KR890014607A - 선형의 인함유 공폴리에스테르, 이의 제조방법 및 이의 난연제로서 용도 - Google Patents
선형의 인함유 공폴리에스테르, 이의 제조방법 및 이의 난연제로서 용도 Download PDFInfo
- Publication number
- KR890014607A KR890014607A KR1019890003572A KR890003572A KR890014607A KR 890014607 A KR890014607 A KR 890014607A KR 1019890003572 A KR1019890003572 A KR 1019890003572A KR 890003572 A KR890003572 A KR 890003572A KR 890014607 A KR890014607 A KR 890014607A
- Authority
- KR
- South Korea
- Prior art keywords
- linear
- range
- poly
- copolyester
- linear copolyester
- Prior art date
Links
- 229920001634 Copolyester Polymers 0.000 title claims 11
- 238000000034 method Methods 0.000 title claims 5
- 239000003063 flame retardant Substances 0.000 title claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 229920000728 polyester Polymers 0.000 claims 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims 4
- 238000002844 melting Methods 0.000 claims 3
- 230000008018 melting Effects 0.000 claims 3
- JARHXLHLCUCUJP-UHFFFAOYSA-N ethene;terephthalic acid Chemical group C=C.OC(=O)C1=CC=C(C(O)=O)C=C1 JARHXLHLCUCUJP-UHFFFAOYSA-N 0.000 claims 2
- -1 poly (vinyl-hydroxymethylenephosphinate Chemical compound 0.000 claims 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
- LDSHXVLXOSCNEH-UHFFFAOYSA-N OC(c1ccccc1)=P(O)=O Chemical compound OC(c1ccccc1)=P(O)=O LDSHXVLXOSCNEH-UHFFFAOYSA-N 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 230000009970 fire resistant effect Effects 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 229920002521 macromolecule Polymers 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
- C08G63/6924—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6926—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- 그의 거대분자속에 : (a) 테레프탈산 ; (b) (C2-C6)-알킬렌글리콜 ; 및 (c) 페닐-히드록시메틸렌 포스핀산에서, 1:1:0.2 내지 1:1:1의 범위에 포함되는 상호비율로 얻는 유닛을 포함하고 난연제로서 유용한 선형 공폴리에스테르(copolyester), 여기서(c) 유닛은 (a) 및 (b) 유닛 사이에 임의로 분포되고 테레프탈 산에서 얻는 선형 폴리에스테르를 일반식(I)의 폴리(비닐-히드록시메틸렌포스핀산염) (I)과 용융조건에서 약 30분 이하의 시간동안 조작하여 접촉시켜 얻으며 :이식에서 : Ph는 페닐기이고 ; R는 수소원자이거나 또는 1 내지 8의 탄소원자를 포함하는 직쇄나 측쇄의 알킬기이고 ; 그리고n는 2.5 내지 100의 범위에 포함되는 수이다.
- 제1항에 있어서, 전술한 선형 공폴리에스테르가 폴리(테레프탈산 에틸렌) 또는 폴리(테레프탈산 부틸렌)인 것을 특징으로 하는 선형 공폴리에스테르.
- 제1항에 있어서, 전술한 폴리(페닐-히드록시메틸렌 포스핀산염) (I)에서 R가 이소부틸이고n가 35 내지 40의 평균치를 가지는 것을 특징으로 하는 선형 공폴리에스테르.
- 제1항에 있어서, 이 방법을 용융조건에서 230℃ 내지 290℃의 범위에 포함되는 온도에서 그리고 200 내지 300mmHg의 범위에 포함되는 압력에서 실시하는 것을 특징으로 하는 선형 공폴리에스테르.
- 제4항에 있어서, 선형 폴리에스테르가 폴리(테레프탈산 에틸렌)이고 그리고 방법은 용융조건에서 270℃ 내지 280℃의 범위에 포함되는 온도에서 그리고 200 내지 300mmHg의 범위에 포함되는 압력에서 실시하는 것을 특징으로 하는 선형 공폴리에스테르.
- 제1항에 있어서, 전술한 접촉시간이 약 20분 보다 짧은 것을 특징으로 하는 선형 공폴리에스테르.
- 제6항에 있어서, 전술한 접촉시간이 10분대가 되는 것을 특징으로 하는 선형 공폴리에스테르.
- 제1항에 있어서, 일강형태로된 것을 특징으로 하는 선형 공폴리에스테르.
- 선형 폴리에스테르 또는 이 선형 폴리에스테르의 혼합물을 용융시키고 제1항 내지 제8항에 따른 선형 공폴리에스테르와 균질화시키는 것을 특징으로 하는 선형 폴리에스테르에 내화성 특성을 부여하는 방법※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT19904A/88 | 1988-03-23 | ||
| IT19904A-88 | 1988-03-23 | ||
| IT19904/88A IT1217348B (it) | 1988-03-23 | 1988-03-23 | Copoliestere lineare contenente fosforo,procedimento per la sua preparazione e suo uso quale agente antifiamma |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR890014607A true KR890014607A (ko) | 1989-10-24 |
| KR930001484B1 KR930001484B1 (ko) | 1993-03-02 |
Family
ID=11162217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019890003572A KR930001484B1 (ko) | 1988-03-23 | 1989-03-22 | 난연성 선형 공폴리에스테르(copolyester)제조방법 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4981945A (ko) |
| EP (1) | EP0334423B1 (ko) |
| JP (1) | JPH026527A (ko) |
| KR (1) | KR930001484B1 (ko) |
| AT (1) | ATE112299T1 (ko) |
| AU (1) | AU614344B2 (ko) |
| CA (1) | CA1318453C (ko) |
| DE (1) | DE68918482T2 (ko) |
| ES (1) | ES2060738T3 (ko) |
| IT (1) | IT1217348B (ko) |
| RU (1) | RU2019547C1 (ko) |
| ZA (1) | ZA891983B (ko) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5447991A (en) * | 1990-07-11 | 1995-09-05 | Enichem Synthesis S.P.A. | Flame-resistant polyolefinic fibres and films |
| IT1246762B (it) * | 1990-07-11 | 1994-11-26 | Enichem Sintesi | Fibre e film poliolefinici resistenti alla fiamma |
| EP0534569A1 (en) * | 1991-09-27 | 1993-03-31 | ENICHEM S.p.A. | Fast-crystallizing polyester compositions |
| IT1255570B (it) * | 1992-10-06 | 1995-11-09 | Alcantara Spa | Tessuto non tessuto microfibroso sintetico antifiamma e procedimento per la sua preparazione |
| US20050113491A1 (en) † | 2003-11-25 | 2005-05-26 | Warren Leslie F.Jr. | Flame retardant polymer compositions and methods for making the same |
| CN101333287B (zh) * | 2007-06-29 | 2011-11-30 | 厦门翔鹭化纤股份有限公司 | 一种阻燃共聚改性聚酯的制备方法 |
| JP5596457B2 (ja) * | 2010-07-29 | 2014-09-24 | 三菱樹脂株式会社 | 難燃性ポリエステル系樹脂組成物及びこれを用いてなる成形品 |
| CN104387571B (zh) * | 2014-11-10 | 2015-10-28 | 杭州湘隽纺织阻燃科技有限公司 | 含磷氮聚对苯二甲酸乙二醇酯阻燃共聚酯及其应用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS559092B2 (ko) * | 1974-03-02 | 1980-03-07 | ||
| US4087403A (en) * | 1976-03-01 | 1978-05-02 | Monsanto Company | Polyphosphinate flame retardants |
| DE2828463C2 (de) * | 1978-06-29 | 1980-08-28 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung linearer, lichtstabilisierter mit TiO2 mattierter Polyester |
| DE2828464C2 (de) * | 1978-06-29 | 1980-08-28 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung linearer, lichtstabilisierter mit TiO2 mattierter Polyester |
| DE3361903D1 (en) * | 1982-04-22 | 1986-03-06 | Anic Spa | Flameproof linear polyester, a process for its preparation, and articles formed from said polyester |
| IT1213588B (it) * | 1986-07-23 | 1989-12-20 | Enichem Sintesi | Additivo antifiamma oligomerico, procedimento per la sua preparazione e suo uso per rendere antifiamma un poliestere lineare. |
-
1988
- 1988-03-23 IT IT19904/88A patent/IT1217348B/it active
-
1989
- 1989-03-15 AT AT89200645T patent/ATE112299T1/de not_active IP Right Cessation
- 1989-03-15 ZA ZA891983A patent/ZA891983B/xx unknown
- 1989-03-15 EP EP89200645A patent/EP0334423B1/en not_active Expired - Lifetime
- 1989-03-15 DE DE68918482T patent/DE68918482T2/de not_active Expired - Fee Related
- 1989-03-15 ES ES89200645T patent/ES2060738T3/es not_active Expired - Lifetime
- 1989-03-17 US US07/324,907 patent/US4981945A/en not_active Expired - Fee Related
- 1989-03-22 KR KR1019890003572A patent/KR930001484B1/ko not_active IP Right Cessation
- 1989-03-22 RU SU894613688A patent/RU2019547C1/ru active
- 1989-03-22 AU AU31626/89A patent/AU614344B2/en not_active Ceased
- 1989-03-22 CA CA000594467A patent/CA1318453C/en not_active Expired - Fee Related
- 1989-03-23 JP JP1069419A patent/JPH026527A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JPH026527A (ja) | 1990-01-10 |
| KR930001484B1 (ko) | 1993-03-02 |
| AU614344B2 (en) | 1991-08-29 |
| EP0334423A2 (en) | 1989-09-27 |
| EP0334423B1 (en) | 1994-09-28 |
| IT8819904A0 (it) | 1988-03-23 |
| IT1217348B (it) | 1990-03-22 |
| DE68918482D1 (de) | 1994-11-03 |
| AU3162689A (en) | 1989-09-28 |
| CA1318453C (en) | 1993-05-25 |
| EP0334423A3 (en) | 1991-01-23 |
| US4981945A (en) | 1991-01-01 |
| ATE112299T1 (de) | 1994-10-15 |
| RU2019547C1 (ru) | 1994-09-15 |
| DE68918482T2 (de) | 1995-04-20 |
| ZA891983B (en) | 1989-11-29 |
| ES2060738T3 (es) | 1994-12-01 |
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| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| G160 | Decision to publish patent application | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| LAPS | Lapse due to unpaid annual fee |