KR870000301A - N-플루오로피리디늄 염의 제조방법 - Google Patents

N-플루오로피리디늄 염의 제조방법 Download PDF

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KR870000301A
KR870000301A KR1019860004407A KR860004407A KR870000301A KR 870000301 A KR870000301 A KR 870000301A KR 1019860004407 A KR1019860004407 A KR 1019860004407A KR 860004407 A KR860004407 A KR 860004407A KR 870000301 A KR870000301 A KR 870000301A
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aryl
alkoxy
aryloxy
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데루오 우메모또
기요이찌 도미따
고오스께 가와다
긴지로 도미사와
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오노다 세멘또 가부시끼가이샤
원본미기재
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Abstract

내용 없음.

Description

N-플루오로피리디늄 염의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (2)

  1. 하기 일반식(Ⅱ)의 피리딘 화합물의 불소와 더불어 하기 일반식(Ⅲ)의 브뢴스테드산-화합물과 반응시킴을 특징으로 하는 하기 일반식(Ⅰ)의 N-플루오로피리디늄의 제조방법.
    [상기 식중, R¹, R², R³, R⁴및 R5, 수소원자, 할로겐원자, 알킬, 아릴, 아실, 알콕시카르보닐, 아릴옥시카르보닐, 카르바모일, 니트로, 시아노, 알킬설포닐, 알릴설포닐, 히드록시, 알콕시, 아실옥시, 아실티오, 아미도, 알칸설포닐옥시 또는 아렌설포닐옥시기를 나타내고; X는 수소 할로겐화물의 짝염기인 F, C1, Br및 I를 제외한 브뢴스테드산의 짝염기를 나타내고; R¹, R², R³, R⁴및 R 는 직접 또는 헤테로원자를 통하여 다양하게 결합함으로써 고리구조를 형성할 수 있으며, X 는 직접 또는 헤테로 원자를 통하여 R¹, R², R³, R⁴및 R5와 다양하게 결합할 수 있고; M은 수소원자, 금속원자, 암모늄잔기, 피리디늄잔기 또는 기 SiR6R7R8(식중, R6, R7및 R8은 알킬, 아릴, 알콕시, 아릴옥시, 아릴옥시기를 나타낸다.) 또는 할로겐 원자를 나타낸다.]
  2. 하기 일반식(Ⅲ)의 피리딘 화합물을 불소와 더불어 하기 일반식(Y)의 루이스산 과반응시킴을 특징으로 하는 하기 일반식(I')의 N-플루오로피리디늄염의 제조방법.
    [상기 식중, R¹, R², R³, R⁴및 R5은 수소원자, 할로겐원자, 알킬, 아릴, 아실, 알콕시카르보닐, 아릴옥시카르보닐, 카르바모일, 니트로, 시아노, 알킬설포닐, 아릴설포닐, 히드록시, 알콕시, 아릴옥시, 아실옥시, 아실티오, 아미도, 알칸설포닐옥시 또는 아렌설포닐옥시기를 나타내고; Y는 루이스산을 나타낸다.]
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860004407A 1985-06-03 1986-06-03 N-플루오로피리디늄 염의 제조방법 KR930004650B1 (ko)

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JP60-118882 1985-06-03
JP11888285 1985-06-03
JP118882 1985-06-03
JP61-48450 1986-03-07
JP4845086 1986-03-07
JP48450 1986-03-07

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KR870000301A true KR870000301A (ko) 1987-02-17
KR930004650B1 KR930004650B1 (ko) 1993-06-02

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EP (1) EP0204535B1 (ko)
KR (1) KR930004650B1 (ko)
CA (1) CA1288777C (ko)
DE (1) DE3686444T2 (ko)

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EP0204535B1 (en) 1992-08-19
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US4996320A (en) 1991-02-26
KR930004650B1 (ko) 1993-06-02
EP0204535A1 (en) 1986-12-10
DE3686444T2 (de) 1993-02-18

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