KR880014016A - 흡수성복합체와 그의 제조방법 - Google Patents

흡수성복합체와 그의 제조방법 Download PDF

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KR880014016A
KR880014016A KR1019880006173A KR880006173A KR880014016A KR 880014016 A KR880014016 A KR 880014016A KR 1019880006173 A KR1019880006173 A KR 1019880006173A KR 880006173 A KR880006173 A KR 880006173A KR 880014016 A KR880014016 A KR 880014016A
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acid
vinylpyridine
base material
fibrous base
aqueous solution
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KR950012339B1 (ko
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게이이치 이토
다케시 시바노
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요시다 마사키
미츠비시유카 가부시키가이샤
다카하라 게이이치로
유니참 가부시키가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/08—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin
    • D06M14/12—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M14/14—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
    • D06M14/04—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y10T428/31895—Paper or wood
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y10T428/31895—Paper or wood
    • Y10T428/31906—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3325—Including a foamed layer or component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/40—Knit fabric [i.e., knit strand or strip material]
    • Y10T442/469—Including a foamed layer or component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/647—Including a foamed layer or component

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerization Catalysts (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

내용 없음

Description

흡수성복합체와 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (20)

  1. 흡수성이 강한 흡수성 폴리머와 조립된 섬유상기재로 이루어진 흡수성 복합체를 제조하는데 있어서, (a) 카르복실기 20% 이상이 알카리금속염 또는 암모늄염으로 중화된 아크릴산을 주성분으로 하는 중합가능한 모노머(이하 "아크릴산형모노머"라 한다.)와, (b) 2-비닐피리딘, 4-비닐피리딘와/또는 그의 염(이하"비닐피리딘형모노머"라 한다.)과, (c) 가교결합제 및 (d) 산화성 레디칼중합 개시제를 함유하는 수용액을 조립된 섬유상기재에다 적용시킨 다음, 환원제를 첨가시키면서 중합시켜서 제조되어지는 흡수성복합체의 제조방법.
  2. 제 1 항에 있어서, 상기 (b)의 비닐피리딘은 상기 (a)의 아크릴산모노머 총량에 대하여 0.001 내지 20몰%를 사용하여 되어지는 방법.
  3. 제 2 항에 있어서, (b)의 비닐피리딘은 상기 (a)의 아크릴산모노머 총량에 대하여 0.01 내지 5몰%를 사용하여 되어지는 방법.
  4. 제 1 항에 있어서, 상기 수용액에는 (a) 메타아크릴산, 이타콘산, 말레산, 푸마르산 2-아크릴아미드-2-메틸프로판설폰산, 2-아크릴로일에탄설폰산, 2-아크릴로일프로판설폰산과 그 염,(b) 이타콘산, 말레산, 푸마르산과 같은 디카르보닐산의 알킬 또는 알콕시에스테르, (c) 비닐설폰산, (d) 메틸아크릴레이트, 에틸아크릴레이트, (e) 하이드록시에틸(메타)아크릴레이트, 하이드록시프로필(메타) 아크릴레이트, (f) 폴리에틸렌 글리콜모노(메타)아크릴레이트로 이루어진 그룹으로부터 선택된 부가가능한 모노머를 포함시켜서 되어지는 방법.
  5. 제 1 항에 있어서, 상기 (a)의 아크릴산모노머는 수산화나트륨 또는 수산화칼륨으로 중화시켜서 되어지는 방법.
  6. 제 1 항에 있어서, 수용액은 그 농도가 20중량% 이상으로 하여서 되어지는 방법.
  7. 제 1 항에 있어서, 상기 (c)의 가교결합제는 그 분자내에 이중결합을 가지면서 상기 (a)의 아크릴모노머와 (또는) 상기 (b)의 비닐피리딘모노머와 공중합시켜서 되어지는 방법.
  8. 제1항에 있어서, 상기 (c)의 산화레디칼중합개시제와 환원제는 산화환원시스템을 형성시켜서 되어지는 방법.
  9. 제 8 항에 있어서, 산화레디칼중합개시제는 (a) 과산화수소, 과황산염 및 히드로 과산화물로부터 선택된 과산화물과, (b) 제 2 세륨염, 과망간산염, 아염소산염 및 하이포염소산염으로 이루어진 그룹으로부터 선택된 것을 사용하여서 되어지는 방법.
  10. 제 8 항에 있어서, 환원제는 아황산염, 티오황산나트륨, 아세트산코발트, 황산 제 2구리, 황산 제 1철, L-아스코르브산 및 L-아스코르브산 알카리금속염으로 이루어진 그룹으로부터 선택된 것을 사용하여서 되어지는 방법.
  11. 제 8 항에 있어서, 산화레디칼중합개시제는 과산화물, 환원제는 L-아스코르브산 또는 그의 알카리금속염을 사용하여서 되어지는 방법.
  12. 제 1 항에 있어서, 섬유상기재는 루우즈한 직물패드, 카이드웨브, 공기층을 갖는 웨브, 종이, 비직물, 직물 또는 편물 등을 사용하여서 되어지는 방법.
  13. 제 1 항에 있어서, 섬유상기재는 셀룰로오즈 섬유 또는 폴리에스테르섬유를 주성분으로 하여서 되어지는 방법.
  14. 제 1 항에 있어서, 수용액은 섬유상기재에다 주기적인 간격으로 점 또는 선형태로 형성시켜서 되어지는 방법.
  15. 제 1 항에 있어서, 환원재는 분사노즐을 통해서 미립자 형태로 적용시켜서 되어지는 방법.
  16. 제 1 항에 있어서, 수용액은 섬유상기재에 적용되어질때 20 내지 60℃의 온도로 유지시켜서 되어지는 방법.
  17. 제 1 항에 있어서, 중합은 실온 내지 60℃의 온도하에서 이루어져서 되어지는 방법.
  18. 제17항에 있어서, 중합은 실온 내지 40℃의 온도하에서 이루어져서 되어지는 방법.
  19. 제 1 항에 있어서, 중합은 수초 내지 10분동안 실시하여서 되어지는 방법.
  20. 흡수성이 강한 흡수성 폴리머와 조립된 섬유상기재로 이루어진 흡수성 복합체에 있어서, (a) 카르복실기 20% 이상이 알카리 금속염 또는 암모늄염으로 중화된 아크릴산을 주성분으로 하는 중합가능한 모노머와, (b)2-비닐피리딘, 4-비닐피리딘와/또는 그의 염과, (c) 가교결합제 및 (d) 산화성레디칼중합개시제를 함유하는 수용액을 조립된 섬유상기재에 적용되고 환원제로 중합시켜서 되어진 흡수성복합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880006173A 1987-05-26 1988-05-26 흡수성복합체와 그의 제조방법 KR950012339B1 (ko)

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JP62-128830 1987-05-26
JP62128830A JPH07121975B2 (ja) 1987-05-26 1987-05-26 吸水性複合体の製造法

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KR880014016A true KR880014016A (ko) 1988-12-22
KR950012339B1 KR950012339B1 (ko) 1995-10-17

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US (1) US4842927A (ko)
EP (1) EP0293762B1 (ko)
JP (1) JPH07121975B2 (ko)
KR (1) KR950012339B1 (ko)
AU (1) AU610593B2 (ko)
CA (1) CA1302181C (ko)
DE (1) DE3868699D1 (ko)
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WO2015151949A1 (ja) * 2014-04-02 2015-10-08 東亞合成株式会社 高強度エラストマー
CN110983753A (zh) * 2019-12-13 2020-04-10 江阴开源非织造布制品有限公司 一种抗菌亲水型无纺布改性剂及其制备方法

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DE3202093A1 (de) * 1982-01-23 1983-08-04 Röhm GmbH, 6100 Darmstadt Acrylkunststoffdispersion
JPH0647626B2 (ja) * 1986-07-01 1994-06-22 三菱油化株式会社 吸水性複合材料の製造法

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DE3868699D1 (de) 1992-04-09
EP0293762A2 (en) 1988-12-07
EP0293762A3 (en) 1990-01-24
ES2030787T3 (es) 1992-11-16
US4842927A (en) 1989-06-27
CA1302181C (en) 1992-06-02
AU1660888A (en) 1988-12-01
KR950012339B1 (ko) 1995-10-17
JPH07121975B2 (ja) 1995-12-25
JPS63291909A (ja) 1988-11-29
AU610593B2 (en) 1991-05-23
EP0293762B1 (en) 1992-03-04

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