KR880011067A - (비닐페닐) 페닐메탄 및 (벤조일페닐) 프로피온산의 제조방법 - Google Patents
(비닐페닐) 페닐메탄 및 (벤조일페닐) 프로피온산의 제조방법 Download PDFInfo
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- KR880011067A KR880011067A KR1019880002899A KR880002899A KR880011067A KR 880011067 A KR880011067 A KR 880011067A KR 1019880002899 A KR1019880002899 A KR 1019880002899A KR 880002899 A KR880002899 A KR 880002899A KR 880011067 A KR880011067 A KR 880011067A
- Authority
- KR
- South Korea
- Prior art keywords
- following formula
- compound
- transition metal
- vinylphenyl
- phenylmethane
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/185—Saturated compounds having only one carboxyl group and containing keto groups
- C07C59/205—Saturated compounds having only one carboxyl group and containing keto groups containing rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
- C07C15/50—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic non-condensed
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
- C07C47/228—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms containing six-membered aromatic rings, e.g. phenylacetaldehyde
- C07C47/23—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms containing six-membered aromatic rings, e.g. phenylacetaldehyde polycyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
- C07C63/33—Polycyclic acids
- C07C63/337—Polycyclic acids with carboxyl groups bound to condensed ring systems
- C07C63/34—Polycyclic acids with carboxyl groups bound to condensed ring systems containing two condensed rings
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (7)
- 하기식 (I)으로 표시되는 (3-비닐페닐)페닐메탄.
- 하기식 (I)으로 표시되는 (3-비닐페닐) 페닐메탄을 전이금속카르보닐화 촉매 존재하에, 일산화탄소 및 수소, 및 물 또는 저급알코올과 반응시킴으로써, 하기식 (Ⅱ)으로 표시되는 α-(3-벤질페닐)프로피온산 유도체를 얻고, 이어서 얻은 하기식 (Ⅱ)의 화합물이 알데히드일 때는 이 화합물의 메틸렌기 및 포르밀기를 동시에 또는 점차 각각 산화하고, 또, 얻어진 하기식 (Ⅱ)의 화합물이 산 또는 그의 에스테르일 때는 이 화합물의 메틸렌기를 산화하고 필요에 따라서 가수분해하는 것을 특징으로 하는 하기식 (Ⅲ)으로 표시되는 α-(3-벤조일페닐)프로피온산의 제조방법.
- 제2항에 있어서, 상기 전이금속 카르보닐화 촉매가, 전이금속착체 촉매인 것을 특징으로 하는 제조방법.
- 제3항에 있어서, 상기 전이금속이, 팔라듐, 로듐, 이리듐, 루테늄, 백금에서 선택된 금속인 것을 특징으로 하는 제조방법.
- 제2항에 있어서, 상기 저급알코올이 탄소수 1에서 4의 알코올인 것을 특징으로 하는 제조방법.
- 제2항에 있어서, 상기 산화가, 주기율표중 제Ⅵ-B, Ⅶ-B 및 Ⅷ족에서 선택되는 금속촉매존재하에 분자상 산소에 의해 산화하는 것을 특징으로 하는 제조방법.
- 제2항에 있어서, 상기 산화가 광망간산산염, 2산화망간, 크롬산염, 중크롬산염, 산화오스뮴, 산화셀렌, 아염소산 또는 차아연소산, 과산화수소, 오존 및 이들의 혼합물에서 선택되는 산화제를 사용해서 산화하는 것을 특징으로 하는 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62-66463 | 1987-03-20 | ||
JP?62-66463 | 1987-03-20 | ||
JP62066463A JPH0784397B2 (ja) | 1987-03-20 | 1987-03-20 | (3−ビニルフエニル)フエニルメタン |
Publications (2)
Publication Number | Publication Date |
---|---|
KR880011067A true KR880011067A (ko) | 1988-10-26 |
KR930010403B1 KR930010403B1 (ko) | 1993-10-23 |
Family
ID=13316496
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019880002899A KR930010403B1 (ko) | 1987-03-20 | 1988-03-18 | (3-비닐페닐) 페닐메탄 |
Country Status (6)
Country | Link |
---|---|
US (1) | US4922052A (ko) |
EP (1) | EP0283038B1 (ko) |
JP (1) | JPH0784397B2 (ko) |
KR (1) | KR930010403B1 (ko) |
CA (1) | CA1302431C (ko) |
DE (1) | DE3863206D1 (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000016952A (ja) | 1998-07-01 | 2000-01-18 | Nippon Petrochem Co Ltd | 炭化水素の製造方法 |
CN103787855B (zh) * | 2014-01-17 | 2015-08-19 | 中国农业大学 | 不对称催化合成(s)-芳姜黄酮的新方法 |
WO2023121740A1 (en) * | 2021-12-20 | 2023-06-29 | Nimml Institute | Immunoregulatory compounds |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1211761A (en) * | 1982-12-25 | 1986-09-23 | Atsushi Sato | Electrical insulating substance and oil-filled electrical appliances containing the same |
-
1987
- 1987-03-20 JP JP62066463A patent/JPH0784397B2/ja not_active Expired - Fee Related
-
1988
- 1988-03-17 CA CA000561701A patent/CA1302431C/en not_active Expired - Lifetime
- 1988-03-18 DE DE8888104374T patent/DE3863206D1/de not_active Expired - Lifetime
- 1988-03-18 KR KR1019880002899A patent/KR930010403B1/ko not_active IP Right Cessation
- 1988-03-18 US US07/169,853 patent/US4922052A/en not_active Expired - Lifetime
- 1988-03-18 EP EP88104374A patent/EP0283038B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPS63230647A (ja) | 1988-09-27 |
EP0283038A1 (en) | 1988-09-21 |
KR930010403B1 (ko) | 1993-10-23 |
DE3863206D1 (de) | 1991-07-18 |
US4922052A (en) | 1990-05-01 |
EP0283038B1 (en) | 1991-06-12 |
JPH0784397B2 (ja) | 1995-09-13 |
CA1302431C (en) | 1992-06-02 |
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