KR890000431A - 치환된 3-(4-니트로페녹시)피라졸과 제초제로서의 이들의 용도 - Google Patents

치환된 3-(4-니트로페녹시)피라졸과 제초제로서의 이들의 용도 Download PDF

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KR890000431A
KR890000431A KR1019880006799A KR880006799A KR890000431A KR 890000431 A KR890000431 A KR 890000431A KR 1019880006799 A KR1019880006799 A KR 1019880006799A KR 880006799 A KR880006799 A KR 880006799A KR 890000431 A KR890000431 A KR 890000431A
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substituent
pyrazole ring
alkoxy
methyl
halo
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모우드릴서 쿠르트
데이비드 로저스 마이클
렌팡리
키이스 앤더슨 데니스
쿠마르 싱 라젠드라
죤 개디 브루스
루이스 토렌스 리사
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아놀드 하비 콜
몬산토 캄파니
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Abstract

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Description

치환된 3-(4-니트로페녹시)피라졸과 제초제로서의 이들의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (29)

  1. 페닐환은 파라니트로치환체를 갖고, 피라졸환의 1위치에는 메틸, 에틸, 할로메틸 혹은 할로에틸 치환체를 갖고, 4위치에는 하이드리도, 할로 혹은 니트로 치환체를 가지며, 5위치에는 클로로, 시아노, 할로메닐, 할로에틸, 메틸티오, 에틸티오, 메틸설피닐, 에틸설피닐, 에틸설포닐 혹은 메톡시메틸 치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 농경에 사용할 수 있는 그의 염.
  2. 제1항에 있어서, 피라졸환의 1위치는 메틸 치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 그의 염.
  3. 제2항에 있어서, 피라졸환의 4위치는 할로치환체를 갖는 것을 특징으로 하는 3-페놀시피라졸 및 그의 염.
  4. 제3항에 있어서, 피라졸환의 4위치는 클로로 혹은 브로모치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 그의 염.
  5. 제4항에 있어서, 피라졸환의 5위치는 트리플루오로메틸, 디플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 그의 염.
  6. 제1항에 있어서, 페닐환은 약 300 이하의 분자량을 갖고 알콕시, 할로알콕시, 디(알콕시), 알콕시카르보닐, 알콕시카르보닐 알콕시, 아미노카르보닐알콕시, 알킬설포닐 아미노카르보닐알콕시, 알킬아미노, 하이드록시알킬아미노, 알콕시아미노, 알콕시킬아미노, 하이드록시카르보닐알킬아미노와 알콕시-카르보닐 알킬옥시이미노로부터 선택된 메타 치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 그의 염.
  7. 제6항에 있어서, 피라졸환의 4위치는 클로로나브로모 치환체를 갖는 것을 특징으로 하는 3-페녹시 피라졸 및 그의 염.
  8. 제7항에 있어서, 피라졸환의 5위치는 디플루오로메틸, 트리플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 3-페녹시피라졸 및 그의 염.
  9. 페닐환은 파라니트로 치환체를 갖고, 피라졸환의 1위치에는 메틸, 에틸, 할로메틸 혹은 할로에틸 치환체를 갖고, 4위치에는 하이드리도, 할로 혹은 니트로치환체를 가지며, 5위치에는 클로로, 시아노, 할로메틸, 할로에밀, 메틸티오, 에틸티오, 메틸설피닐, 에틸설피닐, 에틸설포닐 혹은 메톡시에틸 치환체를 갖는 3-페녹시피라졸 및 농경에 사용할 수 있는 그의 염을 효과적인 양 포함함을 특징으로 하는 제초제 조성물.
  10. 제9항에 있어서, 피라졸환의 1위치는 메틸 치환체를 갖는 것을 특징으로 하는 조성물.
  11. 제10항에 있어서, 피라졸환의 4위치는 클로로 혹은 브로모 치환체를 갖는 것을 특징으로 하는 조성물.
  12. 제11항에 있어서, 피라졸환의 5위치는 트리플루오로메틸, 디플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 조성물.
  13. 제9항에 있어서, 페닐환은 약 300이하의 분자량을 갖고 알콕시, 할로알콕시, 디(알콕시), 알콕시카르보닐, 알콕시카르보닐알콕시, 아미노카르보닐알콕시, 알킬설포닐아미노카르보닐알콕시, 알킬아미노, 하이드록시알킬아미노, 알콕시아미노, 알콕시알킬아미노, 하이드록시카르보닐알킬아미노와 알콕시카르보닐알킬옥시이미노로부터 선택된 메타 치환체를 갖는 것을 특징으로 하는 조성물.
  14. 제13항에 있어서, 피라졸환의 4위치는 클로로나 브로모 치환체를 갖는 것을 특징으로 하는 조성물.
  15. 제13항에 있어서, 피라졸환의 5위치는 디플루오로메틸, 트리플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 조성물.
  16. 페닐환은 파라니트로치환체를 갖고, 피라졸환의 1위치에는 메틸, 에틸, 할로메틸 혹은 할로에틸 치환체를 갖고, 위치에는 하이드리도, 할로 혹은 니트로 치환체를 가지며, 5위치에는 클로, 시아노, 할로메틸, 할로에틸, 메틸티오, 에틸티오, 메틸설피닐, 에틸설피닐, 메틸설포닐, 혹은 메톡시 메틸 치환체를 갖는 유효량의 3-페녹시피라졸 및 농경에 사용할 수 있는 그의 염을 식물에 사용함을 특징으로 하는 원하지 않는 식물의 성장을 제어하는 방법.
  17. 제16항에 있어서, 피라졸환의 1위치는 메틸치환체를 갖는 것을 특징으로 하는 방법.
  18. 제17항에 있어서, 피라졸환의 4위치는 클로로 혹은 브로모 치환체를 갖는 것을 특징으로 하는 방법.
  19. 제18항에 있어서, 피라졸환의 5위치는 트리플루오로메틸, 디플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 방법.
  20. 제16항에 있어서, 페닐환은 약 300이하의 분자량을 갖고 알콕시, 할로알콕시, 디(알콕시), 알콕시카르보닐, 알콕시카르보닐알콕시, 아미노카르보닐알콕시, 알킬설포닐아미노카르보닐알콕시, 알킬아미노, 하이드록시알킬아미노, 알콕시아미노, 알콕시알킬아미노, 하이드록시카르보닐알킬아미노와 알콕시-카르보닐알킬옥시이미노로부터 선택된 메타 치환체를 갖는 것을 특징으로 하는 방법.
  21. 제20항에 있어서, 피라졸환의 4위치는 클로나 브로모 치환체를 갖는 것을 특징으로 하는 방법.
  22. 제21항에 있어서, 피라졸환의 5위치는 디플루오로메틸, 트리플루오로메틸 혹은 메틸설포닐 치환체를 갖는 것을 특징으로 하는 방법.
  23. 다음 구조식으로 표현되는 화합물.
    여기서, R1은 메틸이나 에틸이고, R2는 할로메틸, 할로에틸, 메틸설피닐, 에틸설피닐 혹은 메톡시 메틸이며, R3은 하이드리도 혹은 할로이다.
  24. 제23항에 있어서, R1은 메틸, R2는 트리플루오로메틸이나 디플루오로메틸이며 R3는 하이드리도임을 특징으로 하는 화합물.
  25. 제23항에 있어서, R1은 메틸, R2는 트리플루오로메틸이나 디플루오로메틸이며 R3는 할로임을 특징으로 하는 화합물.
  26. 2,4-(피라졸일옥시)를 하이드록사이드, 유기산화물염, 엔올레이트, 티올레이트, 암모니아 1급아민, 2급아민, 하이드라진과 시아니드로부터 선택된 친핵성시약과 반응시킴을 특징으로 하는 4-(피라졸일옥시) 니트로벤젠의 제조방법.
  27. 제26항에 있어서, 친핵성 시약은 알콕시, 알킬아미노, 알킬티오, 알콕시알킬, 알킬아미노알킬, 알킬티오알킬, 할로, 시아노와 니트로로부터 선택된 하나 이상의 치환체와 치환되거나 치환되지 않은 시아노, 하이드록시, 알콕시, 티오, 알킬티오, 아미노, 알킬아미노, 하이드라지노, 알킬-하이드라지노, 알알콕시아미노와 알킬아미노옥시로부터 선택된 것음을 특징으로 하는 제조방법.
  28. CH3NHNH2와 Y가 하이드리도 또는 할로, R이 하이드리도, 알킬 혹은 페닐, Z가 알콕시, 알킬아미노 혹은 알킬티오인를 반응시킴을 특징으로 하는 다음 구조식의 화합물을 제조하는 방법.
    여기서 A는 할로메틸이고 B는 하이드리도 혹은 할로이다.
  29. 제28항에 있어서, R이 하이드리도이고, Y가 플루오로임을 특징으로 하는 제조방법.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880006799A 1987-06-08 1988-06-07 치환된 3-(4-니트로페녹시) 피라졸과 제초제로서의 이들의 용도 KR900007189B1 (ko)

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US175460 1980-08-05
US5971287A 1987-06-08 1987-06-08
US5943187A 1987-06-08 1987-06-08
US59431 1987-06-08
US059431 1987-06-08
US059712 1987-06-08
US17546388A 1988-04-13 1988-04-13
US17546088A 1988-04-13 1988-04-13
US175461 1988-04-13
US07/175,462 US4948902A (en) 1988-04-13 1988-04-13 Process for making substituted pyrazoles
US175463 1988-04-13
US07/175,461 US4855442A (en) 1988-04-13 1988-04-13 Substituted 3-hydroxy pyrazoles
US175460~3 1988-04-13
US175462 1988-04-13
US59712 2002-01-29

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US5185025A (en) * 1988-11-21 1993-02-09 Monsanto Company Substituted pyrazoles and their use as herbicides
US5045106A (en) * 1988-11-23 1991-09-03 Monsanto Company Herbicidal substituted pyrazoles
EP0442654A3 (en) * 1990-02-16 1992-06-03 Imperial Chemical Industries Plc Heterocyclic compounds
WO1997003948A1 (fr) * 1995-07-21 1997-02-06 Shionogi & Co., Ltd. Derives de benzohydroxymoyle substitues en 2, intermediaire pour la production de ces derives et pesticide utilisant ces derives comme ingredient actif
DE19734664A1 (de) * 1997-08-11 1999-02-18 Bayer Ag (Hetero)Aryloxypyrazole
JP4249982B2 (ja) * 2001-02-20 2009-04-08 財団法人相模中央化学研究所 ピラゾール誘導体とその製造中間体及びそれらの製造方法、並びにそれらを有効成分とする除草剤
WO2006060762A2 (en) * 2004-12-03 2006-06-08 Arena Pharmaceuticals, Inc. Pyrazole derivatives as modulators of the 5-ht2a serotonin receptor useful for the treatment of disorders related thereto
ATE545637T1 (de) * 2005-12-15 2012-03-15 Astrazeneca Ab Substituierte diphenylether, -amine, -sulfide und methane zur behandlung von atemwegserkrankungen
WO2010001869A1 (ja) * 2008-06-30 2010-01-07 武田薬品工業株式会社 4置換ベンゼン化合物およびその用途
WO2010026989A1 (ja) * 2008-09-02 2010-03-11 日産化学工業株式会社 オルト置換ハロアルキルスルホンアニリド誘導体及び除草剤
US20120258891A1 (en) 2011-04-07 2012-10-11 Nimblegen Systems Gmbh Diarylsulfide backbone containing photolabile protecting groups

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