KR890003864A - 섬유강화 불포화 폴리에스테르 수지 조성물 - Google Patents

섬유강화 불포화 폴리에스테르 수지 조성물 Download PDF

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KR890003864A
KR890003864A KR1019880011092A KR880011092A KR890003864A KR 890003864 A KR890003864 A KR 890003864A KR 1019880011092 A KR1019880011092 A KR 1019880011092A KR 880011092 A KR880011092 A KR 880011092A KR 890003864 A KR890003864 A KR 890003864A
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South Korea
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group
acid
fiber
composition according
unsaturated polyester
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KR1019880011092A
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KR940011160B1 (ko
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다니사께 히로까
오꾸무라 히로유끼
나미까와 아끼라
이시까와 마사또
아베 토시아끼
Original Assignee
레이지 니시까와
미쯔비시 가스 캐미칼 캄파니 인코포레이티드
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Publication of KR890003864A publication Critical patent/KR890003864A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C08L75/06—Polyurethanes from polyesters

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

내용 없음

Description

섬유강화 불포화 폴리에스테르 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 주성분으로서, 불포화 폴리에스테르(A)폴리이소시아네이트 화합물(B), 중합성비닐단량체(C)및 섬유 (D)로서 구성되며, 1 (A)는 불포화 디카르본산 또는 그 산무수물 40-100mol% 를 함유한 디카르본산 또는 그 무수물과 일급 히드록실기를 갖는 다가알코올로부터 얻어지고, 히드록실 가(價)가 115-210mg KOH/g이며 산가(酸價)가 5mg KOH/g 이하의 불포화 폴리에스테르이며, 2(B)는말단기가
    이며, 25℃에서의 점도가 10-2000cps인 액상폴리이소시아네이트 화합물이며, 동시에, 하기의 조건(i)(ii)및 (iii) (i)(A)와 (C)와의 합계량에 대하여 50-70중량%의 범위, (ii) (B)의 이소시아네이트기는 (A)의 히드록실기에 대하여 0.75-1.2mol 배(倍)(iii)(D)는 (A)(B)(C)및 (D)의 합계량에 대하여 50-70중량%, 를 만족함을 특징으로 하는 성형가공성및 내충격성이 개선된 섬유강화 불포화 폴리에스테르수지 조성물.
  2. 1항에 있어서, 불포화 디카르본산 또는 그 산무수물이, 말레산, 무수말레산 및 퓨마트산으로되는 그룹에서 선택된 최소 1종의 화합물인것을 특징으로 하는 조성물.
  3. 1항에 있어서, 1급 히드록실기를 갖는 다가알코올이, 에틸렌 글리콜, 디에틸렌글리콜, 1-4-부탄디올 및 네오펜틸글리콜로 구성되는 그룹에서 선택된 최소 1종의 화합물인것을 특징으로 하는 조성물.
  4. 1항에 있어서, 폴리이소시아네이트화합물(B)가, 25℃에서의 점도 30-1500cps인것을 특징으로 하는 조성물.
  5. 1항에 있어서, 폴리이소시아네이트화합물(B)가 , 4,4'-디페닐 메탄디이소시아네이트, 카르보디이미도변성 4,4'-디페닐메탄디이소시아네이트, 4,4G-디페닐메탄디이소시아네이트의 폴리에틸계 프리폴리머, 및 4,4'-디페닐메탄디이소시아네이트의 폴리에스테르계 프리폴리머-로부터 구성되는 그룹에서 선택된 최소 1종의 화합물인 것을 특징으로 하는 조성물.
  6. 1항에 있어서, 중합체 단량체(C)가, 스틸렌, 클로르-스틸렌, 비닐톨루엔, 및(메타)아크릴산 및 그 유도체로 구성되는 그룹에서 선택된 최소 1종의 화합물인 것을 특징으로하는 조성물.
  7. 1항에 있어서, 섬유(D)는, 유리(glass)섬유, 탄소섬유, 및 아라미드(aramid)섬유로 구성되는 그룹에서 선택된 최소 1종의 섬유인것을 특징으로 하는 조성물.
  8. 주성분으로서, 불포화 폴리에스테르(A), 다가알코올(E), 폴리이소시아네이트화합물(B), 중합성비닐단량체(C)및 섬유(D)로 구성되며, ①(A)는,불포화 디카르본산 또는 그산무수물 40-100mol%를 포함한 디카르본산 또는 그 산무수물과 1급 히드록실기를 갖는 다가 알코올로부터 얻어지며, 히드록실가(價)가 115-210mg KOH/g이며 산가가 5mg KOH/g이며 산가가 5mg KOH/g이하의 불포화 폴리에스테르이며, ②(B)는 말단기가
    이며 25℃에서의 점도가 10-2000cps인 액상 폴리이소시아네이트 화합물이며, ③(E)는, 분자중에 최소 2개의 히드록실기를 갖고, 히드록실가(價)35-1100mg KOH/g의 다가 알코올이며, 동시에, 하기의 조건(i)(ii)(iii)및 (iv)(i) (E)와 (A)의 합계량은 (A)(E)및 (C)의 합계량에 해하여의 대하여 50-85중량%의 범위, (iii)(B)의 이소시아네이트기는 (A)와 (E)와의 히드록실기에 대하여 0.75-1.2mol 배(倍)(iv)(D)는 (A)(B)(C)(D)및 (E)합계량에 대하여 50-70중량%,를 만족하는 것을 특징으로 하는 성형가공성 및 내충격성이 개량된 섬유강화 불포화 폴리에스테르 수지조성물.
  9. 8항에 있어서, 다가알코올(E)는 일급히드록실기를 갖는 글리콜인것을 특징으로하는 조성물.
  10. 8항에 있어서, 다가 알코올(E), 폴리에틸렌글리콜 및 폴리 테트라 메틸렌글리콜로 구성되는 그룹에서 선택된 최소 1종의 화합물인 것을 특징으로 하는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880011092A 1987-08-31 1988-08-31 섬유강화 불포화 폴리에스테르수지 조성물 KR940011160B1 (ko)

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JP?62-215492 1987-08-31
JP21549287 1987-08-31
JP62-215492 1987-08-31

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KR890003864A true KR890003864A (ko) 1989-04-18
KR940011160B1 KR940011160B1 (ko) 1994-11-24

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US (1) US4943607A (ko)
EP (1) EP0306281B1 (ko)
KR (1) KR940011160B1 (ko)
DE (1) DE3888264T2 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100485524B1 (ko) * 2002-03-04 2005-04-29 주식회사 태성이앤씨 폐 섬유강화프라스틱의 재생방법

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3133041B2 (ja) * 1989-04-03 2001-02-05 エイ・ジイ・インタナショナル・ケミカル株式会社 繊維強化熱硬化性樹脂成形物の製造方法
US5296545A (en) * 1992-07-14 1994-03-22 Cook Composites And Polymers Surface appearance and processing characteristics for urethane-catalyzed low profile-modified polyester-polyurethane hybrid resins
US5296544A (en) * 1992-07-14 1994-03-22 Cook Composites And Polymers Polyester-polyurethane hybrid resin systems containing low levels of unsaturation having improved low profiling behavior
US5424017A (en) * 1993-04-12 1995-06-13 Hinduja; Murli L. Method for forming fiber-reinforced articles
US5643989A (en) * 1993-10-29 1997-07-01 Azdel, Inc. Fiber reinforced functionalized polyolefin composites
US5428080A (en) * 1994-03-11 1995-06-27 Plastics Manufacturing Company Heat reservoir device and method
JP3456301B2 (ja) * 1995-03-30 2003-10-14 チッソ株式会社 繊維および特定のカーボンブラックを均一に含有する繊維強化熱可塑性複合体
USRE44893E1 (en) 2004-03-26 2014-05-13 Hanwha Azdel, Inc. Fiber reinforced thermoplastic sheets with surface coverings

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA631690A (en) * 1961-11-28 Pittsburgh Plate Glass Company Coating composition containing unsaturated polyester with diisocyanate and vinyl monomer
US3824201A (en) * 1971-08-30 1974-07-16 Gen Tire & Rubber Co Maturated polyester polyurethane compositions
EP0016248B1 (en) * 1978-10-24 1984-02-15 Dainippon Ink And Chemicals, Inc. Method for producing prepreg rovings and method for producing fibre reinforced plastic articles
US4327145A (en) * 1979-10-22 1982-04-27 Dainippon Inc. & Chemicals, Inc. Process for producing sheet molding compound
WO1983000458A1 (en) * 1981-08-10 1983-02-17 Saidla, Glen, W. Molding of unsaturated polyester
US4822849A (en) * 1987-08-03 1989-04-18 Reichhold Chemicals, Inc. Low shrink hybrid resins

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100485524B1 (ko) * 2002-03-04 2005-04-29 주식회사 태성이앤씨 폐 섬유강화프라스틱의 재생방법

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Publication number Publication date
KR940011160B1 (ko) 1994-11-24
EP0306281A3 (en) 1989-12-13
US4943607A (en) 1990-07-24
EP0306281A2 (en) 1989-03-08
EP0306281B1 (en) 1994-03-09
DE3888264D1 (de) 1994-04-14
DE3888264T2 (de) 1994-06-16

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