KR860007217A - 피라졸유도체의 제조방법 - Google Patents
피라졸유도체의 제조방법 Download PDFInfo
- Publication number
- KR860007217A KR860007217A KR1019860001899A KR860001899A KR860007217A KR 860007217 A KR860007217 A KR 860007217A KR 1019860001899 A KR1019860001899 A KR 1019860001899A KR 860001899 A KR860001899 A KR 860001899A KR 860007217 A KR860007217 A KR 860007217A
- Authority
- KR
- South Korea
- Prior art keywords
- radicals
- hydrogen
- alkylsulfonyl
- alkylthio
- cyano
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catching Or Destruction (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (2)
- 일반식(Ⅱ)의 1-페닐피라졸을 필요할 경우 희석제 존재하 및 필요할 경우 촉매 존재하에 질산 또는 질산염으로 니트로화시킴을 특징으로하여, 일반식(Ia)의 4-니트로-1-페닐-피라졸을 제조하는 방법.상기식에서, R1및 R2는 서로 독립적으로, 수소, 알킬, 시클로알킬, 하이드록시알킬, 알콕시알킬, 알킬티오알킬 또는 할로겐노알킬이고, R3',R4',R5',R|6'및 R7'는 각각 서로 독립적으로 수소, 할로겐, 시아노, 니트로, 알킬, 알콕시, 알킬티오, 알킬설피닐, 알킬설포닐 또는 알콕시카보닐이거나, 라디칼-(X)n-R8이며; X는 산소, 황, 설피닐 또는 설포닐이고; n은 0 또는 1이며; R8은 할로게노알킬이고; 단, 라디칼 R3',R4',R5',R6'및 R7'중적에도 하나는 시아노, 알킬티오, 알킬설피닐, 알킬설포닐, 알콕시카보닐 또는, 라디칼-(X)n-R8이거나; 라디칼R3',R4',R|5',R6'또는 중적어도 셋은 같거나 다른 할로겐원자이며; R1및 R2가 동시에 수소일 경우, 라디칼R3',R4',R5',R6'및 R7'중적어도 하나는 불소가 아니다.
- 제1항에 있어서, R1및 R2가 각각 서로 독립적으로 수소이거나, 각각의 경우에 있어서 개별적인 알킬부위의 탄소수가 4까지이고, 필요할 경우 같거나 다른 할로겐원자 9개까지를 갖는 직쇄 또는 측쇄알킬, 하이드록시알킬, 알콕시알킬, 알킬티오알킬 또는 할로게노알킬이거나, 또는 탄소수 3내지 7의 시클로알킬이고; R3',R4',R5',R6'및 R7'는 각각 서로 독립적으로 수소, 불소, 염소, 브롬, 요오드, 시아노 또는 니트로이거나, 각각의 경우에 있어서 개별적인 알킬부위의 탄소수가 4까지인 직쇄 또는 측쇄알킬, 알콕시, 알킬티오, 알킬설피닐, 알킬설포닐 또는 알콕시카보닐이거나, 또는 라디칼 -(X)n-R8이며; X는 산소, 황, 설피닐 또는 설포닐이고; n은 0 또는 1이며; R8탄소수가 4까지이고 같거나 다른 할로겐원자 9개 까지를 갖는 직쇄 또는 측쇄할로게노알킬이며; 단, 라디칼 R3',R4',R5',R6'및 R7'중 적어도 하나는 시아노이거나, 각각의 경우에 있어서 개별적인 알킬부위의 탄소수가 1내지 4인 알킬티오, 알킬설피닐, 알킬설포닐 또는 알콕시 카보닐이거나, 또는 라디칼-(X)n-R8이거나; 라디칼R3',R4',R5',R6'또는 R7'중 적어도 셋은 같거나 다른 할로겐원자이며; R1및 R2가 동시에 수소일 경우, 라디칼 R3',R4',R5',R|6'및 R7'중 적어도 하나는 불소가 아닌 일반식(Ia)의 4-니트로-1-페닐-피라졸의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19853509567 DE3509567A1 (de) | 1985-03-16 | 1985-03-16 | Herbizide und insektizide mittel auf basis von pyrazolderivaten |
DEP3509567.9 | 1985-03-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR860007217A true KR860007217A (ko) | 1986-10-08 |
Family
ID=6265453
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019860001899A KR860007217A (ko) | 1985-03-16 | 1986-03-15 | 피라졸유도체의 제조방법 |
Country Status (17)
Country | Link |
---|---|
US (1) | US4746354A (ko) |
EP (1) | EP0200872B1 (ko) |
JP (1) | JPH0723362B2 (ko) |
KR (1) | KR860007217A (ko) |
AT (1) | ATE52084T1 (ko) |
AU (1) | AU577935B2 (ko) |
BR (1) | BR8601143A (ko) |
DD (1) | DD243847A5 (ko) |
DE (2) | DE3509567A1 (ko) |
DK (1) | DK118586A (ko) |
ES (1) | ES8702895A1 (ko) |
GR (1) | GR860707B (ko) |
HU (1) | HUT42074A (ko) |
IL (1) | IL78139A (ko) |
NZ (1) | NZ215470A (ko) |
TR (1) | TR22444A (ko) |
ZA (1) | ZA861914B (ko) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3501323A1 (de) * | 1985-01-17 | 1986-07-17 | Bayer Ag, 5090 Leverkusen | 1-aryl-4-nitropyrazole |
DE3540839A1 (de) * | 1985-11-18 | 1987-05-27 | Bayer Ag | 1-aryl-pyrazole |
GB8531485D0 (en) * | 1985-12-20 | 1986-02-05 | May & Baker Ltd | Compositions of matter |
US5232940A (en) * | 1985-12-20 | 1993-08-03 | Hatton Leslie R | Derivatives of N-phenylpyrazoles |
US6372774B1 (en) | 1985-12-20 | 2002-04-16 | Rhone-Poulenc Agriculture Ltd. | Derivatives of N-phenylpyrazoles |
US5547974A (en) * | 1985-12-20 | 1996-08-20 | Rhone-Poulenc Agriculture Ltd. | Derivatives of N-phenylpyrazoles |
DE3600287A1 (de) * | 1986-01-08 | 1987-07-16 | Bayer Ag | 1-arylpyrazole |
JPS6425763A (en) * | 1987-04-24 | 1989-01-27 | Mitsubishi Chem Ind | Pyrazoles and insecticide and acaricide containing said pyrazoles as active ingredient |
US6906006B1 (en) | 1988-11-23 | 2005-06-14 | Bayer Aktiengesellschaft | N-arly-substituted nitrogen-containing heterocycles, processes and novel intermediates for their preparation, and their use as herbicides and plant growth regulators |
DE3839480A1 (de) * | 1988-11-23 | 1990-05-31 | Bayer Ag | N-aryl-stickstoffheterocyclen, verfahren sowie neue zwischenprodukte zu ihrer herstellung und ihre verwendung als herbizide und pflanzenwuchsregulatoren |
DE3903799A1 (de) * | 1989-02-09 | 1990-08-16 | Bayer Ag | N-aryl-stickstoffheterocyclen |
IL100110A0 (en) * | 1990-12-26 | 1992-08-18 | American Cyanamid Co | Insecticidal and synergistic miticidal compositions |
US5167691A (en) * | 1991-10-03 | 1992-12-01 | Fmc Corporation | Herbicidal 5-amino-1-phenyl pyrazole compounds |
US5817688A (en) * | 1995-12-19 | 1998-10-06 | Rhone-Poulenc Inc. | Pesticidal 1-arylpyrazole derivatives |
US5922885A (en) | 1995-12-19 | 1999-07-13 | Rhone-Poulenc Inc. | Pesticidal 1-arylpyrazole derivatives |
EP1432688A1 (en) * | 2001-09-25 | 2004-06-30 | Basf Aktiengesellschaft | Insecticidal and acaricidal 3-substituted pyrazoles |
WO2003076409A1 (en) * | 2002-03-14 | 2003-09-18 | Syngenta Participations Ag | Derivatives of 1-phenyl-3-phenylpyrazole as herbicides |
US10202351B2 (en) | 2015-03-10 | 2019-02-12 | Bayer Animal Health Gmbh | Pyrazolyl derivatives as pest control agents |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3869274A (en) * | 1972-08-21 | 1975-03-04 | Abbott Lab | Method and composition for inducing fruit abscission |
DE2819932A1 (de) * | 1978-05-06 | 1979-11-15 | Bayer Ag | N,n-dimethyl-o-pyrazolyl-carbaminsaeureester, verfahren zu ihrer herstellung und ihre verwendung als insektizide |
DE2839270A1 (de) * | 1978-09-09 | 1980-03-20 | Bayer Ag | N,n-dimethyl-o-pyrazolyl-carbaminsaeureester, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
US4496390A (en) * | 1980-02-26 | 1985-01-29 | May & Baker Limited | N-Phenylpyrazole derivatives |
MA19540A1 (fr) * | 1981-07-17 | 1983-04-01 | May & Baker Ltd | Derives du n-phenylpyrazole |
DE3332270A1 (de) * | 1983-09-07 | 1985-03-21 | Bayer Ag, 5090 Leverkusen | Herbizide mittel enthaltend metribuzin in kombination mit 1,4-disubstituierten pyrazol-derivaten |
DE3501323A1 (de) * | 1985-01-17 | 1986-07-17 | Bayer Ag, 5090 Leverkusen | 1-aryl-4-nitropyrazole |
-
1985
- 1985-03-16 DE DE19853509567 patent/DE3509567A1/de not_active Withdrawn
-
1986
- 1986-03-04 US US06/836,268 patent/US4746354A/en not_active Expired - Fee Related
- 1986-03-05 AT AT86102868T patent/ATE52084T1/de active
- 1986-03-05 EP EP86102868A patent/EP0200872B1/de not_active Expired - Lifetime
- 1986-03-05 DE DE8686102868T patent/DE3670486D1/de not_active Expired - Lifetime
- 1986-03-12 JP JP61052736A patent/JPH0723362B2/ja not_active Expired - Lifetime
- 1986-03-13 NZ NZ215470A patent/NZ215470A/xx unknown
- 1986-03-13 AU AU54723/86A patent/AU577935B2/en not_active Ceased
- 1986-03-13 DD DD86287861A patent/DD243847A5/de not_active IP Right Cessation
- 1986-03-13 TR TR13106A patent/TR22444A/xx unknown
- 1986-03-13 IL IL78139A patent/IL78139A/xx unknown
- 1986-03-14 ES ES553031A patent/ES8702895A1/es not_active Expired
- 1986-03-14 HU HU861078A patent/HUT42074A/hu unknown
- 1986-03-14 GR GR860707A patent/GR860707B/el unknown
- 1986-03-14 DK DK118586A patent/DK118586A/da not_active Application Discontinuation
- 1986-03-14 BR BR8601143A patent/BR8601143A/pt unknown
- 1986-03-14 ZA ZA861914A patent/ZA861914B/xx unknown
- 1986-03-15 KR KR1019860001899A patent/KR860007217A/ko not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
AU577935B2 (en) | 1988-10-06 |
IL78139A0 (en) | 1986-07-31 |
ES8702895A1 (es) | 1987-01-16 |
EP0200872A1 (de) | 1986-11-12 |
DK118586D0 (da) | 1986-03-14 |
DK118586A (da) | 1986-09-17 |
JPS61215371A (ja) | 1986-09-25 |
AU5472386A (en) | 1986-10-16 |
IL78139A (en) | 1989-09-28 |
BR8601143A (pt) | 1986-11-25 |
ES553031A0 (es) | 1987-01-16 |
NZ215470A (en) | 1989-06-28 |
TR22444A (tr) | 1987-06-23 |
DD243847A5 (de) | 1987-03-18 |
DE3670486D1 (de) | 1990-05-23 |
US4746354A (en) | 1988-05-24 |
JPH0723362B2 (ja) | 1995-03-15 |
GR860707B (en) | 1986-07-15 |
ATE52084T1 (de) | 1990-05-15 |
HUT42074A (en) | 1987-06-29 |
EP0200872B1 (de) | 1990-04-18 |
DE3509567A1 (de) | 1986-09-18 |
ZA861914B (en) | 1987-07-29 |
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WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |