KR860008264A - Fabric-Flexible Antistatic Nonionic Detergent Composition Containing Sulfosuccinamate Detergent - Google Patents

Fabric-Flexible Antistatic Nonionic Detergent Composition Containing Sulfosuccinamate Detergent Download PDF

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KR860008264A
KR860008264A KR1019860002682A KR860002682A KR860008264A KR 860008264 A KR860008264 A KR 860008264A KR 1019860002682 A KR1019860002682 A KR 1019860002682A KR 860002682 A KR860002682 A KR 860002682A KR 860008264 A KR860008264 A KR 860008264A
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compound
detergent
detergent composition
alkyl
composition
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유우진 윅슨 해롤드
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에이치 에스 실베스터
콜게이트-파아므 올리브 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/42—Amino alcohols or amino ethers
    • C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Abstract

내용 없음No content

Description

설포석시나메이트 세제를 함유하는 직물유연성 대전방지성 비이온 세제조성물Fabric-Flexible Antistatic Nonionic Detergent Composition Containing Sulfosuccinamate Detergent

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (20)

비이온 세제, 모노고급알킬 4급 암모늄 화합물 직물 유연제-대전방지제 및 설포석시나메이트 세제화합물로 구성된 세제 조성물.A detergent composition comprising a nonionic detergent, a monohigher alkyl quaternary ammonium compound fabric softener-antistatic agent and a sulfosuccinamate detergent compound. 제 1항에 있어서, 직쇄 고급 알킬 방향족 설포네이트, 폴리(저급 알콕시) 고급알칸올설페트, 올레핀 설포네이트 및 파라핀 설포네이트로 구성된 군으로부터 선택된 음이온 계면 활성제를 포함하는 세제 조성물.The detergent composition of claim 1 comprising an anionic surfactant selected from the group consisting of straight chain higher alkyl aromatic sulfonates, poly (lower alkoxy) higher alkanolsulfates, olefin sulfonates and paraffin sulfonates. 제 1항에 있어서, 설포석시나메이트 세제 화합물이 하기 구조식(V)의 화합물인 세제 조성물.The detergent composition according to claim 1, wherein the sulfosuccinamate detergent compound is a compound of the following structural formula (V). 상기식에서,In the above formula, Z은 1가 염형성양이온이며, R4는 수소, 저급알킬, 카복시(저급알킬) 또는 1,2-디카복실(저급알킬)이며, R5는 C10-C22의 개쇄 탄화수소이다.Z is a monovalent salt forming cation, R 4 is hydrogen, lower alkyl, carboxy (lower alkyl) or 1,2-dicarboxyl (lower alkyl), and R 5 is a C 10 -C 22 branched hydrocarbon. 제3항에 있어서, 구조식(V)에서, Z이 알칼리금속, 암모늄 또는 아민이며, R4가 수소, 메틸, 에틸, 카복시메틸, 카복시에틸, 1,2-디카복시메틸 또는 1,2-디카복시에틸이며 R5가 포화 또는 불포화, 직쇄 또는 분지쇄의 약 C14-C18의 알킬 또는 알케닐기인 세제 조성물.4. A compound according to claim 3, wherein in formula (V) Z is an alkali metal, ammonium or amine, and R 4 is hydrogen, methyl, ethyl, carboxymethyl, carboxyethyl, 1,2-dicarboxymethyl or 1,2-dica Detergent composition wherein the compound is cyclic ethyl and R 5 is a saturated or unsaturated, straight or branched alkyl or alkenyl group of about C 14 -C 18 . 제 1항에 있어서, 설포석시나메이트 세제 화합물이 디나트륨N-옥타데실설포석시나메이트, 디나트륨 N-올레일설포석시나메이트 또는 테트라나트륨 N-(1,2-디카복시에틸) N-옥타데실 설포석시나메이트인 세제 조성물.The method of claim 1, wherein the sulfosuccinamate detergent compound is disodium N-octadecylsulfosuccinamate, disodium N-oleylsulfosuccinamate or tetrasodium N- (1,2-dicarboxyethyl) N-octa A detergent composition that is decyl sulfosuccinate. 제 1항에 있어서, 약 10-50%의 비이온계면 활성제, 약 1-10%의 모노알킬 4급 화합물 및 약 1-l0% 의 설포콕시나메이트 화합물로 구성된 세제 조성물.The detergent composition of claim 1, wherein the detergent composition consists of about 10-50% nonionic surfactant, about 1-10% monoalkyl quaternary compound, and about 1-10% sulfokoxinate compound. 제 6항에 있어서, 약 12-35%의 비이온 계면 활성제, 약 2-6%의 모노알킬 4급 화합물 및 약 2-6% 의 설포석시나메이트 화합물로 구성된 세제 조성물.7. The detergent composition of claim 6, consisting of about 12-35% nonionic surfactant, about 2-6% monoalkyl quaternary compound and about 2-6% sulfosuccinate compound. 제6항에 있어서, 직쇄 고급 알킬방향족설포네이트, 폴리(저급알콕시) 고급알칸을 설페이트, 올레핀설포네이트 및 파라핀 설포네이트로 구성된 군으로부터 선택된 음이온 계면활성제를 음이온에 대한 모노알킬4급의 비가 약 1.3 : 1-1 : 1.5이 되는 양만큼 포함하는 세제 조성물.7. The monoalkyl quaternary to anion ratio of claim 6, wherein the anionic surfactant selected from the group consisting of straight chain higher alkylaromatic sulfonates, poly (lower alkoxy) higher alkanes comprises sulfate, olefinsulfonate and paraffin sulfonate. : 1-1: Detergent composition containing by the amount used as 1.5. 제 8항에 있어서, 모노알킬 4급에 대한 비이온계면 활성제의 중량비가 약 15 : 1-2 : 1범위이며, 설포석시나메인트에 대한 모노알킬 4급의 중량비가 약 3 : 1-1 : 3범위인 세제 조성물.9. The method of claim 8 wherein the weight ratio of nonionic surfactant to monoalkyl quaternary is in the range of about 15: 1-2: 1, and the weight ratio of monoalkyl quaternary to sulfosuccinate is about 3: 1-1. : Detergent composition in the range of 3. 자동세탁기의 세척사이클에 첨가될 수 있는, 오염된 직물을 세탁하고 유연하게 하는데 사용되는 하기(A)-(J)로 구성된 수성액체 세제 조성물.An aqueous liquid detergent composition consisting of the following (A)-(J) used to wash and soften contaminated fabric, which can be added to a washing cycle of an automatic washing machine. (A) 하기 구조식(I) 및 (Ⅱ)의 화합물들로 구성된 군으로부터 선택된 액체 비이온 세제 약 10-50중량% ;(A) about 10-50% by weight of a liquid nonionic detergent selected from the group consisting of compounds of formulas (I) and (II): RO(CH2CH2O)nH (Ⅰ)RO (CH 2 CH 2 O) n H (I) 상기식에서,In the above formula, R은 C8-C22의 1급 또는 2급 알킬쇄이며,R is a primary or secondary alkyl chain of C 8 -C 22 , n은 평균 약 5-20이다.n is on average about 5-20. 상기식에서,In the above formula, R1은 C4-C15의 1급 또는 2급 알킬쇄이며,R 1 is a primary or secondary alkyl chain of C 4 -C 15 , m은 평균 약 5-20이다.m is on average about 5-20. (B) 하기구조식(Ⅲ) 또는 (Ⅳ)의 모노-고급 알킬 4급 암모늄 화합물 약 1-10중량% ;(B) about 1-10% by weight of the mono-higher alkyl quaternary ammonium compound of formula (III) or (IV); 상기식에서,In the above formula, R2는 C10-C22의 장쇄지방족 라디칼이며 ;R 2 is a long chain aliphatic radical of C 10 -C 22 ; 구조식(Ⅲ)에서 R3들과 구조식(Ⅳ)에서 R3는 각기 독립적으로 저급알킬 또는 하이드록시(저급알킬)이며 ;Structure (Ⅲ) in R 3 and structural formula (Ⅳ) in R 3 are each independently lower alkyl or hydroxy (lower alkyl); X는 수용성 염형성음이온이며 ;X is a water-soluble salt-forming anion; x와 y는 각기 적어도 1의 양수이며,x and y are each a positive integer of at least 1, x+y의 합은 2-15이다.The sum of x + y is 2-15. (C) 하기 구조식의 설포석시나메이트 세제 화합물 약 1-10중량%(C) about 1-10% by weight of sulfosuccinamate detergent compound of the following structural formula 상기식에서,In the above formula, Z은 1가 염형성양이온이며,Z is a monovalent salt forming cation, R4는 수소, 저급알킬, 카복시(저급알킬) 또는 1,2-디카복시(저급알킬)이며,R 4 is hydrogen, lower alkyl, carboxy (lower alkyl) or 1,2-dicarboxy (lower alkyl), R5는 C10-C22의 개쇄 탄화수소이다.R 5 is a C 10 -C 22 branched hydrocarbon. (D) 직쇄 고급알킬 방향족 설포네이트, 폴리-저급알콕시고급알칸올설페이트 및 파라핀설포네이트로 구성된 군으로부터 선택된 음이온 계면 활성제 약 10중량%까지(D) up to about 10% by weight of anionic surfactant selected from the group consisting of straight chain higher alkyl aromatic sulfonates, poly-lower alkoxy higher alkanolsulfates and paraffinsulfonates (E) 광학광택제 약 3%까지(E) up to about 3% of an optical varnish (F) 에톡실화아민 약 15%까지(F) up to about 15% ethoxylated amine (G) 알칼리성물질 약 5%까지(G) up to about 5% alkaline (H) 효소 약 3%까지(H) up to about 3% enzyme (I) 오염유리제 약 3%까지(I) up to about 3% of contaminated glass (J) 수성용매운반체.(J) Aqueous solvent carrier. 제10항에 있어서, 음이온 세제(D)가 (C) : (D)의 비 약 1.3 : 1-1 : 1.5로 존재하는 조성물.The composition of claim 10, wherein the anionic detergent (D) is present at a ratio of about 1.3: 1-1: 1: 1.5 of (C) :( D). 제10항에 있어서,The method of claim 10, (A) 약 12-35%(A) about 12-35% (B) 약 2-6%(B) about 2-6% (C) 약 2-6%(C) about 2-6% (D) (C) : (D)의 비가 약 1.2 : 1-1 : 1.2가 되는 양(D) Amount such that the ratio of (C): (D) is about 1.2: 1-1: 1.2 (E) 0.2-2중량%(E) 0.2-2% by weight (F) 약 10%까지(F) up to about 10% (G) 약 3%까지(G) up to about 3% (H) 약 2%까지(H) up to about 2% (I) 약 2%까지(I) up to about 2% (J) 나머지로 구성된 조성물.(J) A composition consisting of the rest. 제12항에 있어서,The method of claim 12, (A)가 구조식(I)의 화합물(여기서 R은 C12-C15알킬 또는 그 혼합물이며 n은 약 6-13의 수이다)이며 ;(A) is a compound of formula (I) wherein R is C 12 -C 15 alkyl or a mixture thereof and n is a number from about 6-13; (B)가 수지트리메틸암모늄 클로라이드이며,(B) is resin trimethylammonium chloride, (C)가 디나트륨 N-옥타데실설포석시나메이트, 디나트륨N-올레일 설포석시나메이트 또는 테트라나트륨 N-(1,2-디카복시에틸) N-옥타데실 설포석시네이트이며,(C) is disodium N-octadecylsulfosuccinate, disodium N-oleyl sulfosuccinamate or tetrasodium N- (1,2-dicarboxyethyl) N-octadecyl sulfosuccinate, (D)가 직쇄도데실벤젠설포네이트 또는 트리에텐옥시(C12-C15) 알칸올설페이트인 조성물.(D) The composition is linear dodecylbenzenesulfonate or trietheneoxy (C 12 -C 15 ) alkanol sulfate. 제10항에 있어서,The method of claim 10, (A) 구조식 (Ⅰ)의 화합물(여기서 R은 C10-C181급 또는 2급 알킬이며, n은 약 6-13임) 약 15-25%(A) a compound of formula (I), wherein R is C 10 -C 18 primary or secondary alkyl, n is about 6-13 about 15-25% (B) 구조식(Ⅱ)의 화합물(여기서 R2는 C12-C18지방족 라디칼이며, R3는 각기 메틸임) 약 2-6%(B) a compound of formula (II) wherein R 2 is a C 12 -C 18 aliphatic radical and R 3 is each methyl; about 2-6% (C) 구조식(Ⅴ)의 화합물(여기서 R5는 약 14-18개의 탄소원자를 함유하며 R4는 수소 또는 1,2-디카복시에틸임) 약 2-6%와 수성액체 운반체로 구성된 조성물.(C) a composition consisting of about 2-6% of a compound of formula (V) wherein R 5 contains about 14-18 carbon atoms and R 4 is hydrogen or 1,2-dicarboxyethyl and an aqueous liquid carrier. 제14항에 있어서, (B) : (C)의 비가 약 1 : 1-1 : 2범위인 조성물.The composition of claim 14 wherein the ratio of (B): (C) is in the range of about 1: 1-1-1: 2. 제14항에 있어서,The method of claim 14, (D) 직쇄 고급알킬 벤젠설포네이트 또는 폴리에톡시고급알칸올설페이트를 (C) : (D)의 비가 약 1.1 : 1-1 : 1.1이 되는 양만큼 포함하는 조성물.(D) A composition comprising a straight chain higher alkyl benzenesulfonate or polyethoxy higher alkanolsulfate in an amount such that the ratio of (C) :( D) is about 1.1: 1-1: 1.1. 제16항에 있어서, (B) : (C)의 비가 약 1.5 : 약 1-3 : 1범위인 조성물.The composition of claim 16 wherein the ratio of (B): (C) is in the range of about 1.5: about 1-3: 1. 오염된 직물을 제 1항의 세제 조성물 존재하에 수성 세탁욕중에서 접촉시키는 것으로 구성된 오염된직물을 세척하고 유연하게 하는 방법.A method of washing and softening a contaminated fabric consisting of contacting the contaminated fabric in an aqueous laundry bath in the presence of the detergent composition of claim 1. 제18항에 있어서, 세척사이클과 헹굼 사이클을 갖고 있는 자동세탁기내에서 접촉을 수행하며, 세제조성물을 세척사이클중 첨가하는 방법.19. The method of claim 18, wherein the contacting is carried out in an automatic washing machine having a wash cycle and a rinse cycle, and the detergent composition is added during the wash cycle. 제19항에 있어서, 적어도 세척 사이클중 수성 세탁액의 온도가 적어도 약 21℃인 방법.The method of claim 19, wherein the temperature of the aqueous wash liquor is at least about 21 ° C. during at least the wash cycle. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019860002682A 1985-04-10 1986-04-09 Fabric-Flexible Antistatic Nonionic Detergent Composition Containing Sulfosuccinamate Detergent KR860008264A (en)

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JP2557110B2 (en) * 1989-10-06 1996-11-27 花王株式会社 Detergent composition
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ZA974226B (en) * 1996-05-17 1998-12-28 Procter & Gamble Detergent composition
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US6617303B1 (en) 1999-01-11 2003-09-09 Huntsman Petrochemical Corporation Surfactant compositions containing alkoxylated amines
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JP6817067B2 (en) * 2014-02-25 2021-01-20 エルジー ハウスホールド アンド ヘルスケア リミテッド Fiber softener composition
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