KR840002863A - 폴리에스테르화 촉매 - Google Patents
폴리에스테르화 촉매 Download PDFInfo
- Publication number
- KR840002863A KR840002863A KR1019820005905A KR820005905A KR840002863A KR 840002863 A KR840002863 A KR 840002863A KR 1019820005905 A KR1019820005905 A KR 1019820005905A KR 820005905 A KR820005905 A KR 820005905A KR 840002863 A KR840002863 A KR 840002863A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- polyesterification
- methyl
- general formula
- titanate
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 26
- 150000001875 compounds Chemical class 0.000 claims 12
- -1 alkoxy halide Chemical class 0.000 claims 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 8
- 150000004696 coordination complex Chemical group 0.000 claims 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 8
- 229920001296 polysiloxane Polymers 0.000 claims 8
- PVNWCKSAAXYUJO-UHFFFAOYSA-N 1-di(propan-2-yloxy)phosphorylethoxy-ethoxy-ethyl-methylsilane Chemical compound CCO[Si](C)(CC)OC(C)P(=O)(OC(C)C)OC(C)C PVNWCKSAAXYUJO-UHFFFAOYSA-N 0.000 claims 4
- PIECLKBCTBUCRF-UHFFFAOYSA-N 1-dimethoxyphosphorylethoxy-ethoxy-ethyl-methylsilane Chemical compound CCO[Si](C)(CC)OC(C)P(=O)(OC)OC PIECLKBCTBUCRF-UHFFFAOYSA-N 0.000 claims 3
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 3
- 125000003963 dichloro group Chemical group Cl* 0.000 claims 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 3
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 claims 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 229910052787 antimony Inorganic materials 0.000 claims 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 229920000728 polyester Polymers 0.000 claims 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims 1
- YTFPDXBJFXUWDT-UHFFFAOYSA-N 1-diethoxyphosphorylethoxy-ethoxy-ethyl-methylsilane Chemical compound C(C)OP(=O)(OCC)C(C)O[Si](OCC)(C)CC YTFPDXBJFXUWDT-UHFFFAOYSA-N 0.000 claims 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 claims 1
- DVNPFNZTPMWRAX-UHFFFAOYSA-N 2-triethoxysilylethanethiol Chemical compound CCO[Si](CCS)(OCC)OCC DVNPFNZTPMWRAX-UHFFFAOYSA-N 0.000 claims 1
- GBQYMXVQHATSCC-UHFFFAOYSA-N 3-triethoxysilylpropanenitrile Chemical compound CCO[Si](OCC)(OCC)CCC#N GBQYMXVQHATSCC-UHFFFAOYSA-N 0.000 claims 1
- 229920001634 Copolyester Polymers 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- 125000001188 haloalkyl group Chemical group 0.000 claims 1
- 229910052736 halogen Chemical group 0.000 claims 1
- 150000002367 halogens Chemical group 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000003377 silicon compounds Chemical class 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/87—Non-metals or inter-compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Polyesters Or Polycarbonates (AREA)
- Artificial Filaments (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (17)
- 일반식(Ⅴ)의 금속알콕시 할라이드(A)와 일반식(Ⅰ),(Ⅱ),(Ⅲ) 또는 (Ⅳ)에서 선택한 실리콘 화합물(B)가 2:1 내지 1:10의 몰비인 배위착물로 이루어짐을 특징으로 하는 디카르복실산 화합물과 지방족글리콜과의 고형 섬유 형성 폴리에스테르 또는 코폴리에스테르 제조용 폴리에스테르 촉매상기에서, M은 티티늄, 아연, 게르마늄, 주석, 납 및 안티몬 중의 적어도 하나이고; R은 일반식(Ⅴ)에서는 1내지 20의 탄소원자를 갖는 알킬, 아릴, 알킬아릴, 및 할로겐이고, 일반식(Ⅰ)에서는 메틸, 에틸, 부틸, 메톡시, 에톡시, 부톡시 또는 트리메틸실록시이며; a 및 b 1 내지 3의 값을 갖는 정수이고;(a+b)의 합은 정수 4이하이고[단 M이 안티몬이면 a는 1 내지 4의 값을 갖는 정수이고 (a+b)의 합은 5이하이며];일반식(Ⅴ)에서 X는, F, Cl, Br 또는 I중의 하나이고, W는 CH2=CX- 또는이고; 이때 R*는 1 내지 4의 탄소원자를 갖는 알킬 또는 할로알킬이고 X는 수소 또는 메틸(단 m이 1일 때는 메틸)이며;R**는 메틸, 에틸, 부틸, 아세톡시, 메톡시, 에톡시 또는 부톡시이고;R'은 메틸, 메톡시, 에톡시, 부톡시, 또는 트리메틸실록시이고; R"는 메톡시, 에톡시, 부톡시, 트리메틸실록시 또는 비닐 디메틸실록시이고; R"'는 메틸, 에틸, 부틸 또는 트리메틸시릴이고; Me는 메틸이고; Z는 메틸 또는 W이고; Q는 NCCH2-, NH2CH2NHCH2-, NC-, HS- 또는 H.SCH2CH2S-그룹이고;n 은 2 내지 5의 값을 갖는 정수이고; m은 0 또는 1의 값을 갖는 정수이고; 일반식(Ⅲ)에서 x는 1내지 100의 값을 갖는 정수이며; 그리고 y는 1 내지 100의 값을 갖는 정수이다.
- 제1항에 있어서, 실리콘 화합물(B)이 다음 일반식의 화합물의 폴리에스테르화 촉매.상기 일반식에서 W, R, R', R", n 및 m은 상기과 같다.
- 제1항에 있어서, 실리콘 화합물(B)이 다음 일반식의 화합물인 폴리에스테르화 촉매상기 일반식에서 Me, W 및 Z는 상기와 같다.
- 제1항에 있어서, 실리콘 화합물(B)이 다음 일반식의 화합물인 폴리에스테르화 촉매상기 일반식에서 Me, W, R"', x 및 y는 상기와 같다.
- 제1항에 있어서, 실리콘 화합물(B)이 다음 일반식의 화합물인 폴리에스테르화 촉매상기 일반식에서 Q 및 R**는 상기와 같다.
- 제1항에 있어서, 실리콘 화합물(B)이 디에톡시 포스포릴 에틸 메틸 디에톡시실란인 폴리에스테르화 촉매.
- 제1항에 있어서, 실리콘 화합물(B)이 3-아미노프로필트리에톡시실란인 폴리에스테르화 촉매.
- 제1항에 있어서, 실리콘 화합물(B)이 2-시아노에틸트리에톡시실란인 폴리에스테르화 촉매.
- 제1항에 있어서, 실리콘 화합물(B)이 2-메르캅토에틸트리에톡시실란인 폴리에스테르화 촉매.
- 제1항에 있어서, 촉매가 모노브로모 트리(이소-프로폭시)티탄산염과 디(이소프로폭시)포스포릴 에틸 메틸 디에톡시 실란의 배위 착물인 폴리에스테르화 촉매.
- 제1항에 있어서, 촉매가 모노클로로트리(이소프로폭시)티탄산염과 디(이소프로폭시)포스포릴 에틸 메틸 디에톡시 실란의 배위 착물인 폴리에스테르화 촉매.
- 제1항에 있어서, 촉매가 디클로로(디이소프로필)티탄산염과 디(이소프로폭시)포스포릴 에틸 메틸 디에톡시 실란의 배위 착물인 폴리에스테르화 촉매.
- 제1항에 있어서, 촉매가 모노클로로트리(부톡시)티탄산염과 디(메톡시)포스포릴 에틸 메틸 디에톡시 실란의 배위 착물인 폴리에스테르화 촉매.
- 제1항에 있어서, 촉매가 모노브로모트리(부톡시)티탄산염과 디(메톡시)포스포릴 에틸 메틸 디에톡시 실란의 배위 착물인 폴리에스테르화 촉매.
- 제1항에 있어서, 촉매가 디클로로 디이소프로폭시 티탄산염과 디(이소프로폭시)포스포릴 에틸 메틸 디에톡시 실란의 배위 착물인 폴리에스테르화 촉매.
- 제1항에 있어서, 촉매가 디클로로부톡시 티탄산염과 디(이소프로폭시)포스포릴-에틸 메틸 디(에톡실란)의 배위 착물인 폴리에스테르화 촉매.
- 제1항에 있어서, 촉매가 디클로로 디(이소프로폭시) 티탄산염과 디(메톡시)포스포릴 에틸 메틸 디에톡시실란의 배위 착물인 폴리에스테르화 촉매.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US336,293 | 1981-12-31 | ||
| US06/336,293 US4394295A (en) | 1981-12-31 | 1981-12-31 | Coordination complexes as polyesterification catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR840002863A true KR840002863A (ko) | 1984-07-21 |
Family
ID=23315439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019820005905A KR840002863A (ko) | 1981-12-31 | 1982-12-31 | 폴리에스테르화 촉매 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4394295A (ko) |
| EP (1) | EP0085192B1 (ko) |
| JP (1) | JPS58120633A (ko) |
| KR (1) | KR840002863A (ko) |
| BR (1) | BR8207507A (ko) |
| CA (1) | CA1190554A (ko) |
| DD (1) | DD210289A5 (ko) |
| DE (1) | DE3272644D1 (ko) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999019379A1 (fr) * | 1997-10-15 | 1999-04-22 | Daicel Chemical Industries, Ltd. | Procedes de preparation de polymeres monodisperses, procedes de polymerisation en continu de monomeres cycliques et polymeres obtenus par ces procedes |
| US6346070B1 (en) | 1998-12-25 | 2002-02-12 | Mitsui Chemicals Inc | Catalyst for polyester production, process for producing polyester using the catalyst, polyester obtained by the process, and uses of the polyester |
| KR101026097B1 (ko) | 2003-06-03 | 2011-03-31 | 미쓰비시 가가꾸 가부시키가이샤 | 폴리에스테르 제조용 촉매, 이를 이용한 폴리에스테르의제조 방법, 및 티탄 함유 폴리에틸렌 테레프탈레이트 |
| JP4855161B2 (ja) * | 2006-07-13 | 2012-01-18 | 富士電機株式会社 | 変成器 |
| GB0720579D0 (en) * | 2007-10-20 | 2007-11-28 | Phosphonics Ltd | Functionalised materials and uses thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD85443A (ko) * | ||||
| NL6606830A (ko) * | 1965-05-19 | 1966-11-21 | ||
| US3852247A (en) * | 1970-11-02 | 1974-12-03 | Fiber Industries Inc | Polymerization catalyst |
| US4143057A (en) * | 1977-02-28 | 1979-03-06 | Union Carbide Corporation | Coordination complexes as catalysts |
| US4254241A (en) * | 1979-12-12 | 1981-03-03 | Union Carbide Corporation | Process for producing polyoxyalkylene glycol modified polyesters |
-
1981
- 1981-12-31 US US06/336,293 patent/US4394295A/en not_active Expired - Fee Related
-
1982
- 1982-12-02 CA CA000416854A patent/CA1190554A/en not_active Expired
- 1982-12-27 BR BR8207507A patent/BR8207507A/pt unknown
- 1982-12-30 DD DD82246831A patent/DD210289A5/de unknown
- 1982-12-31 DE DE8282112128T patent/DE3272644D1/de not_active Expired
- 1982-12-31 KR KR1019820005905A patent/KR840002863A/ko unknown
- 1982-12-31 EP EP82112128A patent/EP0085192B1/en not_active Expired
- 1982-12-31 JP JP57235073A patent/JPS58120633A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US4394295A (en) | 1983-07-19 |
| BR8207507A (pt) | 1983-10-18 |
| EP0085192A1 (en) | 1983-08-10 |
| EP0085192B1 (en) | 1986-08-13 |
| JPS58120633A (ja) | 1983-07-18 |
| CA1190554A (en) | 1985-07-16 |
| DE3272644D1 (en) | 1986-09-18 |
| DD210289A5 (de) | 1984-06-06 |
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