KR830008966A - 에탄올의 제조방법 - Google Patents
에탄올의 제조방법 Download PDFInfo
- Publication number
- KR830008966A KR830008966A KR1019820000007A KR820000007A KR830008966A KR 830008966 A KR830008966 A KR 830008966A KR 1019820000007 A KR1019820000007 A KR 1019820000007A KR 820000007 A KR820000007 A KR 820000007A KR 830008966 A KR830008966 A KR 830008966A
- Authority
- KR
- South Korea
- Prior art keywords
- cobalt
- manufacturing ethanol
- ethanol
- methanol
- absence
- Prior art date
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims 4
- 238000004519 manufacturing process Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- -1 cobalt (II) iodide cobalt (II) Chemical compound 0.000 claims 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 125000005496 phosphonium group Chemical group 0.000 claims 1
- 150000003304 ruthenium compounds Chemical class 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0239—Quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0255—Phosphorus containing compounds
- B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
- B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
- B01J31/30—Halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (1)
- 적어도 35바아의 압력과 적어도 150℃의 온도에서 불활성 액체인 산소화된 탄화수소 용매의 존재 또는 부존재하에 일산화탄소, 수소 및 메탄올의 혼합물을 (a) 루테늄 화합물, (b) 4자 포스포늄 또는 암모늄 염기 또는 염과 (c) 요오드화 코발트(II) 브롬화 코발트(II) 또는 염화 코발트(II)로 구성된 촉매계와 접촉시켜 에탄올을 제조하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US224199 | 1981-01-08 | ||
| US06/224,199 US4371724A (en) | 1981-01-08 | 1981-01-08 | Ethanol synthesis by homologation of methanol |
| US06/223,514 US4374285A (en) | 1981-01-08 | 1981-01-08 | Synthesis of ethanol by homologation of methanol |
| US223514 | 1998-12-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR830008966A true KR830008966A (ko) | 1983-12-16 |
Family
ID=26917866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019820000007A KR830008966A (ko) | 1981-01-08 | 1982-01-04 | 에탄올의 제조방법 |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0056679B1 (ko) |
| KR (1) | KR830008966A (ko) |
| AU (1) | AU547227B2 (ko) |
| BR (1) | BR8200053A (ko) |
| CA (1) | CA1184205A (ko) |
| DE (1) | DE3263044D1 (ko) |
| DK (1) | DK1482A (ko) |
| ES (1) | ES508572A0 (ko) |
| IN (1) | IN155699B (ko) |
| PL (1) | PL235002A1 (ko) |
| YU (1) | YU2682A (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3330507A1 (de) * | 1983-08-24 | 1985-03-07 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von ethanol |
| DE3728981A1 (de) * | 1987-08-29 | 1989-03-09 | Ruhrchemie Ag | Verfahren zur herstellung von ethanol im gemisch mit propanol und butanol |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE877598C (de) * | 1943-06-10 | 1953-05-26 | Basf Ag | Verfahren zur Herstellung von Alkoholen |
| US3248432A (en) * | 1961-12-12 | 1966-04-26 | Commercial Solvents Corp | Process for the production of ethyl alcohol |
| US4168391A (en) * | 1977-12-05 | 1979-09-18 | Celanese Corporation | Production of ethanol from methanol |
| JPS55145622A (en) * | 1979-05-02 | 1980-11-13 | Mitsubishi Gas Chem Co Inc | Preparation of ethanol |
| FR2458528A1 (fr) * | 1979-06-07 | 1981-01-02 | Rhone Poulenc Ind | Procede d'homologation du methanol |
| US4233466A (en) * | 1979-11-15 | 1980-11-11 | Union Carbide Corporation | Homologation process for the production of ethanol from methanol |
-
1982
- 1982-01-04 KR KR1019820000007A patent/KR830008966A/ko unknown
- 1982-01-04 DE DE8282300010T patent/DE3263044D1/de not_active Expired
- 1982-01-04 IN IN15/CAL/82A patent/IN155699B/en unknown
- 1982-01-04 EP EP19820300010 patent/EP0056679B1/en not_active Expired
- 1982-01-05 DK DK1482A patent/DK1482A/da not_active Application Discontinuation
- 1982-01-06 CA CA000393627A patent/CA1184205A/en not_active Expired
- 1982-01-07 BR BR8200053A patent/BR8200053A/pt unknown
- 1982-01-07 YU YU2682A patent/YU2682A/xx unknown
- 1982-01-07 AU AU79253/82A patent/AU547227B2/en not_active Ceased
- 1982-01-07 ES ES508572A patent/ES508572A0/es active Granted
- 1982-02-08 PL PL23500282A patent/PL235002A1/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES8300662A1 (es) | 1982-11-01 |
| BR8200053A (pt) | 1982-10-26 |
| IN155699B (ko) | 1985-02-23 |
| YU2682A (en) | 1984-12-31 |
| DK1482A (da) | 1982-07-09 |
| CA1184205A (en) | 1985-03-19 |
| PL235002A1 (ko) | 1982-09-13 |
| ES508572A0 (es) | 1982-11-01 |
| AU547227B2 (en) | 1985-10-10 |
| EP0056679A1 (en) | 1982-07-28 |
| DE3263044D1 (en) | 1985-05-23 |
| EP0056679B1 (en) | 1985-04-17 |
| AU7925382A (en) | 1982-07-15 |
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