ES8300662A1 - "un procedimiento para la preparacion de etanol". - Google Patents

"un procedimiento para la preparacion de etanol".

Info

Publication number
ES8300662A1
ES8300662A1 ES508572A ES508572A ES8300662A1 ES 8300662 A1 ES8300662 A1 ES 8300662A1 ES 508572 A ES508572 A ES 508572A ES 508572 A ES508572 A ES 508572A ES 8300662 A1 ES8300662 A1 ES 8300662A1
Authority
ES
Spain
Prior art keywords
methanol
ethanol
homologation
cobalt
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES508572A
Other languages
English (en)
Other versions
ES508572A0 (es
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Texaco Development Corp
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/224,199 external-priority patent/US4371724A/en
Priority claimed from US06/223,514 external-priority patent/US4374285A/en
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Publication of ES8300662A1 publication Critical patent/ES8300662A1/es
Publication of ES508572A0 publication Critical patent/ES508572A0/es
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/32—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions without formation of -OH groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0239—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PROCEDIMIENTO PARA LA OBTENCION DE ETANOL. CONSISTE EN LA REACCION DE UNA MEZCLA CONSTITUIDA POR MONOXIDO DE CARBONO, HIDROGENO Y METANOL EN CONTACTO CON UN CATALIZADOR QUE CONSTA DE UN COMPUESTO DE RUTENIO, UNA SAL O UNA BASE DE AMONIO O DE FOSFONIO CUATERNARIO Y YODURO, BROMURO O CLORURO DE COBALTO (II). LA REACCION SE LLEVA A CABO A UNA PRESION ENTRE 135 Y 700 BARES Y A UNA TEMPERATURA ENTRE 180 Y 250<025>C.
ES508572A 1981-01-08 1982-01-07 "un procedimiento para la preparacion de etanol". Granted ES508572A0 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/224,199 US4371724A (en) 1981-01-08 1981-01-08 Ethanol synthesis by homologation of methanol
US06/223,514 US4374285A (en) 1981-01-08 1981-01-08 Synthesis of ethanol by homologation of methanol

Publications (2)

Publication Number Publication Date
ES8300662A1 true ES8300662A1 (es) 1982-11-01
ES508572A0 ES508572A0 (es) 1982-11-01

Family

ID=26917866

Family Applications (1)

Application Number Title Priority Date Filing Date
ES508572A Granted ES508572A0 (es) 1981-01-08 1982-01-07 "un procedimiento para la preparacion de etanol".

Country Status (11)

Country Link
EP (1) EP0056679B1 (es)
KR (1) KR830008966A (es)
AU (1) AU547227B2 (es)
BR (1) BR8200053A (es)
CA (1) CA1184205A (es)
DE (1) DE3263044D1 (es)
DK (1) DK1482A (es)
ES (1) ES508572A0 (es)
IN (1) IN155699B (es)
PL (1) PL235002A1 (es)
YU (1) YU2682A (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3330507A1 (de) * 1983-08-24 1985-03-07 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von ethanol
DE3728981A1 (de) * 1987-08-29 1989-03-09 Ruhrchemie Ag Verfahren zur herstellung von ethanol im gemisch mit propanol und butanol

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE877598C (de) * 1943-06-10 1953-05-26 Basf Ag Verfahren zur Herstellung von Alkoholen
US3248432A (en) * 1961-12-12 1966-04-26 Commercial Solvents Corp Process for the production of ethyl alcohol
US4168391A (en) * 1977-12-05 1979-09-18 Celanese Corporation Production of ethanol from methanol
JPS55145622A (en) * 1979-05-02 1980-11-13 Mitsubishi Gas Chem Co Inc Preparation of ethanol
FR2458528A1 (fr) * 1979-06-07 1981-01-02 Rhone Poulenc Ind Procede d'homologation du methanol
US4233466A (en) * 1979-11-15 1980-11-11 Union Carbide Corporation Homologation process for the production of ethanol from methanol

Also Published As

Publication number Publication date
BR8200053A (pt) 1982-10-26
IN155699B (es) 1985-02-23
YU2682A (en) 1984-12-31
DK1482A (da) 1982-07-09
CA1184205A (en) 1985-03-19
PL235002A1 (es) 1982-09-13
ES508572A0 (es) 1982-11-01
AU547227B2 (en) 1985-10-10
EP0056679A1 (en) 1982-07-28
DE3263044D1 (en) 1985-05-23
EP0056679B1 (en) 1985-04-17
KR830008966A (ko) 1983-12-16
AU7925382A (en) 1982-07-15

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