KR900004768A - 촉매 용액의 제조 방법 및 그를 사용한 중합체의 제조 방법 - Google Patents
촉매 용액의 제조 방법 및 그를 사용한 중합체의 제조 방법 Download PDFInfo
- Publication number
- KR900004768A KR900004768A KR1019890013471A KR890013471A KR900004768A KR 900004768 A KR900004768 A KR 900004768A KR 1019890013471 A KR1019890013471 A KR 1019890013471A KR 890013471 A KR890013471 A KR 890013471A KR 900004768 A KR900004768 A KR 900004768A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst solution
- palladium
- monocarboxylic acid
- polymer
- group
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 5
- 238000004519 manufacturing process Methods 0.000 title claims 4
- 229920000642 polymer Polymers 0.000 title claims 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 6
- 238000000034 method Methods 0.000 claims 6
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 229910052736 halogen Inorganic materials 0.000 claims 3
- -1 halogen monocarboxylic acid Chemical class 0.000 claims 3
- 229910052763 palladium Inorganic materials 0.000 claims 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 2
- 125000005647 linker group Chemical group 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 2
- 150000002940 palladium Chemical class 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- 239000002798 polar solvent Substances 0.000 claims 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 claims 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G67/00—Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
- C08G67/02—Copolymers of carbon monoxide and aliphatic unsaturated compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Polyethers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Medicinal Preparation (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 비양성자성 극성 용매 내에서, 모노카르복실산의 팔라듐염과 일반식(R2)2P-R-P(R2)2(여기서 R2는 아릴리가 결합된 인원자에 대해 오르토위치에, 적어도 한개의 알콕시 치환체를 함유한 아릴기를 나타내고 R은 연결내에, 적어도 두개의 탄소원자를 함유한 2가 유기연결기임)의 비스포핀을 배합시키고, 이렇게 얻어진 혼합물에 2 이하의 pKa를 갖는 할로겐 모노카르복실산을 첨가시키는 것을 특징으로 하는 촉매 용액의 제조방법.
- 제1항에 있어서, 비양성자성 극성용매가 아세톤, 메틸에틸케톤, 테트라히드로푸란, 감마-부티로락톤, N-메틸피롤리돈 및 술폴란으로 구성된 군중에서 선택되는 것을 특징으로 하는 방법.
- 제1항 또는 제2항에 있어서, 사용된 모노카르복실산의 팔라듐염이 팔라듐 아세테이트인 것을 특징으로 하는 방법.
- 제1항 내지 제3항중 어느 한 항에 있어서, 기 R2가, 페닐기가 결합된 인원자에 대해 오로토 위치에, 적어도 한개의 메톡시 치환체를 함유한 페닐기이고 연결기 R이 연결내에 그중 적어도 두개의 탄소원자인 세개의 원자를 함유한 비스포스핀을 사용하는 것을 특징으로 하는 방법.
- 제1항 내지 제4항중 어느 한 항에 있어서, 팔라듐 몰당 1.0-1.5몰량의 비스포스핀을 사용하는 것을 특징으로 하는 방법.
- 제1항 내지 제5항중 어느 한 항에 있어서, 2 이하의 pKa를 갖는, 사용된 할로겐 모노카르복실산이 트리플루오로아세트산인 것을 특징으로 하는 방법.
- 제1항 내지 제6항중 어느 한 항에 있어서, 팔라듐 몰당, 촉매용액내에 7.5-30몰의 그들의 음이온이 존재할 정도로 할로겐 모노카르복실산을 사용하는 것을 특징으로 하는 방법.
- 중합체가 불용성이거나 실질적으로 불용성인 희석제가 존재하는 가운데 고온 및 고압에서, 단량체를 제1항에서 청구된대로 제조된 촉매용액과 접촉시킴으로써, 하나이상의 올레핀형 불포화 화합물과 일산화탄소의 중합체를 제조하는 것을 특징으로 하는 중합체인 제조방법.
- 제8항에 있어서, 40-120℃의 온도, 20-150 바아의 압력 및 중합될 혼합물내 10:1-1:5의, 올레핀형 불포화 화합물(들)대 일산화탄소의 몰비에서 중합될 올레핀형 불포화 화합물 몰당 10-7-10-3몰의 팔라듐을 함유하는 촉매 용액을 사용하여 반응을 수행하는 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8802347 | 1988-09-22 | ||
| NL8802347 | 1988-09-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR900004768A true KR900004768A (ko) | 1990-04-13 |
Family
ID=19852950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019890013471A KR900004768A (ko) | 1988-09-22 | 1989-09-19 | 촉매 용액의 제조 방법 및 그를 사용한 중합체의 제조 방법 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5010171A (ko) |
| EP (1) | EP0360359B1 (ko) |
| JP (1) | JP2846898B2 (ko) |
| KR (1) | KR900004768A (ko) |
| AT (1) | ATE88201T1 (ko) |
| AU (1) | AU612896B2 (ko) |
| BR (1) | BR8904723A (ko) |
| DE (1) | DE68905982T2 (ko) |
| ES (1) | ES2055013T3 (ko) |
| ZA (1) | ZA897172B (ko) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8902934A (nl) * | 1989-11-28 | 1991-06-17 | Shell Int Research | Bereiding van polymeren. |
| GB9020976D0 (en) * | 1990-09-26 | 1990-11-07 | British Petroleum Co Plc | Process for preparing polyketones |
| JPH06502439A (ja) * | 1990-10-10 | 1994-03-17 | アクゾ ナムローゼ フェンノートシャップ | 一酸化炭素とプロピレンの共重合体及びその製造法 |
| GB9107887D0 (en) * | 1991-04-13 | 1991-05-29 | British Petroleum Co Plc | Preparation of palladium catalysts |
| GB9114488D0 (en) * | 1991-07-04 | 1991-08-21 | British Petroleum Co Plc | Process for preparing polyketones |
| US5554777A (en) * | 1993-01-22 | 1996-09-10 | The Dow Chemical Compamy | Catalyst for the preparation of linear carbon monoxide/alpha-olefin copolymers |
| US5654250A (en) * | 1994-05-19 | 1997-08-05 | Shell Oil Company | Preparation of catalyst solution |
| US6103919A (en) * | 1998-07-07 | 2000-08-15 | Arteva North America S.A.R.L. | Catalytic system and method for coupling of aromatic compounds |
| DE19837912C1 (de) * | 1998-08-20 | 1999-10-28 | Implex Hear Tech Ag | Energieversorgungsmodul für eine implantierbare Vorrichtung |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE49010T1 (de) * | 1983-04-06 | 1990-01-15 | Shell Int Research | Verfahren zur herstellung von polyketonen. |
| NL8403035A (nl) * | 1984-10-05 | 1986-05-01 | Shell Int Research | Werkwijze ter bereiding van polyketonen. |
| IN166314B (ko) * | 1985-08-29 | 1990-04-07 | Shell Int Research | |
| IN168306B (ko) * | 1986-03-05 | 1991-03-09 | Shell Int Research | |
| CA1271877A (en) * | 1986-03-24 | 1990-07-17 | Johannes A.M. Van Broekhoven | Polymer preparation |
| IN171627B (ko) * | 1986-08-26 | 1992-11-28 | Shell Int Research | |
| AU612173B2 (en) * | 1987-08-28 | 1991-07-04 | Shell Internationale Research Maatschappij B.V. | Preparation of olefin/CO copolymers |
| EP0319083A3 (en) * | 1987-11-30 | 1990-11-07 | Shell Internationale Researchmaatschappij B.V. | Polyketone polymer preparation |
-
1989
- 1989-09-15 US US07/408,012 patent/US5010171A/en not_active Expired - Fee Related
- 1989-09-19 KR KR1019890013471A patent/KR900004768A/ko not_active Application Discontinuation
- 1989-09-20 AU AU41590/89A patent/AU612896B2/en not_active Ceased
- 1989-09-20 JP JP1244880A patent/JP2846898B2/ja not_active Expired - Fee Related
- 1989-09-20 BR BR898904723A patent/BR8904723A/pt not_active Application Discontinuation
- 1989-09-20 ZA ZA897172A patent/ZA897172B/xx unknown
- 1989-09-21 DE DE8989202390T patent/DE68905982T2/de not_active Expired - Lifetime
- 1989-09-21 AT AT89202390T patent/ATE88201T1/de not_active IP Right Cessation
- 1989-09-21 EP EP89202390A patent/EP0360359B1/en not_active Expired - Lifetime
- 1989-09-21 ES ES89202390T patent/ES2055013T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| BR8904723A (pt) | 1990-05-01 |
| ZA897172B (en) | 1990-06-27 |
| JP2846898B2 (ja) | 1999-01-13 |
| DE68905982T2 (de) | 1993-09-16 |
| DE68905982D1 (de) | 1993-05-19 |
| ES2055013T3 (es) | 1994-08-16 |
| EP0360359B1 (en) | 1993-04-14 |
| JPH02115224A (ja) | 1990-04-27 |
| ATE88201T1 (de) | 1993-04-15 |
| EP0360359A1 (en) | 1990-03-28 |
| AU4159089A (en) | 1990-03-29 |
| US5010171A (en) | 1991-04-23 |
| AU612896B2 (en) | 1991-07-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WITB | Written withdrawal of application |