KR870007227A - 온도에 안전한 액체 조성물 - Google Patents
온도에 안전한 액체 조성물 Download PDFInfo
- Publication number
- KR870007227A KR870007227A KR870000065A KR870000065A KR870007227A KR 870007227 A KR870007227 A KR 870007227A KR 870000065 A KR870000065 A KR 870000065A KR 870000065 A KR870000065 A KR 870000065A KR 870007227 A KR870007227 A KR 870007227A
- Authority
- KR
- South Korea
- Prior art keywords
- phenylenediamine
- dinitro
- composition
- group
- phenyl
- Prior art date
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- 239000007788 liquid Substances 0.000 title claims 3
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims 13
- UFBJCMHMOXMLKC-UHFFFAOYSA-N 2,4-dinitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O UFBJCMHMOXMLKC-UHFFFAOYSA-N 0.000 claims 13
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 9
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 9
- 239000002904 solvent Substances 0.000 claims 9
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 5
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 4
- ZJNLYGOUHDJHMG-UHFFFAOYSA-N 1-n,4-n-bis(5-methylhexan-2-yl)benzene-1,4-diamine Chemical compound CC(C)CCC(C)NC1=CC=C(NC(C)CCC(C)C)C=C1 ZJNLYGOUHDJHMG-UHFFFAOYSA-N 0.000 claims 3
- PWNBRRGFUVBTQG-UHFFFAOYSA-N 1-n,4-n-di(propan-2-yl)benzene-1,4-diamine Chemical compound CC(C)NC1=CC=C(NC(C)C)C=C1 PWNBRRGFUVBTQG-UHFFFAOYSA-N 0.000 claims 3
- OUBMGJOQLXMSNT-UHFFFAOYSA-N N-isopropyl-N'-phenyl-p-phenylenediamine Chemical group C1=CC(NC(C)C)=CC=C1NC1=CC=CC=C1 OUBMGJOQLXMSNT-UHFFFAOYSA-N 0.000 claims 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 3
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims 3
- 239000008096 xylene Substances 0.000 claims 3
- HOYRZHJJAHRMLL-UHFFFAOYSA-N 2,6-dinitro-p-cresol Chemical compound CC1=CC([N+]([O-])=O)=C(O)C([N+]([O-])=O)=C1 HOYRZHJJAHRMLL-UHFFFAOYSA-N 0.000 claims 2
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 150000004985 diamines Chemical class 0.000 claims 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 2
- MHKBMNACOMRIAW-UHFFFAOYSA-N 2,3-dinitrophenol Chemical class OC1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O MHKBMNACOMRIAW-UHFFFAOYSA-N 0.000 claims 1
- -1 dinitro phenyl Chemical group 0.000 claims 1
- FSWDLYNGJBGFJH-UHFFFAOYSA-N n,n'-di-2-butyl-1,4-phenylenediamine Chemical compound CCC(C)NC1=CC=C(NC(C)CC)C=C1 FSWDLYNGJBGFJH-UHFFFAOYSA-N 0.000 claims 1
- 150000004986 phenylenediamines Chemical class 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/32—Compounds containing nitrogen bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/13—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups
- C07C205/26—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups and being further substituted by halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/13—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups
- C07C205/20—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C07C205/21—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring
- C07C205/23—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by hydroxy groups having nitro groups and hydroxy groups bound to carbon atoms of six-membered aromatic rings having nitro groups and hydroxy groups bound to carbon atoms of the same non-condensed six-membered aromatic ring having two nitro groups bound to the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/20—Use of additives, e.g. for stabilisation
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (17)
- 방향족 탄화수소 용매에 용해된 하기 일반식의 디니트로 페놀로 구성되며 :(여기서 R 및 R1중의 하나는 니트로이며 다른 것은 수소, 염소 및 C1-C8알킬로 구성되어 있는 군으로 부터 선택된다)상기 용매내에 용해된 디니트로 페놀의 양이, 페닐렌 디아민이 존재하지 않을 경우에 상기 용매내에 용해될 수 있는 디니트로 페닐의 양보다 클 정도로 충분한 양의 하기 일반식의 페닐렌디아민을 더 포함하여 구성되는 엑체 조성물.(여기서 R2및 R3는, 수소, C1-C12알킬, 페닐 및 C1-C|8알킬로 치환된 페닐로 구성되어 있는 군으로부터 각각 독립적으로 선택된다)
- 제1항에 있어서, 디니트로 페놀이 2,6-디니트로-P-크레졸, 4,6-디니트로-0-크레졸, 2,6-디니트로-P-이소프로필 페놀, 4,6-디니트로-0-이소프로필페놀 및 4,6-디니트로-0-sec-부틸페놀로 구성되어 있는 군으로 부터 선택된 조성물.
- 제1항에 있어서, 페닐렌디아민이 N-페닐-N′-이소프로필-P-페닐렌디아민, N-레닐-N′-(1,3-디메틸부틸)-P-페닐렌디아민, N-페닐-N′-(1,3-디메틸펜틸)-P-페닐렌디아민, N,N′-디이소프로필-P-페닐렌디아민, N,N′-디-sec-부틸-P-페닐렌디아민 및 N,N′-비스(1,4-디메틸펜틸)-P-페닐렌디아민으로 구성되어 있는 군으로 부터 선택된 조성물.
- 제1항에 있어서, 방향족 탄화수소 용매가 벤젠, 톨루엔, 크실렌, 에틸벤젠, 스티렌, 비닐톨루엔, 디비닐벤젠 및 알파-메틸스티렌으로 구성되어 있는 군으로 부터 선택된 조성물.
- 제4항에 있어서, 방향족 탄화수소가 스티렌 및 에틸벤젠으로 구성되어 있는 군으로 선택된 조성물.
- 제1항에 있어서, 디니트로페놀+페닐렌디아민:방향족 탄화수소 용매의 중량비가 약 1:4-약 2:1인 조성물.
- 제1항에 있어서, 디니트로페놀:페닐렌디아민의 중량비가 약 2:3-3:2인 조성물.
- 하기 A,B,C로 구성되는 저온 안정성 액체 조성물.A) 하기 일반식의 디니트로페놀:여기서, R 및 R1중의 하나는 니트로이며 다른 것은 수소, 염소 및 C1-C8알킬로 구성되어 있는 군으로 부터 선택된다;B) 하기 일반식의 페닐렌디아민 :여기서 R2및 R3는 수소, C1-C12알킬, 페닐 및 C1-C|8알킬로 치환된 페닐로 구성되어 있는 군으로 부터 각각 독립적으로 선택된다 ; 및C) 방향족 탄화수소 용매 ; 여기서 성분 A:성분 B는 약 1:9-약 9:1 ; 및 여기서 성분 A+성분 B:성분 C는 최소한 약 1:10
- 제8항에 있어서, 디니트로페놀이 2,6-디니트로-P-크레줄, 4,6-디니트로-0-클레졸, 2,6-디니트로-P-이소프로필페놀, 4,6-디니트로-0-이소프로필레놀 및 4,6-디니트로-0-sec-부틸페놀로 구성되어 있는 군으로 부터 선택된 조성물.
- 제8항에 있어서, 페닐렌디아민이 N-페닐-N′-이소프로필-P-페닐렌디아민, N-페닐-N′-(1,3-디메틸부틸)-P-페닐렌디아민, N-페닐-N′-(1,3-디메틸펜틸)-P-페닐렌디아민, N,N′-디이소프로필-P-페닐렌디아민, N,N′-디-sec-부틸-P-페닐렌디아민 및 N,N′-비스(1,4-디메틸펜틸)-P-페닐렌디아민으로 구성되어 있는 군으로 부터 선택된 조성물.
- 제8항에 있어서, 방향족 탄화수소 용매가 벤젠, 톨루엔, 크실렌, 에틸벤젠, 스티렌, 비닐톨루엔, 디비닐벤젠 및 알파-메틸스티렌으로 구성되어 있는 군으로 부터 선택된 조성물.
- 제8항에 있어서, 방향족 탄화수소가 스티렌 및 에틸벤젠으로 구성되어 있는 군으로 부터 선택된 조성물.
- 제8항에 있어서, 디니트로페놀+페닐렌디아민:방향족 탄화수소 용매의 중량비가 약 1:4-약 2:1인 조성물.
- 제8항에 있어서, 디니트로페놀:페닐렌디아민의 중량비가 약 2:3-3:2인 조성물.
- 제8항에 있어서, 디니트로페놀이 2,6-디니트로-P-크레졸, 4,6-디니트로-0-클레졸, 2,6-디니트로-P-이소프로필페놀, 4,6-디니트로-0-이소프로필페놀 및 4,6-디니트로-0-sec-부틸페놀로 구성되어 있는 군으로 부터 선택되고, 페닐렌디아민이 N-페닐-N′-이소프로필-P-페닐렌디아민, N-페닐-N′-(1,3-디메틸부틸)-P-페닐렌디아민, N-페닐-N′-(1,3-디메틸펜틸)-P-페닐렌디아민, N,N′-디이소프로필-P-페닐렌디아민, N,N′- 디-sec-부틸-P-페닐렌디아민 및 N,N′-비스(1,4-디메틸펜틸)-P-페닐렌디아민으로 구성되어 있는 군으로 구성되어 있는 군으로 부터 선택되고 방향족 탄화수소 용매가 벤젠, 톨루엔, 크실렌, 에틸벤젠, 스티렌, 비닐톨루엔, 디비닐벤젠 및 알파-메틸스티렌으로 구성되어 있는 군으로 부터 선택된 조성물.
- 제15항에 있어서, 디니트로페놀+페닐렌디아민 : 방향족 탄화수소 용매의 중량비가 약 1:4-약 2:1인 조성물.
- 제15항에 있어서, 디니트로페놀:페닐렌디아민의 중량비가 약 2:3-3:2인 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US817324 | 1986-01-09 | ||
US06/817,324 US4664845A (en) | 1986-01-09 | 1986-01-09 | Phenylenediamine solubilizer for dinitrophenol in aromatic solvent |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870007227A true KR870007227A (ko) | 1987-08-17 |
KR910004552B1 KR910004552B1 (ko) | 1991-07-06 |
Family
ID=25222823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870000065A KR910004552B1 (ko) | 1986-01-09 | 1987-01-08 | 온도에 안정한 액체 조성물 |
Country Status (18)
Country | Link |
---|---|
US (1) | US4664845A (ko) |
EP (1) | EP0234671B1 (ko) |
JP (1) | JPH01152146A (ko) |
KR (1) | KR910004552B1 (ko) |
CN (1) | CN1004139B (ko) |
AR (1) | AR245096A1 (ko) |
AT (1) | ATE63534T1 (ko) |
AU (1) | AU595571B2 (ko) |
BR (1) | BR8700050A (ko) |
CA (1) | CA1275168C (ko) |
DE (1) | DE3770019D1 (ko) |
DK (1) | DK11387A (ko) |
ES (1) | ES2022880B3 (ko) |
FI (1) | FI84906C (ko) |
IN (1) | IN166453B (ko) |
MX (1) | MX165080B (ko) |
PT (1) | PT84086B (ko) |
ZA (1) | ZA8769B (ko) |
Families Citing this family (12)
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US4915873A (en) * | 1988-01-22 | 1990-04-10 | Uniroyal Chemical Company, Inc. | Polymerization inhibitor composition for vinyl aromatic compounds |
DE3825163A1 (de) * | 1988-07-23 | 1990-02-01 | Wella Ag | Verwendung von 2,6-dinitro-phenol-derivaten in haarfaerbemitteln |
US5312952A (en) * | 1992-04-23 | 1994-05-17 | Uniroyal Chemical Company, Inc. | Polymerization inhibitor for vinyl aromatics |
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US6339177B1 (en) * | 2000-05-24 | 2002-01-15 | Sea Lion Technology, Inc. | Dinitroalkyl aromatics polymerization retarders or inhibitors and methods for making and for using same |
US20060069219A1 (en) * | 2004-09-28 | 2006-03-30 | Vilan Kosover | Sulfonated phenols with nitrophenols as polymerization inhibitors |
US8098683B2 (en) * | 2004-10-06 | 2012-01-17 | Broadcom Corporation | Method and system for implementing a single weight (SW) single channel (SC) MIMO system with no insertion loss |
US20080200616A1 (en) * | 2004-11-15 | 2008-08-21 | Seiji Tanizaki | Method of Inhibiting Polymerization Giving Copolymer of Divinylbenzene and Aromatic Vinyl Compound |
US7696290B2 (en) * | 2004-12-03 | 2010-04-13 | Crompton Corporation | Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosanilines as polymerization inhibitors |
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US2526567A (en) * | 1948-07-06 | 1950-10-17 | Dow Chemical Co | Stabilization of nuclear chlorostyrenes by 2, 6-dinitrophenols |
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US3366702A (en) * | 1965-05-03 | 1968-01-30 | Marathon Oil Co | Preparation of unsaturated hydrocarbons by pyrolysis, and related compositions |
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FR2142369A5 (ko) * | 1971-06-18 | 1973-01-26 | Huels Chemische Werke Ag | |
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US4457806A (en) * | 1982-06-28 | 1984-07-03 | The Sherwin-Williams Company | Process for vinyl aromatic monomer polymerization inhibition |
US4466905A (en) * | 1983-04-11 | 1984-08-21 | Cosden Technology, Inc. | Polymerization inhibition process for vinyl aromatic compounds |
US4468343A (en) * | 1983-04-11 | 1984-08-28 | Cosden Technology, Inc. | Polymerization co-inhibitors for vinyl aromatic compounds |
US4568711A (en) * | 1984-12-07 | 1986-02-04 | The Firestone Tire & Rubber Company | Synergistic additive combination for guayule rubber stabilization |
US4654451A (en) * | 1985-12-27 | 1987-03-31 | Atlantic Richfield Company | Inhibiting polymerization of vinyl aromatic monomers |
-
1986
- 1986-01-09 US US06/817,324 patent/US4664845A/en not_active Expired - Lifetime
- 1986-03-07 IN IN212/DEL/86A patent/IN166453B/en unknown
-
1987
- 1987-01-06 AT AT87300037T patent/ATE63534T1/de not_active IP Right Cessation
- 1987-01-06 AU AU67177/87A patent/AU595571B2/en not_active Ceased
- 1987-01-06 ZA ZA8769A patent/ZA8769B/xx unknown
- 1987-01-06 DE DE8787300037T patent/DE3770019D1/de not_active Expired - Fee Related
- 1987-01-06 ES ES87300037T patent/ES2022880B3/es not_active Expired - Lifetime
- 1987-01-06 EP EP87300037A patent/EP0234671B1/en not_active Expired - Lifetime
- 1987-01-07 CA CA000526832A patent/CA1275168C/en not_active Expired - Fee Related
- 1987-01-08 KR KR1019870000065A patent/KR910004552B1/ko not_active IP Right Cessation
- 1987-01-08 BR BR8700050A patent/BR8700050A/pt not_active IP Right Cessation
- 1987-01-08 FI FI870071A patent/FI84906C/fi not_active IP Right Cessation
- 1987-01-08 CN CN87100819.XA patent/CN1004139B/zh not_active Expired
- 1987-01-09 DK DK011387A patent/DK11387A/da not_active Application Discontinuation
- 1987-01-09 JP JP62003094A patent/JPH01152146A/ja active Granted
- 1987-01-09 PT PT84086A patent/PT84086B/pt not_active IP Right Cessation
- 1987-01-09 AR AR87306440A patent/AR245096A1/es active
- 1987-01-09 MX MX4906A patent/MX165080B/es unknown
Also Published As
Publication number | Publication date |
---|---|
ZA8769B (en) | 1987-08-26 |
IN166453B (ko) | 1990-05-12 |
PT84086A (en) | 1987-02-01 |
DK11387D0 (da) | 1987-01-09 |
EP0234671B1 (en) | 1991-05-15 |
FI84906C (fi) | 1992-02-10 |
PT84086B (pt) | 1989-02-28 |
CN1004139B (zh) | 1989-05-10 |
BR8700050A (pt) | 1987-12-01 |
AR245096A1 (es) | 1993-12-30 |
CN87100819A (zh) | 1987-09-23 |
US4664845A (en) | 1987-05-12 |
AU595571B2 (en) | 1990-04-05 |
ATE63534T1 (de) | 1991-06-15 |
KR910004552B1 (ko) | 1991-07-06 |
FI84906B (fi) | 1991-10-31 |
CA1275168C (en) | 1990-10-16 |
EP0234671A1 (en) | 1987-09-02 |
FI870071A0 (fi) | 1987-01-08 |
DE3770019D1 (de) | 1991-06-20 |
FI870071A (fi) | 1987-07-10 |
AU6717787A (en) | 1987-07-16 |
JPH0588699B2 (ko) | 1993-12-24 |
ES2022880B3 (es) | 1991-12-16 |
JPH01152146A (ja) | 1989-06-14 |
DK11387A (da) | 1987-07-10 |
MX165080B (es) | 1992-10-21 |
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