KR900006403A - 질소 함유 헤테로시클릭 화합물 및 비닐-종단 폴리우레탄/폴리아미드 중합체와 그들로 구성된 코우팅/점착 조성물 - Google Patents

질소 함유 헤테로시클릭 화합물 및 비닐-종단 폴리우레탄/폴리아미드 중합체와 그들로 구성된 코우팅/점착 조성물 Download PDF

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KR900006403A
KR900006403A KR1019890013132A KR890013132A KR900006403A KR 900006403 A KR900006403 A KR 900006403A KR 1019890013132 A KR1019890013132 A KR 1019890013132A KR 890013132 A KR890013132 A KR 890013132A KR 900006403 A KR900006403 A KR 900006403A
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melamine
tris
vinyl
radical
weight percent
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에스 포어기언 피이터
루 유시
싱 볼원트
에이 핸더슨 쥬니어 윌리엄
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알퐁스 아아르 노에
아메리칸 사이아나밋드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
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    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/40—Nitrogen atoms
    • C07D251/54—Three nitrogen atoms
    • C07D251/70—Other substituted melamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
    • C08F290/14—Polymers provided for in subclass C08G
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/92—Polyurethane having terminal ethylenic unsaturation

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  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
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Abstract

내용 없음

Description

질소 함유 헤테로시클릭 화합물 및 비닐-종단 폴리우레탄/폴리아미드 중합체와 그들로 구성된 코우팅/점착 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 적어도 두개의 비닐-종단 치환체 및 적어도 한개의 카르바밀메틸치환체를 함유하는 질소함유 헤테로시클릭 화합물.
  2. 제1항에 있어서, 비닐-종단 치환체 및 카르바밀 메틸치환체가 멜라민, 멜라민의 소중합체, 벤조구아나민, 벤조구아나민의 소중합체, 글리콜루릴, 글리콜루릴의 소중합체 및 이들의 혼합물로 구성된 군으로 부터 선택된 질소 함유 헤테로시클릭 핵(nucleus)에 부착된 질소 함유 헤테로시클릭 화합물.
  3. 하기 일반식에 의해 표현된 치환된 트리아미노트리아진 화합물 :
    상기식에서, 치환체 R은 하기와 같다 : R은 아크릴아미도, 아크릴레이트, 알릴옥시, 메타크릴레이트, 메탈릴옥시, 아크릴오일옥시, 아크릴오일알콕시, 메타크릴오일옥시알콕시, 메타크릴오일옥시, 메타크릴아미도, 또는 OR6, 또는 카르바밀이고, 여기서, R6는 수소 또는 C1-C18지방족, 지환족 또는 방향족 라디칼이고, 적어도 한개의 R치환체가 카르바밀이고, 단, 적어도 두개의 R치환체는 아크릴아미도, 아크릴레이트, 알릴옥시, 메타크릴레이트, 메탈릴옥시, 아크릴오일옥시, 아크릴오일옥시알콕시, 메타크릴오일옥시알콕시, 메타크릴오일옥시, 및 메타크릴아미도로부터 선택된다.
  4. 하기 일반식에 의해 표현된 멜라민-형 화합물 : C3N6(CH2)a(H)(6-a)(R1)m(R2)n(R3)a-(+m); 상기식에서, a는 3-6이고, R1은및및및 또는 이들의 혼합물로부터 선택된 치환체이고 (여기서, Z는 CH2CH2-O- 또는이고, R4는 수소 또는 C1-C18알킬라디칼임), R2는 일반식의 카르바밀 라디칼이고(여기서, R5는 C1-C18알킬, 지방족, 히드록시알킬, 알콕시 알킬 또는 방향족라디칼임), R3는 -OR6(여기서, R6는 수소 또는 C1-C18지방족, 지환족, 또는 방향족 라디칼)이고, 단 m은 적어도 2이고, n은 적어도 1이고, (m+n)의 합은 적어도 3이다.
  5. 하기 화합물로 구성된 군으로 부터 선택된 화합물 : N2,N4,N6-트리스(아크릴아미도메틸)-N2,N4,N6-트리스(2-에틸헥실카르바밀메틸)멜라민, N2,N4,N6-트리스(2-에틸헥실카르바메틸)-N2,N4,N6-트리스(2-아크릴오일옥시에톡시메틸)멜라민, N2,N4-비스(메틸카르바밀메틸)-N2,N4,N6,N6-테트라커스(2-아크릴오일옥시에톡시메틸)멜라민, N2N4-비스(메틸카르바밀메틸)-N2N4N6N6-테트라키스(2-메타크릴오일옥시에톡시메틸)멜라민, N2,N4,N6-트리스(프로필카르바밀메틸)-N2,N4,N6-트리스(2-아크릴오일옥시에톡시메틸)멜라민, N2,N4-비스(프로필카르바밀메틸)-N2,N4,N6,N6-테트라키스(2-아크릴오일옥시프로필옥시메틸)멜라민, N2,N4,N6-트리스(프로필카르바밀메틸)-N2,N4,N6-트리스(2-메타크릴오일옥시에톡시메틸)멜라민, N2,N4-비스(메틸카르바메틸)-N2,N4,N6,N6-테트라키스(2-메타크릴오일옥시에톡시메틸)멜라민, N2,N4,N6-트리스(아크릴아미도메틸)-N2,N4,N6-트리스(메틸카르바밀메틸)멜라민, N2,N4,N6-트리스(메틸카르바밀메틸)-N2,N4,N6-트리스(2-아크릴올옥시에톡시메틸)멜라민, N2,N4,N6-트리스(메틸카르바밀메틸)-N2,N4,N6-트리스(2-메타크릴올옥시에톡시메틸)멜라민, N2,N4,N6-트리스(메틸카르바밀메틸)-N2,N4,N6-트리스(2-아크릴올옥시에톡시메틸)멜라민, N2,N4,N6-트리스(프로필카르바밀메틸)-N2,N4,N6-트리스(2-메타크릴올옥시프로필옥시메틸)멜라민, N2,N4-비스(프로필카르바밀메틸)-N2,N4,N6-테트라키스(2-메타크릴올옥시프로필옥시메틸)멜라민, N2,N4-비스(프로필카르바밀메틸)-N2,N4,N6,N6-테트라키스(2-아크릴옥시에톡시메틸)멜라민, N2,N4,N6-트리스(프로필카르바밀메틸)-N2,N4,N6-트리스(아크릴아미도메틸)멜라민, 및 이들의 혼합물.
  6. 하기 일반식에 의해 표현된 벤조구아나민 화합물 : (C6H5)C3N5-(CH2)b(H)4-b-(R1)m(R2)n(R3)b-(n+m) 상기식에서, b는 3 또는 4이고, R1은 및및및 및또는 이들의 혼합물(여기서, Z는 CH2CH2-O- 또는 임)로 이루어진 군으로부터 선택된 치환체이고, R4는 수소 또는 C1-C18알킬라디칼이고, R2는 일반식(여기서, R5는 C1-C18알킬, 지방족, 히드록시알킬, 알콕시 알킬 또는 방향족라디칼임)이고, R3는 -OR6(여기서, R6는 수소 또는 C1-C18지방족, 지환족, 또는 방향족 라디칼임)이고, 단 m은 적어도 2이고, n은 적어도 1이고, (m+n)의 합은 적어도 3이다.
  7. 하기 일반식에 의패 표현된 글리콜루릴형 화합물 : C4H2N4(O)2-(CH2)C(H)4-C-(R1)m(R2)n(R3)C-(m+n); 상기식에서, C는 3 또는 4이고, R1은 및및 또는 이들의 혼합물 (여기서, Z는 CH2CH2-O- 또는 이고, R4는 수소 또는 C1-C18알킬라디칼임)으로 구성된 군으로부터 선택된 치환체이고, R2는 일반식(여기서 R5는 C1-C18알킬, 지방족, 히드록시알킬, 알콕시 알킬 또는 방향족라디칼임)의 카르바밀라디칼이고, R3는 -OR6(여기서, R6는 수소 또는 C1-C18지방족, 지환족, 또는 방향족 라디칼임)이고, 단 m은 적어도 2이고, n은 적어도 1이고, (m+n)의 합은 적어도 3이다.
  8. 비닐산, 비닐 알코올 또는 비닐 아미드와 폴리이소시아네이트를 반응시킨 후에, 두번째 단계에서는 첫번째 단계의 반응 생성물을 고분자량 폴리올과 반응시키는 방법에 의해 제조된, 약 3,000-약80,000의 분자량을 가지고, 적어도 두개의 비닐 말단기를 함유하는 비닐-종단 폴리우레탄/폴리아미드 중합체.
  9. 하기 (A)-(D)로 구성된 경화성 코우팅/밀봉 조성물 : (A) 약5-약70중량% 적어도 한개의 카르바밀메틸기, 및 적어도 두개의 비닐-종단 유기기를 반응기로서 갖는 적어도 한개의 질소 함유 헤테로시클릭 화합물; (B) 약 30-약 90중량%의, 약 3,000-약 80,000의 분자량을 가지는 비닐-종단 폴리우레탄/폴리아미드 중합체; (C) 약 2-약 30중량%의 중합가능한 희석제; (D) 약 0.5-약 5중량%의 자유-라디칼촉매, 여기서, 성분(A),(B),(C) 및 (D)의 합은 100중량%이하이다.
  10. 하기 (A)-(E)로 구성된 경화성 접착 조성물 : (A) 약5-약70중량% 적어도 한개의 카르바밀메틸기, 및 적어도 두개의 비닐-종단 유기기를 반응기로서 갖는 적어도 한개의 질소 화합물; (B) 약 30-약 90중량%의, 약 3,000-약 80,000의 분자량을 가지는 비닐-종단 폴리우레탄/폴리아미드 중합체; (C) 약 2-약 30중량%의 중합가능한 희석제; (D) 약 0.5-약 5중량%의 자유-라디칼촉매, (E) 약 0.5-약 10중량%의, 접착 촉진제/커플링제 여기서, 성분(A),(B),(C),(D) 및 (E)의 합은 100중량%이하이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890013132A 1988-10-31 1989-09-09 질소 함유 헤테로시클릭 화합물 KR0158200B1 (ko)

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KR1019980013162A KR0170629B1 (ko) 1988-10-31 1998-04-14 비닐-종단 폴리우레탄/폴리아미드 중합체 및 이를 포함하는 코우팅/밀봉 및 점착 조성물

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USD7/264,661 1988-10-31
US7/264,661 1988-10-31
US07/264,661 US5175201A (en) 1988-10-31 1988-10-31 Vinyl-terminated carbamylmethylated melamines, vinyl-terminated polyurethane/polyamide polymers and coating/adhesive compositions containing same

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ATE132493T1 (de) 1996-01-15
KR0158200B1 (ko) 1999-01-15
MX169828B (es) 1993-07-27
JP2941862B2 (ja) 1999-08-30
NO894321L (no) 1990-05-02
EP0366884A3 (en) 1991-07-24
EP0366884B1 (en) 1996-01-03
DE68925339D1 (de) 1996-02-15
NO302829B1 (no) 1998-04-27
NO894321D0 (no) 1989-10-30
US5175201A (en) 1992-12-29
US5359014A (en) 1994-10-25
CA1339662C (en) 1998-02-10
BR8905534A (pt) 1990-05-29
EP0366884A2 (en) 1990-05-09
DE68925339T2 (de) 1996-08-01
JPH02172980A (ja) 1990-07-04

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