KR880012719A - 점착성 아크릴계 감압성 접착제 - Google Patents

점착성 아크릴계 감압성 접착제 Download PDF

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KR880012719A
KR880012719A KR1019880004080A KR880004080A KR880012719A KR 880012719 A KR880012719 A KR 880012719A KR 1019880004080 A KR1019880004080 A KR 1019880004080A KR 880004080 A KR880004080 A KR 880004080A KR 880012719 A KR880012719 A KR 880012719A
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copolymer
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존 트레이니 월리암
리 무어 체릴
켄트 마틴 미카엘
더글라스 문 존
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도날드 밀리 셀
미네소타 마이닝 앤드 메뉴팩츄 어링 컴패니
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    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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    • C09J139/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Adhesives based on derivatives of such polymers
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    • C09J139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
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    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
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    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y10T428/24959—Thickness [relative or absolute] of adhesive layers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249982—With component specified as adhesive or bonding agent
    • Y10T428/249983—As outermost component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
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    • Y10T428/249984—Adhesive or bonding component contains voids
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    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
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    • Y10T428/249985—Composition of adhesive or bonding component specified
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    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852—Adhesive compositions
    • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
    • Y10T428/2887—Adhesive compositions including addition polymer from unsaturated monomer including nitrogen containing polymer [e.g., polyacrylonitrile, polymethacrylonitrile, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
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    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
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    • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
    • Y10T428/2891—Adhesive compositions including addition polymer from unsaturated monomer including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof

Abstract

내용 없음

Description

점착성 아크릴계 감압성 접착제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. (1)(a) 알킬기가 평균 약4-14개의 탄소원자를 가지며, 아크릴산 에스테르는 그 자체가 끈적거리며 늘일수 있는 탄성 접착물질로 중합가능한 비 3차 알킬알코올의 아크릴산 에스테르, 및 (b) (a)및 (b)전체 단량체들의 10~40부에 달하는 양의 N-비닐 락탐으로 이루어진 단량체들의 아크릴계 공중합체, 및(2) 최소한 1종의 폴리(이소보르닐메타크릴레이트), 로진의 펜타에리트리톨 에스테르 및 혼성-지방족/방향족 중합체성 점착수지로부터 선택된, 아크릴계 공중합체(1)100부당 약5~50부의 양의 점착수지의 중량비 혼합물로서, 상기 공중합체가 95%를 초과하는 단량체 전환인자를 갖고 THF내에서 최소한 50%겔에 의해 입증된 바와 같이 교차결합되며, 점착수지는 고-고형량 자동차 도료 시스템에 대해 감압성 접착제의 영구 접착력을 강화 시킴을 특징으로하는 감압성 접착제.
  2. 제1항에 있어서, 상기 점착수지(2)가 최소한 30℃의 Tg를 가짐을 특징으로하는 감압성 접착제.
  3. 제1항에 있어서, 상기 점착수지(2)가 300~3000의 Mn을 가짐을 특징으로 하는 감압성 접착제.
  4. 제1항에 있어서, 상기 점착수지(2)가 8~9(cal/cm3)1/2의 용해도 매개변수를 가짐을 특징으로하는 감압성 접착제.
  5. 제4항에 있어서, 접착수지가 90~20중량%의 방향족 함량 및 상응하는 10~80중량%의 지방족 함량을 가짐을 특징으로하는 감압성 접착제.
  6. 제1항에 있어서, N-비닐-락탐이 N-비닐-2-피롤리돈임을 특징으로하는 감압성 접착제.
  7. 제1항에 있어서, N-비닐-락탐이 N-비닐-카프로 락탐임을 특징으로하는 감압성 접착제.
  8. 최소한 0.3mm의 두께를 갖는 거품 또는 거품형 코어 및 코어보다는 얇은 치밀한 감압성 접착 표면층으로 이루어지며, 표면층의 감압성 접착제가: (1)(a)알킬기가 평균 약4~14개의 탄소원자를 가지며, 아크릴산 에스테르는 그 자체가 끈적거리며 늘일수 있는 탄성 접착물질로 중합가능한 비3차 알킬알코올의 아크릴산 에스테르 및,(b) (a)및(b)전체 단량체들의 10~40부에 달하는 양의 N-비닐-2-피롤리돈 및 N-비닐-카프로락탐중 최소한 1종의 중량비 공중합체, 및 (2)최소한 1종의 폴리(이소보르닐메타크릴레이트), 로진의펜타에리트리톨 에스테르 및 혼성-지방족/방향족 중합체성 점착수지로부터 선택된, 공중합체(1) 100부당 약5~50부의 양의 접착수지의 혼합물로서, 상기 공중합체가 95%를 초과하는 단량체 전환인자를 갖고 THF내에서 최소한 50%겔에의해 입증된 바와같이 교차결합되며, 점착수지는 고-고형량 자동차 도료 스시템에 대한 감압성 접착제의 영구 접착력을 강화시킴을 특징으로하는 감압성 접착 테이프.
  9. 제8항에 있어서, 코아가 코어의 5~65부피%에 달하는 마이크로버블이 분산된 감압성 접착제로 이루어진 거품형임을 특징으로하는 감압성 접착 테이프.
  10. 제9항에 있어서, 상술한 치밀한 감압성 접착제 표면층의 두께가 0.2mm보다 크지않음을 특징으로하는 감압성 접착테이프.
  11. 제9항에 있어서, 거품형 코어가 마이크로버블내의 빈공간 이외에 실질적으로 빈곳을 갖지 않음을 특징으로하는 감압성 접착 테이프.
  12. 제8항에 있어서, 코아가 셀룰과 감압성 접착제로 이루어진 거품임을 특징으로하는 감압성 접착테이프.
  13. 제8항에 있어서, 코아가 거품형 열가소성 수지임을 특징으로하는 감압성 접착테이프.
  14. (1)(a) 알킬기가 평균 약4-14개의 탄소원자를 가지며, 아크릴산 에스테르는 그 자체가 끈적거리며 늘일수 있는 탄성 접착물질로 중합가능한 비 3차 알킬알코올의 아크릴산 에스테르, 및 (b) (a)및 (b)전체 단량체들의 10~40부에 달하는 양의 N-비닐 락탐의 중량비 아크릴계 공중합체, 및(2) 최소한 1종의 폴리(이소보르닐메타크릴레이트), 로진의 펜타에리트리톨 에스테르 및 혼성-지방족/방향족 중합체성 점착수지로부터 선택된, 아크릴계 공중합체(1)100부당 약5~50부의 양의 점착수지의 혼합물로서, 상기 공중합체가 95%를 초과하는 단량체 전환인자를 갖고 THF내에서 최소한 50%겔에 의해 입증된 바와 같이 교차결합되며, 점착수지는 고-고형량 자동차 도료 시스템에 대해 감암성 접착제의 영구 접착력을 강화 시키는 감압성접착제의 층을 운반하는 가요성 배킹을 포함함을 특징으로하는 감압성 접착 테이프.
  15. 제14항에 있어서, N-비닐-락탐이 N-비닐-2-피롤리돈임을 특징으로하는 감압성 접착테이프.
  16. (1)(a) 알킬기가 평균 약4-14개의 탄소원자를 가지며, 아크릴산 에스테르는 그 자체가 끈적거리며 늘일수 있는 탄성 접착물질로 중합가능한 비 3차 알킬알코올의 아크릴산 에스테르, 및 (b) (a)및 (b)전체 단량체들의 10~40부에 달하는 양의 N-비닐 락탐의 중량비 아크릴계 공중합체, 및(2) 최소한 1종의 폴리(이소보르닐메타크릴레이트), 로진의 펜타에리트리톨 에스테르 및 혼성-지방족/방향족 중합체성 점착수지로부터 선택된, 아크릴계 공중합체, 상기 공중 합체가 95%를 초과하는 단량체 전환인자를 갖고 THF내에서 최소한 50%겔에 의해 입증된 바와 같이 교차결합되며, 점착수지는 고-고형량 자동차 도료 시스템에 대해 감암성 접착제의 영구 접착력을 강화시킴을 특징으로 하는 감압성 접착제의 층을 갖는장식 또는 보호품.
  17. 제16항에 있어서, N-비닐-락탐이 N-비닐-2-피롤리돈임을 특징으로하는 장식 또는 보호품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880004080A 1987-04-10 1988-04-09 점착성 아크릴 감압 접착제 KR960005179B1 (ko)

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US07/036,589 US4726982A (en) 1987-04-10 1987-04-10 Tackified acrylic pressure-sensitive adhesive and composite article
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EP0286420A3 (en) 1990-07-04
JPS63308079A (ja) 1988-12-15
EP0286420B1 (en) 1993-02-10
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US4726982A (en) 1988-02-23
DE3878289D1 (de) 1993-03-25
DE3878289T2 (de) 1993-07-15

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