KR890002252A - 공액 디엔 중합체의 제조 방법 - Google Patents
공액 디엔 중합체의 제조 방법 Download PDFInfo
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- KR890002252A KR890002252A KR1019880008999A KR880008999A KR890002252A KR 890002252 A KR890002252 A KR 890002252A KR 1019880008999 A KR1019880008999 A KR 1019880008999A KR 880008999 A KR880008999 A KR 880008999A KR 890002252 A KR890002252 A KR 890002252A
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- compound
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- cobalt
- mol
- conjugated diene
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- 150000001993 dienes Chemical class 0.000 title claims 8
- 229920000642 polymer Polymers 0.000 title claims 5
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 150000001869 cobalt compounds Chemical class 0.000 claims 16
- 238000000034 method Methods 0.000 claims 16
- -1 aluminum compound Chemical class 0.000 claims 14
- 150000001875 compounds Chemical class 0.000 claims 13
- 125000000217 alkyl group Chemical group 0.000 claims 12
- 150000002903 organophosphorus compounds Chemical class 0.000 claims 10
- 229910052782 aluminium Inorganic materials 0.000 claims 7
- 239000003054 catalyst Substances 0.000 claims 7
- 229910052739 hydrogen Inorganic materials 0.000 claims 7
- 239000001257 hydrogen Substances 0.000 claims 7
- 125000004432 carbon atom Chemical group C* 0.000 claims 6
- 150000002431 hydrogen Chemical class 0.000 claims 5
- 239000004215 Carbon black (E152) Substances 0.000 claims 4
- 229930195733 hydrocarbon Natural products 0.000 claims 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 229910017052 cobalt Inorganic materials 0.000 claims 3
- 239000010941 cobalt Substances 0.000 claims 3
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 3
- 150000008282 halocarbons Chemical class 0.000 claims 3
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 238000006116 polymerization reaction Methods 0.000 claims 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 claims 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 claims 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims 2
- 125000004915 dibutylamino group Chemical group C(CCC)N(CCCC)* 0.000 claims 2
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 claims 2
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 claims 2
- 125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 2
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims 1
- 239000007818 Grignard reagent Substances 0.000 claims 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- NBICYCZLCAMSBG-UHFFFAOYSA-L [Co+2].CCCCCC=CC([O-])=O.CCCCCC=CC([O-])=O Chemical compound [Co+2].CCCCCC=CC([O-])=O.CCCCCC=CC([O-])=O NBICYCZLCAMSBG-UHFFFAOYSA-L 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 230000029936 alkylation Effects 0.000 claims 1
- 238000005804 alkylation reaction Methods 0.000 claims 1
- 150000001412 amines Chemical group 0.000 claims 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 claims 1
- 210000004556 brain Anatomy 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims 1
- AVWLPUQJODERGA-UHFFFAOYSA-L cobalt(2+);diiodide Chemical compound [Co+2].[I-].[I-] AVWLPUQJODERGA-UHFFFAOYSA-L 0.000 claims 1
- BZRRQSJJPUGBAA-UHFFFAOYSA-L cobalt(ii) bromide Chemical compound Br[Co]Br BZRRQSJJPUGBAA-UHFFFAOYSA-L 0.000 claims 1
- BZPRATGFHKWAKR-UHFFFAOYSA-N cobalt;pentane-2,4-dione Chemical compound [Co].CC(=O)CC(C)=O.CC(=O)CC(C)=O BZPRATGFHKWAKR-UHFFFAOYSA-N 0.000 claims 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 claims 1
- MXRAALVNBULTLB-UHFFFAOYSA-N dipropylaluminum Chemical compound CCC[Al]CCC MXRAALVNBULTLB-UHFFFAOYSA-N 0.000 claims 1
- 125000004914 dipropylamino group Chemical group C(CC)N(CCC)* 0.000 claims 1
- 150000004795 grignard reagents Chemical class 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 125000001841 imino group Chemical group [H]N=* 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- 239000003446 ligand Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 claims 1
- 125000005609 naphthenate group Chemical group 0.000 claims 1
- 150000002823 nitrates Chemical class 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 150000002894 organic compounds Chemical group 0.000 claims 1
- 235000021317 phosphate Nutrition 0.000 claims 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims 1
- 150000003222 pyridines Chemical class 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 claims 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 claims 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims 1
- JQPMDTQDAXRDGS-UHFFFAOYSA-N triphenylalumane Chemical compound C1=CC=CC=C1[Al](C=1C=CC=CC=1)C1=CC=CC=C1 JQPMDTQDAXRDGS-UHFFFAOYSA-N 0.000 claims 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 150000003003 phosphines Chemical class 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5022—Aromatic phosphines (P-C aromatic linkage)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도 및 제2도는 실시예 1 및 2에서 얻어진 포스핀 호합물의 적외선 흡수 스팩트럼을 나타낸 것임.
제3도 및 제4도는 실시예 1 및 2에서 얻어진 포스핀 화합물의 NMR 스팩트럼을 나타낸 것임.
Claims (35)
- 탄화수소 또는 할로겐화 탄소수소 용매 중에서, (A)코발트 화합물, (B)유기 알루미늄 화합물, (C) 유기알미늄 화합물 1몰 당 0.25-1.5몰의 몰 및 (D)일반식(식중, R1및 R2는 수소, 알킬기 또는 알릴기이고, X는 전자공여성 기임)으로 표시되는 유기 인화합물로 되는 촉매에 공액 디엔을 접촉시키는 것을 특징으로 하는 공액 디엔 중합체의 제조방법.
- 제1항에 있어서, (D)의 유기 인화합물의 전자공여성기가 메톡시기(-OCH3)또는 에톡시기(-OC2H5)인 방법.
- 제1항에 있어서, (A)코발트 화합물이 1-3가의 코발트 화합물인 방법.
- 제1항에 있어서, (A)코발트 화합물이 코발트의 할로겐화물이나 또는 황산염, 질산염, 탄산염, 인산염, 수산화물, 시안화물, 티오시안화물, 나프텐산염, 옥텐산염 및 이들의 착체에서 선택된 적어도 1종인 방법.
- 제1항에 있어서, 코발트 화합물이 브롬화 코발트(Ⅱ)트리페닐포스핀 착체, 아세틸아세톤 코발트(Ⅱ), 오텐산 코발트, 나프텐산 코발트, 염화코발트(Ⅱ), 브롬화 코발트(Ⅱ) 요오드화 코발트(Ⅱ), 및 이들 할로겐화 코발트의 피리딘 착체, 에틸키산토겐산 코발트에서 선택된 적어도 1종인 방법.
- 제1항에 있어서, (B)성분의 유기 알루미늄 화합물이 일반식 AIR3(여기서, R는 탄소수 1-6의 알킬기임) 또는 AIR2Y(여기서, R는 탄소수 1-6의 알킬기를, Y는 염소, 브롬 또는 요오드 등의 할로겐을 나타냄)으로 표시되는 것인 방법.
- 제1항에 있어서, 알루미늄 화합물이 트리에틸 알루미늄, 트리플로필알루미늄, 트리아소프로필알루미늄, 트리부틸알루미늄, 트리이소부틸알루미늄, 트리헥실 알루미늄, 트리페닐알루미늄, 디에틸알루미늄모노클로라이드, 디프로필알루미늄모노클로라이드, 이소부틸 알루미늄모노 클로라이드에서 선택된 적어도 1종인 방법.
- 제1항에 있어서, (D)유기 인화합물의 R1및 R2가 탄소수 1-4의 알킬기인 방법.
- 제1항에 있어서, (D)유기 인화합물의 R1및 R2가 메틸기인 방법.
- 제1항에 있어서, (D)유기 인화합물의 X가 일반식 -O-R6또는(여기서, R6는 수소 또는 탄소수 1-6알킬기이고, 또 R7및 R8은 수소, 알킬기 및 페닐기에서 선택됨)으로 표시된느 것인 방법.
- 제1항에 있어서, (D)유기 인화합물의 X가 메톡시기, 에톡시기, 프로폭시기, 부톡시기, 페톡시기, 히드록시기, 디메틸아미노기, 디에틸아미노기, 디프로필아미노기, 디부틸아미노기, 메틸아미노기, 에틸아미노기, 아미뇌에서 선택된 것인 방법.
- 제1항에 있어서, 공액 디엔이 부타디엔, 이소푸렌, 피페릴렌인 방법.
- 제1항에 있어서, (A)코발트 화합물과 (B)유기 알루미늄 화합물의 사용비율이 코발트 화합물 1몰당 유기 알루미늄 화합물 1-1000몰인 방법.
- 제1항에 있어서, (A)코발트 화합물과 (B)유기 알루미늄 화합물의 사용 비율이 코발트 화합물 1몰당 유기 알루미늄 화합물 5-100몰인 방법.
- 제1항에 있어서, 촉매의 (C)성분의 물의 사용량이 (B)유기 알루미늄 화합물 1몰 당 0.25-1.5몰인 방법.
- 제1항에 있어서, 촉매의 (C)성분인 물의 사용량이 (B)유기 알루미늄 호합물 1몰당 0.5-1몰인 방법.
- 제1항에 있어서, (D)유기 인화합물의 사용량이 (A)코발트 화합물 1몰당 0.5몰 이상, 통상 0.5-10몰인 방법.
- 제1항에 있어서, (D)유기 인화합물의 사용량이 (A)코발트 화합물 1몰 당 1-5몰인 방법.
- 제1항에 있어서, 촉매 사용량이 공액 디엔 1몰 당 코발트 화합물을 기준으로 하여 0.001-밀리몰인 방법.
- 제1항에 있어서, 촉매 사용량이 공액 디엔 1몰 당 코발트 화합물을 기준으로 하여 0.01-0.5밀리몰인 방법.
- 제1항에 있어서 탄화수소 또는 할로겐화 탄화수소 용매가 n-펜탄, n-헥산, n-헵탄, 이소옥탄 중에서 선택된 지방족 탄화수소, 시클로헥산, 데칼린, 테트랄린 중에서 선택된 지환식 탄화수소, 벤젠, 톨루엔, 키실렌, 큐멘중에서 선택된 방향족 탄화수소, 염화메틸렌, 클로로포름, 사염화탄소, 트리클로로에틸렌, 퍼클로로에틸렌, 클로로벤젠, 브로모벤젠, 클로로톨루엔 중에서 선택된 할로겐화 탄화수소 중 적어도 1종인 방법.
- 제1항에 있어서, 중합해서 얻어지는 중합체의 결정화도가 10-50%인 방법.
- 제1항에 있어서, 중합해서 얻어지는 공액 디엔 중합체의 비닐결합 함량이 90%이상이 방법.
- 제1항에 있어서, 중합해서 얻어지는 공액 디엔 중합체의 비닐결합 함령이 93%이상인 방법.
- 하기 일반식(식중, R1및 R2는 수소, 알킬기 또는 아릴기를 나타내고, X는 전자공여성 기를 나타냄)으로 표시되는 유기 인화합물.
- 제25항에 있어서, R1및 R2가 탄소수 1-6의 알킬기인 화합물.
- 제25항에 있어서, R1및 R2가 탄소수 1-3의 알킬기인 화합물.
- 제25항에 있어서, R1및 R2가 CH2인 화합물.
- 제25항에 있어서, X가 -O-R6또는(식중, R6는 수소 또는 탄소수 1-6의 알킬기이고, 또 R7및 R8은 수소, 알킬기 및 페닐기에서 선택된 것임)으로 표시되는 것인 화합물.
- 제25항에 있어서, X가 -O-R6인 화합물.
- 제25항에 있어서, X가 메톡시기, 에톡시기, 프로폭시기, 부톡시기, 페녹시기, 히드록시기, 디메틸 아미노기, 디에틸아미노기, 이프로필아미노기, 디부틸아미노기, 메틸아미노기, 에틸아미노기, 이미노기 중에서 선택된 것인 화합물.
- 제25항에 있어서, X가 메톡시기인 화합물.
- 2.6-디알킬페놀을 할로겐화시킨 후, 알킬화시키고, Mg로 그리니아르 시약으로 하고, 삼할로겐화인, 아인산트리알킬 및 아인산트리아릴에서 선택된 적어도 1종과 반응 시킴을 특징으로 하는 하기 일반식(식중, R1및 R2는 수소, 알킬기 또는 아릴기를 나타내고, X는 전자공여성 기를 나타냄)으로 표시되는 유기 인화합물의 제조방법.
- 제25항의 유기 인화합물을 배위자로하는 금속 촉매 조성물.
- 제25항의 유기 인화합물과 코발트 화합물과의 혼합물 또는 착제로 되는 촉매 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62180605A JP2508110B2 (ja) | 1987-07-20 | 1987-07-20 | 共役ジエン重合体の製造方法 |
| JP62-180605 | 1987-07-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR890002252A true KR890002252A (ko) | 1989-04-10 |
| KR960004476B1 KR960004476B1 (ko) | 1996-04-06 |
Family
ID=16086172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880008999A KR960004476B1 (ko) | 1987-07-20 | 1988-07-19 | 공액 디엔 중합체의 제조방법 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4954125A (ko) |
| EP (1) | EP0300772B1 (ko) |
| JP (1) | JP2508110B2 (ko) |
| KR (1) | KR960004476B1 (ko) |
| DE (1) | DE3887221T2 (ko) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3463811B2 (ja) * | 1991-04-24 | 2003-11-05 | Ｊｓｒ株式会社 | ブタジエン系重合体の製造方法 |
| DE4119332A1 (de) * | 1991-06-12 | 1992-12-17 | Huels Chemische Werke Ag | Verfahren zur herstellung von methylidengruppen enthaltenden (alpha), (omega) -ungesaettigten oligomeren aus (alpha), (omega) -diolefinen in gegenwart von aluminiumorganischen verbindungen als katalysator |
| DE19508088A1 (de) * | 1995-03-08 | 1996-09-12 | Huels Chemische Werke Ag | Verfahren zur Herstellung eines Oligomer-Gemisches aus alpha,omega-Diolefinen |
| US5557023A (en) * | 1995-05-23 | 1996-09-17 | The Governors Of The University Of Alberta | Olefin oligomerization in the presence of novel complexes |
| US6576725B1 (en) * | 2002-01-18 | 2003-06-10 | Bridgestone Corporation | Iron-based catalyst for producing high-vinyl polybutadiene |
| AU2003281627A1 (en) * | 2002-07-22 | 2004-02-09 | Jsr Corporation | Process for producing crystalline 1,2-polybutadiene |
| ZA200711159B (en) | 2006-12-28 | 2009-03-25 | Bridgestone Corp | Amine-containing alkoxysilyl-functionalized polymers |
| US8324329B2 (en) * | 2007-08-07 | 2012-12-04 | Bridgestone Corporation | Process for producing functionalized polymers |
| US7879958B2 (en) | 2007-08-07 | 2011-02-01 | Bridgestone Corporation | Polyhydroxy compounds as polymerization quenching agents |
| EP3328919B1 (en) | 2015-07-29 | 2021-03-10 | Bridgestone Corporation | Processes for preparing functionalized polymers, related functionalizing compound and preparation thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3498963A (en) * | 1966-09-26 | 1970-03-03 | Japan Synthetic Rubber Co Ltd | Process for the catalytic preparation of 1,2-polybutadiene having a high percentage of vinyl configuration |
| US3522332A (en) * | 1967-06-02 | 1970-07-28 | Japan Synthetic Rubber Co Ltd | Process for the preparation of 1,2-polybutadiene |
| JPS53143685A (en) * | 1977-05-23 | 1978-12-14 | Japan Synthetic Rubber Co Ltd | Preparation of 1,2-polybutadiene |
| US4306085A (en) * | 1979-07-05 | 1981-12-15 | Shell Oil Company | Hydroformylation process using resin-ligand-metal catalyst |
| DE3563611D1 (en) * | 1984-03-06 | 1988-08-11 | Mitsubishi Chem Ind | Method for the partial hydrogenation of conjugated dienes |
-
1987
- 1987-07-20 JP JP62180605A patent/JP2508110B2/ja not_active Expired - Lifetime
-
1988
- 1988-06-20 US US07/208,664 patent/US4954125A/en not_active Expired - Lifetime
- 1988-07-19 KR KR1019880008999A patent/KR960004476B1/ko not_active IP Right Cessation
- 1988-07-20 DE DE3887221T patent/DE3887221T2/de not_active Expired - Lifetime
- 1988-07-20 EP EP88306676A patent/EP0300772B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0300772A1 (en) | 1989-01-25 |
| EP0300772B1 (en) | 1994-01-19 |
| DE3887221T2 (de) | 1994-05-19 |
| KR960004476B1 (ko) | 1996-04-06 |
| DE3887221D1 (de) | 1994-03-03 |
| JPS6424810A (en) | 1989-01-26 |
| JP2508110B2 (ja) | 1996-06-19 |
| US4954125A (en) | 1990-09-04 |
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