KR900006447A - 이소시아네이트 반응성 혼합물, 및 연질 폴리우레탄 기포체의 제조시 이의 용도 - Google Patents

이소시아네이트 반응성 혼합물, 및 연질 폴리우레탄 기포체의 제조시 이의 용도 Download PDF

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KR900006447A
KR900006447A KR1019890014306A KR890014306A KR900006447A KR 900006447 A KR900006447 A KR 900006447A KR 1019890014306 A KR1019890014306 A KR 1019890014306A KR 890014306 A KR890014306 A KR 890014306A KR 900006447 A KR900006447 A KR 900006447A
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KR1019890014306A
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엠.밀리런 찰스
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하워드리 노블
모베이 코포레이션
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/50Polyethers having heteroatoms other than oxygen
    • C08G18/5021Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5024Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
    • C08G18/482Mixtures of polyethers containing at least one polyether containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6685Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0008Foam properties flexible

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

내용 없음

Description

이소시아네이트 반응성 혼합물, 및 연질 폴리우레탄 기포체의 제조시 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. A) 성분 B) 및 C) 100중량부당 일반식 H2N-R-NH2(여기서, R은 C4내지 C10직쇄 또는 측쇄 알킬렌 그룹이거나, C4내지 C15알리사이클릭 그룹이다)의 아민 0 내지 3중량부, B) 분자량이 약 400 내지 약 5000이며 2 내지 3개의 1급 아미노그룹을 함유하는 폴리옥시알킬렌 폴리아민 0 내지 30중량%, 및 C) 성분 B) 및 C) 총 100중량%당 2내지 3개의 하이드록실 작용기를 지니며 분자량이 약 1000 내지 약 10,000인 하나 이상의 폴리에테르 폴리하이드록실 화합물 70 내지 100%를 함유함을 특징으로 하는, 이소시아네이트 반응성 조성물.
  2. 제1항에 있어서, R이 C4내지 C10측쇄 알킬렌그룹인 조성물.
  3. 제2항에 있어서, 성분 A)가 1.5-디아미노-2-메틸펜탄인 조성물.
  4. 제1항에 있어서, 성분 A)가 0.05 내지 2.5중량부의 양으로 존재하는 조성물.
  5. 제1항에 있어서, 성분 A)가 0.25 내지 1.5중량부의 양으로 존재하는 조성물.
  6. 제4항에 있어서, 성분 B)가 1 내지 20중량%의 양으로 존재하는 조성물.
  7. 제6항에 있어서, 성분 B)가 2.5 내지 15중량%의 양으로 존재하는 조성물.
  8. A) 성분 B) 및 C) 100중량부당 일반식 H2N-R-NH2(여기서, R은 C4내지 C10직쇄 또는 측쇄 알킬렌 그룹이거나, C4내지 C15알리사이클릭 그룹이다)의 아민 0 내지 3중량부, B) 분자량이 약 400 내지 약 5000이며 2 내지 3개의 1급 아미노그룹을 함유하는 폴리옥시알킬렌 폴리아민 0 내지 30중량%, 및 C) 성분 B) 및 C) 총 100중량%당 2내지 3개의 하이드록실 작용기를 지니며 분자량이 약 1000 내지 약 10,000인 하나 이상의 폴리에테르 폴리하이드록실 화합물 70 내지 100%; 및 D) 메틸렌 비스(페닐 이소시아 네이트) 약 40 내지 약 85중량%를 함유하는 폴리메틸렌폴리올(페닐 이소시아네이트) 및/또는 이러한 이소시아네이트의 예비 중합체(여기서, 예비 중합체의 이소시아네이트 함량은 약 15 내지 약 30중량%이다)를, E) 발포제 존재하에 이소시아네이트 지수 60 내지 140에서 반응시킴으로써 제조된 연질 기포체.
  9. 제8항에 있어서, R이 C4내지 C10측쇄 알킬렌그룹인 기포체.
  10. 제9항에 있어서, 성분 A)가 1.5-디아미노-2-메틸펜탄인 기포체.
  11. 제8항에 있어서, 성분 A)가 0.05 내지 2.25중량부의 양으로 존재하는 기포체.
  12. 제11항에 있어서, 성분 A)가 0.25 내지 1.5중량부의 양으로 존재하는 기포체.
  13. 제11항에 있어서, 성분 B)가 1 내지 20중량%의 양으로 존재하는 기포체.
  14. 제13항에 있어서, 성분 B)가 2.5 내지 15중량%의 양으로 존재하는 기포체.
  15. 제8항에 있어서, 상기 지수가 90 내지 120인 기포체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890014306A 1988-10-06 1989-10-05 이소시아네이트 반응성 혼합물, 및 연질 폴리우레탄 기포체의 제조시 이의 용도 KR900006447A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/254,326 US4876292A (en) 1988-10-06 1988-10-06 Isocyanate reactive mixture and the use thereof in the manufacture of flexible polyurethane foams
US7/254,326 1988-10-06

Publications (1)

Publication Number Publication Date
KR900006447A true KR900006447A (ko) 1990-05-08

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Family Applications (1)

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KR1019890014306A KR900006447A (ko) 1988-10-06 1989-10-05 이소시아네이트 반응성 혼합물, 및 연질 폴리우레탄 기포체의 제조시 이의 용도

Country Status (6)

Country Link
US (1) US4876292A (ko)
EP (1) EP0362647B1 (ko)
JP (1) JPH02155911A (ko)
KR (1) KR900006447A (ko)
DE (1) DE68903260T2 (ko)
ES (1) ES2052853T3 (ko)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2009492A1 (en) * 1989-03-09 1990-09-09 Charles M. Milliren Preparation of flexible polyurethane foams
US5006569A (en) * 1989-08-16 1991-04-09 Pmc, Inc. Density reduction in flexible polyurethane foams
US5028637A (en) * 1989-10-06 1991-07-02 Mobay Corporation Isocyanate reactive mixture and the use thereof in the manufacture of flexible polyurethane foams
US5071809A (en) * 1990-05-07 1991-12-10 Air Products And Chemicals, Inc. Tertiary amine catalysts for polyurethanes
ES2110100T3 (es) * 1992-06-26 1998-02-01 Minnesota Mining & Mfg Elastomeros de poliuretano/poliurea.
US5278197A (en) * 1993-07-06 1994-01-11 Miles Inc. Soft, flexible polyurethane foam
US5821275A (en) * 1997-11-10 1998-10-13 Bayer Corporation Flexible foams and flexible molded foams based on liquid isocyanate-terminated allophanate-modified MDI prepolymer blends and processes for the production of these foams
US5874485A (en) * 1997-11-10 1999-02-23 Bayer Corporation Flexible foams and flexible molded foams based on allophanate-modified diphenylmethane diisocyanates and processes for the production of these foams
US6482913B1 (en) * 2000-02-07 2002-11-19 Bayer Aktiengesellschaft Liquid MDI adducts wtih improved freeze stability
US6271279B1 (en) 2000-07-10 2001-08-07 Bayer Corporation High resilient flexible urethane foam and flexible molded foams based on allophanate modified isocyanates
US6376567B1 (en) 2000-12-07 2002-04-23 Bayer Corporation Polyisocyanate compositions and a process for the production of low-density flexible foams with low humid aged compression sets from these polyisocyanate compositions
US6750367B2 (en) * 2002-05-09 2004-06-15 Bayer Polymers Llc Tetralin isocyanates
US7078443B2 (en) * 2003-10-22 2006-07-18 Intellectual Property Holdings, Llc Viscoelastic foam layer and composition
CN102015810B (zh) * 2008-02-29 2014-07-16 陶氏环球技术有限责任公司 储存和运输稳定的基于天然油的多元醇和胺引发多元醇的多元醇共混物
ES2378504T3 (es) * 2008-06-10 2012-04-13 Dow Global Technologies Inc. Procedimiento para preparar una espuma rígida de poliuretano a partir de polioles iniciados con metilenbis(ciclohexilamina)
US9758619B2 (en) 2011-08-25 2017-09-12 Dow Global Technologies Llc Process for making polyether alcohols having oxyethylene units by polymerization of ethylene carbonate in the presence of double metal cyanide catalysts
KR101987510B1 (ko) 2011-08-31 2019-06-10 다우 글로벌 테크놀로지스 엘엘씨 가수분해성 실란 화합물을 사용한 가요성 폴리우레탄 폼의 제조 방법
WO2013048999A1 (en) 2011-09-27 2013-04-04 Dow Global Technologies Llc Method for preparing flexible polyurethane foam with hydrolysable silane compounds
US20220235168A1 (en) * 2021-01-22 2022-07-28 Covestro Llc Processes for making molded flexible foams and flexible foams produced thereby
US11738487B2 (en) * 2021-01-22 2023-08-29 Covestro Llc Processes for making molded flexible foams and flexible foams produced thereby

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL253697A (ko) * 1959-07-13
FR92371E (ko) * 1966-11-23
US3948825A (en) * 1974-07-05 1976-04-06 Basf Wyandotte Corporation Curing agent for use in making cellular polyurethane compositions
US4048102A (en) * 1975-04-21 1977-09-13 The Dow Chemical Company Process for preparing flexible polyurethane foams
US4256849A (en) * 1976-10-21 1981-03-17 Bayer Aktiengesellschaft Process for the production of cold setting foams which contain urethane groups prepared from a mixture of 4,4-diphenyl methane diisocyanate and 2,4-diphenyl methane diisocyanate
US4239856A (en) * 1978-08-28 1980-12-16 Texaco Development Corp. Method for preparing high-resilient flexible urethane foams
DE2965737D1 (de) * 1978-10-03 1983-07-28 Ici Plc Liquid polyisocyanate compositions
US4296213A (en) * 1979-10-17 1981-10-20 Texaco Inc. Polyurethane foams using a polyurea polymer polyol
US4269945A (en) * 1980-01-24 1981-05-26 The Dow Chemical Company Reaction injection molded polyurethanes employing aliphatic amine chain extenders
US4269946A (en) * 1980-01-31 1981-05-26 The Goodyear Tire & Rubber Company Low density high resiliency foams
US4585804A (en) * 1981-03-25 1986-04-29 The Dow Chemical Company Rigid foam with improved "K" factor by reacting a polyol, a polyisocyanate and at least one compound having at least one primary aliphatic amine group
US4365025A (en) * 1981-12-08 1982-12-21 W. R. Grace & Co. Flexible polyurethane foams from polymethylene polyphenyl isocyanate containing prepolymers
US4495081A (en) * 1982-07-13 1985-01-22 The Dow Chemical Company Compositions containing polyether polyols and aliphatic primary amines
US4687788A (en) * 1982-10-08 1987-08-18 The Dow Chemical Company Dimensionally stable urethane elastomers
US4530941A (en) * 1983-01-26 1985-07-23 The Dow Chemical Company Reaction injection molded polyurethanes employing high molecular weight polyols
US4569952A (en) * 1984-05-03 1986-02-11 Mobay Chemical Corporation Flexible polyurethane foams having improved load bearing characteristics and mixtures useful therein
DE3500337A1 (de) * 1985-01-08 1986-07-10 Bayer Ag, 5090 Leverkusen Stabile dispersionen von polyharnstoffen und/oder polyhydrazodicarbonamiden in hoehermolekularen, mindestens eine hydroxylgruppe aufweisenden hydroxylverbindungen, ein verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyurethankunststoffen
DE3529251A1 (de) * 1985-08-16 1987-02-26 Bayer Ag Kalthaertende zusammensetzungen, ein verfahren zu ihrer herstellung und ihre verwendung zur polyurethanherstellung
JPH0699535B2 (ja) * 1986-01-31 1994-12-07 日本ポリウレタン工業株式会社 ポリウレタンフォームの製造法
US4742091A (en) * 1986-08-13 1988-05-03 Texaco Inc. Rim elastomer
US4761465A (en) * 1987-07-27 1988-08-02 Texaco Inc. Difunctional isocyanate-terminated polyoxyalkylene diamine prepolymers and polymer coatings applications

Also Published As

Publication number Publication date
DE68903260D1 (de) 1992-11-26
ES2052853T3 (es) 1994-07-16
JPH02155911A (ja) 1990-06-15
US4876292A (en) 1989-10-24
DE68903260T2 (de) 1993-03-04
EP0362647B1 (en) 1992-10-21
EP0362647A1 (en) 1990-04-11

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