GB1455781A - Production of carboxylic acids and esters - Google Patents

Production of carboxylic acids and esters

Info

Publication number
GB1455781A
GB1455781A GB67974A GB67974A GB1455781A GB 1455781 A GB1455781 A GB 1455781A GB 67974 A GB67974 A GB 67974A GB 67974 A GB67974 A GB 67974A GB 1455781 A GB1455781 A GB 1455781A
Authority
GB
United Kingdom
Prior art keywords
esters
cobalt
iodide
constituent
carboxylic acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB67974A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1455781A publication Critical patent/GB1455781A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1455781 Carboxylic acids and esters SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ BV 7 Jan 1974 [8 Jan 1973] 00679/74 Heading C2C Carboxylic acids and their esters are prepared by contacting an alcohol in the liquid phase with carbon monoxide at elevated temperature and pressure in the presence of a cobalt/iodide containing catalyst which also comprises a platinum containing promoter. Aliphatic alcohols preferably primary or secondary alkanols, and compounds such as ethers, halides and esters which revert to alcohol under the reaction conditions, are used. The cobalt constituent may be in the form of a salt, e.g. cobalt iodide, and the iodide constituent may be as free iodine or iodine compounds. The platinum constituent may be as an inorganic or organic compound or as a complex with a ligand, many of which are listed. Examples describe the preparation of methyl acetate and acetic acid from methanol using cobalt iodide and platinum compounds, e.g. chloroplatinic acid as catalysts. Ethyl propionate, octanoic acid and heptyl alcohol, and t-butyl pivalate are also prepared.
GB67974A 1973-01-08 1974-01-07 Production of carboxylic acids and esters Expired GB1455781A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US00321896A US3856856A (en) 1973-01-08 1973-01-08 Production of carboxylic acids and esters

Publications (1)

Publication Number Publication Date
GB1455781A true GB1455781A (en) 1976-11-17

Family

ID=23252506

Family Applications (1)

Application Number Title Priority Date Filing Date
GB67974A Expired GB1455781A (en) 1973-01-08 1974-01-07 Production of carboxylic acids and esters

Country Status (7)

Country Link
US (1) US3856856A (en)
JP (1) JPS5740129B2 (en)
DE (1) DE2400534C2 (en)
FR (1) FR2213255B1 (en)
GB (1) GB1455781A (en)
IT (1) IT1006771B (en)
NL (1) NL7400149A (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4559183A (en) * 1973-09-04 1985-12-17 The Halcon Sd Group, Inc. Preparation of carboxylic acid anhydrides
US4698187A (en) * 1973-09-04 1987-10-06 The Halcon Sd Group, Inc. Preparation of carboxylic acid anhydrides
US4115444A (en) * 1975-03-10 1978-09-19 Halcon International, Inc. Process for preparing carboxylic acid anhydrides
US4133963A (en) * 1975-11-19 1979-01-09 Eastman Kodak Company Process for the production of carboxylic acids
US4218340A (en) * 1975-11-19 1980-08-19 Eastman Kodak Company Nickel and cobalt containing carbonylation catalyst compositions for the production of carboxylic acids and their esters
US4356320A (en) * 1976-11-08 1982-10-26 The Halcon Sd Group, Inc. Preparation of carboxylic acids
US4913728A (en) * 1979-01-29 1990-04-03 Minnesota Mining And Manufacturing Company Substituted-4-alkylthioalkane-sulfonanilides and operatives
US4320230A (en) * 1979-09-24 1982-03-16 Exxon Research & Engineering Co. Methanol homologation using iron-cobalt carbonyl cluster catalyst
US4652677A (en) * 1980-03-10 1987-03-24 The Standard Oil Company Selective hydrocarboxylation of propylene to isobutyric acid
CA1195340A (en) * 1980-11-14 1985-10-15 The Standard Oil Company Selective hydrocarboxylation of propylene to isobutyric acid
US4484002A (en) * 1982-01-13 1984-11-20 Texaco Inc. Process for producing methyl acetate from methanol and carbon monoxide using a novel catalyst system
DE3323654A1 (en) * 1983-07-01 1985-01-03 Basf Ag, 6700 Ludwigshafen METHOD FOR PRODUCING ACETIC ACID AND METHYL ACETATE
US4990654A (en) * 1984-08-16 1991-02-05 Union Carbide Chemicals And Plastics Company Inc. Production of acetate esters from alcohols using rhodium complex catalysts
US4613623A (en) * 1985-07-23 1986-09-23 The United States Of America As Represented By The United States Department Of Energy Low temperature synthesis of methyl formate
US4939292A (en) * 1985-08-01 1990-07-03 Phillips Petroleum Company Synthesis of esters from alcohols containing carbon monoxide as an impurity
US6160163A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Method for the vapor-phase carbonylation of lower aliphatic alcohols using a supported platinum catalyst and halide promoter
US6159896A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Iridium catalyst for carbonylation of lower aliphatic alcohols

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2593440A (en) * 1948-04-22 1952-04-22 Eastman Kodak Co Manufacture of carboxyl compounds
GB713515A (en) * 1951-09-14 1954-08-11 Basf Ag Improvements in the production of carboxylic acid esters
CA1026355A (en) * 1972-04-12 1978-02-14 Hoechst Aktiengesellschaft PROCESS FOR THE MANUFACTURE OF VINYL ACETIC ACID AND OPTIONALLY OF .alpha.-BUTYROLACTONE

Also Published As

Publication number Publication date
NL7400149A (en) 1974-07-10
US3856856A (en) 1974-12-24
DE2400534A1 (en) 1974-07-11
DE2400534C2 (en) 1983-07-28
FR2213255B1 (en) 1978-06-16
IT1006771B (en) 1976-10-20
FR2213255A1 (en) 1974-08-02
JPS5740129B2 (en) 1982-08-25
JPS49100020A (en) 1974-09-20

Similar Documents

Publication Publication Date Title
GB1455781A (en) Production of carboxylic acids and esters
US4430506A (en) Hydrocarbonylation/carbonylation of alkyl carboxylates
RU94033107A (en) Process for preparing acetic acid, and catalyst system for preparing acetic acid
ID28416A (en) METHANOL CARBONILATION WITH THE EXISTENCE OF A RHODIUM, IRIDIUM OR IODIDE CATALYTIC SYSTEM
ES8700648A1 (en) Methanol carbonylation process.
GB1234641A (en)
GB1333449A (en) Process for the oxacylation of olefins in the gaseous phase
JPS5824415B2 (en) Ariel Sakusan no Seihou
US4431835A (en) Hydrocarbonylation/carbonylation of alkyl carboxylates
US4405815A (en) Process for the production of acetaldehyde and ethanol
GB1188777A (en) Process for the Manufacture of Carboxylic Acids and Unsaturated Esters of Carboxylic Acids
GB1344383A (en) Monomethyl and dimethyl terephthalate
GB1491377A (en) Preparation of esters
US4389532A (en) Process for the preparation of acetaldehyde
US4658053A (en) Production of esters
GB1430415A (en) Process for the manufacture of vinyl acetic acid and optionally of ypsilon-butyrolactone
GB1461924A (en) Process for the manufacture of unsaturated esters of carboxylic acids
JPS5917101B2 (en) Manufacturing method of adipic acid diester
GB1215210A (en) Preparation of unsaturated esters
CN106187730A (en) A kind of 4 propioloyl benzaldehydes and preparation method thereof
GB1217468A (en) Ester mixtures
US4355173A (en) Process for the preparation of alkyl carboxylate
US4060690A (en) Method of preparing arylacetic acid alkyl esters
US2734913A (en) Production of carboxylic acid esters by
EP0098689A1 (en) Process for the production of monocarboxylic acid anhydrides

Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee