KR890010014A - 신규의 보호 이소시아네이트 및 그의 제조 및 사용방법 - Google Patents

신규의 보호 이소시아네이트 및 그의 제조 및 사용방법 Download PDF

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Publication number
KR890010014A
KR890010014A KR1019880016452A KR880016452A KR890010014A KR 890010014 A KR890010014 A KR 890010014A KR 1019880016452 A KR1019880016452 A KR 1019880016452A KR 880016452 A KR880016452 A KR 880016452A KR 890010014 A KR890010014 A KR 890010014A
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South Korea
Prior art keywords
coating
curing agent
ketoxime
isocyanate curing
novel protective
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KR1019880016452A
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English (en)
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KR920010138B1 (ko
Inventor
쥬니어 피터 카마치크
제임스 맥콜럼 그레고리
Iii세 죠지 윌리암 마우어
Original Assignee
헬렌 에이. 파블릭크
피피지 인더스트리즈, 인코포레이티드
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Priority claimed from US07/131,888 external-priority patent/US4846946A/en
Priority claimed from US07/131,889 external-priority patent/US4824925A/en
Application filed by 헬렌 에이. 파블릭크, 피피지 인더스트리즈, 인코포레이티드 filed Critical 헬렌 에이. 파블릭크
Publication of KR890010014A publication Critical patent/KR890010014A/ko
Application granted granted Critical
Publication of KR920010138B1 publication Critical patent/KR920010138B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4488—Cathodic paints
    • C09D5/4496—Cathodic paints characterised by the nature of the curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0809—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups
    • C08G18/0814—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups containing ammonium groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
    • C08G18/643—Reaction products of epoxy resins with at least equivalent amounts of amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C08G18/8022—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with polyols having at least three hydroxy groups
    • C08G18/8029—Masked aromatic polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • C08G18/8077—Oximes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Molecular Biology (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

신규의 보호 이소시아네이트 및 그의 제조 및 사용방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. (a) 메타-크실릴렌 디이소시아네이트 또는 그의 예비중하체와 (b)탄소수 3 내지 5의 캐톡심을 반응시켜 제조된 신규의 보호 이소싱네이트 경화제.
  2. 제1항에 있어서, 케톡심이 메틸에틸 케톡심인 신규의 보호 이소시아네이트 경화제.
  3. 제1항에 있어서, 예비중합체가, 트리메틸올프로판, 폴리카프로락톤트리올 및 트리메틸올 에탄으로 구성된 그룹으로부터 선택된 폴리올과 메타-크실릴렌 디이소시아네이트를 반응시켜 제조되는 신규의 보호 이소시아네이트 경화제.
  4. 제1항에 있어서, 케톡심의 -OH 대 이소시아네이트의 -NCO의 당량비가 0.3 내지 1:1인 신규의 보호 이소시아네이트 경화제.
  5. 제1항의 경화제 및 활성수소 함유물질을 포함하는 경화가능 조성물.
  6. 활성수소 함유 물질 및 제1항의 경화제를 포함하는 수-기재 도장 조성물.
  7. 제6항에 있어서, 이온성 전착가능 그룹을 함유하는 수-기재 도장조성물.
  8. 제7항에 있어서, 이온성 그룹이 양이온성인 수-기재 도장조성물.
  9. 활성수소 함유물질 및 제1항의 경화제를 포함하는 수성분산액에 담궈진 양극과 음극 사이에 전류가 통하도록 하는 것을 포함하여 전극으로서 작용하는 전기전도성 기질을 전착시키는 방법.
  10. 제9항에 있어서, 수성분산액이 양이온성 그룹을 함유하는 방법.
  11. (i)제5항에 경화가능 조성물을 포함하는 도장 조성물을 기질에 적용시키고, (ii)적용된 피막을 경화시키기에 충분한 온도로 가열시키을 포함하여, 보호 이소시아네이트 경화제를 포함하는 피막의 변색을 감소시키는 방법.
  12. 제11항에 있어서, 도장조성물을 전착에 의해 적용시키는 방법.
  13. 기본 피막을 적용시키고 이어서 상부피막을 적용시킨 다음 적용된 피막을 유효온도로 경화시킴을 포함하여, 보호 이소시아네이트 경화제를 함유하는 다중 피막의 변색을 감소시키는 방법에 있어서, (i)메타 크실릴렌 디이소시아네이트 또는 그의 예비중합체와 (ii)탄소수 3 내지 5의 케톡심의 반응생성물인 보호 이소시아네이트를 포함함을 특징으로 하는 방법.
  14. 제13항에 있어서, 상부 피막이 유색 코딩이거나 투명코팅인 방법.
  15. 제14항에 있어서, 유색 코팅이 파스텔 코팅인 방법.
  16. 제13항에 있어서, 상부 피막이 래커 또는 분말 코팅인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880016452A 1987-12-11 1988-12-10 신규의 보호 이소시아네이트 및 그의 제조 및 사용방법 KR920010138B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/131,888 US4846946A (en) 1987-12-11 1987-12-11 Process for reducing attendant color shift in coatings containing blocked isocyanates
US131.888 1987-12-11
US07/131,889 US4824925A (en) 1987-12-11 1987-12-11 Novel blocked isocyanates and curable compositions containing the same

Publications (2)

Publication Number Publication Date
KR890010014A true KR890010014A (ko) 1989-08-05
KR920010138B1 KR920010138B1 (ko) 1992-11-16

Family

ID=26829891

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880016452A KR920010138B1 (ko) 1987-12-11 1988-12-10 신규의 보호 이소시아네이트 및 그의 제조 및 사용방법

Country Status (7)

Country Link
EP (1) EP0319929A3 (ko)
JP (1) JPH021721A (ko)
KR (1) KR920010138B1 (ko)
AR (1) AR245153A1 (ko)
AU (1) AU598408B2 (ko)
BR (1) BR8806503A (ko)
CA (1) CA1332488C (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100938212B1 (ko) * 2009-07-27 2010-01-22 (주)새론테크 보행로 포장재 조성물

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4891111A (en) * 1988-04-25 1990-01-02 Ppg Industries, Inc. Cationic electrocoating compositions
EP0403779B1 (en) * 1989-06-19 1995-04-05 Cytec Technology Corp. Curable powder coating compositions containing caprolactam-blocked isocyanates
NL1006369C2 (nl) * 1997-06-20 1998-12-22 Tno Toepassing van met oxime beschermde isocyanaatgroepen bij de UV-uitharding van harsen bij lage temperatuur, alsmede UV-uithardbare harsen die dergelijke oxime-beschermde isocyanaatgroepen bevatten en de toepassing hiervan in UV-uithardbare bekledingssamenstellingen.
CN112625212A (zh) * 2021-01-14 2021-04-09 甘肃银光聚银化工有限公司 一种间苯二甲基二异氰酸酯固化剂的制备方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE955994C (de) * 1955-02-08 1957-01-10 Bayer Ag Verfahren zur Herstellung von lichtechten Flaechengebilden aus unter Verwendung von Polyisocyanaten gebildeten Kunstharzen
US3846378A (en) * 1972-04-17 1974-11-05 Burlington Industries Inc Synchronous process for thermally-curable blocked polyurethanes
JPS538568B2 (ko) * 1974-09-20 1978-03-30
JPS57212250A (en) * 1981-06-24 1982-12-27 Toyobo Co Ltd Aqueous dispersion
EP0182996A1 (en) * 1984-10-26 1986-06-04 American Cyanamid Company Polyfunctional tertiary aralkyl isocyanate compounds and compositions
US4596744A (en) * 1985-01-29 1986-06-24 Inmont Corporation Oxime blocked isocyanate cross-linker for cathodic electrocoat

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100938212B1 (ko) * 2009-07-27 2010-01-22 (주)새론테크 보행로 포장재 조성물

Also Published As

Publication number Publication date
EP0319929A2 (en) 1989-06-14
KR920010138B1 (ko) 1992-11-16
EP0319929A3 (en) 1990-01-17
AR245153A1 (es) 1993-12-30
JPH021721A (ja) 1990-01-08
AU598408B2 (en) 1990-06-21
AU2668288A (en) 1989-06-15
BR8806503A (pt) 1989-08-22
CA1332488C (en) 1994-10-11

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