, 4-디클로로-β-메틸펜에틸)-피리딘 및 구리(II)아세테이트의 1:1 착화물, 3-[α-부틸리덴-2, 4-디클로로-β-(2-프로피닐)-펜에틸]-피리딘, 3-(2,4-디클로로-β-메틸-α-메틸렌펜에틸]-피리딘, 3-(2, 4-디클로로-β-메틸-α-메틸렌펜에틸)-피리딘 및 구리(II)아세테이트의 1:1 착화물 및 3-(2, 4-디클로로-β-에틸-α-메톡시메틸렌 펜에틸)-피리딘 중에서 선택된 그룹 하나이상의 유효량 및 제형 보조제를 함유하는 살진균성 조성물.
  9. a) 일반식(II)의 케톤을 일반식(III)의 트리페닐포스포늄염과 반응시키거나, b)일반식(I)화합물의 N-옥사이드 또는 N-아미노염의 제조를 위해, 이를 N-산화시키거나 이를 일반식 (IV)의 아민 유도체와 반응시키거나, c)일반식 (I)화합물 또는 N-옥사이드의 산부가염 제조를 위해 일반식(I)의 화합물 또는 이의 N-옥사이드를 산화 반응시키거나, d) 일반식 (I)화합물의 구리 착화물의 제조를 위해, 이를 일반식(V)의 구리염과 반응시킴을 특징으로 하여 일반식(I)의 화합물을 제조하는 방법.
    상기식에서, X는 그룹(a) 또는 (b)이고,
    R1및 R2는 메틸 또는 함께 에틸렌을 나타내고, R3는 수소, 염소, C1-4-알킬 또는 메톡시이고, R4는 수소 또는 메틸이고, R5는 메틸(R4가 수소인 경우),C|1-4알킬, 알릴 또는 프로파르길이거나, R4및 R5가 함께 에틸렌을 나타내고,
    Y는 그룹(a') 또는 (b')이고,
    Hal는 클로라이드 또는 브롬마이드 이온이고, A3는 생리학적으로 상용성 염의 잔기이고, A2는 유기 또는 무기산의 음이온이다.
  10. 제 1항 내지 6항에 따른 화합물 또는 제 7항 또는 8항에 따른 조성물 유효량으로 보호될 유전자좌(locus)를 처리함을 특징으로 하여, 농업 및 원예분야 에서의 진균류를 조절하는 방법.
  11. 농업 및 원예에서 진균류를 조절하기 위한, 제 1항 내지 6항에 따른 화합물 또는 제 7항 또는 8항에 조성물의 용도.
  12. 제 1항에 있어서, 제 9항에 따른 방법으로 또는 이와 화학적으로 분명히 동일한 방법으로 제조된 화합물.
  13. 제 7항에 있어서, 실시예 6내지 8중 어느 하나에 기술된 살균조성물.
  14. 제 9항에 있어서, 실시예 1내지 3중 어느 하나에 기술된 방법.
  15. 제 10항에 있어서, 본 명세서에 실질적으로 기술된 방법.
    ※참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019900002482A 1989-03-01 1990-02-27 헤테로사이클릭 화합물 KR900014318A (ko)

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AU (1) AU638434B2 (ko)
BR (1) BR9000897A (ko)
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US5360459A (en) 1991-05-13 1994-11-01 The Lubrizol Corporation Copper-containing organometallic complexes and concentrates and diesel fuels containing same

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JPS62169766A (ja) * 1986-01-23 1987-07-25 Ishihara Sangyo Kaisha Ltd ピリジン系化合物及びそれらを含有する有害生物防除剤
GB8605281D0 (en) * 1986-03-04 1986-04-09 Ici Plc Diphenyl ether derivatives
DE4018260A1 (de) * 1990-06-07 1991-12-12 Basf Ag Derivate des (beta)-picolins und diese enthaltende pflanzenschutzmittel

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PT93310A (pt) 1990-11-07
HUT53874A (en) 1990-12-28
EP0385267A2 (de) 1990-09-05
HU207044B (en) 1993-03-01
JPH02275856A (ja) 1990-11-09
AU5003290A (en) 1990-09-06
PT93310B (pt) 1996-01-31
AU638434B2 (en) 1993-07-01
ZA901358B (en) 1990-11-28
EP0385267A3 (de) 1991-09-04
US5036074A (en) 1991-07-30
BR9000897A (pt) 1991-02-13
HU901038D0 (en) 1990-05-28

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