KR850002976A - 치환된 아졸릴-테트라하이드로푸란-2-일리덴-메탄유도체의 제조방법 - Google Patents

치환된 아졸릴-테트라하이드로푸란-2-일리덴-메탄유도체의 제조방법 Download PDF

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KR850002976A
KR850002976A KR1019840006296A KR840006296A KR850002976A KR 850002976 A KR850002976 A KR 850002976A KR 1019840006296 A KR1019840006296 A KR 1019840006296A KR 840006296 A KR840006296 A KR 840006296A KR 850002976 A KR850002976 A KR 850002976A
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엘베 한스-루드비히 (외 5)
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게르하르트 뮐러, 하인쯔-게르트 뮐러
바이엘 아크티엔 게젤샤프트
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Abstract

내용 없음

Description

치환된 아졸릴-테트라하이드로푸란-2-일리덴-메타유도체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (4)

  1. 일반식(Ⅱ)의 할로게노-(티오)에테르-케톤을 희석제 및 산결합제 존재하에서 이미다졸 또는 1,2,4-트리아졸과 반응시키고, 필요에 따라, 수득된 일반식(Ⅰa)의 치환된 아졸릴-테트라하이드로푸란-2-일리덴-메타유도체를 산화시키고, 필요에 따라, 수득된 일반식(Ⅰ)의 화합물에 산 또는 금속염을 가함을 특징으로 하여 일반식(Ⅰ)의 치환된 아졸릴-테트라하이드로푸란-2-일리덴-메탄 유도체 및 그의 산부가염 및 금속염의 복합체를 제조하는 방법.
    상기식에서, A는 질소원자 또는 CH그룹이고; X는 산소, 황 또는 SO 또는 SO2그룹이고; R은 임의로 치환된 아릴이고; R1내지 R6은 동일 상이하며 수소, 알킬, 할로게노알킬 또는 할로겐이고, 할로겐 또는 할로게노 알킬 치환체는 최대한 3개까지이며, 단, X가 산소일 경우 R1및 R2가 동시에 메틸이 아니고; R1및 R2는 그들이 결합된 탄소원자와 함께 임의로 치환된 사이클로알킬을 나타내거나 R2및 R3는 그들이 결합된 탄소원자와 함께 임의로 치환된 사이클로알킬을 나타내고; Y는 산소 또는 황이고; Hal 및 Hal'은 할로겐이다.
  2. 제1항에 있어서, A가 질소원자 또는 CH그룹이고; X가 산소, 황 SO 또는 SO2그룹이고; R이 동일 또는 상이한 치환체에 의하여 임의로 모노-, 디-또는 트리-치환된 페닐인데 여기에서 치환체는 할로겐 탄소원자수 1 내지 4개의 알킬, 각 경우에 탄소원자수 1 또는 2개인 알콕시 및 알킬티오, 할로게노알킬, 각 경우에 탄소원자수 1 또는 2개이고 1내지 5개의 동일 또는 상이한 할로겐원자를 갖는 할로게노악콕시 및 할로게노알킬티오, 알콕시그룹에 탄소원자수 1 내지 4개인 알콕시카보닐, 알콕시그룹에 탄소원자수 1 내지 4개이고 알칼그룹에 탄소원자수 1 또는 2개인 알콕시미노알킬, 니트로, 시아노 및 할로겐 및/또는 탄소원자수 1 또는 2개인 알킬에 의해 임의로 치환된 페닐 및 페녹시이고; R1내지 R6이 동일 또느 상이하며 수소, 탄소원자수 1 내지 4개인 직쇄 또는 측쇄알킬 또는 탄소원자수 1 또는 2개이고 1 내지 5개의 동일 또는 상이한 할로겐원자를 가지는 할로게노알킬이고, 할로게노알킬 치환체는 최대한 3개까지이며, 단, X가 산소일 경우 R1및 R2가 동시에 메틸이아니거나; R3내지 R6이 동일 또는 상이하며 할로겐이고, 할로겐 치환체는 최대할 3개까지이며; R1및 R2이 그들이 결합된 탄소원자와 함께 탄소원자수 4 내지 7개인 사이클로알킬을 나타내고 임의로는 탄소원자수 1 또는 2개의 알킬에 의해 치환되거나; R2및 R3이 그들이 결합된 탄소원자와 함께 탄소원자수 4 내지 7개인 사이클로알킬을 나타내고 임의로는 탄소원자수 1 또는 2개인 알킬에 의해 치환되는 일반식(Ⅰ)의 치환된 아졸릴-테트라하이드로푸란-2-일리덴-메탄 유도체 및 그의 산부가염 및 금속염의 복합체를 제조하는 방법.
  3. 제1항에 있어서, A가 질소원자 또는 CH그룹이고; X가 산소, 황 또는 SO 또는 SO2그룹이고; R이 동일 또는 상이한 치환체에 의하여 임의로 모노-, 디-또는 트리-치환된 페닐인데 여기에서 치환체는 할로겐, 탄소원자수 1 내지 4개인 알킬, 각 경우에 탄소원자수 1 또는 2개인 알콕시 및 알킬티오, 할로게노알킬, 각 경우에 탄소원자수 1 또는 2개이고, 1 내지 5개의 동일 또는 상이한 불소 또는 염소원자를 갖는 할로게노알콕시 및 할로게노알킬티오, 알킬그룹에 탄소원자수 1 내지 4개인 알콕시카보닐, 알콕시 그룹에 탄소원자수 1 내지 4개이고 알킬그룹에 탄소원자수 1 또는 2개인 알콕시미노알킬, 니트로, 시아노 및 할로겐 및/또는 탄소원자수 1 또는 2개인 알킬에 의해 임의로 치환된 페닐 및 페녹시이고; R1내지 R6이 동일 또는 상이하며 수소, 탄소원자수 1 내지 4개인 직쇄 또는 측쇄 알킬 또는 탄소원자수 1 또는 2개이고 1 내지 5개의 동일 또는 상이한 불소 또는 염소원자를 가지는 할로게노알킬이고, 할로게노알킬치환체는 최대한 3개까지이며, 단, X가 산소일 경우 R1및 R2가 동시에 메틸이 아니거나; R3내지 R이 동일 또는 상이하며 할로겐이고 할로겐 치환체는 최대한 3개까지이며; R1및 R2이 그들이 결합된 탄소원자와 함께 탄소원자수 4 내지 7개인 사이클로알킬을 나타내고 임의로는 탄소원자수 1 또는 2개인 알킬에 의해 치환되거나; R2및 R3이 그들이 결합된 탄소원자와 함께 탄소원자수 4 내지 7개인 사이클로 알킬을 나타내고 임의로는 탄소원자수 1 또는 2개인 알킬에 의해 치환되는 일반식(Ⅰ)의 치환된 아졸릴-테트라하이드로푸란-2-일리덴-메탄 유도체 및 그의 산부가염 및 금속염의 복합체를 제조하는 방법.
  4. 제1항에 있어서, A가 질소원자 또는 CH그룹이고; X가 산소, 황 또는 SO 또는 SO2그룹이고; R이 동일 또는 상이한 치환체에 의하여 임의로 모노-, 디- 또는 트리-치환된 페닐이며, 여기에서 치환체는 불소, 염소, 브롬, 메틸, 에틸, 3급부틸, 메톡시, 메틸티오, 트리플루오로메틸, 트리플루오로메톡시, 트리플루오로메틸티오, 메톡시카보닐, 에톡시카보닐, 메톡시미노메틸, 1-메톡시미노에틸, 니트로, 시아노 및 염소 및 염소 및/또는 메틸에 의해 임의로 치환된 페닐 및 페녹시이고; R1내지 R6가 동일 또는 상이하여 수소, 메틸, 에틸 또는 1 내지 3개의 동일 또는 상이한 할로겐원자(예 : 불소 및 염소원자)를 갖는 할로게노메틸이고 할로게노메틸 치환체는 최대한 3개까지이며, 단, X가 산소일 경우 R1및 R2가 동시에 메틸이 아니거나; R3내지 R6가 동일 또는 상이하며 불소, 염소 또는 브롬이고 불소, 염소 또는 브롬치환체는 최대한 3개까지이며; R1및 R2가 그들이 결합된 탄소원자와 함께 사이클로펜틸 또는 사이클로헥실을 나타내거나; R2및 R3가 그들이 결해된 탄소원자와 함께 사이클로펜틸 또는 사이클로헥실을 나타내는 일반식(Ⅰ)의 치환된 아졸릴-테트라하이드로푸란-2-일리덴-메탄유도체 및 그의 산부가염 및 금속염의 복합체를 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840006296A 1983-10-11 1984-10-11 치환된 아졸릴-테트라하이드로푸란-2-일리덴-메탄유도체의 제조방법 KR850002976A (ko)

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DE19833336859 DE3336859A1 (de) 1983-10-11 1983-10-11 Substituierte azolyl-tetrahydro-furan-2-yliden-methan-derivate
DEP3336859.7 1983-10-11

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US4228177A (en) * 1979-08-08 1980-10-14 E. R. Squibb & Sons, Inc. 2,3-Dihydro-3-(1H-imidazol-1-ylmethylene)-4H-1-benzothiopyran-4-ones
US4384879A (en) * 1980-07-15 1983-05-24 Ciba-Geigy Corporation 4-(1H-Azolylmethyl)-1,3-dioxolan-5-one derivatives, production thereof and use thereof as growth regulators and/or microbicides
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DE3145890A1 (de) * 1981-11-19 1983-05-26 Bayer Ag, 5090 Leverkusen Azolylvinyldithioacetale, verfahren zu ihrer herstellung und ihre verwendung als fungizide
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US4562198A (en) 1985-12-31
DK483784A (da) 1985-04-12
EP0141995A3 (de) 1986-12-10
HU195076B (en) 1988-04-28
HUT37547A (en) 1986-01-23
AU3384184A (en) 1985-04-18
AU566160B2 (en) 1987-10-08
DE3336859A1 (de) 1985-04-25
CA1237137A (en) 1988-05-24
IL73193A0 (en) 1985-01-31
ZA847894B (en) 1985-06-26
PT79296B (en) 1986-09-10
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JPS60104086A (ja) 1985-06-08
IL73193A (en) 1988-07-31

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