KR840005999A - 메탄올의 촉매적 제조방법 - Google Patents

메탄올의 촉매적 제조방법 Download PDF

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Publication number
KR840005999A
KR840005999A KR1019830003799A KR830003799A KR840005999A KR 840005999 A KR840005999 A KR 840005999A KR 1019830003799 A KR1019830003799 A KR 1019830003799A KR 830003799 A KR830003799 A KR 830003799A KR 840005999 A KR840005999 A KR 840005999A
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KR
South Korea
Prior art keywords
surface area
total surface
carbon
ratio
palladium
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KR1019830003799A
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English (en)
Inventor
윌리암 죠이너 리차드 (외 2)
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원본미기재
더 브리티시 페트롤룸 캄파니 피·엘·시
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Publication of KR840005999A publication Critical patent/KR840005999A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/04—Methanol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음

Description

메탄올의 촉매적 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 수소 및 일산화탄소로 이루어진 원료물질을 메탄올로의 전환반응이 일어날 수 있는 온도 및 압력조건하에서 지지체상에 분산된 팔라듐 금속을 함유하는 촉매상에 통과시켜 멘탄올을 제조하는 방법에 있어서, 촉매가 촉진제로 주기율표의 ⅠA족 또는 ⅡA족 원소 또는 란타니드를 함유하며, 지지체는 전표면적이 적어도 100m2/g이고 전표면적에 대한 BET 표면적의 비가 5:1 이하이며 에지 (edge) 표면적에 대한 전표면적의 비가 적어도 10:1의 흑염-함유 탄소임을 특징으로 하는 방법.
  2. 제1항에 있어서, 탄소의 전표면적이 적어도 150m2/g인 방법.
  3. 제2항에 있어서, 전표면적이 적어도 200m2/g인 방법.
  4. 제1항 내지 3항중의 어느 하나에 있어서, 전표면적에 대한 BET 표면적의 비가 3:1 이하인 방법.
  5. 제1항 내지 4항중의 어느 하나에 있어서, 탄소의 에지 표면적에 대한 전표면적의 비가 적어도 30:1인 방법.
  6. 제1항 내지 5항중 어느 하나에 있어서, 탄소상에 팔라듐 할라이드를 침적시키고, 팔라듐 할라이드를 수소로 환원시켜 할라이드를 제거한 후에 촉진제의 염을 침적시켜 촉매를 제조하는 방법.
  7. 제1항 내지 6항중의 어느 하나에 있어서, 팔라듐 할라이드 및 촉진제염을 각각 별개의 수용액으로 침적시키는 방법.
  8. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830003799A 1982-08-14 1983-08-13 메탄올의 촉매적 제조방법 KR840005999A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8223453 1982-08-14
GB8223453 1982-08-14

Publications (1)

Publication Number Publication Date
KR840005999A true KR840005999A (ko) 1984-11-21

Family

ID=10532315

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019830003799A KR840005999A (ko) 1982-08-14 1983-08-13 메탄올의 촉매적 제조방법

Country Status (16)

Country Link
US (1) US4476250A (ko)
EP (1) EP0101645B1 (ko)
JP (1) JPS5948426A (ko)
KR (1) KR840005999A (ko)
AU (1) AU554395B2 (ko)
BR (1) BR8307482A (ko)
CA (1) CA1200561A (ko)
DD (1) DD216447A5 (ko)
DE (1) DE3361071D1 (ko)
DK (1) DK369583A (ko)
ES (1) ES524926A0 (ko)
GB (1) GB2125400B (ko)
NO (1) NO832891L (ko)
PL (1) PL243411A1 (ko)
WO (1) WO1984000749A1 (ko)
ZA (1) ZA835809B (ko)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8321255D0 (en) * 1983-08-06 1983-09-07 British Petroleum Co Plc Methanol conversion process
JPS60195079A (ja) * 1984-03-14 1985-10-03 日立化成工業株式会社 パワ−モジユ−ル基板及びその製造方法
FR2565126A1 (fr) * 1984-05-30 1985-12-06 Applic Catalytiques Ste Ly Nouvelle composition catalytique pour la combustion d'hydrocarbures et plus particulierement du methane
JPS61143332A (ja) * 1984-12-18 1986-07-01 Agency Of Ind Science & Technol 含酸素化合物の合成法
US5427762A (en) * 1987-05-27 1995-06-27 Hydrocarb Corporation Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol
ZA908290B (en) * 1989-10-20 1991-09-25 Hydrocarb Corp Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol
US8293186B2 (en) * 2004-07-29 2012-10-23 Gas Technologies Llc Method and apparatus for producing methanol
US7578981B2 (en) * 2004-07-29 2009-08-25 Gas Technologies Llc System for direct-oxygenation of alkane gases
US9180426B2 (en) * 2004-07-29 2015-11-10 Gas Technologies, Llc Scrubber for methanol production system
US7456327B2 (en) 2004-07-29 2008-11-25 Gas Technologies, Llc Method for direct-oxygenation of alkane gases
US8202916B2 (en) * 2004-07-29 2012-06-19 Gas Technologies Llc Method of and apparatus for producing methanol
US7642293B2 (en) * 2004-07-29 2010-01-05 Gas Technologies Llc Method and apparatus for producing methanol with hydrocarbon recycling
US7910787B2 (en) * 2004-07-29 2011-03-22 Gas Technologies Llc Method and system for methanol production
US7687669B2 (en) 2005-12-27 2010-03-30 Gas Technologies Llc Method for direct-oxygenation of alkane gases
US7879296B2 (en) * 2005-12-27 2011-02-01 Gas Technologies Llc Tandem reactor system having an injectively-mixed backmixing reaction chamber, tubular-reactor, and axially movable interface
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
JP5662044B2 (ja) * 2010-03-31 2015-01-28 大阪瓦斯株式会社 触媒の活性化の程度を判定する方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1397293A (en) * 1972-09-01 1975-06-11 British Petroleum Co Platinum group metal catalysts and their use
FR2282940A1 (fr) * 1974-09-02 1976-03-26 British Petroleum Co Catalyseur d'un metal du groupe du platine et son support
BE849121A (fr) * 1975-12-08 1977-06-07 Formation selective d'hydrocarbures oxygenes avec un catalyseur au palladium
IT1085879B (it) * 1976-04-08 1985-05-28 Basf Ag Processo per la preparazione di chetoni superiori
US4289710A (en) * 1979-12-19 1981-09-15 Union Carbide Corporation Process for producing methanol from synthesis gas with palladium-calcium catalysts
US4289709A (en) * 1979-12-19 1981-09-15 Union Carbide Corporation Preparation of methanol from synthesis gas with promoted palladium catalysts

Also Published As

Publication number Publication date
EP0101645A1 (en) 1984-02-29
NO832891L (no) 1984-02-15
BR8307482A (pt) 1984-08-14
CA1200561A (en) 1986-02-11
GB8321678D0 (en) 1983-09-14
WO1984000749A1 (en) 1984-03-01
ES8600185A1 (es) 1985-10-01
PL243411A1 (en) 1984-07-30
US4476250A (en) 1984-10-09
ES524926A0 (es) 1985-10-01
GB2125400B (en) 1986-03-19
JPS5948426A (ja) 1984-03-19
DK369583D0 (da) 1983-08-12
AU554395B2 (en) 1986-08-21
EP0101645B1 (en) 1985-10-23
DK369583A (da) 1984-02-15
ZA835809B (en) 1985-03-27
AU1767083A (en) 1984-02-16
DD216447A5 (de) 1984-12-12
GB2125400A (en) 1984-03-07
DE3361071D1 (en) 1985-11-28

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