KR890701685A - 연질 열가소송 조성물 - Google Patents

연질 열가소송 조성물

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KR890701685A
KR890701685A KR1019880700784A KR880700784A KR890701685A KR 890701685 A KR890701685 A KR 890701685A KR 1019880700784 A KR1019880700784 A KR 1019880700784A KR 880700784 A KR880700784 A KR 880700784A KR 890701685 A KR890701685 A KR 890701685A
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KR960003280B1 (ko
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피이 솔트만 로버트
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제임즈 제이 플린
이 아이듀우판 디 네모아 앤드 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C08L23/0876—Neutralised polymers, i.e. ionomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C08L23/0884—Epoxide containing esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

연질 열가소송 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기a)-c)를 용융 블렌딩시킴으로써 형성된 부분적으로 그라프트화된, 다상 연질 열가소성 조성물: a) 폴리 에틸렌, 폴리프로필렌 및 이들의 공중합체, 폴리부틸렌, 폴리-4-메틸펜트-1-엔, 폴리스티렌 및 이들의 공중합체, 폴리페닐렌 옥시드, 폴리페닐렌 설파이드 및 포리술폰에서 선택되고, 조성물의 최소한 하나의 연속성을 구성하는, 25-50부피%의 최소한 하나의 열가소성 수지, b) 10-74부피%의 최소한 하나의 에틸렌 공중합체, E/X/Y [이 식에서 E는 E/X/T의 최소한 50중량%인 에틸렌이고, X는 1-35중량%인 산-함유 불포화 모노-카르복실산이며, Y는 0-49중량%인, 최소한 하나의 알킬아크릴레이트, 알킬 메타릴레이트, 비닐에테르, (여기서 알킬 및 에테르 라디칼은 1-12개 탄소원자를 함유한다.), 일산화 탄소, 이산화 탄소, 이산화 황, 또는 이들의 혼합물에서 유도된 부분이며, 더 나아가서 산 함유 부분내에 있는 산기는 금속에 의해0-100%중화된] 및 c)에폭시드, 이소시아네이트, 아지리딘, 실란, 알킬 할로겐화물, 알파-할로케톤, 알파-할로 알디히드 또는 옥시졸린 중 최소한 하나에서 선택된 반응성기를 함유하고 성분 b) 내에 있는 산-함유부분과 반응하는 최소한 하나의 중합체 그라프팅제 1-50부피%(여기서 성분 b) + 성분 c) 100 당 반응성기의 MMOLS로서 표현되는, 그라프팅제에 의해 조성물에 제공된 반응기의 양이 1-35이고, 더 나아가서 중합체 그라프팅제, 성분 Cso에 있는 반응성기는 0.5-15중량%이고 중합체 그라프팅제의 나머지는 최소한 50중량%의 에틸렌과, 알킬 및 에테르가 1-12개 탄소원자를 함유하는 최소한 하나의 알킬 아크릴레이트, 알킬 메타크릴레이트, 비닐 에테르, 일산화 탄소, 이산화황 또는 이들의 혼합물로부터 유도된 부분 0-49중량%를 함유함)[상기 부피%는 성분 a), 성분 b) 및 성분 c)만의 합을 기준으로 한 것이고 혼합하기 전에 개개 성분의 밀도에서부터 계산된 것임]
  2. 제1항에 있어서, 성분 a)가 폴리에틸렌, 폴리프로필렌, 및 이들의 공중합체에서 선택된 조성물.
  3. 제2항에 있어서, 성분 a)가 폴리프로필렌에서 선택된 조성물.
  4. 제1항에 있어서, 성분 a)는 27-48부피%의 양으로 존재하고, 성분 b)는 20-69부피%의 양으로 존재하며, 성분 c)는 4-35부피%의 양으로 존재하는 조성물.
  5. 제4항에 있어서, 성분 a)가 28-46부피5의 양으로 존재하고, 성분 b)가 30-65부피%의 양으로 존재하며, 성분 c)가 7-25부피%의 양으로 존재하는 조성물.
  6. 제1항에 있어서, 성분 b)는 최소한 55중량%의 에틸렌, 3-30중량%의 불포화 모노-카르복실산 및, 알킬 아크릴레이트, 알킬메타크릴레이트 및 이들의 혼합물 중 최소한 하나에서, 유도된 부분(여기서 알킬 라디칼은 1-8개 탄소 원자를 함유함) 0-35중량%를 포함하며 더 나아가서 불포화 모노-카르복실산 내에 있는 산기는 나트륨, 아연, 마그네슘, 칼슘, 및 리튬에서 선택된 최소한 하나의 금속이온에 의해 0-80%가 중화되는 조성물.
  7. 제6항에 있어서, 성분 b)는 최소한 60중량%의 에틸렌, 메타크릴 산 및 아크릴산에서 선택된 산-함유부분 5-15중량%, 메틸 아크릴레이트, 이소-부틸 아크릴레이트 중 최소한 하나에서 유도된 부분 0-25중량%를 포함하고 더 나아가서 이 산기가 나트륨, 아연, 마그네슘 및 칼슘에서 선택된 최소한 하나의 금속이온에 의해 30-70%가 중화된 조성물.
  8. 제1항에 있어서, 성분 c)는 4-11개 탄소원자를 함유하는 에폭시드에서 선택된 반응성 기를 함유하고, 성분 b)+성분 c)의 100당 반응성기의 MMOLS로서 표현되는, 성분 c)에 의해 조성물에 제공된 반응성 기의 양, X는 5-30이고 더 나아가서 성분 c) 내에 있는 반응성기의 양은 1-10중량%이고, 성분 c)의 나머지는 에틸렌이 최소한 55중량%이고, 알킬 아크릴레이트, 알킬 메타크릴레이트, 또는 이들의 혼합물 중 최소한 하나에서 유도된 부분(여기서 알킬 라디칼은 1-8개 탄소원자를 함유함다)이 0-35중량%인 조성물.
  9. 제8항에 있어서, 성분 c)가 글리시딜 메타크릴레이트 및 글리시딜 아크릴레이트에서 유도된 에폭시드에서 선택된 반응성 기를 함유하고, 반응성 기의 양 X가 성분 b)+성분 c)의 100 당 반응성기 10-25MMOLS인 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880700784A 1987-11-13 1987-11-13 연질 열가소성 조성물 KR960003280B1 (ko)

Applications Claiming Priority (1)

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PCT/US1987/002922 WO1989004346A1 (en) 1987-11-13 1987-11-13 Flexible thermoplastic composition

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KR890701685A true KR890701685A (ko) 1989-12-21
KR960003280B1 KR960003280B1 (ko) 1996-03-08

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EP (1) EP0341268B1 (ko)
JP (1) JP2627002B2 (ko)
KR (1) KR960003280B1 (ko)
BR (1) BR8707939A (ko)
DK (1) DK169683B1 (ko)
WO (1) WO1989004346A1 (ko)

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JPH05147106A (ja) * 1991-05-29 1993-06-15 Sumitomo Electric Ind Ltd 熱回復性物品
JP3375780B2 (ja) * 1995-03-29 2003-02-10 三井化学株式会社 重包装袋用ポリエチレン樹脂組成物およびその組成物からなる重包装袋用ポリエチレン樹脂フィルム
JP3660035B2 (ja) * 1995-11-29 2005-06-15 三井・デュポンポリケミカル株式会社 ポリフェニレンオキシド樹脂組成物
US6034176A (en) * 1998-03-31 2000-03-07 Teknor Apex Company Polymer compositions
CN102120862B (zh) * 2011-04-08 2012-12-12 成都盛泽科技有限公司 一种制造塑料管道嵌件的聚合物合金

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US3600468A (en) * 1968-10-31 1971-08-17 Dow Chemical Co Adhesive blend comprising an ethylene/unsaturated acid copolymer and an ethylene/unsaturated ester copolymer
GB1363304A (en) * 1970-07-30 1974-08-14 Sumitomo Chemical Co Polyolefin compositions
JPS57108153A (en) * 1980-12-25 1982-07-06 Sumitomo Chem Co Ltd Resin composition
US4387188A (en) * 1981-02-23 1983-06-07 E. I. Du Pont De Nemours And Company Molding resins based on blends of acid copolymer/linear polyolefin/reinforcing fiber
US4480054A (en) * 1983-07-15 1984-10-30 E. I Du Pont De Nemours And Company Foamable polymer blend compositions
JPS60240747A (ja) * 1984-05-15 1985-11-29 Showa Denko Kk 架橋性組成物及びエステル架橋型重合体
JPH06875B2 (ja) * 1984-11-05 1994-01-05 住友化学工業株式会社 ポリオレフイン組成物
US4696967A (en) * 1985-05-21 1987-09-29 Bp Performance Polymers Inc. Thermoplastic elastomer compositions
JPH0611820B2 (ja) * 1985-08-16 1994-02-16 イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− ハロゲンを含まない難燃性熱可塑性組成物
US4710544A (en) * 1985-11-07 1987-12-01 E. I. Du Pont De Nemours And Company Thermoplastic composition of polyolefin and high ethylene content ethylene/alkyl acrylate elastomer

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JP2627002B2 (ja) 1997-07-02
JPH02502195A (ja) 1990-07-19
EP0341268A1 (en) 1989-11-15
DK169683B1 (da) 1995-01-09
BR8707939A (pt) 1990-03-27
EP0341268B1 (en) 1993-08-25
EP0341268A4 (en) 1991-01-16
DK345789A (da) 1989-07-12
KR960003280B1 (ko) 1996-03-08
DK345789D0 (da) 1989-07-12
WO1989004346A1 (en) 1989-05-18

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