KR850003897A - 소성가공용 윤활제 및 소성가공방법 - Google Patents
소성가공용 윤활제 및 소성가공방법 Download PDFInfo
- Publication number
- KR850003897A KR850003897A KR1019840005934A KR840005934A KR850003897A KR 850003897 A KR850003897 A KR 850003897A KR 1019840005934 A KR1019840005934 A KR 1019840005934A KR 840005934 A KR840005934 A KR 840005934A KR 850003897 A KR850003897 A KR 850003897A
- Authority
- KR
- South Korea
- Prior art keywords
- phosphate
- parts
- weight
- plastic working
- phosphite
- Prior art date
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- 239000000314 lubricant Substances 0.000 title claims description 10
- 239000004033 plastic Substances 0.000 title claims 40
- 238000003672 processing method Methods 0.000 title claims 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 16
- 239000010452 phosphate Substances 0.000 claims description 16
- -1 phosphorus compound Chemical class 0.000 claims description 13
- 239000010687 lubricating oil Substances 0.000 claims 31
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 12
- 238000000034 method Methods 0.000 claims 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims 10
- 239000000194 fatty acid Substances 0.000 claims 10
- 229930195729 fatty acid Natural products 0.000 claims 10
- 239000002253 acid Substances 0.000 claims 9
- 230000002378 acidificating effect Effects 0.000 claims 8
- 229910052783 alkali metal Inorganic materials 0.000 claims 8
- 150000001340 alkali metals Chemical class 0.000 claims 8
- 150000004665 fatty acids Chemical class 0.000 claims 8
- 150000001875 compounds Chemical class 0.000 claims 7
- 239000003995 emulsifying agent Substances 0.000 claims 7
- 150000002894 organic compounds Chemical class 0.000 claims 7
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 7
- 150000003018 phosphorus compounds Chemical class 0.000 claims 7
- 239000011574 phosphorus Substances 0.000 claims 6
- 229910052698 phosphorus Inorganic materials 0.000 claims 6
- 239000003795 chemical substances by application Substances 0.000 claims 4
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims 4
- 230000001050 lubricating effect Effects 0.000 claims 4
- 229920000137 polyphosphoric acid Polymers 0.000 claims 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 3
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 239000007769 metal material Substances 0.000 claims 3
- 239000002480 mineral oil Substances 0.000 claims 3
- 235000010446 mineral oil Nutrition 0.000 claims 3
- 239000003921 oil Substances 0.000 claims 3
- 229920001021 polysulfide Polymers 0.000 claims 3
- 239000005077 polysulfide Substances 0.000 claims 3
- 150000008117 polysulfides Polymers 0.000 claims 3
- 239000011593 sulfur Substances 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- AROCLDYPZXMJPW-UHFFFAOYSA-N 1-(octyldisulfanyl)octane Chemical compound CCCCCCCCSSCCCCCCCC AROCLDYPZXMJPW-UHFFFAOYSA-N 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 2
- 229920000388 Polyphosphate Polymers 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 230000005494 condensation Effects 0.000 claims 2
- 238000009833 condensation Methods 0.000 claims 2
- 235000011180 diphosphates Nutrition 0.000 claims 2
- 239000001205 polyphosphate Substances 0.000 claims 2
- 235000011176 polyphosphates Nutrition 0.000 claims 2
- 229940048084 pyrophosphate Drugs 0.000 claims 2
- 229940005657 pyrophosphoric acid Drugs 0.000 claims 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical group C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims 2
- GPOGLVDBOFRHDV-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)O GPOGLVDBOFRHDV-UHFFFAOYSA-N 0.000 claims 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 claims 1
- HGJOFJDIHKHKAU-UHFFFAOYSA-N 2,2-dimethylthiirane Chemical compound CC1(C)CS1 HGJOFJDIHKHKAU-UHFFFAOYSA-N 0.000 claims 1
- BXJCEULFBLJODE-UHFFFAOYSA-N 2-chloroethyl dihydrogen phosphite Chemical compound OP(O)OCCCl BXJCEULFBLJODE-UHFFFAOYSA-N 0.000 claims 1
- ADRNSOYXKABLGT-UHFFFAOYSA-N 8-methylnonyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCC(C)C)OC1=CC=CC=C1 ADRNSOYXKABLGT-UHFFFAOYSA-N 0.000 claims 1
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 claims 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims 1
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 claims 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- SXXILWLQSQDLDL-UHFFFAOYSA-N bis(8-methylnonyl) phenyl phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OC1=CC=CC=C1 SXXILWLQSQDLDL-UHFFFAOYSA-N 0.000 claims 1
- FJTUUPVRIANHEX-UHFFFAOYSA-N butan-1-ol;phosphoric acid Chemical compound CCCCO.OP(O)(O)=O FJTUUPVRIANHEX-UHFFFAOYSA-N 0.000 claims 1
- BNMJSBUIDQYHIN-UHFFFAOYSA-N butyl dihydrogen phosphate Chemical compound CCCCOP(O)(O)=O BNMJSBUIDQYHIN-UHFFFAOYSA-N 0.000 claims 1
- GVPWHKZIJBODOX-UHFFFAOYSA-N dibenzyl disulphide Natural products C=1C=CC=CC=1CSSCC1=CC=CC=C1 GVPWHKZIJBODOX-UHFFFAOYSA-N 0.000 claims 1
- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 claims 1
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 claims 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical group C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 claims 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 150000002148 esters Chemical group 0.000 claims 1
- 238000010304 firing Methods 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 claims 1
- QPPQHRDVPBTVEV-UHFFFAOYSA-N isopropyl dihydrogen phosphate Chemical compound CC(C)OP(O)(O)=O QPPQHRDVPBTVEV-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 235000015250 liver sausages Nutrition 0.000 claims 1
- 238000005555 metalworking Methods 0.000 claims 1
- 125000005341 metaphosphate group Chemical group 0.000 claims 1
- DUDRFISLZJPLTJ-UHFFFAOYSA-N methane;phosphoric acid Chemical compound C.OP(O)(O)=O DUDRFISLZJPLTJ-UHFFFAOYSA-N 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000011707 mineral Substances 0.000 claims 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 claims 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000012188 paraffin wax Substances 0.000 claims 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims 1
- OHRVKCZTBPSUIK-UHFFFAOYSA-N tridodecyl phosphate Chemical compound CCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCC)OCCCCCCCCCCCC OHRVKCZTBPSUIK-UHFFFAOYSA-N 0.000 claims 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 claims 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 claims 1
- KENFVQBKAYNBKN-UHFFFAOYSA-N trihexadecyl phosphate Chemical compound CCCCCCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCC KENFVQBKAYNBKN-UHFFFAOYSA-N 0.000 claims 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 claims 1
- FDGZUBKNYGBWHI-UHFFFAOYSA-N trioctadecyl phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC FDGZUBKNYGBWHI-UHFFFAOYSA-N 0.000 claims 1
- CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 claims 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims 1
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 claims 1
- GXZLXDRFEDHOAU-UHFFFAOYSA-N tris(4-phenylphenyl) phosphate Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1OP(OC=1C=CC(=CC=1)C=1C=CC=CC=1)(=O)OC(C=C1)=CC=C1C1=CC=CC=C1 GXZLXDRFEDHOAU-UHFFFAOYSA-N 0.000 claims 1
- DECPGQLXYYCNEZ-UHFFFAOYSA-N tris(6-methylheptyl) phosphite Chemical compound CC(C)CCCCCOP(OCCCCCC(C)C)OCCCCCC(C)C DECPGQLXYYCNEZ-UHFFFAOYSA-N 0.000 claims 1
- QEDNBHNWMHJNAB-UHFFFAOYSA-N tris(8-methylnonyl) phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OCCCCCCCC(C)C QEDNBHNWMHJNAB-UHFFFAOYSA-N 0.000 claims 1
- JZNDMMGBXUYFNQ-UHFFFAOYSA-N tris(dodecylsulfanyl)phosphane Chemical compound CCCCCCCCCCCCSP(SCCCCCCCCCCCC)SCCCCCCCCCCCC JZNDMMGBXUYFNQ-UHFFFAOYSA-N 0.000 claims 1
- SVETUDAIEHYIKZ-IUPFWZBJSA-N tris[(z)-octadec-9-enyl] phosphate Chemical compound CCCCCCCC\C=C/CCCCCCCCOP(=O)(OCCCCCCCC\C=C/CCCCCCCC)OCCCCCCCC\C=C/CCCCCCCC SVETUDAIEHYIKZ-IUPFWZBJSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
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- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/24—Compounds containing phosphorus, arsenic or antimony
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- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
- C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
- C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
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- C10M135/02—Sulfurised compounds
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/20—Thiols; Sulfides; Polysulfides
- C10M135/22—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
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- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
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- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
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Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 냉간가공용의 소재형상예를 나타낸 측면도.
제2도는 제1도에 나타낸 소재에 본원 발명의 윤활제를 사용하여 냉간가공하기 위한 장치의 단면도.
제3도는 축합인산화합물의 배합량과 가공특성의 관계를 나타낸 그래프.
Claims (28)
- 윤활유와 하기 일반식(1) 및 (2)로 표시되는 쇄상으로 축합한 인화합물 :Hn+2PnO3n+1………………(1)MnHnPnO3n+1………………(2)(식중, n은 2 이상의 정수, M은 알칼리금속을 나타냄)또는 하기 일반식(3) 및 (4)로 표시되는 현상으로 축합한 인화합물 :(HPO3)n……………………(3)MxHy(PO3)x+y……………………(4)(식중, n은 2 이상의 정, M은 알칼리금속, x와 y는 1이상의 정수)의 최소한 하나의 축합인화합물로 이루어진 것을 특징으로 하는 소성가공용 실질적으로 Water-free인 액상윤활제.
- 윤활유가 광유 또는 합성유인 것을 특징으로 하는 특허청구의 범위 1기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 축합인화합물이 메타인산, 폴리인산, 피로인산, 산성메타인산염, 산성폴리인산염 및 산성피로인산염의 최소한 하나임을 특징으로 하는 특허청구의 범위 1 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 윤활유 100중량부에 대해 축합인화합물이 2∼20 중량부인 것을 특징으로 하는 특허청구의 범위 1 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 지방산을 함유하는 것을 특징으로 하는 특허청구의 범위 1 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 윤활유 100 중량부에 대해 지방산이 1∼3 중량부 인것을 특징으로 하는 특허청구의 범위 5 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 윤활유와 하기 일반식 (1) 및 (2)로 표시되는 쇄상으로 축합한 인화합물 :Hn+2PnO3n+1………………(1)MnHnPnO3n+1………………(2)(식중, n은 2 이상의 정수, M은 알칼리금속을 나타냄)또는 하기 일반식(3) 및 (4)로 표시되는 현상으로 축합한 인화합물 :(HPO3)n……………………(3)MxHy(PO3)x+y……………………(4)(식중, n은 2 이상의 정수, M은 알칼리금속, X와 Y는 1 이상의 정수)의 최소한 하나의 축합인화합물과, 인, 유황, 염소원소를 함유하는 유기화합물의 최소한 하나의 극압제로 이루어진 소성가공용 실질적으로 Water-free인 액상윤활제)
- 윤활유가 광유 또는 합성유인 것을 특징으로 하는 특허청구의 범위 7 기재의 소성가공용 실질적으로 Waer-free인 액상윤활제.
- 축합인화합물이 메탄인산, 폴리인산, 피로인산. 산성메타인산, 산성폴리인산염 및 산성피로인산염의 최소한 하나인 것을 특징으로 하는 특허청구의 범위 7 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 유기화합물 극압제가 트리페닐포스파이트, 트리크레질포스파이트, 디페닐노닐페닐포스파이트, 토리스(노닐페닐)포스파이트, 트리이소옥틸포스파이트, 디페닐이소데실포스파이트, 페닐디이소데실포스파이트, 트리이소데실포스파이트, 트리라우릴포스파이트, 트리옥타데실포스파이트, 트리올레일포스파이트, 트리라우릴트리티오포스파이트, 디이소데실하이드로디엔포스파이트, 디라우릴하이드로디엔포스파이트, 디올레일하이드로디엔포스파이트, 토리스클로로에틸포스파이트, 토리스트리데실포스파이트, 디부틸하이드로디엔포스파이트, 트리메틸포스페이트, 트리에틸포스페이트, 트리부틸포스페이트, 트리부톡시에틸포스페이트, 트리페닐포스페이트, 트리크레딜포스페이트, 트리크실레닐포스페이트, 크레딜디페닐포스페이트, 옥틸디페닐포스페이트, 크실레닐디페닐포스페이트, 트리라우릴포스페이트, 트리세틸포스페이트, 트리스테아릴포스페이트, 트리올레일포스페이트, 디부틸포스페이트, 모노부틸포스페이트, 디옥틸포스페이트, 모노이소대실포스페이트, 트리스크로로에틸포스페이트,토리수디클로로프로필포스페이트, 메틸아시드포스페이트, 이소프로필아시드포스페이트, 부틸아시드포스페이트, 옥틸아시트포스페이트, 이소데실아시드포스페이트, 라우릴아시드포스페이트, 트리데칸올아시드포스페이트, 옥타데실아시드포스페이트, 올레일아시드포스페이트, 황화유지, 황희디벤텐, 황화이소부텐, 황화올레핀, 디벤질디설파이드, 폴리설파이드,잔틱디설파이드,디테트라부틸설파이드,디페닐설파이드,디n옥틸디설파이드, 디테트라노닐폴리설파이드,디 n옥틸디설파이드,폴리옥시에틸렌폴리설파이드, 염소계 파라핀,염소화유지,염소화지방산 에스테르,5여화지방산 에스테르의 최 최소한 하나인 것을 특징으로 하는 특허청구의 범위 7 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 윤활유 100 중량부에 대한 축합인화합물이 1∼10 중량부, 상기 유기화합물 극압제가 5∼30 중량부인 것을 특징으로 하는 특허청구의 범위 7 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 지방산을 포함하는 것을 특징으로 하는 특허청구의 범위 7 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 윤활유 100 중량부에 대한 축합인화합물이 1∼10 중량부, 상기 유기화합물 극압제가 1∼30 중량부, 지방산이 6∼20 중량부인 것을 특징으로 하는 특허청구 범위 12 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 유화제를 포함하는 것을 특징으로 하는 특허청구의 범위 1 도는 7 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 윤활유 100 중량부에 대해 유화제가 0.1∼5 중량부인 것을 특징으로 하는 특허청구의 범위 14 기재의 소성가공용 실직적으로 Water-ferr인 액상윤활제.
- 40℃에서 점도가 50∼200mm2/S의 광유 100 중량부, 쇄상폴리인산 3∼8 중량부, 산성인산에스테르 9∼24 중량부, 유화제 0.5∼2 중량부로 이루어진 소성가공용 실질적으로 Water-free인 액상윤활제.
- 산성인산에스테르가 디올레일하이드로디엔포스파이트, 유화제가 폴리매릭호박산의 에스테르인 것을 특징으로 하는 특허청구 범위 16 기재의 소성가공용 실질적으로 Water-free인 액상윤활제.
- 소성가공하는 금속재료표면 또는 이것에 대향하는 급형가공면에 소성가공용 윤활제를 도포하여, 가공시에 발생하는 열을 이용하여, 상기 금속표면산에 윤활피막을 형성하는 소성가공방법에 있어서, 소성가공용 윤활제로서 윤활유와 하기 일반식 (1) 및 (2)로 표시되는 쇄상으로 축합한 인화합물.Hn+2PnO3n+1………………(1)MnHnPnO3n+1………………(2)(식중, n은 2 이상의 정수, M은 알칼리금속을 나타냄 또는 하기 일반식 (3) 및 (4)로 표시되는 현상으로 축합한 인화합물 :(HPO3)n……………………(3)MxHy(PO3)x+y……………………(4)(식중, n은 2 이상의 정수, M은 알칼리금속, x와 y는 1 이상의 정수)의 최소한 하나의 축합인화합물로 이루어진 실질적으로 Water-free인 소성가공용 윤활제를 사용하는 것을 특징으로 하는 소성가공방법.
- 윤활유 100 중량부에 대해 축합인화합물이 2∼20 중량부인 것을 특징으로 하는 특허청구의 범위 18기재의 소성가공방법.
- 지방산을 포함하는 것을 특징으로 하는 특허청구의 범위 18 기재의 소성가공방법.
- 윤활유 100 중량부에 대해 지방산이 1∼33 중량부인 것을 특징으로 하는 측허청구의 범위 20 기재의 소성가공방법.
- 소성가공하는 금속재료표면 또는 이것에 대향하는 금형가공면에 소성가공용 윤활제를 도포하여 가공시에 발생하는 열을 이용해서 상기 금속표면상에 윤활피막을 형성하는 소성가공방법에 있어서, 소성가공용 윤활제로서 윤활유와 하기식 (1) 및 (2) 로 표시되는 쇄상으로 축합한 인화합물 :Hn+2PnO3n+1………………(1)MnHnPnO3n+1………………(2)(식중, n은 2 이상의 정수, M은 알칼리금속을 나타냄)또는 하기 일반식(3) 및 (4)로 표시되는 현상으로 축합한 인화합물 :(HPO3)n……………………(3)MxHy(PO3)x+y……………………(4)(식중, n은 2 이상의 정수, M은 알칼리금속, x와 y는 이상의 정수)의 최소한 하나의 축합인화합물과, 인, 유황, 염소원소를 함유하는 유기화합물의 최소한 하나의 극압제로 이루어진 소성가공용 실질적으로 Watre-free인 액상윤활제를 사용하는 소성가공방법.
- 윤활유 100 중량부에 대해 축합인화합물이 1∼10 중량부, 상기 유기화합물 극압제가 5∼30 중량부인 것을 특징으로 하는 특허청구의 범위 22 기재의 소성가공방법.
- 지방산을 함유하는 것을 특징으로 하는 특허청구의 범위 22 기재의 소성가공방법.
- 윤활유 100 중량부에 대해 축합인화합물이 1∼10 중량부, 상기 유기화합물 극압제가 1∼30 중량부, 지방산이 6∼20 중량부인 것을 특징으로 하는 특허청구의 범위 22 기재의 소성가공방법.
- 유화제를 함유하는 것을 특징으로 하는 특허청구의 범위 18 또는 22 기재의 소성가공방법.
- 윤활유 100 중량부에 대해 유화제가 0.1∼5 중량부인 것을 특징으로 하는 특허청구의 범위 26 기재의 소성가공방법.
- 소성가공하는 금속재료 표면 또는 이것에 대향하는 금속가공면에 소송가공용 윤활제를 도포하여, 가공시에 발생하는 열을 이용해서 상기 금속표면상에 윤활피막을 형성하는 소성가공방법에 있어서, 40℃에서 점도가 50∼200mm2/S인 광유 100 중량부, 쇄상폴리인산 3∼8 중량부, 산성인산에스테르 9∼24 중량부, 유화제 0.5∼2 중량부로 이루어진 소성가공 실질적으로 Water-free인 액상윤활제를 사용하는 것을 특징으러 하는 소성가공방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP83-79752 | 1983-09-28 | ||
JP179752/83 | 1983-09-28 | ||
JP17975283A JPS6071697A (ja) | 1983-09-28 | 1983-09-28 | 塑性加工用潤滑剤 |
JP83-238517 | 1983-12-16 | ||
JP23851783A JPS60130692A (ja) | 1983-12-16 | 1983-12-16 | 冷間加工用潤滑剤及び冷間加工方法 |
JP238517/83 | 1983-12-16 |
Publications (2)
Publication Number | Publication Date |
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KR850003897A true KR850003897A (ko) | 1985-06-29 |
KR870001545B1 KR870001545B1 (ko) | 1987-09-02 |
Family
ID=26499506
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Application Number | Title | Priority Date | Filing Date |
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KR1019840005934A KR870001545B1 (ko) | 1983-09-28 | 1984-09-27 | 소성가공용 윤활제 및 소성가공방법 |
Country Status (4)
Country | Link |
---|---|
US (1) | US4612127A (ko) |
EP (1) | EP0135932B1 (ko) |
KR (1) | KR870001545B1 (ko) |
DE (1) | DE3482123D1 (ko) |
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KR970010933A (ko) * | 1995-08-03 | 1997-03-27 | 이데미쓰 쇼스께 | 함침베어링용 기름조성물 |
KR100693399B1 (ko) * | 2006-10-13 | 2007-03-12 | 바위산업 주식회사 | 석재 가공용 절삭유 조성물 |
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DE3484392D1 (de) * | 1983-12-19 | 1991-05-08 | Hitachi Ltd | Fluessiges schmiermittel vom emulsionstyp fuer das formen von metall, verfahren zur herstellung dieses schmiermittels und verfahren fuer das formen mit diesem schmiermittel. |
JPS60130693A (ja) * | 1983-12-19 | 1985-07-12 | Hitachi Ltd | 金属加工用潤滑油及びその使用方法 |
JPS61291687A (ja) * | 1985-06-19 | 1986-12-22 | Hitachi Ltd | アルミニウム冷間鍛造用潤滑剤 |
JPH01282295A (ja) * | 1988-05-07 | 1989-11-14 | Toyota Central Res & Dev Lab Inc | 金属加工用潤滑油組成物およびその製造法 |
JPH0813980B2 (ja) * | 1988-06-14 | 1996-02-14 | 協同油脂株式会社 | 鋼の熱間圧延潤滑剤組成物 |
AU625675B2 (en) * | 1988-06-14 | 1992-07-16 | Kyodo Yushi Co., Ltd. | Lubricant composition for hot-rolling of steel |
US5344468A (en) * | 1991-06-14 | 1994-09-06 | Ethyl Petroleum Additives, Inc. | Organic phosphates and their use as wear inhibitors |
US6030543A (en) * | 1993-03-04 | 2000-02-29 | Great Lakes Chemical Corporation | Aircraft hydraulic fluid basestocks |
US5495737A (en) * | 1994-07-15 | 1996-03-05 | Cleveland State University | Elevated temperature metal forming lubrication |
AU697033B2 (en) * | 1994-12-09 | 1998-09-24 | Exxon Chemical Patents Inc. | Synergistic antioxidant systems |
AU710294B2 (en) * | 1995-09-12 | 1999-09-16 | Lubrizol Corporation, The | Lubrication fluids for reduced air entrainment and improved gear protection |
AU719520B2 (en) * | 1995-09-19 | 2000-05-11 | Lubrizol Corporation, The | Additive compositions for lubricants and functional fluids |
US5584201A (en) * | 1995-11-20 | 1996-12-17 | Cleveland State University | Elevated temperature metal forming lubrication method |
EP0979266A2 (en) * | 1996-08-30 | 2000-02-16 | Solutia Inc. | Novel water soluble metal working fluids |
DE19728806A1 (de) * | 1997-07-05 | 1999-01-07 | Rhein Chemie Rheinau Gmbh | Geschwefelte unverzweigte Verbindungen, ein Verfahren zu ihrer Herstellung und ihre Verwendung |
US6165950A (en) * | 1997-11-26 | 2000-12-26 | Pabu Services, Inc. | Phosphate lubricant compositions and metal forming use |
FR2820431B1 (fr) * | 2001-02-06 | 2007-04-27 | Rhodia Chimie Sa | Procede de deformation de metaux mettant en oeuvre un lubrifiant aqueux additive permettant d'augmenter la productivite |
FR2822841B1 (fr) * | 2001-04-02 | 2004-03-26 | Ceca Sa | Additifs de tribologie solides pour compositions lubrifiantes |
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JP2004161976A (ja) * | 2002-03-18 | 2004-06-10 | Cosmo Sekiyu Lubricants Kk | 潤滑油組成物及びその製造方法 |
US6767870B2 (en) * | 2002-07-18 | 2004-07-27 | C&C Oil Company | Solid lubricant for lubricating rotary trunnion supported equipment |
KR20060015536A (ko) * | 2003-04-28 | 2006-02-17 | 그레이트 레이크스 케미칼 (유럽) 게엠베하 | 윤활제 조성물 |
US8283296B2 (en) * | 2006-10-11 | 2012-10-09 | Henkel Ag & Co., Kgaa | Lubricant for hot forging applications |
CN101029271B (zh) * | 2007-04-09 | 2010-10-13 | 大连三达奥克化学有限公司 | 镀锌钢板冲压拉伸润滑油及生产方法 |
EP3569680A1 (en) * | 2018-05-17 | 2019-11-20 | Biotronik Ag | Lubricant, particularly for use in a direct or indirect tubular impact extrusion process, particularly for manufacturing of magnesium alloy tubes |
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US3184409A (en) * | 1962-01-31 | 1965-05-18 | Exxon Research Engineering Co | Hydrocarbon compositions containing iodine as an antifriction agent |
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DE2850244A1 (de) * | 1978-11-20 | 1980-05-29 | Hoechst Ag | Additiv fuer die metallbearbeitung |
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-
1984
- 1984-09-26 US US06/654,686 patent/US4612127A/en not_active Expired - Fee Related
- 1984-09-26 DE DE8484111469T patent/DE3482123D1/de not_active Expired - Lifetime
- 1984-09-26 EP EP84111469A patent/EP0135932B1/en not_active Expired - Lifetime
- 1984-09-27 KR KR1019840005934A patent/KR870001545B1/ko not_active IP Right Cessation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR970010933A (ko) * | 1995-08-03 | 1997-03-27 | 이데미쓰 쇼스께 | 함침베어링용 기름조성물 |
KR100693399B1 (ko) * | 2006-10-13 | 2007-03-12 | 바위산업 주식회사 | 석재 가공용 절삭유 조성물 |
Also Published As
Publication number | Publication date |
---|---|
KR870001545B1 (ko) | 1987-09-02 |
EP0135932A2 (en) | 1985-04-03 |
EP0135932A3 (en) | 1986-08-27 |
EP0135932B1 (en) | 1990-05-02 |
DE3482123D1 (de) | 1990-06-07 |
US4612127A (en) | 1986-09-16 |
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