KR860007302A - 고분자형 산화방지제 및 그의 제조방법 - Google Patents

고분자형 산화방지제 및 그의 제조방법 Download PDF

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KR860007302A
KR860007302A KR1019860001986A KR860001986A KR860007302A KR 860007302 A KR860007302 A KR 860007302A KR 1019860001986 A KR1019860001986 A KR 1019860001986A KR 860001986 A KR860001986 A KR 860001986A KR 860007302 A KR860007302 A KR 860007302A
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South Korea
Prior art keywords
friedel
producing
chloromethylstyrene
ethylphenol
cresol
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KR1019860001986A
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English (en)
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KR930012016B1 (ko
Inventor
요시가즈 아리마쓰
미노루 사이또오
가쓰야 다니
히데유끼 미다무라
겐이찌 가쓰오
아쓰시 가지
Original Assignee
도오요오 보오세끼 가부시끼가이샤
다끼자와 사부로오
도오요오 보오세끼가부시끼가이샤
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Priority claimed from JP60062899A external-priority patent/JPS61221284A/ja
Priority claimed from JP60138495A external-priority patent/JPS61296024A/ja
Application filed by 도오요오 보오세끼 가부시끼가이샤, 다끼자와 사부로오, 도오요오 보오세끼가부시끼가이샤 filed Critical 도오요오 보오세끼 가부시끼가이샤
Publication of KR860007302A publication Critical patent/KR860007302A/ko
Application granted granted Critical
Publication of KR930012016B1 publication Critical patent/KR930012016B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
    • C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/31—Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain
    • C08G2261/312—Non-condensed aromatic systems, e.g. benzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/34—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain
    • C08G2261/342—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3424—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms non-conjugated, e.g. paracyclophanes or xylenes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

내용 없음

Description

고분자형 산화방지제 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1도는 본 발명의 실시예 1에서 얻어지는 산화방지제의 적의 흡수 스펙트럼을 나타낸 도,

Claims (7)

  1. 주로 일반식(I) 및 (Ⅱ)
    (R은 메틸 또는 에틸기를 표시한다)로 표시되는 구성단위로 이루어지고 일반식(I)과 (Ⅱ)의 단위의 합계물이 전체의 50% 이상인 것을 특징으로 하는 고분자형 산화방지제.
  2. 제 1 항에 있어서, 수평균분자량이 1,000 내지 8,000인 것을 특징으로 하는 고분자형 산화방지제.
  3. p-크레졸 또는 p-에틸페놀, 클로로메틸스티렌 및 디비닐벤젠을 실질적으로 불활성인 용매중에서 프리델. 크라프트(Friedel-Crafts)촉매의 존재하에 반응시키는 것을 특징으로 하는 특허청구의 범위 제 1 항에 기재된 고분자형 산화방지제의 제조 방법.
  4. p-크레졸 또는 p-에틸페놀과 클로로메틸 스티렌을 실질적으로 불활성인 용매중에서 프리델. 크라프트 촉매의 존재하에 반응시키는 것을 특징으로 하는 특허청구의 범위 제 1 항에 기재된 고분자형 산화방지제의 제조 방법.
  5. 제 3 항 또는 제 4 항에 있어서 용매가 클로로벤젠인 것을 특징으로 하는 고분자형 산화 방지제의 제조방법.
  6. 제 3 항 또는 제 4 항에 있어서 프리델. 크라프트촉매가 염화 제 2 주석인 것을 특징으로 하는 고분자형 산화 방지제의 제조방법.
  7. 제 3 항 또는 제 4 항에 있어서, p-크레졸 또는 p-에틸페놀과 클로로메틸스티렌 또는 클로로메틸스티렌과 디비닐벤젠을 실질적으로 불활성인 용매중에서 프리델. 크라프트 촉매의 존재하에 반응시키는 방법에서 p-크레졸 또는 p-에틸페놀과 프리델. 크라프트 촉매의 용액중에 클로로메틸스티렌 또는 클로로메틸 스티렌과 디비닐벤젠과의 용액을 35℃이하의 온도에서 반응시킨 후 그것 보다도 높여진 온도에서 염화수소를 제거하는 것을 특징으로 하는 고분자형 산화 방지제의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860001986A 1985-03-26 1986-03-18 고분자형 산화방지제 및 그의 제조방법 KR930012016B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP60062899A JPS61221284A (ja) 1985-03-26 1985-03-26 高分子型酸化防止剤およびその製造方法
JP???60-62899 1985-03-26
JP62899 1985-03-26
JP138495 1985-06-24
JP60138495A JPS61296024A (ja) 1985-06-24 1985-06-24 高分子型酸化防止剤の製造方法
JP???60-138495 1985-06-24

Publications (2)

Publication Number Publication Date
KR860007302A true KR860007302A (ko) 1986-10-10
KR930012016B1 KR930012016B1 (ko) 1993-12-23

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Application Number Title Priority Date Filing Date
KR1019860001986A KR930012016B1 (ko) 1985-03-26 1986-03-18 고분자형 산화방지제 및 그의 제조방법

Country Status (2)

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US (1) US4824929A (ko)
KR (1) KR930012016B1 (ko)

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* Cited by examiner, † Cited by third party
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US5270403A (en) * 1991-03-29 1993-12-14 Dainippon Ink And Chemicals, Inc. Epoxy resin hardener and epoxy resin composition
US5837798A (en) * 1995-07-12 1998-11-17 Georgia-Pacific Resins Phenolic polymers made by aralkylation reactions
US5674970A (en) * 1995-07-12 1997-10-07 Georgia-Pacific Resins, Inc. Phenolic polymers made by aralkylation reactions
US5756655A (en) * 1997-01-10 1998-05-26 Georgia-Pacific Resins, Inc. Preparation of phenolic polymers by aralkylation reactions
US6100381A (en) * 1998-11-03 2000-08-08 Eastman Kodak Company Enzyme method of manufacturing gelatin
US6399740B1 (en) 1999-07-06 2002-06-04 Georgia-Pacific Resins, Inc. Process for reducing mono-functional and non-functional by-products during aralkylation of phenolics
US6372834B1 (en) * 1999-12-15 2002-04-16 Dupont Toray-Co. Ltd. Stabilized spandex
AU2005269754A1 (en) * 2004-07-23 2006-02-09 Polnox Corporation Anti-oxidant macromonomers and polymers and methods of making and using the same
US7902317B2 (en) * 2004-12-03 2011-03-08 Polnox Corporation Synthesis of aniline and phenol-based antioxidant macromonomers and corresponding polymers
EP1861484A2 (en) * 2005-02-22 2007-12-05 Polnox Corporation Nitrogen and hindered phenol containing dual functional macromolecular antioxidants: synthesis , performances and applications
CA2606303A1 (en) * 2005-03-25 2006-10-05 Polnox Corporation Alkylated and polymeric macromolecular antioxidants and methods of making and using the same
US7705176B2 (en) * 2005-10-27 2010-04-27 Polnox Corporation Macromolecular antioxidants based on sterically hindered phenols and phosphites
EP1966293A1 (en) * 2005-10-27 2008-09-10 Polnox Corporation Stabilized polyolefin compositions
US20070106059A1 (en) * 2005-10-27 2007-05-10 Cholli Ashok L Macromolecular antioxidants and polymeric macromolecular antioxidants
WO2007064843A1 (en) 2005-12-02 2007-06-07 Polnox Corporation Lubricant oil compositions
WO2008005358A2 (en) * 2006-07-06 2008-01-10 Polnox Corporation Novel macromolecular antioxidants comprising differing antioxidant moieties: structures, methods of making and using the same
US7767853B2 (en) 2006-10-20 2010-08-03 Polnox Corporation Antioxidants and methods of making and using the same
US10294423B2 (en) 2013-11-22 2019-05-21 Polnox Corporation Macromolecular antioxidants based on dual type moiety per molecule: structures, methods of making and using the same
WO2018160879A2 (en) 2017-03-01 2018-09-07 Polnox Corporation Macromolecular corrosion (mcin) inhibitors: structures, methods of making and using the same

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US3004953A (en) * 1959-03-02 1961-10-17 Dow Chemical Co Reaction products of phenols and diisopropenylbenzene
US3553290A (en) * 1968-04-10 1971-01-05 Du Pont Spandex fibers stabilized with condensates of substituted phenols and divinyl benzenes
US3546173A (en) * 1968-04-10 1970-12-08 Du Pont Process for preparing condensates of para-alkyl phenols and divinyl aromatic compounds
US3996199A (en) * 1976-02-17 1976-12-07 Dynapol Corporation Oil soluble polymeric antioxidant prepared by condensation of divinylbenzene, hydroxyanisole, tertiary butyl hydroquinone, tertiary butyl phenol and bisphenol A under ortho alkylation conditions

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US4824929A (en) 1989-04-25
KR930012016B1 (ko) 1993-12-23

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