KR890000535A - N-(폴리옥시알킬)-n- (알킬)아민으로부터 제조된 탄성체(5) - Google Patents

N-(폴리옥시알킬)-n- (알킬)아민으로부터 제조된 탄성체(5) Download PDF

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KR890000535A
KR890000535A KR1019880007881A KR880007881A KR890000535A KR 890000535 A KR890000535 A KR 890000535A KR 1019880007881 A KR1019880007881 A KR 1019880007881A KR 880007881 A KR880007881 A KR 880007881A KR 890000535 A KR890000535 A KR 890000535A
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마이클 저킨 리차드
바크스비 니글
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티모티 엔.비숍
유니온 카바이드 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3228—Polyamines acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00—Compositions for reaction injection moulding processes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyethers (AREA)

Abstract

내용 없음

Description

N-(플리옥시알킬)-N-(알킬)아민으로부터 제조된 탄성체(5)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (26)

  1. 하기 일반식의 N-(폴리옥시알킬)-N-(알킬)아민을 연쇄 연장제의 존재하에서 이소시아네이트와 반응시킴을 특징으로하여, 탄성체를 제조하는 방법.
    R[H](hz)[(P)p(S)s(T)t]z-(hz)
    상기식에서, R은 쩨레비티노프(Zerewitinoff)활성 수소원자를 함유하는 화합물을 기본으로 하는 개시제 라디칼이고, H는 일반식
    의 그룹이며, P는 일반식
    의 그룹이고, S는 일반식
    의 그룹이며, T는 일반식
    의 그룹이고, a는 0 내지 175이며, b는 0 내지 175이고, c는 0 내지 30이며, n은 1 내지 3이고, 단 n이 1인 경우 a+b+c는 반드시 2 이상이어야 하고, R'는 탄소수 2 내지 18의 알킬그룹이며, R"는 수소 또는 탄소수 18이하의 알킬그룹이고, R"' 및 R""는 각각 독립적으로 탄소수 2 내지 12의 알킬그룹이며, h는 0 내지 0.7이고, P는 0 내지 0.5이며, S는 0.5 내지 1이고, t는 0 내지 0.15이며,Z는 2 내지 6이며, 단 Z가 2이고 a가 0인 경우에 b는 반드시 22보다 커야 한다.
  2. 제 1 항에 있어서, R이 탄소원자 2 내지 6개를 함유하며, a는 0 내지 150이며, b는 20 내지 115이고, c가 0 내지 15이며, R'가 탄소수 2의 알킬그룹이며, Rc'가 탄소수 2 내지 6의 알킬그룹인 방법.
  3. 제 2 항에 있어서, R이 탄소원자 3 내지 6개를 함유하며, a가 0 내지 90이고, b가 25 내지 98이고, c가 0 내지 2이고, R"'가 이소프로필그룹이며, Z가 3 내지 6인 방법.
  4. 제 1 항에 있어서, R이 18 내지 400의 분자량을 갖는 방법.
  5. 제 1 항에 있어서, R이 탄소원자 3 내지 6개를 함유하는 방법.
  6. 제 5 항에 있어서, R이인 방법.
  7. 제 1 항에 있어서, N-(폴리옥시알킬)-N-(알킬)아민이 1,000 내지 10,000의 당량을 갖는 방법.
  8. 제 1 항의 방법에 따라 제조된 탄성체.
  9. 제 2 항의 방법에 따라 제조된 탄성체.
  10. 제 3 항의 방법에 따라 제조된 탄성체.
  11. 제 4 항의 방법에 따라 제조된 탄성체.
  12. 제 5 항의 방법에 따라 제조된 탄성체.
  13. 제 6 항의 방법에 따라 제조된 탄성체.
  14. 제 7 항의 방법에 따라 제조된 탄성체.
  15. 당량이 약 1,000 내지 10,000인 하기 일반식의 N-(폴리옥시알킬)-N-(알킬)아민을 연쇄 연장제의 존재하에서 이소시아네이트 반응시킴을 특징으로하여, 폴리우레아 및/또는 폴리우레탄-우레아 탄성체를 제조하는 방법.
    R[H](hz)[(P)p(S)s(T)t]z-(hz)
    상기식에서, R은 쩨레비티노프(Zerewitinoff) 활성 수소원자를 함유하는 화합물을 기본으로 하는 개시제 라디칼이며, H는 일반식
    의 그룹이고, P는 일반식
    의 그룹이며, S는 일반식
    의 그룹이며, T는 일반식
    의 그룹이며, a는 0 내지 175이며, b는 0 내지 175이고, c는 0 내지 30이며, n은 1 내지 3이고, 단 n은 1인 경우 a+b+c는 반드시 2 이상이어야 하고, R'는 탄소수 2 내지 18의 알킬그룹이며, R"는 수소 또는 탄소수 18이하의 알킬그룹이고, R"' 및 R""는 각각 독립적으로 탄소수 2 내지 12의 알킬 또는 아릴그룹이며, h는 0 내지 0.3이고, P는 0 내지 0.4이며, S는 0.7 내지 1이고, t는 0 내지 0.05이며,Z는 3 내지 6이다.
  16. 제 5 항에 있어서, a는 0 내지 150이고, b는 20 내지 115이고, c가 0 내지 15이고, R'가 탄소수 2의 알킬그룹이며, R"'가 탄소수 원자 2 내지 6를 함유하는 방법.
  17. 제15항에 있어서, R이 탄소원자 3 내지 6개를 함유하고, a가 0 내지 90이고, b가 25 내지 98이고, c가 0 내지 2이며, R"'가 이소프로필그룹인 방법.
  18. 제16항에 있어서, R이 18 내지 400의 분자량을 갖는 방법.
  19. 제18항에 있어서, R이인 방법.
  20. 제15항의 방법에 따라 제조된 탄성체.
  21. 제16항의 방법에 따라 제조된 탄성체.
  22. 제17항의 방법에 따라 제조된 탄성체.
  23. 제18항의 방법에 따라 제조된 탄성체.
  24. 제19항의 방법에 따라 제조된 탄성체.
  25. 제 1 항의 방법에 따라 제조된 주조(cast) 탄성체.
  26. 제 1 항의 방법에 따라 제조된 반응사출성형 탄성체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880007881A 1987-06-30 1988-06-29 N-(폴리옥시알킬)-n-(알킬)아민으로부터 제조된 탄성체 KR930007874B1 (ko)

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US6781987A 1987-06-30 1987-06-30
US067,819 1987-06-30
US067819 1987-06-30
US07/176,221 US4902768A (en) 1987-06-30 1988-03-31 Elastomers prepared from N-(polyoxyalkyl)-N-(alkyl)amines
US176221 1988-03-31
US176,221 1988-05-31

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KR930007874B1 KR930007874B1 (ko) 1993-08-21

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US (1) US4902768A (ko)
EP (1) EP0298359B1 (ko)
JP (1) JP2612746B2 (ko)
KR (1) KR930007874B1 (ko)
AT (1) ATE156845T1 (ko)
AU (1) AU609833B2 (ko)
BR (1) BR8803203A (ko)
CA (1) CA1337135C (ko)
DE (1) DE3855995T2 (ko)

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AU1854488A (en) 1989-01-05
EP0298359B1 (en) 1997-08-13
EP0298359A2 (en) 1989-01-11
ATE156845T1 (de) 1997-08-15
JPS6481816A (en) 1989-03-28
AU609833B2 (en) 1991-05-09
KR930007874B1 (ko) 1993-08-21
CA1337135C (en) 1995-09-26
JP2612746B2 (ja) 1997-05-21
DE3855995T2 (de) 1997-12-18
US4902768A (en) 1990-02-20
EP0298359A3 (en) 1989-01-25
DE3855995D1 (de) 1997-09-18
BR8803203A (pt) 1989-01-31

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