KR870011232A - 윤활제 및 첨가제로 사용될 수 있는 신규의 폴리플루오르 화합물 - Google Patents

윤활제 및 첨가제로 사용될 수 있는 신규의 폴리플루오르 화합물 Download PDF

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KR870011232A
KR870011232A KR870005433A KR870005433A KR870011232A KR 870011232 A KR870011232 A KR 870011232A KR 870005433 A KR870005433 A KR 870005433A KR 870005433 A KR870005433 A KR 870005433A KR 870011232 A KR870011232 A KR 870011232A
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radical
carbon atoms
hydrogen
compound
polyfluorine
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도미니끄 바쎄
삐에르 둬뤄알
쟝끌로드 파야르
로르 제르마노
마르 에르망
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쟝 드불렁제
아또샹
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M133/08—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/12—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
    • C10M133/14—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/062—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/251—Alcohol fueled engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines
    • C10N2040/253—Small diesel engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C10N2040/28—Rotary engines
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B1/00—Engines characterised by fuel-air mixture compression
    • F02B1/02—Engines characterised by fuel-air mixture compression with positive ignition
    • F02B1/04—Engines characterised by fuel-air mixture compression with positive ignition with fuel-air mixture admission into cylinder

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Abstract

내용 없음

Description

윤활제 및 첨가제로 사용될 수 있는 신규의 폴리플루오르 화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 하기 일반식의 폴리플루오르 화합물을 한 종류 이상 함유함을 특징으로 하는 윤활제:
    상기 식에서
    Rf는 퍼플루오르라디칼 표시하며,
    a는 0-10의 정수이며,
    b는 0 또는 1이나 동시에 a가 0이고 c가 1일 때만 1이 될 수 있으며,
    c는 1-4까지의 정수이나 a가 0외에 다른 숫자이면 2이며,
    m 및 n은 각각 0 또는 1이며,
    X는 임의로 치환된 아릴라디칼이며,
    Y는 2-히드록시-1-페닐에틸기를 표시하며,
    R1및 R1′는 동일하거나 다를 수 있으며, 각각 수소원자, 1-20개의 탄소원자를 함유하는알킬라디칼, 5 또는 6개의 탄소원자를 함유하는 시클로알킬라디칼 또는 임으로 치환된 아릴라디칼이며,
    R2및 R2′는 동일하거나 다를 수 있으며, 각각 수소원자 또는 지방족, 지환족 또는 방향족 카르복실산의 아실잔류물이며, (a+m+n)이 0이면, 기호 R1및 R2중 하나는 수소 또는 메틸라디칼 이외의 다른 라디칼이다.
  2. 제1항에 있어서, Rf가 직쇄 또는 측쇄의 2내지 20개의 탄소원자를 함유하는 퍼플루오로안킬라디칼 임을 특징으로 하는 윤활제.
  3. 제1항 또는 제2항에 있어서, Rf라디칼이 서로 다른 폴리플루오르 화합물의 혼합물을 함유함을 특징으로 하는 윤활제.
  4. 제1항 또는 제2항에 있어서, a가 0이고 c가 1 또는 2임을 특징으로 하는 윤활제.
  5. 제1항 또는 제2항에 있어서, m이 1이고 X가 비치환되거나 1-4개의 탄소원자를 함유하는 알킬 또는 알콕시기로 치환된 페닐라디칼임을 특징으로 하는 윤활제.
  6. 제1항 또는 제2항에 있어서, 하기 일반식으로부터 폴리플루오르 화합물이 선택됨을 특징으로 하는 화합물:
    상기 식에서, (b+c)합이 2이고, R1″는 수소원자 또는 메틸라디칼이며, R1′′′는 2-16의 짝수개 탄소원자를 함유하는 알킬라디칼이며, R3는 지방족, 지환족 또는 방향족 라디칼이다.
  7. 제1항 또는 제2항에 있어서, 폴리플루오르 화합물의 농도가 적어도 0.01중량%, 바람직하게는 0.05-0.5%임을 특징으로 하는 윤활제.
  8. 제1항 또는 제2항에 있어서, 폴리플루오르 화합물이 통상적인 첨가물과 결합되어 있음을 특징으로 하는 윤활제.
  9. 하기 일반식의 폴리설루오르 화합물:
    상기 식에서,
    Rf는 피플루오르라디칼을 표시하며,
    a는 0-10의 정수이며,
    b는 0또는 1이나 동시에 a가 0이고 c가 1일 때만 1이 될 수 있으며,
    c는 1-4사이의 정수이나, a가 0외에 다른 숫자이면 2이며,
    m 및 n은 각각 0또는 1이며,
    X는 임의로 치환된 아릴라디칼이며,
    Y는 2-히드록시-1-페닐에틸기를 표시하며
    R1및 R1′는 동일하거나 다를 수 있으며, 각각 수소원자, 1-20개의 탄소원자를 함유하는 알킬라디칼, 5 또는 6개의 탄소원자를 함유하는 시클로알킬라디칼 또는 임으로 치환된 아릴라디칼이며,
    R2및 R2′는 동일하거나 다를 수 있으며, 각각 수소원자 또는 지방족, 지환족 또는 방향족 카르복실산의 아실잔류물이며, a+m+n이 0이면, 기호 R1및 R2중 하나는 수소 또는 메틸라디칼 이외의 다른 라디칼이다.
  10. 제9항에 있어서, Rf가 직쇄 또는 측쇄의 2-20개 탄소원자를 함유하는 퍼플루오로알킬라디칼임을 특징으로 하는 화합물.
  11. 제9항 또는 제10항에 있어서, 하기 일반식을 가짐을 특징으로 하는 화합물:
    상기 식에서,(b+c)합이 2이고, R1″가 수소원자 또는 메틸라디칼이며, R3은 지방족, 지환족 또는 방향족 라디칼이다.
  12. 제9항 또는 제10항에 있어서, 하기 일반식을 가짐을 특징으로 하는 화합물:
    상기 식에서, (b+c)합이 2이고, R1′′′은 2-16의 짝수개 탄소원자를 함유하는 알킬라디칼이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870005433A 1986-05-30 1987-05-30 윤활제 KR900004515B1 (ko)

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FR86-0778 1986-05-30
FR7789 1986-05-30
FR8607789A FR2599378B1 (fr) 1986-05-30 1986-05-30 Lubrifiants et nouveaux composes polyfluores utilisables comme additifs

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KR870011232A true KR870011232A (ko) 1987-12-21
KR900004515B1 KR900004515B1 (ko) 1990-06-28

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CN (1) CN1015718B (ko)
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US4584404A (en) * 1974-01-10 1986-04-22 Eli Lilly And Company Substituted phenoxyphenylproply dimethylamines
FR2520377B1 (fr) * 1982-01-22 1985-09-13 Ugine Kuhlmann Application des amines a chaine polyfluoree comme additifs pour lubrifiants
FR2551454B1 (fr) * 1983-08-31 1986-06-27 Ugine Kuhlmann Compositions lubrifiantes contenant des fluorures de lithium, de calcium et/ou de baryum

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EP0248697B1 (fr) 1990-08-08
NO871809D0 (no) 1987-04-30
IL82067A0 (en) 1987-10-20
CN1015718B (zh) 1992-03-04
NO871809L (no) 1987-12-01
TR23509A (tr) 1990-02-14
FR2599378B1 (fr) 1988-07-29
JPH01131139A (ja) 1989-05-24
EP0248697A1 (fr) 1987-12-09
PT84980B (pt) 1990-02-08
US4832859A (en) 1989-05-23
DK274387A (da) 1987-12-01
FR2599378A1 (fr) 1987-12-04
DE3764192D1 (de) 1990-09-13
JPS62290798A (ja) 1987-12-17
ZA873886B (en) 1988-01-27
JPH0210198B2 (ko) 1990-03-07
CA1277994C (fr) 1990-12-18
JPH0686412B2 (ja) 1994-11-02
DK274387D0 (da) 1987-05-29
GR870841B (en) 1987-09-24
CN87103969A (zh) 1987-12-16
PT84980A (fr) 1987-06-01
FI872355A (fi) 1987-12-01
KR900004515B1 (ko) 1990-06-28
FI872355A0 (fi) 1987-05-27
ES2005603A6 (es) 1989-03-16
AU589777B2 (en) 1989-10-19
AU7364487A (en) 1987-12-03
IN169565B (ko) 1991-11-09
IL82067A (en) 1991-03-10

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