KR890002411A - L-2-아미노-4-메틸포스피노부티르산의 효소적 제조방법 - Google Patents

L-2-아미노-4-메틸포스피노부티르산의 효소적 제조방법 Download PDF

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Publication number
KR890002411A
KR890002411A KR1019880009265A KR880009265A KR890002411A KR 890002411 A KR890002411 A KR 890002411A KR 1019880009265 A KR1019880009265 A KR 1019880009265A KR 880009265 A KR880009265 A KR 880009265A KR 890002411 A KR890002411 A KR 890002411A
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South Korea
Prior art keywords
amino
culturing
carried out
acid
aqueous
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KR1019880009265A
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English (en)
Inventor
불브란트 디이터
켈러 라인홀트
Original Assignee
하인리히 벡커,베른하르트 벡크
훽스트 아크티엔게젤샤프트
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Application filed by 하인리히 벡커,베른하르트 벡크, 훽스트 아크티엔게젤샤프트 filed Critical 하인리히 벡커,베른하르트 벡크
Publication of KR890002411A publication Critical patent/KR890002411A/ko

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    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00—Preparation of nitrogen-containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P13/00—Preparation of nitrogen-containing organic compounds
    • C12P13/04—Alpha- or beta- amino acids
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P41/00—Processes using enzymes or microorganisms to separate optical isomers from a racemic mixture
    • C12P41/006—Processes using enzymes or microorganisms to separate optical isomers from a racemic mixture by reactions involving C-N bonds, e.g. nitriles, amides, hydantoins, carbamates, lactames, transamination reactions, or keto group formation from racemic mixtures
    • C12P41/007—Processes using enzymes or microorganisms to separate optical isomers from a racemic mixture by reactions involving C-N bonds, e.g. nitriles, amides, hydantoins, carbamates, lactames, transamination reactions, or keto group formation from racemic mixtures by reactions involving acyl derivatives of racemic amines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Microbiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Analytical Chemistry (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Enzymes And Modification Thereof (AREA)

Abstract

내용 없음

Description

L-2-아미노-4-메틸포스피노부티르산의 효소적 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 수성 또는 수성-유기 매질중에서 구조식(Ⅰ)의 D,L-2-아미노-4-페닐포스피노부티르산의 N-펜아세틸 유도체를 치토산(chitosan)상에/내에 고정화된 이 콜라이(E.coli) ATCC 11105세포와 함께 배양시킴을 특징으로 하여, D,L-2-아미노-4-메틸포스피노부티르산을 효소적으로 분할하는 방법.
  2. 제1항에 있어서, 수성 매질이 부틸아세테이트, 3급-부틸메틸에테르 또는 메틸이소부틸케톤으로 포화되는 방법.
  3. 제1항 또는 2항에 있어서, 배양을 20 내지 45℃에서 수행하는 방법.
  4. 제3항에 있어서, 배양을 30 내지 40℃에서 수행하는 방법.
  5. 제1항에 내지 4항중 어느 한 항에 있어서, 배양을 pH 3 내지 9에서 수행하는 방법.
  6. 제5항에 있어서, 배양을 pH 6 내지 8.5에서 수행하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880009265A 1987-07-25 1988-07-23 L-2-아미노-4-메틸포스피노부티르산의 효소적 제조방법 KR890002411A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3724722.0 1987-07-25
DE19873724722 DE3724722A1 (de) 1987-07-25 1987-07-25 Verbessertes verfahren zur enzymatischen herstellung von l-2-amino-4-methylphosphinobuttersaeure

Publications (1)

Publication Number Publication Date
KR890002411A true KR890002411A (ko) 1989-04-10

Family

ID=6332382

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880009265A KR890002411A (ko) 1987-07-25 1988-07-23 L-2-아미노-4-메틸포스피노부티르산의 효소적 제조방법

Country Status (14)

Country Link
EP (1) EP0301391B1 (ko)
JP (1) JPS6451099A (ko)
KR (1) KR890002411A (ko)
AT (1) ATE85814T1 (ko)
AU (1) AU606185B2 (ko)
CA (1) CA1323593C (ko)
DD (1) DD272476A5 (ko)
DE (2) DE3724722A1 (ko)
DK (1) DK412088A (ko)
ES (1) ES2039515T3 (ko)
GR (1) GR3007701T3 (ko)
HU (1) HU202589B (ko)
IL (1) IL87218A (ko)
ZA (1) ZA885295B (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3903446A1 (de) * 1989-02-06 1990-10-18 Hoechst Ag Verfahren zur enzymatischen trennung von 2-amino-4-methylphosphinobuttersaeurederivaten
US5051525A (en) * 1989-02-06 1991-09-24 Hoechst Aktiengesellschaft N-acyl-2-amino acid amides containing phosphinic esters, process for their preparation, and N-acyl-2-amino acids nitriles as precursors
IL101539A (en) 1991-04-16 1998-09-24 Monsanto Europe Sa Mono-ammonium salts of the history of N phosphonomethyl glycyl which are not hygroscopes, their preparations and pesticides containing
AU2001294365A1 (en) * 2000-08-28 2002-03-13 Dsm N.V. Process for the preparation of a beta-lactam nucleus and the application thereof
EP2278017B1 (en) * 2002-02-26 2015-03-25 Syngenta Limited A method of selectively producing male or female sterile plants
CN112940031B (zh) * 2021-02-01 2022-08-02 河北威远生物化工有限公司 一种n-萘乙酰草铵膦及其合成方法及以其合成l-草铵膦的合成方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1369462A (en) * 1971-11-23 1974-10-09 Beecham Group Ltd Enzymic resolution of racemic n-acyl-dl-amino acids
JPS5547630A (en) * 1978-10-02 1980-04-04 Meiji Seika Kaisha Ltd Optical resolution of phosphorus-containing amino acid
DE3005632C2 (de) * 1980-02-15 1985-06-05 Joachim Prof. Dr. Klein Verfahren zur Herstellung von Biokatalysatoren mit hoher mechanischer Festigkeit und hoher Beladung an enzymatisch aktiver Substanz
DE3048612C2 (de) * 1980-12-23 1982-12-02 Hoechst Ag, 6000 Frankfurt "Verfahren zur enzymatischen Trennung von L-2-Ami no-4-methylphosphinobuttersäure"
DE3903446A1 (de) * 1989-02-06 1990-10-18 Hoechst Ag Verfahren zur enzymatischen trennung von 2-amino-4-methylphosphinobuttersaeurederivaten

Also Published As

Publication number Publication date
EP0301391A1 (de) 1989-02-01
DD272476A5 (de) 1989-10-11
ATE85814T1 (de) 1993-03-15
IL87218A (en) 1992-01-15
ZA885295B (en) 1989-03-29
DE3724722A1 (de) 1989-02-16
DK412088D0 (da) 1988-07-22
JPS6451099A (en) 1989-02-27
GR3007701T3 (ko) 1993-08-31
DE3878499D1 (de) 1993-03-25
ES2039515T3 (es) 1993-10-01
HUT50214A (en) 1989-12-28
AU606185B2 (en) 1991-01-31
HU202589B (en) 1991-03-28
IL87218A0 (en) 1988-12-30
DK412088A (da) 1989-01-26
EP0301391B1 (de) 1993-02-17
AU1973388A (en) 1989-04-20
CA1323593C (en) 1993-10-26

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