KR880012522A - 신규한 중합성 비닐단량체 및 그로 부터 제조된 비닐수지 - Google Patents

신규한 중합성 비닐단량체 및 그로 부터 제조된 비닐수지 Download PDF

Info

Publication number
KR880012522A
KR880012522A KR1019880004105A KR880004105A KR880012522A KR 880012522 A KR880012522 A KR 880012522A KR 1019880004105 A KR1019880004105 A KR 1019880004105A KR 880004105 A KR880004105 A KR 880004105A KR 880012522 A KR880012522 A KR 880012522A
Authority
KR
South Korea
Prior art keywords
vinyl monomer
formula
hydrogen atom
methyl group
real number
Prior art date
Application number
KR1019880004105A
Other languages
English (en)
Other versions
KR960000038B1 (ko
Inventor
료오조오 다까가와
히사끼 다나베
고오지 이사꾸라
미쯔오 야마다
히로하루 오오스기
류우조오 미즈구찌
요시오 에구찌
Original Assignee
사사끼 가즈오
닛뽄 페인트 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP62089316A external-priority patent/JP2572983B2/ja
Priority claimed from JP25648787A external-priority patent/JP2645380B2/ja
Application filed by 사사끼 가즈오, 닛뽄 페인트 가부시끼가이샤 filed Critical 사사끼 가즈오
Publication of KR880012522A publication Critical patent/KR880012522A/ko
Application granted granted Critical
Publication of KR960000038B1 publication Critical patent/KR960000038B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/282—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing two or more oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

내용 없음

Description

신규한 중합성 비닐단량체 및 그로 부터 제조된 비닐수지
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 다음 식으로 나타낸 중합성 비닐단량체
    상기식에서 R은 수소원자 또는 메틸기를 나타내며,n은 3 내지 100의 실수이다.
  2. 아크릴 또는 메타크릴산 할로겐화물과 루이스산의 금속염의 존재하에 테트라히드로푸란을 개환 중합 반응시키고, 물, 알칼리 수용액 도는 4차 암모늄 염기로 중합을 종결시키는 것으로 이루어지는 다음식의 중합성 비닐단량체의 제조방법.
    상기식에서 R은 수소원자 또는 메틸기를 나타내며, n은 3 내지 100의 실수이다.
  3. 브론스테드산의 존재하에 테트라히드로푸란을 개환 중합 반응시키고 아클릴산의 금속염, 메탈크릴산의 금속염, 아크릴산의 아미염 및 메타크릴산의 아민염으로 구성되는 군으로 부터 선택된 것으로 중합을 종결시키는 것으로 이루어지는 다음 식의 중합성 비닐단량체의 제조방법.
    상기식에서 R은 수소원자 또는 메틸기를 나타내며, n은 3내지 100의 실수이다.
  4. 다음식
    (상기식에서 R은 수소원자 또는 메틸기이며, n은 3내지 100의 실수임)으로 나타낸 적어도 한가지 중합성 비닐단량체 20 내지 100몰%와, 상기 비닐단량체 이외에 적어도 한가지,β-에틸렌계 불포화화합물 80 내지 0몰%의 중합반응에 의해 제조되고, 수지가 1000 내지 100.000의 수평균뷴자량을 갖는 것을 특징으로 하는 비닐수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880004105A 1987-04-10 1988-04-11 신규한 중합성 비닐단량체 및 그로부터 제조된 비닐수지 KR960000038B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP62089316A JP2572983B2 (ja) 1987-04-10 1987-04-10 オキシテトラメチレン構造を有する重合反応性単量体組成物ならびにその製法
JP62-089316 1987-04-10
JP25648787A JP2645380B2 (ja) 1987-10-12 1987-10-12 アクリル樹脂組成物
JP62-256487 1987-10-12

Publications (2)

Publication Number Publication Date
KR880012522A true KR880012522A (ko) 1988-11-28
KR960000038B1 KR960000038B1 (ko) 1996-01-03

Family

ID=26430745

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880004105A KR960000038B1 (ko) 1987-04-10 1988-04-11 신규한 중합성 비닐단량체 및 그로부터 제조된 비닐수지

Country Status (6)

Country Link
US (1) US4978777A (ko)
EP (1) EP0286454B1 (ko)
KR (1) KR960000038B1 (ko)
AU (1) AU614512B2 (ko)
CA (1) CA1317313C (ko)
DE (2) DE286454T1 (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR890013140A (ko) * 1988-02-29 1989-09-21 사사끼 가즈오 피복조성물
DE4108046A1 (de) * 1991-03-13 1992-09-17 Basf Ag Verfahren zur herstellung von polyoxyalkylenglykol-monoestern von monocarbonsaeuren
US5290411A (en) * 1992-07-14 1994-03-01 California Institute Of Technology Acrylic polymer electrophoresis support media
DE4243722A1 (de) * 1992-12-23 1994-06-30 Basf Ag Verfahren zur Herstellung von Polyetherglykolen
DE4433606A1 (de) * 1994-09-21 1996-03-28 Basf Ag Verfahren zur Herstellung von Polyetrahydrofuran
GB9521253D0 (en) * 1995-10-17 1995-12-20 Luthra Ajay K Biocompatible lubricious hydrophilic materials for medical devices
DE19719875A1 (de) * 1997-05-12 1998-11-19 Basf Ag Verfahren zur Polymerisation cyclischer Ether
TW442513B (en) 1999-05-19 2001-06-23 Dairen Chemical Corp Method for preparing polyether diol
EP1511777A4 (en) * 2002-05-10 2005-06-15 Univ North Carolina State STEREO REGULAR POLAR VINYL POLYMERS AND MANUFACTURING METHOD THEREFOR
DE112005001483B4 (de) * 2004-06-21 2017-03-23 Sekisui Chemical Co., Ltd. Bindemittelharz-Zusammensetzung, und deren Verwendung als Paste und Grünfolie

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL213586A (ko) * 1956-01-09
US3380831A (en) * 1964-05-26 1968-04-30 Du Pont Photopolymerizable compositions and elements
US4264705A (en) * 1979-12-26 1981-04-28 Uniroyal, Inc. Multilayered elastomeric printing plate
DE3162780D1 (en) * 1980-06-11 1984-04-26 Bp Chem Int Ltd Unsaturated ester polyether polyols and the use thereof as non-ionic surfactants
GB8410497D0 (en) * 1984-04-25 1984-05-31 Allied Colloids Ltd Synthesis of vinyl esters
CA1292476C (en) * 1985-11-13 1991-11-26 Robert A. Lieberman Radiation-hardenable diluents
DE3704915A1 (de) * 1987-02-17 1988-08-25 Hoechst Ag Elektrochemisches verfahren zum austausch von halogenatomen in einer organischen verbindung

Also Published As

Publication number Publication date
US4978777A (en) 1990-12-18
AU614512B2 (en) 1991-09-05
KR960000038B1 (ko) 1996-01-03
AU1446288A (en) 1988-10-13
EP0286454A1 (en) 1988-10-12
CA1317313C (en) 1993-05-04
DE3866922D1 (de) 1992-01-30
EP0286454B1 (en) 1991-12-18
DE286454T1 (de) 1989-02-16

Similar Documents

Publication Publication Date Title
KR900006012A (ko) 수용성 양이온 중합체 분산액의 제조방법
KR890701651A (ko) 수성피복 조성물
KR880012522A (ko) 신규한 중합성 비닐단량체 및 그로 부터 제조된 비닐수지
ATE416204T1 (de) Wässrige emulsionspolymerisation von funktionalisierten fluormonomeren
KR950032323A (ko) 아크릴적 중합체들의 제조방법
KR910000914A (ko) 폴리머/폴리올용 안정화제
KR880000484A (ko) 폴리페닐렌 에테르의 그라프트 중합체
KR900018217A (ko) 수용성 중합체의 제법
KR840007237A (ko) 수성코팅조성물 및 그 제조방법
US5750781A (en) Process for preparing an aqueous copolymer solution
ATE127810T1 (de) Verfahren zur herstellung von acrylpolymere in suspension.
KR930002453A (ko) 전기 전도성 코우팅 조성물
KR930006053A (ko) 중합체 스케일 방지제, 중합체 스케일 부착을 방지하는데 유효한 중합 용기 및 당해 용기를 사용하여 중합체를 제조하는 방법
ES2026733T3 (es) Dispersiones acuosas de polimeros termorreticulables a base de (met)acrilato de alquilo, su procedimiento de preparacion y su aplicacion principalmente como aglutinantes y/o agentes de impregnacion.
KR950701652A (ko) 오니(汚泥)탈수제(sudge dehydration agent)
DE3660381D1 (en) Curable polymers based on unsaturated esters of furoic acid, method for their preparation and their use in the preparation of coatings
GB1445931A (en) Imidazole polymers and preparation thereof with radiation and chemical initiator
KR860003282A (ko) 수성 중합화에 의한 저분자량 비닐할리드/비닐 에스테르 공중합체의 제조방법
KR900012959A (ko) 중합체 에멀션
JPS534086A (en) Preparation of aqueous polymers
KR960014159A (ko) 높은 고체 함량의 라텍스 제조방법
JP2011116877A (ja) マレイン酸／（メタ）アクリル酸共重合体の製造方法及びそれを使用した繊維処理剤
GB1003935A (en) Copolymers of unsaturated epoxy compounds
KR850001235A (ko) 중간분자량의 아크릴 중합체의 제조방법
KR910002913A (ko) 에리토르베이트를 수-팽창성 중합체의 중합용 산화환원 개시제 시스템의 성분으로 사용하는 방법

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee