KR870010000A - 살균제 - Google Patents

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KR870010000A
KR870010000A KR870003495A KR870003495A KR870010000A KR 870010000 A KR870010000 A KR 870010000A KR 870003495 A KR870003495 A KR 870003495A KR 870003495 A KR870003495 A KR 870003495A KR 870010000 A KR870010000 A KR 870010000A
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KR870003495A
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KR950003924B1 (ko
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마가렛트 안토니 비비엔
마틴 클라우 존
디프레인 폴
리차드 엘리스 고프레이 크리스토퍼
젤프 크라우리 패트릭
안더톤 켄네스
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알란 브라이안 백
임페리알 케미칼 인더스트리스 피엘씨
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Priority claimed from GB878701627A external-priority patent/GB8701627D0/en
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Abstract

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Description

살균제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 구조식(1)을 가지는 화합물, 그것의 입체 이성체 및 금속 착물.
    식중, W는 R1O2C-C=CH-ZR2,
    R1및 R2는 같거나 다르고, 알킬 또는 플루오로알킬그룹,
    Z는 산소 또는 황 원자중 하나,
    A, B, D 및 E는 같거나 다르고, 수소 또는 할로겐원자, 또는 하이드록시, 임의 치환 알킬, 임의 치환알콕시, 임의 치환 아랄킬, 임의 치환 아릴알콕시, 임의 치환 알케닐, 임의 치환 알키닐, 임의 치환 아릴, 임의 치환 아릴옥시, 임의 치환 아릴티오, 임의 치환 헤테로 아열옥시, 임의 치환 헤테로 아릴티오, 임의 치환 아실옥시, 임의 치환 아미노, 임의 치환 아릴아조, 임의 치환 아실아미노, 니트로, 시아노 -CO2R3, -CONR3R4, -COR3, -CR3=NR4, -N=CR3R4또는 -S(O)nR3그룹,
    A, B, D 및 E의 둘은 환의 근접 위치에 있을 때 임의로 결합하여 하나 이상의 헤테로 원자를 임의로 포함하는 방향족 또는 지방족 같은 축합환을 형성,
    n은 0, 1 또는 2,
    R3및 R4는 같거나 다르고, 수소 원자 또는 알킬, 사이클로알킬, 이클로알킬알킬, 알케닐, 알키닐, 임의 치환 아릴 또는 임의 치환 아랄킬 그룹.
  2. 제1항에 있어서, A, B, D 및 E가 수소, 할로겐 C1-4알킬, 트리플루오로메틸,
    C1-4알콕시, 트리플루오로메톡시, 아랄킬, -COOR3(R3는 C1-4알킬 또는 아릴), 아릴옥시,아릴티오, 헤테로아릴옥시, 헤테로아릴티오, 벤질옥시, 벤질티오 및 페닐 시메틸로 구성되는 그룹에서 선택되고, 모두가 할로겐, 시아노, 니트로, C1-4알킬, C1-4알콕시, 트리플루오로메틸 및 트리플루오로메톡시로 구성되는 그룹에서 선택된 하나 이상의 환 치환체를 가지는 화합물.
  3. 제1항 또는 제2항에 있어서, A, B, D 및 E의 최소한 하나가 수소가 아니고 치환체 W에 대하여 피리딘 환오르토 위치에 있는 화합물.
  4. 전기한 항의 어느 한 항에 있어서, R1및 R2가 둘다 메틸인 화합물.
  5. 전기한 항의 어느 한 항에 있어서, Z가 산소인 화합물.
  6. 구조식(2)를 가지는 화합물.
    식중, 아크릴레이트 그룹에 대하여 오르토 위치에 있는, A는 페녹시(하나 이상의 플루오로, 클로로, 브로모, 메틸, 메톡시, 트리플루오로메틸, 트리플루오로메톡시, 시아노 또는 니트로로 임의 치환), 페닐티오, 벤질, 페닐에틸, 페닐에테닐(E)-또는 (Z)-이성체 중 하는), 벤질옥시, 페닐옥시메틸, 벤질티오, -COOR3(R3는 메틸, 에틸, 알릴 또는 페닐), 피리디닐-, 피리미디닐- 또는 피라지닐-옥시 또는-티오(클로로, 브로모 또는 트리플루오로메틸로 임의 치환), 또는 벤족사졸일-옥시 또는-티오.
  7. (1) G가 금속 원자인 구조식(3)의 화합물을
    적당한 용매내에서 R2L화합물로 처리하거나, 또는 G가 수소인 구조식(3)의 화합물을 적당한 용매내에서 염기 및 R2L 화합물로 처리하거나 ; 또는
    (2) 구조식(12)의 화합물로 부터 산성 또는 염기성
    조건 하에 알카놀 R2ZH를 제거하거나 ; 또는
    (3) 구조식(7)의 알파-케토 에스테르를 적당한 용매내
    에서 Ph3P=CHZR2의 인 일리드로 처리하거나 ; 또는A가 임의 치환 페녹시메틸, 페닐티오메틸, 알콕시메틸, 알킬티오메틸 또는 하이드록시메틸 그룹일 때,
    (4) 구조식(15)의 화합물을 적당한 용매내에서 염기의
    존재하에 임의 치환 페놀 또는 티오페놀과 반응시키거나 또는 알콕사이드, 알킬티올레이트 또는 하이드록사이드 이온과 반응시키거나; 또는 A가 임의 치환 알케닐 또는 -CHR5=CR6R7의 페닐알케닐일 때,
    (5) 구조식(16)의 화합물을 적당한 용매내에서 염기로
    처리하고, 구조식(17)의 화합물로 처리하는 것으로 구성되는,
    식중, A, B, D, E, R1, R2, R3및 Z는 다른 언급이 없는한 제1항의 정의와 같고,
    G는 수소 또는 금속 원자,
    L은 이탈 그룹,
    Ph는 페닐,
    R5는 수소, C1-4알킬 또는 임의 치환 페닐,
    R6및 R7은 수소, C1-8알킬, 할로알킬, 임의 치환 페닐 또는 CO2R3,
    Y는 -P(O)(OR8)2또는 -P+Ar3,
    R8은 C1-4알킬,
    Ar은 임의 치환 페닐
    제1항에 따르는 화합물을 제조하는 방법.
  8. 구조식(3)-(5), (7) 및 (12)-(16)의 중간 생성물.
  9. 활성 성분으로서 제1항의 화합물 및 살균적으로 허용 가능한 담체 또는 희석제로 구성되는 살균 조성물.
  10. 제1항의 화합물 또는 제9항의 조성물을 식물 또는 씨 또는 그것의 소재지에 사용하는 것으로 구성되는, 균류를 공격하는 방법.
  11. 제1항의 살충/살선충 화합물이 담체 또는 희석제와 결합된 것으로 구성되는 살충/살선충 조성물.
  12. 제1항 구조식(1)의 살충/살선충 화합물의 유효량 또는 제11항의 조성물을 곤충 또는 산충 또는 그것의 소재지에 투약하는 것으로 구성되는, 곤충 및 선충을 박멸 또는 조절하는 방법.
  13. 제1항 구조식(1)의 식물 생장 조절 화합물 및 담체 또는 희석제로 구성되는 구조식(1)의 식물 생장 조절 조성물.
  14. 제1항 구조식(1)의 식물 생장 조절 화합물 또는 제13항의 조성물을 식물 또는 식물의 씨 또는 그것의 소재지에 사용하는 것으로 구성되는, 식물 생장을 조절하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870003495A 1986-04-17 1987-04-13 살균제의 제조방법 KR950003924B1 (ko)

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GB868609456A GB8609456D0 (en) 1986-04-17 1986-04-17 Fungicides
GB878701627A GB8701627D0 (en) 1987-01-26 1987-01-26 Fungicides
GB8701627 1987-01-26

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GB8724251D0 (en) * 1987-10-15 1987-11-18 Ici Plc Chemical process
US5264440A (en) * 1989-02-10 1993-11-23 Imperial Chemical Industries Plc Fungicides
DE3904931A1 (de) * 1989-02-17 1990-08-23 Bayer Ag Pyridyl-substituierte acrylsaeureester
GB8908875D0 (en) * 1989-04-19 1989-06-07 Ici Plc Fungicides
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EP0243012A2 (en) 1987-10-28
JPH0819102B2 (ja) 1996-02-28
DK187687A (da) 1987-10-18
HUT43240A (en) 1987-10-28
GR3006778T3 (ko) 1993-06-30
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DE3783503T2 (de) 1993-05-13
AU609036B2 (en) 1991-04-26
EP0243012B1 (en) 1993-01-13
AU7135587A (en) 1987-10-22
CA1288094C (en) 1991-08-27
NZ219858A (en) 1989-10-27
DE3783503D1 (de) 1993-02-25
US5112386A (en) 1992-05-12
CN87103544A (zh) 1988-04-06
ES2053533T3 (es) 1994-08-01
US4826531A (en) 1989-05-02
DK187687D0 (da) 1987-04-10
JPS62255478A (ja) 1987-11-07
DK164595B (da) 1992-07-20
CN1022885C (zh) 1993-12-01

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