KR840001185A - Method for preparing cation exchange resin - Google Patents

Method for preparing cation exchange resin Download PDF

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Publication number
KR840001185A
KR840001185A KR1019820003757A KR820003757A KR840001185A KR 840001185 A KR840001185 A KR 840001185A KR 1019820003757 A KR1019820003757 A KR 1019820003757A KR 820003757 A KR820003757 A KR 820003757A KR 840001185 A KR840001185 A KR 840001185A
Authority
KR
South Korea
Prior art keywords
styrene
exchange resin
cation exchange
sulfonation reaction
divinylbenzene
Prior art date
Application number
KR1019820003757A
Other languages
Korean (ko)
Other versions
KR890001758B1 (en
Inventor
요시하루 미사까 (외 4)
Original Assignee
쓰쯔끼 에이지
미쯔비시 가세이 고교 가부시끼 가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP56131356A external-priority patent/JPS6050361B2/en
Priority claimed from JP57070652A external-priority patent/JPS58187405A/en
Application filed by 쓰쯔끼 에이지, 미쯔비시 가세이 고교 가부시끼 가이샤 filed Critical 쓰쯔끼 에이지
Publication of KR840001185A publication Critical patent/KR840001185A/en
Application granted granted Critical
Publication of KR890001758B1 publication Critical patent/KR890001758B1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16—Organic material
    • B01J39/18—Macromolecular compounds
    • B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages

Abstract

내용 없음No content

Description

양이온 교환수지의 제조방법Method for preparing cation exchange resin

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (9)

(1( 스티렌, (2) 디비닐벤젠 및 (3) 아크릴산, 메타크릴산 및 이들의 저급알킬 에스테르의 군으로부터 선택된 1개이상의 화합물로 이루어진 단량체 혼합물을 현탁중합시키고, 또 수득된 공중합체 입자를 설폰화반응시킴을 특징으로 하여, 양이온 교환수지를 제조하는 방법.(1) Suspending polymerizing a monomer mixture consisting of at least one compound selected from the group consisting of (1 (styrene, (2) divinylbenzene and (3) acrylic acid, methacrylic acid and lower alkyl esters thereof), Method for producing a cation exchange resin, characterized in that the sulfonation reaction. 제1항에 있어서, 단량체(3)의 양이 스티렌 1몰당 2내지 20몰%인 방법.The process according to claim 1, wherein the amount of monomer (3) is 2 to 20 mol% per mol of styrene. 제1항에 있어서, 디비닐벤젠의 양이 스티렌 1몰당 0.8 내지 55몰%인 방법.The process according to claim 1, wherein the amount of divinylbenzene is 0.8 to 55 mol% per mol of styrene. 제1항에 있어서, 공중합체 입자가 0.1 내지 1.Omm의 입자직경을 갖는 방법.The method of claim 1 wherein the copolymer particles have a particle diameter of 0.1 to 1.0 mm. 제1항에 있어서, 95 내지 100% 황산을 사용하여 설폰화반응을 진행시키는 방법.The process of claim 1 wherein the sulfonation reaction is carried out using 95-100% sulfuric acid. (1) 스티렌, (2) 디비닐벤젠 및 (3) 아크릴산, 메타크릴산 및 이들의저급알킬에스테르의 군으로부터 선택된 1개이상의 화합물로 이루어진 단량체 혼합물을 현탁중합 시키고 또 수득된 공중합체 입자를, 유기용매로 구성된 팽윤제가 없는 상태에서 설폰화반응 시킴을 특징으로 하여, 양이온교환 수지를 제조하는 방법.(1) suspension polymerization of a monomer mixture consisting of styrene, (2) divinylbenzene and (3) at least one compound selected from the group of acrylic acid, methacrylic acid and lower alkyl esters thereof, A method for producing a cation exchange resin, characterized in that a sulfonation reaction is carried out in the absence of a swelling agent composed of an organic solvent. 제6항에 있어서, 설폰화반응 온도가 50 내지 150℃인 방법.The method according to claim 6, wherein the sulfonation reaction temperature is 50 to 150 ° C. (1) 스티렌, (2) 디비닐벤젠 및 (3) 아크릴산, 메타크릴산 및 이들의 저급알킬에스테르 군으로부터 선택된 1개이상의 화합물로 이루어진 단량체 혼합물을 현탁 중합시키고, 또 수득된 공중합체 입자를 유기용매로 구성된 팽윤제 존제하에서 약 50 내지 100℃로 설폰화반응시킴을 특징으로 하여 양이온 교환수지를 제조하는 방법.Suspension polymerization of the monomer mixture consisting of (1) styrene, (2) divinylbenzene and (3) at least one compound selected from acrylic acid, methacrylic acid and lower alkyl esters thereof, and the obtained copolymer particles A method for producing a cation exchange resin, characterized in that the sulfonation reaction at about 50 to 100 ℃ in the presence of a swelling agent consisting of a solvent. 제8항에 있어서, 팽윤제가 방향족 탄화수소, 방향족 할로겐화 탄화수소와 지방족 할로겐화 탄화수소의 군에서 선택된 1개이상의 유기용매인 방법.The method of claim 8, wherein the swelling agent is at least one organic solvent selected from the group of aromatic hydrocarbons, aromatic halogenated hydrocarbons and aliphatic halogenated hydrocarbons. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR8203757A 1981-08-21 1982-08-21 Process for producing cation exchange resin KR890001758B1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP13156 1981-08-21
JP131356/81 1981-08-21
JP56131356A JPS6050361B2 (en) 1981-08-21 1981-08-21 Manufacturing method of cation exchange resin
JP70652 1982-04-27
JP57070652A JPS58187405A (en) 1982-04-27 1982-04-27 Production of strongly acidic cation-exchanging resin

Publications (2)

Publication Number Publication Date
KR840001185A true KR840001185A (en) 1984-03-28
KR890001758B1 KR890001758B1 (en) 1989-05-19

Family

ID=26411786

Family Applications (1)

Application Number Title Priority Date Filing Date
KR8203757A KR890001758B1 (en) 1981-08-21 1982-08-21 Process for producing cation exchange resin

Country Status (5)

Country Link
KR (1) KR890001758B1 (en)
DE (1) DE3230559A1 (en)
FR (1) FR2511614B1 (en)
GB (1) GB2105346B (en)
NL (1) NL8203274A (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2587708B1 (en) * 1985-09-20 1988-03-18 Ceca Sa COPOLYMERS OF STYRENE SULFONIC ACIDS WITH IMPROVED THERMAL STABILITY. APPLICATION, PARTICULARLY TO DRILLING FLUIDS
CA2061250A1 (en) * 1991-02-20 1992-08-21 Nobuyuki Higosaki Process of removing suspended metal corrosion products insoluble or sparingly soluble in water and condensate treating equipment
US6784213B2 (en) * 2001-06-22 2004-08-31 Rohm And Haas Company Method for preparation of strong acid cation exchange resins
DE10353534A1 (en) * 2003-11-14 2005-06-16 Bayer Chemicals Ag chelate
DE102007060790A1 (en) 2007-12-18 2009-06-25 Lanxess Deutschland Gmbh Process for the preparation of cation exchangers
KR101294632B1 (en) * 2011-04-28 2013-08-09 충남대학교산학협력단 Ion exchange resin for recovery cobalt ion with good swelling and adsorption and Method for preparing the same
KR101294631B1 (en) * 2011-04-28 2013-08-09 충남대학교산학협력단 Ion exchange resin for recovering Indium with good swelling and adsorption and Method for preparing the same
CN108623733A (en) * 2017-03-24 2018-10-09 鹤壁市山城区牟山大道大唐离子交换树脂应用研究所 Resin intermediate containing Third monomer

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1068153A (en) * 1951-11-28 1954-06-23 Rohm & Haas Improvements relating to an insoluble cation exchange resin and its preparation process
DE1155603B (en) * 1961-10-26 1963-10-10 Wolfen Filmfab Veb Process for the production of cation exchange resins containing sulfonic acid groups

Also Published As

Publication number Publication date
NL8203274A (en) 1983-03-16
KR890001758B1 (en) 1989-05-19
GB2105346A (en) 1983-03-23
FR2511614B1 (en) 1987-05-07
DE3230559A1 (en) 1983-03-03
GB2105346B (en) 1985-01-03
FR2511614A1 (en) 1983-02-25

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