KR890000431A - 치환된 3-(4-니트로페녹시)피라졸과 제초제로서의 이들의 용도 - Google Patents
치환된 3-(4-니트로페녹시)피라졸과 제초제로서의 이들의 용도 Download PDFInfo
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- KR890000431A KR890000431A KR1019880006799A KR880006799A KR890000431A KR 890000431 A KR890000431 A KR 890000431A KR 1019880006799 A KR1019880006799 A KR 1019880006799A KR 880006799 A KR880006799 A KR 880006799A KR 890000431 A KR890000431 A KR 890000431A
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- Prior art keywords
- substituent
- pyrazole ring
- alkoxy
- methyl
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- 239000004009 herbicide Substances 0.000 title claims 2
- USWPAGYVGGDPBF-UHFFFAOYSA-N 5-(4-nitrophenoxy)-1h-pyrazole Chemical class C1=CC([N+](=O)[O-])=CC=C1OC1=NNC=C1 USWPAGYVGGDPBF-UHFFFAOYSA-N 0.000 title 1
- 125000003226 pyrazolyl group Chemical group 0.000 claims 19
- -1 methylthio, ethylthio, methylsulfinyl Chemical group 0.000 claims 12
- 125000005843 halogen group Chemical group 0.000 claims 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 10
- 150000003839 salts Chemical class 0.000 claims 10
- KMZIZRHLLMNWNT-UHFFFAOYSA-N 5-phenoxy-1h-pyrazole Chemical compound C=1C=CC=CC=1OC=1C=CNN=1 KMZIZRHLLMNWNT-UHFFFAOYSA-N 0.000 claims 9
- 125000003545 alkoxy group Chemical group 0.000 claims 9
- 125000001145 hydrido group Chemical group *[H] 0.000 claims 9
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 claims 8
- 238000000034 method Methods 0.000 claims 8
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 8
- 125000003282 alkyl amino group Chemical group 0.000 claims 6
- 125000001309 chloro group Chemical group Cl* 0.000 claims 6
- 125000004970 halomethyl group Chemical group 0.000 claims 6
- 125000001424 substituent group Chemical group 0.000 claims 6
- 125000001246 bromo group Chemical group Br* 0.000 claims 5
- 125000000033 alkoxyamino group Chemical group 0.000 claims 4
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 4
- 125000004093 cyano group Chemical group *C#N 0.000 claims 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 4
- 125000004969 haloethyl group Chemical group 0.000 claims 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 4
- 125000005085 alkoxycarbonylalkoxy group Chemical group 0.000 claims 3
- 125000004414 alkyl thio group Chemical group 0.000 claims 3
- 125000005121 aminocarbonylalkoxy group Chemical group 0.000 claims 3
- 125000004438 haloalkoxy group Chemical group 0.000 claims 3
- 125000005191 hydroxyalkylamino group Chemical group 0.000 claims 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- 125000006125 ethylsulfonyl group Chemical group 0.000 claims 2
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 claims 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 claims 2
- 239000012434 nucleophilic reagent Substances 0.000 claims 2
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 claims 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims 1
- 125000000278 alkyl amino alkyl group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000005276 alkyl hydrazino group Chemical group 0.000 claims 1
- 125000006350 alkyl thio alkyl group Chemical group 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- 238000009313 farming Methods 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 230000002363 herbicidal effect Effects 0.000 claims 1
- 150000002429 hydrazines Chemical class 0.000 claims 1
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 125000006216 methylsulfinyl group Chemical group [H]C([H])([H])S(*)=O 0.000 claims 1
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 150000005324 oxide salts Chemical class 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 150000003335 secondary amines Chemical class 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
- 150000007944 thiolates Chemical class 0.000 claims 1
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- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
- C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
- C07D231/20—One oxygen atom attached in position 3 or 5
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
- C07D231/20—One oxygen atom attached in position 3 or 5
- C07D231/22—One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
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- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/28—Two oxygen or sulfur atoms
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- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
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- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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Abstract
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Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (29)
- 페닐환은 파라니트로치환체를 갖고, 피라졸환의 1위치에는 메틸, 에틸, 할로메틸 혹은 할로에틸 치환체를 갖고, 4위치에는 하이드리도, 할로 혹은 니트로 치환체를 가지며, 5위치에는 클로로, 시아노, 할로메닐, 할로에틸, 메틸티오, 에틸티오, 메틸설피닐, 에틸설피닐, 에틸설포닐 혹은 메톡시메틸 치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 농경에 사용할 수 있는 그의 염.
- 제1항에 있어서, 피라졸환의 1위치는 메틸 치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 그의 염.
- 제2항에 있어서, 피라졸환의 4위치는 할로치환체를 갖는 것을 특징으로 하는 3-페놀시피라졸 및 그의 염.
- 제3항에 있어서, 피라졸환의 4위치는 클로로 혹은 브로모치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 그의 염.
- 제4항에 있어서, 피라졸환의 5위치는 트리플루오로메틸, 디플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 그의 염.
- 제1항에 있어서, 페닐환은 약 300 이하의 분자량을 갖고 알콕시, 할로알콕시, 디(알콕시), 알콕시카르보닐, 알콕시카르보닐 알콕시, 아미노카르보닐알콕시, 알킬설포닐 아미노카르보닐알콕시, 알킬아미노, 하이드록시알킬아미노, 알콕시아미노, 알콕시킬아미노, 하이드록시카르보닐알킬아미노와 알콕시-카르보닐 알킬옥시이미노로부터 선택된 메타 치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 그의 염.
- 제6항에 있어서, 피라졸환의 4위치는 클로로나브로모 치환체를 갖는 것을 특징으로 하는 3-페녹시 피라졸 및 그의 염.
- 제7항에 있어서, 피라졸환의 5위치는 디플루오로메틸, 트리플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 그의 염.
- 페닐환은 파라니트로 치환체를 갖고, 피라졸환의 1위치에는 메틸, 에틸, 할로메틸 혹은 할로에틸 치환체를 갖고, 4위치에는 하이드리도, 할로 혹은 니트로치환체를 가지며, 5위치에는 클로로, 시아노, 할로메틸, 할로에밀, 메틸티오, 에틸티오, 메틸설피닐, 에틸설피닐, 에틸설포닐 혹은 메톡시에틸 치환체를 갖는 3-페녹시피라졸 및 농경에 사용할 수 있는 그의 염을 효과적인 양 포함함을 특징으로 하는 제초제 조성물.
- 제9항에 있어서, 피라졸환의 1위치는 메틸 치환체를 갖는 것을 특징으로 하는 조성물.
- 제10항에 있어서, 피라졸환의 4위치는 클로로 혹은 브로모 치환체를 갖는 것을 특징으로 하는 조성물.
- 제11항에 있어서, 피라졸환의 5위치는 트리플루오로메틸, 디플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 조성물.
- 제9항에 있어서, 페닐환은 약 300이하의 분자량을 갖고 알콕시, 할로알콕시, 디(알콕시), 알콕시카르보닐, 알콕시카르보닐알콕시, 아미노카르보닐알콕시, 알킬설포닐아미노카르보닐알콕시, 알킬아미노, 하이드록시알킬아미노, 알콕시아미노, 알콕시알킬아미노, 하이드록시카르보닐알킬아미노와 알콕시카르보닐알킬옥시이미노로부터 선택된 메타 치환체를 갖는 것을 특징으로 하는 조성물.
- 제13항에 있어서, 피라졸환의 4위치는 클로로나 브로모 치환체를 갖는 것을 특징으로 하는 조성물.
- 제13항에 있어서, 피라졸환의 5위치는 디플루오로메틸, 트리플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 조성물.
- 페닐환은 파라니트로치환체를 갖고, 피라졸환의 1위치에는 메틸, 에틸, 할로메틸 혹은 할로에틸 치환체를 갖고, 위치에는 하이드리도, 할로 혹은 니트로 치환체를 가지며, 5위치에는 클로, 시아노, 할로메틸, 할로에틸, 메틸티오, 에틸티오, 메틸설피닐, 에틸설피닐, 메틸설포닐, 혹은 메톡시 메틸 치환체를 갖는 유효량의 3-페녹시피라졸 및 농경에 사용할 수 있는 그의 염을 식물에 사용함을 특징으로 하는 원하지 않는 식물의 성장을 제어하는 방법.
- 제16항에 있어서, 피라졸환의 1위치는 메틸치환체를 갖는 것을 특징으로 하는 방법.
- 제17항에 있어서, 피라졸환의 4위치는 클로로 혹은 브로모 치환체를 갖는 것을 특징으로 하는 방법.
- 제18항에 있어서, 피라졸환의 5위치는 트리플루오로메틸, 디플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 방법.
- 제16항에 있어서, 페닐환은 약 300이하의 분자량을 갖고 알콕시, 할로알콕시, 디(알콕시), 알콕시카르보닐, 알콕시카르보닐알콕시, 아미노카르보닐알콕시, 알킬설포닐아미노카르보닐알콕시, 알킬아미노, 하이드록시알킬아미노, 알콕시아미노, 알콕시알킬아미노, 하이드록시카르보닐알킬아미노와 알콕시-카르보닐알킬옥시이미노로부터 선택된 메타 치환체를 갖는 것을 특징으로 하는 방법.
- 제20항에 있어서, 피라졸환의 4위치는 클로나 브로모 치환체를 갖는 것을 특징으로 하는 방법.
- 제21항에 있어서, 피라졸환의 5위치는 디플루오로메틸, 트리플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 방법.
- 다음 구조식으로 표현되는 화합물.여기서, R1은 메틸이나 에틸이고, R2는 할로메틸, 할로에틸, 메틸설피닐, 에틸설피닐 혹은 메톡시 메틸이며, R3은 하이드리도 혹은 할로이다.
- 제23항에 있어서, R1은 메틸, R2는 트리플루오로메틸이나 디플루오로메틸이며 R3는 하이드리도임을 특징으로 하는 화합물.
- 제23항에 있어서, R1은 메틸, R2는 트리플루오로메틸이나 디플루오로메틸이며 R3는 할로임을 특징으로 하는 화합물.
- 2,4-(피라졸일옥시)를 하이드록사이드, 유기산화물염, 엔올레이트, 티올레이트, 암모니아 1급아민, 2급아민, 하이드라진과 시아니드로부터 선택된 친핵성시약과 반응시킴을 특징으로 하는 4-(피라졸일옥시) 니트로벤젠의 제조방법.
- 제26항에 있어서, 친핵성 시약은 알콕시, 알킬아미노, 알킬티오, 알콕시알킬, 알킬아미노알킬, 알킬티오알킬, 할로, 시아노와 니트로로부터 선택된 하나 이상의 치환체와 치환되거나 치환되지 않은 시아노, 하이드록시, 알콕시, 티오, 알킬티오, 아미노, 알킬아미노, 하이드라지노, 알킬-하이드라지노, 알알콕시아미노와 알킬아미노옥시로부터 선택된 것음을 특징으로 하는 제조방법.
- CH3NHNH2와 Y가 하이드리도 또는 할로, R이 하이드리도, 알킬 혹은 페닐, Z가 알콕시, 알킬아미노 혹은 알킬티오인를 반응시킴을 특징으로 하는 다음 구조식의 화합물을 제조하는 방법.여기서 A는 할로메틸이고 B는 하이드리도 혹은 할로이다.
- 제28항에 있어서, R이 하이드리도이고, Y가 플루오로임을 특징으로 하는 제조방법.※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (15)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US175460 | 1980-08-05 | ||
US5971287A | 1987-06-08 | 1987-06-08 | |
US5943187A | 1987-06-08 | 1987-06-08 | |
US59431 | 1987-06-08 | ||
US059431 | 1987-06-08 | ||
US059712 | 1987-06-08 | ||
US17546388A | 1988-04-13 | 1988-04-13 | |
US17546088A | 1988-04-13 | 1988-04-13 | |
US175461 | 1988-04-13 | ||
US07/175,462 US4948902A (en) | 1988-04-13 | 1988-04-13 | Process for making substituted pyrazoles |
US175463 | 1988-04-13 | ||
US07/175,461 US4855442A (en) | 1988-04-13 | 1988-04-13 | Substituted 3-hydroxy pyrazoles |
US175460~3 | 1988-04-13 | ||
US175462 | 1988-04-13 | ||
US59712 | 2002-01-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890000431A true KR890000431A (ko) | 1989-03-14 |
KR900007189B1 KR900007189B1 (ko) | 1990-09-29 |
Family
ID=27556795
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880006799A KR900007189B1 (ko) | 1987-06-08 | 1988-06-07 | 치환된 3-(4-니트로페녹시) 피라졸과 제초제로서의 이들의 용도 |
Country Status (13)
Country | Link |
---|---|
EP (1) | EP0295233A3 (ko) |
JP (1) | JPS6425764A (ko) |
KR (1) | KR900007189B1 (ko) |
AU (1) | AU607225B2 (ko) |
BR (1) | BR8802760A (ko) |
DK (1) | DK308688A (ko) |
ES (1) | ES2007310A4 (ko) |
FI (1) | FI882680A (ko) |
HU (1) | HU204259B (ko) |
NO (1) | NO169387C (ko) |
NZ (1) | NZ224920A (ko) |
PT (1) | PT87666B (ko) |
YU (1) | YU110188A (ko) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5185025A (en) * | 1988-11-21 | 1993-02-09 | Monsanto Company | Substituted pyrazoles and their use as herbicides |
US5045106A (en) * | 1988-11-23 | 1991-09-03 | Monsanto Company | Herbicidal substituted pyrazoles |
EP0442654A3 (en) * | 1990-02-16 | 1992-06-03 | Imperial Chemical Industries Plc | Heterocyclic compounds |
WO1997003948A1 (fr) * | 1995-07-21 | 1997-02-06 | Shionogi & Co., Ltd. | Derives de benzohydroxymoyle substitues en 2, intermediaire pour la production de ces derives et pesticide utilisant ces derives comme ingredient actif |
DE19734664A1 (de) * | 1997-08-11 | 1999-02-18 | Bayer Ag | (Hetero)Aryloxypyrazole |
JP4249982B2 (ja) * | 2001-02-20 | 2009-04-08 | 財団法人相模中央化学研究所 | ピラゾール誘導体とその製造中間体及びそれらの製造方法、並びにそれらを有効成分とする除草剤 |
WO2006060762A2 (en) * | 2004-12-03 | 2006-06-08 | Arena Pharmaceuticals, Inc. | Pyrazole derivatives as modulators of the 5-ht2a serotonin receptor useful for the treatment of disorders related thereto |
ATE545637T1 (de) * | 2005-12-15 | 2012-03-15 | Astrazeneca Ab | Substituierte diphenylether, -amine, -sulfide und methane zur behandlung von atemwegserkrankungen |
WO2010001869A1 (ja) * | 2008-06-30 | 2010-01-07 | 武田薬品工業株式会社 | 4置換ベンゼン化合物およびその用途 |
WO2010026989A1 (ja) * | 2008-09-02 | 2010-03-11 | 日産化学工業株式会社 | オルト置換ハロアルキルスルホンアニリド誘導体及び除草剤 |
US20120258891A1 (en) | 2011-04-07 | 2012-10-11 | Nimblegen Systems Gmbh | Diarylsulfide backbone containing photolabile protecting groups |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2644588A1 (de) * | 1976-10-02 | 1978-04-06 | Bayer Ag | N,n-dimethyl-o-pyrazolyl-carbaminsaeureester, verfahren zu ihrer herstellung und ihre verwendung als insektizide |
DE2829289A1 (de) * | 1978-07-04 | 1980-01-24 | Basf Ag | Pyrazolaetherderivate |
JPS5785371A (en) * | 1980-11-13 | 1982-05-28 | Ihara Chem Ind Co Ltd | 4-fluoro-5-oxypyrazole derivative |
US4744815A (en) * | 1985-05-11 | 1988-05-17 | Nissan Chemical Industries, Ltd. | 4-benzoyl-1-alkyl (alkenyl) - pyrazoles, composition containing them, herbicidal method of using them, and intermediate in their preparation |
CA1300137C (en) * | 1985-12-27 | 1992-05-05 | Hiroshi Hamaguchi | Pyrazole oxime derivative and its production and use |
AU611014B2 (en) * | 1988-05-06 | 1991-05-30 | Sumitomo Chemical Company, Limited | A pyrazole compound and its production and use |
-
1988
- 1988-06-07 JP JP63140361A patent/JPS6425764A/ja active Granted
- 1988-06-07 AU AU17450/88A patent/AU607225B2/en not_active Ceased
- 1988-06-07 PT PT87666A patent/PT87666B/pt not_active IP Right Cessation
- 1988-06-07 YU YU01101/88A patent/YU110188A/xx unknown
- 1988-06-07 ES ES88870104T patent/ES2007310A4/es active Pending
- 1988-06-07 BR BR8802760A patent/BR8802760A/pt not_active Application Discontinuation
- 1988-06-07 FI FI882680A patent/FI882680A/fi not_active Application Discontinuation
- 1988-06-07 EP EP88870104A patent/EP0295233A3/en not_active Withdrawn
- 1988-06-07 NZ NZ224920A patent/NZ224920A/xx unknown
- 1988-06-07 NO NO882509A patent/NO169387C/no unknown
- 1988-06-07 HU HU882946A patent/HU204259B/hu not_active IP Right Cessation
- 1988-06-07 KR KR1019880006799A patent/KR900007189B1/ko not_active IP Right Cessation
- 1988-06-07 DK DK308688A patent/DK308688A/da not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
BR8802760A (pt) | 1988-12-27 |
PT87666B (pt) | 1992-09-30 |
YU110188A (en) | 1990-08-31 |
DK308688A (da) | 1988-12-09 |
HUT52063A (en) | 1990-06-28 |
FI882680A (fi) | 1988-12-09 |
EP0295233A2 (en) | 1988-12-14 |
NZ224920A (en) | 1990-10-26 |
EP0295233A3 (en) | 1989-03-15 |
AU607225B2 (en) | 1991-02-28 |
HU204259B (en) | 1991-12-30 |
NO882509L (no) | 1988-12-09 |
FI882680A0 (fi) | 1988-06-07 |
NO882509D0 (no) | 1988-06-07 |
DK308688D0 (da) | 1988-06-07 |
ES2007310A4 (es) | 1989-06-16 |
PT87666A (pt) | 1988-07-01 |
JPH0575746B2 (ko) | 1993-10-21 |
NO169387C (no) | 1992-06-17 |
KR900007189B1 (ko) | 1990-09-29 |
JPS6425764A (en) | 1989-01-27 |
AU1745088A (en) | 1988-12-08 |
NO169387B (no) | 1992-03-09 |
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